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At least 91 records · Page 5

Using CFD Techniques to Predict Slosh Force Frequency and Damping Rate

Resonant effects and energy dissipation due to sloshing fuel inside propellant tanks are problems that arise in the initial design of any spacecraft or launch vehicle. A faster and more reliable method for calculating these effects during the design stages is needed. Using Computational Fluid Dynamics (CFD) techniques, a model of these fuel tanks can be created and used to predict important parameters such as resonant slosh frequency and damping rate. This initial study addresses the case of free surface slosh. Future studies will focus on creating models for tanks fitted with propellant management devices (PMD) such as diaphragms and baffles.

Marsell, Brandon

Analytical and numerical investigation of structural response of compliant wall materials

Theoretical analysis of an electrostatically driven wall system for a compliant wall drag reduction program is reported. The electrostatic wall system is capable of producing deflections of many orders greater than the thicknesses and at small wavelengths. An intermediate large response theory was used for structural analysis. The theoretical predictions were compared to bench test results, and good agreement between the two was obtained. The effects of aerodynamic loads and perturbation electric fields on the theoretical solutions were considered. It was shown that for very small wavelengths (approximately 2mm) the aerodynamic effects can be estimated using potential theory without loss of accuracy, and the perturbation electric fields do not affect solutions as long as the deflections are less than one percent of the wavelength. Resonance effects for this type of structure were shown to be fairly small.

Goglia, G. L.

Amidination of ligands for chemical and field-effect passivation stabilizes perovskite solar cells

Surface passivation has driven the rapid increase in the power conversion efficiency (PCE) of perovskite solar cells (PSCs). However, state-of-the-art surface passivation techniques rely on ammonium ligands that suffer deprotonation under light and thermal stress. We developed a library of amidinium ligands, of interest for their resonance effect–enhanced N–H bonds that may resist deprotonation, to increase the thermal stability of passivation layers on perovskite surfaces. This strategy resulted in a >10-fold reduction in the ligand deprotonation equilibrium constant and a twofold increase in the maintenance of photoluminescence quantum yield after aging at 85°C under illumination in air. Here, implementing this approach, we achieved a certified quasi–steady-state PCE of 26.3% for inverted PSCs; and we report retention of ≥90% PCE after 1100 hours of continuous 1-sun maximum power point operation at 85°C.

Yang, Yi

Vibrational Fermi Resonance in Atomically Thin Black Phosphorus

Fermi resonance is a phenomenon involving the hybridization of two coincidentally quasi-degenerate states that is observed in the vibrational or electronic spectra of molecules. Despite numerous examples in molecular systems, vibrational Fermi resonances in dispersive semiconducting systems remain largely unexplored due to the rarity of occurrence. Here we report a vibrational Fermi resonance in atomically thin black phosphorus. The Fermi resonance arises via anharmonic mixing of a fundamental Raman mode and a Davydov component of an infrared mode, leading to a doublet with mixed character. The extent of Fermi coupling can be modulated by the application of external biaxial strain. The consequences of Fermi hybridization are revealed by electronic resonance effects in the thickness-dependent and excitation-wavelength-dependent Raman spectrum, which is predicted by ab initio hybrid functional simulations including excitonic interactions. This work reveals new insight into electron–phonon coupling in black phosphorus and demonstrates a novel method for modulating Fermi resonances in 2D semiconductors.

74 ATOMIC AND MOLECULAR PHYSICS

Effect of activation temperature on quantum efficiency and lifetime of NEA truncated nanocone array GaAs photocathode

This study investigates the quantum efficiency (QE) and operational lifetime of a negative electron affinity GaAs truncated nanocone array (TNCA) photocathode benchmarked against a conventional flat GaAs photocathode under varying activation temperatures. The TNCA structure demonstrated a QE of up to 13.6% at 590 nm with room temperature (RT) activation—approximately 1.5 times higher than its flat counterpart. This enhancement is due to Mie resonance effects within the nanostructure, as confirmed by finite-difference time-domain simulations. Moreover, the TNCA photocathode exhibits significantly extended charge lifetime, with enhancement factors of ∼6.1 and ∼19.8 under RT and 50 °C activations, respectively. These gains are primarily attributed to increased effective surface area and optimized dipole layer formation at elevated temperatures. In addition, shorter excitation wavelengths further contribute to lifetime improvements. These findings underscore the TNCA GaAs photocathode’s potential as a high QE, long lifetime electron source for many large-scale electron accelerators.

Cs-NF3 activation

Mars physical parameters as determined from Mariner 9 observations of the natural satellites and Doppler tracking

Mariner 9 Doppler tracking data and television photographs of Deimos and Phobos were analyzed to determine the gravity field, mass, and spin-axis direction of Mars and the natural satellite orbits. The solutions agree with previously published results. Radio data consisted of an apoapsis state vector for each of revolutions 5-195 obtained from one-revolution fits of Doppler data. Optical data consisted of TV photographs of Phobos and Deimos taken between revolutions 25 and 221. A first-order analytical theory, extended to include dominant second-order resonance effects on the Mariner 9 orbit, was used to calculate the motion of the spacecraft, Deimos, and Phobos. The feasibility of combining radio and optical data in long-arc solutions for accurate determination of orbits and physical parameters is demonstrated. The analytical theory developed for the evolution of a highly eccentric orbit in shallow resonance is accurate to plus or minus 1 km in the apoapsis state vector of Mariner 9 over a period of 200 revolutions.

Born, G. H.

Bridge Connectivity Dictates Spin Interactions and Triplet Pair Dynamics in Intramolecular Singlet Fission

Electron spin plays a critical role in determining the structure, dynamics, and reactivities of molecular excited states, including multiexciton processes such as singlet fission. These systems exhibit triplet pair states whose excited state dynamics can be widely tuned through molecular engineering. For example, the electronic coupling between covalently linked chromophores can be readily modulated using chemical bridges to control proximity, quantum interference, or resonance effects. However, less is known about how spin coupling interactions are impacted by chromophore architecture, and how this influences triplet pair recombination dynamics. Here, in this study, we investigate the role of bridge connectivity and chromophore identity in modulating interchromophore exchange and dipolar coupling interactions for a series of pentacene and tetracene dimers bridged by alternant hydrocarbons (phenylene, naphthalene, anthracene). Using both time-resolved electron paramagnetic resonance and transient absorption spectroscopy, we find that the boundedness and recombination pathways of the triplet pair spins are highly sensitive to molecular architecture and chromophore-specific magnetic dipolar interactions. Notably, nominally ferromagnetic and antiferromagnetic eigenstates result in distinct spin state orderings, consistent with predictions from quantum interference-based graphical models. These findings establish new design principles for tuning spin dynamics in iSF materials, with implications for photonic and quantum information applications.

He, Guiying [City Univ. of New York (CUNY), NY (Un

The electromagnetic radiation from simple sources in the presence of a homogeneous dielectric sphere

In this research, the effect of a homogeneous dielectric sphere on the electromagnetic radiation from simple sources is treated as a boundary value problem, and the solution is obtained by the technique of dyadic Green's functions. Exact representations of the electric fields in the various regions due to a source located inside, outside, or on the surface of a dielectric sphere are formulated. Particular attention is given to the effect of sphere size, source location, dielectric constant, and dielectric loss on the radiation patterns and directivity of small spheres (less than 5 wavelengths in diameter) using the Huygens' source excitation. The computed results are found to closely agree with those measured for waveguide-excited plexiglas spheres. Radiation patterns for an extended Huygens' source and for curved electric dipoles located on the sphere's surface are also presented. The resonance phenomenon associated with the dielectric sphere is studied in terms of the modal representation of the radiated fields. It is found that when the sphere is excited at certain frequencies, much of the energy is radiated into the sidelobes. The addition of a moderate amount of dielectric loss, however, quickly attenuates this resonance effect. A computer program which may be used to calculate the directivity and radiation pattern of a Huygens' source located inside or on the surface of a lossy dielectric sphere is listed.

Mason, V. B.

Theoretical study of refraction effects on noise produced by turbulent jets

The transmission of acoustic disturbances from the interior of a jet into the ambient air is studied. The jet is assumed infinitely long with mean velocity profile independent of streamwise location. The noise generator is a sequence of transient sources drifting with the local fluid and confined to a short length of the jet. In Part 1, supersonic jets are considered. Numerical results for mean-square pressure versus angle in the far-field show unexpected peaks which are very sharp. Analysis of simplified models indicates that these are complex quasi-resonant effects which appear to the stationary observer in a high frequency range. The peaks are real for the idealized model, but would be smoothed by mathematical integration over source position, velocity, and frequency. Subsonic jets were considered in part 2, and a preliminary study of the near-field was attempted. Mean-square radial displacements (or mean radial energy flow or space-time correlations of radial pressure gradient) are first found for very simple cases. The most difficult case studied is a sequence of transient sources at the center of a uniform-velocity circular cylindrical jet. Here a numerical triple integration is required and seems feasible although only preliminary results for mean square radial displacement are now available. These preliminary results show disturbances decreasing with increasing radial distance, and with increasing distance upstream and downstream from the source. A trend towards greater downstream disturbances appears even in the near field.

Graham, E. W.

The dynamics of global positioning system orbits and the determination of precise ephemerides

The suggestion made on the basis of the analytical orbit perturbation theory that the errors in the ephemerides of the GPS satellites are due mostly to resonant effects that can be corrected by adjusting a few parameters in a empirical acceleration formula is tested using simulations and actual data analysis. Data from the Spring 1985 Experiment were used to calculate improved ephemerides, and these ephemerides were used in the estimation of the coordinates of GPS stations within the continental United States, previously positioned with VLBI. The results of this test support the idea that the errors are mostly of a resonant nature and can be corrected.

Colombo, Oscar L.

Some tunnel-wall effects on transonic flutter

Significant effects of wind-tunnel walls were observed on the transonic flutter boundaries of wall-mounted models during two flutter model research studies. In these studies, flutter experiments with cantilevered SST-type wing models were conducted in three different wind tunnels. The experimental results are compared to flutter boundaries calculated for the models in free air. The results indicate that transonic flutter boundaries can be affected by tunnel-wall interference, tunnel resonances, and shock-wave reflections, and that flutter model data accuracy is a function of model/tunnel size and tunnel wall porosity. However, models within the recommended size limits should give accurate results in transonic tunnels with normal ventilation. A flutter trend analysis for a two-dimensional wing-demonstrating tunnel wall and resonance effects on flutter are also presented.

Ruhlin, C. L.

O-Mode Instability for Non-Thermal Continuum Radiation Generated Near the Plasmapause

Analysis of the ordinary mode (O-mode) instability is performed to comprehend the nonthermal continuum (NTC) radiation near the plasmapause, taking into account the relativistic wave-electron resonance effect. The energy source is the anisotropy in the velocity of the minority suprathermal electron population. Numerical solutions demonstrate that the O-mode can be unstable with multiple narrow frequency bands located close to harmonics of the electron cyclotron frequency above the local electron plasma frequency. These waves have narrow beaming angle bands of nearly 90° relative to the ambient magnetic field. Our findings indicate that NTC radiation generated by this wave-electron resonance instability near the plasmapause can propagate nearer to the magnetic equator with multiple harmonics, which is in agreement with a recent statistical study using Van Allen Probes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY

Quantitative Determination of Electronic Effects in Free Radicals through Open-Shell Hammett Substituent Constants

Hammett substituent constants (σ), which quantify the electronic effects of functional groups, are widely used for predicting the properties of organic compounds and investigating reaction mechanisms. While these values have been obtained for a wide range of closed-shell substituents, measurements of analogous values for open-shell substituents are rare due to challenges associated with their short lifetimes. Here, in this report, we developed a combined experimental and computational approach for quantifying the electronic properties of open-shell substituents based on changes in nitrile vibrational frequencies (ν(C≡N)). By coupling pulse radiolysis and time-resolved infrared spectroscopy (PR-TRIR), we measured ν(C≡N) IR bands of 30 para - and meta -substituted benzonitriles bearing C-, N-, and S-centered radicals. A linear scaling relationship was obtained between these experimental values and values obtained from DFT calculations. Using these computed values, two different Hammett constants, σ m , and σ p + , were determined for a series of C-, N-, O-, S-, Si-, and B-centered radicals. The differences between σm and σp+ values enable the separate evaluation of inductive and resonance effects in these open-shell substituents. The results suggest that there are three classes of radicals: one is electron withdrawing (σ m , σ p + > 0), one is electron donating (σm, σp+ < 0), and one is inductively withdrawing but resonance donating (σ m > 0, σ p + < 0). Our study represents a general approach to the analysis of the electronic properties of open-shell species and has potential applications in a wide range of molecular processes involving free radical intermediates.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Radar Differential Phase Signatures of Ice Orientation for the Prediction of Lightning Initiation and Cessation

The majority of lightning-related casualties typically occur during thunderstorm initiation (e.g., first flash) or dissipation (e.g., last flash). The physics of electrification and lightning production during thunderstorm initiation is fairly well understood. As such, the literature includes a number of studies presenting various radar techniques (using reflectivity and, if available, other dual-polarimetric parameters) for the anticipation of initial electrification and first lightning flash. These radar techniques have shown considerable skill at forecasting first flash. On the other hand, electrical processes and lightning production during thunderstorm dissipation are not nearly as well understood and few, if any, successful techniques have been developed to anticipate the last flash and subsequent cessation of lightning. One promising approach involves the use of dual-polarimetric radar variables to infer the presence of oriented ice crystals in lightning producing storms. In the absence of strong vertical electric fields, ice crystals fall with their largest (semi-major) axis in the horizontal associated with gravitational and aerodynamic forces. In thunderstorms, strong vertical electric fields (100-200 kV m(sup -1)) have been shown to orient small (less than 2 mm) ice crystals such that their semi-major axis is vertical (or nearly vertical). After a lightning flash, the electric field is typically relaxed and prior radar research suggests that ice crystals rapidly resume their preferred horizontal orientation. In active thunderstorms, the vertical electric field quickly recovers and the ice crystals repeat this cycle of orientation for each nearby flash. This change in ice crystal orientation from primarily horizontal to vertical during the development of strong vertical electric fields prior to a lightning flash forms the physical basis for anticipating lightning initiation and, potentially, cessation. Research has shown that radar reflectivity (Z) and other co-polar back-scattering radar measurements like differential reflectivity (Z(sub dr)) typically measured by operational dual-polarimetric radars are not sensitive to these changes in ice crystal orientation. However, prior research has demonstrated that oriented ice crystals cause significant propagation effects that can be routinely measured by most dual-polarimetric radars from X-band (3 cm) to S-band (10 cm) wavelengths using the differential propagation phase shift (often just called differential phase, phi(sub dp)) or its range derivative, the specific differential phase (K(sub dp)). Advantages of the differential phase include independence from absolute or relative power calibration, attenuation, differential attenuation and relative insensitivity to ground clutter and partial beam occultation effects (as long as the signal remains above noise). In research mode, these sorts of techniques have been used to anticipate initial cloud electrification, lightning initiation, and cessation. In this study, we develop a simplified model of ice crystal size, shape, orientation, dielectric, and associated radar scattering and propagation effects in order to simulate various idealized scenarios of ice crystals responding to a hypothetical electric field and their dual-polarimetric radar signatures leading up to lightning initiation and particularly cessation. The sensitivity of the K(sub dp) ice orientation signature to various ice properties and radar wavelength will be explored. Since K(sub dp) is proportional to frequency in the Rayleigh- Gans scattering regime, the ice orientation signatures should be more obvious at higher (lower) frequencies (wavelengths). As a result, simulations at radar wavelengths from 10 cm down to 1 cm (Ka-band) will be conducted. Resonance effects will be considered using the T-matrix method. Since most K(sub dp) Vbased observations have been shown at S-band, we will present ice orientation signatures from C-band (UAH/NASA ARMOR) and X-bd (UAH MAX) dual-polarimetric radars located in Northern Alabama. Issues related to optimal radar scanning for the detection of oriented ice will be discussed. Preliminary suggestions on how these differential phase signatures of oriented ice could contribute to lightning initiation and cessation algorithms will be presented.

Carey, L.D.

Comparison of Measured Flapwise Structural Bending Moments on a Teetering Rotor Blade With Results Calculated From the Measured Pressure Distribution

Flapwise bending moments were calculated for a teetering rotor blade using a reasonably rapid theoretical method in which airloads obtained from wind-tunnel tests were employed. The calculated moments agreed reasonably well with those measured with strain gages under the same test conditions. The range of the tests included one hovering and two forward-flight conditions. The rotor speed for the test was very near blade resonance, and difficult-to-calculate resonance effects apparently were responsible for the largest differences between the calculated and measured harmonic components of blade bending moments. These differences, moreover, were largely nullified when the harmonic components were combined to give a comparison of the calculated and measured blade total- moment time histories. The degree of agreement shown is therefore considered adequate to warrant the use of the theoretical method in establishing and applying methods of prediction of rotor-blade fatigue loads. At the same time, the validity of the experimental methods of obtaining both airload and blade stress measurement is also indicated to be adequate for use in establishing improved methods for prediction of rotor-blade fatigue loads during the design stage. The blade stiffnesses and natural frequencies were measured and found to be in close agreement with calculated values; however, for a condition of blade resonance the use of the experimental stiffness values resulted in better agreement between calculated and measured blade stresses.

Mayo, Alton P.

Identification of Rotorcraft Structural Dynamics from Flight and Wind Tunnel Data

Excessive vibration remains one one of the most difficult problems that faces the helicopter industry today, affecting all production helicopters at some phase of their development. Vibrations in rotating structures may arise from external periodic dynamic airloads whose frequencies are are close to the natural frequencies of the rotating system itself. The goal for the structures engineer would thus be to design a structure as free from resonance effects as possible. In the case of a helicopter rotor blade these dynamic loads are a consequence of asymmetric airload distribution on the rotor blade in forward flight, leading to a rich collection of higher harmonic airloads that force rotor and airframe response. Accurate prediction of the dynamic characteristics of a helicopter rotor blade will provide the opportunity to affect in a positive manner noise intensity, vibration level, durability, reliability and operating costs by reducing objectionable frequencies or moving them to a different frequency range and thus providing us with a lower vibration rotor. In fact, the dynamic characteristics tend to define the operating limits of a rotorcraft. As computing power has increased greatly over the last decade, researchers and engineers have turned to analyzing the vibrational characteristics of aerospace structures at the design and development stage of the production of an aircraft. Modern rotor blade construction methods lead to products with low mass and low inherent damping so careful design and analysis is required to avoid resonance and an undesirable dynamic performance. In addition, accurate modal analysis is necessary for several current approaches in elastic system identification and active control.

McKillip, Robert M., Jr.

Effect of Space Vehicle Structure Vibration on Control Moment Gyroscope Dynamics

Control Moment Gyroscopes (CMGs) are used for non-propulsive attitude control of satellites and space stations, including the International Space Station (ISS). CMGs could be essential for future long duration space missions due to the fact that they help to save propellant. CMGs were successfully tested on the ground for many years, and have been successfully used on satellites. However, operations have shown that the CMG service life on the ISS is significantly shorter than predicted. Since the dynamic environment of the ISS differs greatly from the nominal environment of satellites, it was important to analyze how operations specific to the station (dockings and undockings, huge solar array motion, crew exercising, robotic operations, etc) can affect the CMG performance. This task became even more important since the first CMG failure onboard the ISS. The CMG failure resulted in the limitation of the attitude control capabilities, more propellant consumption, and additional operational issues. Therefore, the goal of this work was to find out how the vibrations of a space vehicle structure, caused by a variety of onboard operations, can affect the CMG dynamics and performance. The equations of CMG motion were derived and analyzed for the case when the gyro foundation can vibrate in any direction. The analysis was performed for unbalanced CMG gimbals to match the CMG configuration on ISS. The analysis showed that vehicle structure vibrations can amplify and significantly change the CMG motion if the gyro gimbals are unbalanced in flight. The resonance frequencies were found. It was shown that the resonance effect depends on the magnitude of gimbal imbalance, on the direction of a structure vibration, and on gimbal bearing friction. Computer modeling results of CMG dynamics affected by the external vibration are presented. The results can explain some of the CMG vibration telemetry observed on ISS. This work shows that balancing the CMG gimbals decreases the effect of vehicle structure vibration on CMGs. Additionally, the effect of external vibrations may also be decreased by increasing the gimbal bearing friction. With the suggested modifications there may be no need to lower the gimbal rates below the nominal design requirements as it is currently done on ISS. The conclusions of this work

Dobrinskaya, Tatiana

A new Monte Carlo generator for BSM physics in B → K*ℓ+ℓ− decays with an application to lepton non-universality in angular distributions

Abstract Within the widely used EvtGen framework, we have added a new event generator model forB → K * ℓ + ℓ − with improved standard model (SM) decay amplitudes and possible BSM physics contributions, which are implemented in the operator product expansion in terms of Wilson coefficients. This event generator can then be used to estimate the statistical sensitivity of a simulated experiment to the most general BSM signal resulting from dimension-six operators. We describe the advantages and potential of the newly developed ‘Sibidanov Physics Generator’ in improving the experimental sensitivity of searches for lepton non-universal BSM physics and clarifying signatures. The new generator can properly simulate BSM scenarios, interference between SM and BSM amplitudes, and correlations between different BSM observables as well as acceptance bias. We show that exploiting such correlations substantially improves experimental sensitivity. As a demonstration of the utility of the MC generator, we examine the prospects for improved measurements of lepton non-universality in angular distributions forB→K * ℓ + ℓ − decays from the expected 50 ab −1 data set of the Belle II experiment, using a four-dimensional unbinned maximum likelihood fit. We describe promising experimental signatures and correlations between observables. The use of lepton-universality violating ∆-observables significantly reduces uncertainties in the SM expectations due to QCD and resonance effects and is ideally suited for Belle II with the large data sets expected in the next decade. Thanks to the clean experimental environment of ane + e − machine, Belle II should be able to probe BSM physics in the Wilson coefficientsC 7 and$$ {C}_7^{\prime } $$ C 7 ′ , which appear at lowq 2 in the di-electron channel.

Physics