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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Cesium Removal from Surrogate Pyroprocessing Salt by Electrodeposition

Active metals in used nuclear fuel dissolve into the salt during pyroprocessing and are not removed by electrorefining or drawdown operations. The buildup of 137 Cs over time increases the heat load and ionizing radiation level of the salt such that it must be replaced frequently, resulting in a significant amount of salt waste. An effective means of managing cesium in the molten salt electrolyte would increase the efficiency of pyroprocessing and decrease the volume of salt waste requiring disposal. A previous report summarized issues that must be addressed when developing a removal strategy and assessed the suitability of existing methods and remaining technological gaps to their application (Rose and Thomas 2023). Cesium is extremely stable in molten salt as a chloride—even more stable than the LiCl-KCl eutectic base salt used for pyroprocessing fuel—which makes removing cesium a challenge. However, sufficiently strong atomic interactions occur between active metal species and liquid metals that make the electrodeposition of active metal fission products into liquid metal electrodes energetically favorable. The feasibility of recovering cesium from LiCl-KCl pyroprocessing salt through electrodeposition into liquid metals is eing assessed by identifying potentially effective liquid metals and performing tests to determine the effectiveness of electrodepositing cesium from a LiCl/KCl salt into these liquid metals. Previous studies investigating the electrodeposition of Sr 2+ , and Ba 2+ into zinc, cadmium, bismuth, lead, tin and antimony have shown that alkali and alkaline earth metals can be electrodeposited at liquid metal cathodes (Kim et al., 2018). The removal of Ba 2+ and Sr 2+ was measured to be more efficient than the removal of monovalent cations due to the greater thermochemical driving force for alloying those elements with the liquid metal (Jang et al. 2022). Because the equilibrium potentials are dependent on the interactions of the active metal in the liquid metal, it is likely that the other alkali metals Li + , and K + , will deposit from LiCl/KCl salt with the Cs + . Therefore, application of this method to recover active metals from pyroprocessing salt will benefit from the use of a liquid metal and set of operating conditions that sufficiently increase the reduction potential of cesium to remove cesium from the waste salt with an acceptable amount of co-deposited lithium and potassium.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1973

Incipient separation pressure rise for a Mach 3.8 turbulent boundary layer.

Additional incipient separation data presented cover a range of Reynolds numbers not covered in previous investigations conducted by Seebaugh (1968) and Rose (1972). A novel technique for detecting incipient separation is discussed. Several methods for detecting separation are considered. One method is based on the introduction of alcohol at a minute rate into the boundary layer.

Rose, W. C.↗
NASA NTRS1984

A compact finite element method for elastic bodies

A nonconforming finite method is described for treating linear equilibrium problems, and a convergence proof showing second order accuracy is given. The close relationship to a related compact finite difference scheme due to Phillips and Rose is examined. A condensation technique is shown to preserve the compactness property and suggests an approach to a certain type of homogenization.

Rose, M. E.↗
NASA NTRS1985

Active-region plages and the Hyades anomaly?

The Hyades are known to differ in their photometric properties (Crawford 1969; Campbell 1984) and spectral properties (Rose 1984) from field stars of similar metal abundance. Using spectra of solar plages, it is demonstrated that the Hyades spectral anomalies are caused by excess emission from magnetic regions (plages) on the surfaces of these cluster stars. It is further speculated that the Hyades photometric anomalies arise from the same cause, but photometric data on solar plages necessary to resolve this issue are not available. The Pleiades stars and a few extreme emission stars show similar spectral anomalies, but of such magnitude to indicate that plages on Pleiades stars have higher surface brightnesses than on the sun and do not merely cover a larger fraction of the stars.

Labonte, B. J.↗
NASA NTRS1996

Radar Observations of Asteroid 1620 Geographos

Goldstone radar observations of Geographos from August 28 through September 2, 1994 yield over 400 delay-Doppler images whose linear spatial resolutions range from approximately 75 - 151 m, and 138 pairs of dual-polarization (OC, SC) spectra with one-dimensional resolution of 103 m. Each data type provides thorough rotational coverage. The images contain an intrinsic north/south ambiguity, but the equatorial view allows accurate determination of the shape of the radar-facing part of the asteroid's pole-on silhouette at any rotation phase. Sums of co-registered images that cover nearly a full rotation have defined the extremely elongated shape of that silhouette (S. J. Ostro, K. D. Rosema, R. S. Hudson, R. F. Jurgens, J. D. Giorgini, R. Winkler, D. K. Yeomans, D. Choate, R. Rose, M. A. Slade, S. D. Howard, and D. L. Mitchell 1995, Nature 375, 474-477). Here we present individual images and co-registered sums over approximately 30 deg of rotation phase that show the silhouette's structural characteristics in finer detail and also reveal numerous contrast features "inside" the silhouette. Those features include several candidate craters as well as indications of other sorts of large-scale topographic relief, including a prominent central indentation. Protuberances at the asteroid's ends may be related to the pattern of ejecta removal and deposition caused by the asteroid's gravity field. The asteroid's surface is homogeneous and displays only modest roughness at centimeter-to-meter scales. Our estimates of radar cross section and the currently available constraints on the asteroid's dimensions are consistent with a near-surface bulk density between 2 and 3 g/cc. The delay-Doppler trajectory of Geographos' center of mass has been determined to about 200 m on August 28 and to about 100 m on August 31, an improvement of two orders of magnitude over pre-observation ephemerides.

Ostro, Steven J.↗
NASA NTRS2003

Validation of the Archived CERES Surface and Atmosphere Radiation Budget (SARB) at SGP

The CERES Surface and Atmosphere Radiation Budget (SARB) product (Charlock et al, 2002) includes the vertical profile of broadband SW, broadband LW, and 8-12 micron window (WN) fluxes; upwelling and downwelling at TOA, 70 hPa, 200 hPa, 500 hPa, and the surface; and for all-sky and clear-sky conditions. We test the archived CERES TRMM record of SARB for January-August 1998 and focus on discrepancies with ground-based measurements at SGP. The CERES SARB is generated by a highly modified Fu-Liou radiative transfer code (Fu and Liou, 1993). The most critical inputs for this application are cloud optical properties (fractional area, optical depth, particle size and phase, height of top, and estimate of geometrical thickness Minnis et al., 2002) from the narrowband VIRS imager. Numerous VIRS pixels (approx. 2km resolution at nadir) are matched to each of the large (approx. 20km) CERES broadband footprints (Wielicki et al, 1996). Other inputs include temperature and humidity from ECMWF (Rabier et al, 1998) , NCEP ozone profiles from SBUV and TOVS (Yang et al, 2001), aerosol optical thickness (AOT) from the Model for Atmospheric Transport and Chemistry (MATCH) aerosol assimilation (Collins et al., 2001) or alternately from the VIRS imager (Ignatov and Stowe, 2000). VIRS AOT is available for clear and partly cloudy ocean footprints during daylight; and only when viewing geometry renders a contribution from sunglint as unlikely. For other footprints, AOT is taken from MATCH. AOT is apportioned into fractions of dust (Tegan and Lacis, 1996), sea salt, sulfate, dust, soluble organic, insoluble organic, and soot (Hess et al., 1996) using the 6-hourly MATCH output. Tuned fluxes are retrieved by adjusting inputs to nudge computed TOA fluxes toward CERES observations (Rose et al, 1997). In clear conditions, the fields of humidity, surface skin temperature, surface albedo and AOT are adjusted to produce a closer match of computed and observed fluxes at TOA. When CERES footprints have clouds, the cloud optical thickness, fractional area within the footprint, and temperature of cloud top are adjusted by the tuning algorithm. Both tuned and untuned fluxes are archived, as are the respective adjustments to any parameters at the surface or within the atmosphere.

Charlock, Thomas P.↗
NASA NTRS2011

Grid Fin Stabilization of the Orion Launch Abort Vehicle

Wind tunnel tests were conducted by Nielsen Engineering & Research (NEAR) and Rose Engineering & Research (REAR) in conjunction with the NASA Engineering & Safety Center (NESC) on a 6%-scale model of the Orion launch abort vehicle (LAV) configured with four grid fins mounted near the base of the vehicle. The objectives of these tests were to 1) quantify LAV stability augmentation provided by the grid fins from subsonic through supersonic Mach numbers, 2) assess the benefits of swept grid fins versus unswept grid fins on the LAV, 3) determine the effects of the LAV abort motors on grid fin aerodynamics, and 4) generate an aerodynamic database for use in the future application of grid fins to small length-to-diameter ratio vehicles similar to the LAV. The tests were conducted in NASA Ames Research Center's 11x11-foot transonic wind tunnel from Mach 0.5 through Mach 1.3 and in their 9x7-foot supersonic wind tunnel from Mach 1.6 through Mach 2.5. Force- and moment-coefficient data were collected for the complete vehicle and for each individual grid fin as a function of angle of attack and sideslip angle. Tests were conducted with both swept and unswept grid fins with the simulated abort motors (cold jets) off and on. The swept grid fins were designed with a 22.5deg aft sweep angle for both the frame and the internal lattice so that the frontal projection of the swept fins was the same as for the unswept fins. Data from these tests indicate that both unswept and swept grid fins provide significant improvements in pitch stability as compared to the baseline vehicle over the Mach number range investigated. The swept fins typically provide improved stability as compared to the unswept fins, but the performance gap diminished as Mach number was increased. The aerodynamic performance of the fins was not observed to degrade when the abort motors were turned on. Results from these tests indicate that grid fins can be a robust solution for stabilizing the Orion LAV over a wide range of operating conditions.

Pruzan, Daniel A.↗
DOE OSTI2025

A minor respiratory process with major global implications: is atmospheric methane oxidation in tree stems driven by stem respiration rather than microbial methanotrophy?

Tree stem surfaces are widely recognized as sites of carbon dioxide (CO₂) efflux and oxygen (O₂) influx, reflecting the dynamics of aerobic respiration of photosynthate substrates, such as sugars, delivered via the phloem. Stems are also largely considered passive conduits for methane (CH₄) produced in anoxic soils via microbial methanogenesis, where CH₄ is thought to be transported upward through the transpiration stream and/or diffusion and emitted through stem surfaces and the canopy. However, recent observations from dynamic stem chambers suggest that stems may also act as active sinks for atmospheric CH₄. Despite these findings, the extent and drivers of stem CH₄ consumption remain poorly characterized across biomes, species, and environmental gradients, and its quantitative relationship to stem respiration has not been established. Moreover, previous studies captured only snapshot fluxes, leaving diurnal patterns of CH₄ exchange uncharacterized. Here, we address these limitations by combining real-time measurements of stem CH₄ and O₂ uptake under ambient conditions in a California cherry tree, using a dynamic stem gas exchange system with three chambers receiving a continuous flow of ambient air and automated chamber and reference air sampling every 10 min. Our results confirm that stems of upland trees can actively consume both atmospheric CH₄ and O₂, but with decreasing temperature sensitivity as daily temperatures increase. Early mornings were marked by rapid influxes of both gases, followed by declining uptake as temperatures rose further. Methane uptake was tightly coupled with O₂ influx and represented a minor (0.012% ± 0.002%) fraction of stem respiratory activity, as determined by concurrent O₂ uptake. These findings suggest that while atmospheric CH₄ oxidation is a minor respiratory process in stems, it is strongly linked with stem physiological activity. This challenges the current assumption that terrestrial CH₄ uptake is driven solely by microbial methanotrophy and raises the possibility that living stem tissues may contribute to CH₄ oxidation through an as-yet-unidentified plant-based mechanism.

Atmospheric greenhouse gases↗
DOE OSTI2026

Space Mission Options for Reconnaissance and Mitigation of Asteroid 2024 YR4

Near-Earth asteroid 2024 YR 4 was discovered on 2024-12-27 and its probability of Earth impact in December 2032 peaked at ~3% on 2025-02-18. Additional observations ruled out Earth impact by 2025-02-23. However, the probability of lunar impact in December 2032 then rose, reaching ~4% by the end of the apparition in May 2025. James Webb Space Telescope (JWST) observations on 2025-03-26 estimated the asteroid’s diameter at 60 ± 7 m. Studies of 2024 YR 4 ’s potential lunar impact effects suggest lunar ejecta could increase micrometeoroid debris flux in low Earth orbit up to 1000 times above background levels over just a few days, possibly threatening astronauts and spacecraft. In this work, we present options for space missions to 2024 YR 4 that could be utilized if lunar impact is confirmed. Here, we cover flyby & rendezvous reconnaissance, deflection, and robust disruption of the asteroid. We examine both rapid-response and delayed launch options through 2032. We evaluate chemical and solar electric propulsion, various launch vehicles, optimized deep space maneuvers, and gravity assists. Re-tasking extant spacecraft and using built spacecraft not yet launched are also considered. The best reconnaissance mission options launch in late 2028, leaving only approximately three years for development at the time of this writing in August 2025. Deflection missions were assessed and appear impractical. However, kinetic robust disruption missions are available with launches between April 2030 and April 2032. Nuclear robust disruption missions are also available with launches between late 2029 and late 2031. Finally, even if lunar impact is ruled out there is significant potential utility in deploying a reconnaissance mission to characterize the asteroid.

Asteroid deflection↗
DOE OSTI2025

Impact of salinity on morphology, growth, and pigment profiles of Scenedesmus obliquus HTB1 under ambient air and elevated CO 2 (10 %) conditions

Certain microalgal species, such as Scenedesmus obliquus strain HTB1, thrive under high CO 2 concentrations, making them promising for carbon sequestration to mitigate climate change. Isolated from the Baltimore Inner Harbor, HTB1 grows faster with 10 % CO 2 than with ambient air. To investigate its responses to salinity and elevated CO 2 , two experiments were conducted. In the first, HTB1 was cultured at seven different salinities (0, 17.5, 20, 22.5, 25, 27.5, and 30 ppt) (parts per thousand) under ambient air. Higher salinity caused cell shrinkage, color changes from green to pale white, reduced pigments like zeaxanthin, lutein, and chlorophyll b, but increased canthaxanthin. Growth declined significantly above 22.5 ppt. The second experiment compared HTB1's response to salinity (0, 10, 20 ppt) under air and 10 % CO 2 . Cultures under 10 % CO 2 showed minimal color changes, while those under air shifted from green to brown, with salinity having less inhibitory effects on growth under elevated CO 2 . Interestingly, lutein and canthaxanthin levels rose with salinity in 10 % CO 2 . These findings indicate that elevated CO 2 mitigates salt stress in HTB1, reducing its impact on growth and promoting adaptive pigment changes. This study sheds light on how salinity and CO 2 interact to influence HTB1's morphology, growth, and pigment composition, enhancing our understanding of its resilience and potential applications.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2026

Geochemical evolution in Cacapon member: Fluid-rock interaction experiments and model insights for Appalachian Basin geothermal development

Here, this study combines recirculated flow-through experimental results conducted for 17 days at 90C and 200 PSI with reactive transport modeling to estimate fluid-rock interactions occurring in a sandy mudstone using an interbedded sandstone-shale sample from the Cacapon Member of the upper Tuscarora Sandstone/lower Rose Hill Formation for the purpose of geothermal exploration. Results suggest that the fluid and rock are likely to be in or near partial-equilibrium after approximately one year. In addition, after >400 h of continuous injection at 0.05 mL/min (5*10 −8 m 3 /min) the reactive front is restricted to the first ∼13% of the 4 cm*1.6 cm experimental rock length, whereas after >9100 h (∼1 year), the reactive front extends to 30% total length. The rate of changes in dissolution or precipitation are however, very minimal, with all major rock-forming minerals having rates <10 −11 mol/L porous media/s. Reservoir rock in the presence of dilute brine as may be the case during operation of an enhanced geothermal system would experience little alteration during the shut-in phase, and possibly up to one year. These results have utility in geothermal exploration for reservoirs at similar temperatures as well as general fluid-sandy mudstone rock interaction geochemistry.

Appalachian Basin↗
DOE OSTI2024

Understanding the heat generation mechanisms and the interplay between joule heat and entropy effects as a function of state of charge in lithium-ion batteries

The thermal performance of lithium-ion battery cells is critical for ensuring their safe and reliable operation across various applications. In this study, we employed an isothermal calorimetry method to investigate the heat generation of commercial 18650 lithium-ion battery fresh cells during charge and discharge at different current rates, ranging from 0.05C to 0.5C, and across various temperatures: 20 °C, 30 °C, 40 °C, and 50 °C. Our findings revealed a direct correlation between heat generation and current rates, indicating that higher current rates lead to increased heat generation within the cells. Conversely, we observed that heat generation remained relatively stable as the temperature rose, suggesting that temperature changes within this range may not significantly impact the heat generation of fresh cells during typical operations. Furthermore, our study explored irreversible heat generation, which depends on the applied current and overpotential, using the galvanostatic intermittent titration technique at 0.05C–0.5C and 30 °C. Additionally, electrochemical impedance spectroscopy was performed on the same cells during charge and discharge at 20 °C, 30 °C, and 40 °C to analyze cell impedance. Finally, our results indicated a consistent dependence of impedance on the state of charge and depth of discharge, with a significant increase in impedance observed at the end of the discharge process.

25 ENERGY STORAGE↗
DOE OSTI2026

Geothermal district energy systems coupled with seasonal underground thermal energy storage: a U.S. techno-economic screening by climate and geology

In the United States, cooling-dominated commercial building loads can cause geothermal heat pump-based district energy systems to accumulate a long-term subsurface thermal imbalance, motivating the incorporation of seasonal underground thermal energy storage. We developed a transferable workflow to evaluate geothermal district systems that pair ground heat exchangers with seasonal underground thermal energy storage. Using standardized hourly loads for seven commercial buildings and a uniform cost framework, we simulated ten U.S. cities with a physics-based ground heat exchanger model, subsurface storage simulations, and economic assessment to isolate the roles of climate and hydrogeology. In cooling-dominated cities, underground thermal energy storage supplied the majority of annual cooling, cutting electricity use and summer peaks substantially while achieving levelized costs comparable to or below conventional chiller-boiler plants. In cooler climates, the storage share shrunk, required borefield size and costs rose, and levelized cost of energy increased nearly linearly with declining underground thermal energy storage fraction, indicating storage fraction as the primary economic lever. Sensitivity analysis showed capital risk dominated by borefield drilling and surface heating, ventilation, and air-conditioning and piping, with underground thermal energy storage costs secondary. This workflow provides a transparent foundation for site-specific design and screening of next-generation geothermal district energy systems.

25 ENERGY STORAGE↗
DOE OSTI2026

Optimizing aluminum oxide passivation layers—Laser-induced plasmas for layer formation, real-time diagnostics, and layer evaluation

Molten salts have beneficial thermophysical and electrolytic properties, but the aggressive nature of molten salts requires corrosion mitigation strategies, such as structural material surface treatment. In this study, a laser-induced breakdown spectroscopy (LIBS) system was used to simultaneously ablate and monitor de-excitation spectra to form and identify dense alumina passivation layers. Additionally, high-frequency (kHz) LIBS imaging allowed rapid elemental mapping and depth profiling for surface O/Al ratios via minimally destructive analysis. The paired t-test rejected the null hypothesis that air and Ar cover gases were equivalent (p = 0.00012), and the analysis of variance (ANOVA) showed that overlap between shots (p = 0.03112) and cover gas flow rate (p = 0.02729) were statistically significant. At 75% overlap, the O/Al ratio increased to 10% ± 2%, and 90% overlap rose further to 31% ± 2%. Regardless of overlap, tuning the gas flow from 0.5 to 2.5 L min −1 enhanced the O/Al ratio by 24% ± 4%. LIBS depth profiling showed a 3× increase in layer thickness from 75% to 90% overlap. Molecular band peaks of AlO, a precursor to Al 2 O 3 found during treatment, suggest that band intensity could be used for real-time Al 2 O 3 optimization. Ultimately, by adjusting laser spot overlap and cover gas flow rate, a 266 nm laser was shown to form Al 2 O 3 layers on an Al6061 sample, with cover gas flow rate primarily affecting the O/Al ratio and layer thickness correlating with laser spot overlap. This combination of molecular spectra collection, imaging, and depth profiling demonstrated the robust layer analysis capabilities of LIBS.

Corrosion↗
DOE OSTI2025

Hydrology controls thermokarst and alters carbon cycling and methane emissions in peatlands near the southern limit of permafrost

Permafrost peatlands store vast amounts of frozen carbon across northern landscapes. When ground ice melts, surface subsidence produces thermokarst landforms that expand wetlands at the edges of permafrost plateaus. Thermokarst represents an accelerating climate feedback, but uncertainties remain about how ground ice, hydrology, and vegetation interact to shape landscape change and carbon fluxes. We extended the process-based model ecosys to simulate thermokarst dynamics in laterally coupled 2D transects at a well-characterized boreal peatland site in Canada’s Northwest Territories. After benchmarking against site observations, we varied ground ice content and hydrologic boundary conditions across ranges typical near the southern permafrost limit. Simulations revealed distinct degradation regimes governed by the elevation difference between the frost table and the external water table. Rates of lateral retreat, the thaw-driven encroachment of wetlands into adjacent plateaus, ranged from 0 to >2 m yr −1 under identical weather forcing, consistent with observations and highlighting the strong role of WT and ground ice. Simulated vegetation dynamics indicate that black spruce mortality cannot be explained by anoxia alone, pointing to additional stressors such as root damage, pathogens, or physical destabilization. Despite large hydrologic shifts, net ecosystem CO 2 exchange remained a slight sink after collapse, while methane (CH 4 ) emissions rose by one to two orders of magnitude. As a result, lateral retreat substantially increases the greenhouse warming potential of permafrost peatlands (1.7 million km 2 in area), with simulated emissions of 0.1–10 Mt CO 2 -eq decade −1 depending on hydrology and retreat rates. These results underscore the need to account for both ground ice and hydrologic dynamics when assessing thermokarst-driven climate feedbacks.

carbon cycling↗
DOE OSTI2025

Optical evolution of AT 2024wpp: the high-velocity outflows in Cow-like transients are consistent with high spherical symmetry

ABSTRACT We present the analysis of optical/near-infrared (NIR) data and host galaxy properties of a bright, extremely rapidly evolving transient, AT 2024wpp, which resembles the enigmatic AT 2018cow. AT 2024wpp rose to a peak brightness of $c=-21.9$ mag in 4.3 d and remained above the half-maximum brightness for only 6.7 d. The blackbody fits to the photometry show that the event remained persistently hot ($T\gtrsim 20\, 000$ K) with a rapidly receding photosphere ($v\sim 11\, 500$ km s$^{-1}$), similarly to AT 2018cow albeit with a several times larger photosphere. $JH$ photometry reveals an NIR excess over the thermal emission at $\sim +20$ d, indicating a presence of an additional component. The spectra are consistent with blackbody emission throughout our spectral sequence ending at $+21.9$ d, showing a tentative, very broad emission feature at $\sim 5500$ Å – implying that the optical photosphere is likely within a near-relativistic outflow. Furthermore, reports of strong X-ray and radio emission cement the nature of AT 2024wpp as a likely Cow-like transient. AT 2024wpp is the second event of the class with optical polarimetry. Our $BVRI$ observations obtained from $+6.1$ to $+14.4$ d show a low polarization of $P\lesssim 0.5$ per cent across all bands, similar to AT 2018cow that was consistent with $P\sim 0$ per cent during the same outflow-driven phase. In the absence of evidence for a preferential viewing angle, it is unlikely that both events would have shown low polarization in the case that their photospheres were aspherical. As such, we conclude that the near-relativistic outflows launched in these events are likely highly spherical, but polarimetric observations of further events are crucial to constrain their ejecta geometry and stratification in detail.

Pursiainen, M.↗
DOE OSTI2025

Rethinking 𝛼−RuCl 3 : Parameters, models, and phase diagram

RuCl 3 was likely the first ever deliberately synthesized ruthenium compound, following the discovery of the 44 Ru element in 1844. For a long time it was known as an oxidation catalyst, with its physical properties being discrepant and confusing, until a decade ago when its allotropic form 𝛼−RuCl 3 rose to exceptional prominence. This “rediscovery” of 𝛼−RuCl 3 has not only reshaped the hunt for a material manifestation of the Kitaev spin liquid, but it has opened the floodgates of theoretical and experimental research in the many unusual phases and excitations that the anisotropic-exchange magnets as a class of compounds have to offer. Given its importance for the field of Kitaev materials, it is astonishing that the low-energy spin model that describes this compound and its possible proximity to the much-desired spin-liquid state is still a subject of significant debate ten years later. In the present study, we argue that the existing key phenomenological observations put strong natural constraints on the effective microscopic spin model of 𝛼−RuCl 3 , and specifically on its spin-orbit-induced anisotropic-exchange parameters that are responsible for the nontrivial physical properties of this material. These constraints allow one to focus on the relevant region of the multidimensional phase diagram of the 𝛼−RuCl 3 model, suggest an intuitive description of it via a different parametrization of the exchange matrix, offer a unifying view on the earlier assessments of its parameters, and bring closer together several approaches to the derivation of anisotropic-exchange models. We explore extended phase diagrams relevant to the 𝛼−RuCl 3 parameter space using quasiclassical, Luttinger-Tisza, exact diagonalization, and density-matrix renormalization-group methods, demonstrating a remarkably close quantitative accord between them on the general structure and hierarchy of the phases, with the zigzag, ferromagnetic, and incommensurate phases that are proximate to each other. As a result, one of the highlights is the detailed agreement on the nature of the incommensurate phases that realize two distinct counterrotating helical states.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗