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At least 91 records · Page 5

Generic Repository Concepts and Thermal Analysis for Advanced Fuel Cycles - 12477

A geologic disposal concept for spent nuclear fuel (SNF) or high-level waste (HLW) consists of three components: waste inventory, geologic setting, and concept of operations. A set of reference geologic disposal concepts has been developed by the U.S. Department of Energy (DOE), Used Fuel Disposition campaign. Reference concepts are identified for crystalline rock, clay/shale, bedded salt, and deep borehole (crystalline basement) geologic settings. These were analyzed for waste inventory cases representing a range of waste types that could be produced by advanced nuclear fuel cycles. Concepts of operation consisting of emplacement mode, repository layout, and engineered barrier descriptions, were selected based on international progress. All of these disposal concepts are enclosed emplacement modes, whereby waste packages are in direct contact with encapsulating engineered or natural materials. Enclosed modes have less capacity to dissipate heat than open modes such as that proposed for a repository at Yucca Mountain. Thermal analysis has identified important relationships between waste package size and capacity, and the duration of surface decay storage needed to meet temperature limits for different disposal concepts. For the crystalline rock and clay/shale repository concepts, a waste package surface temperature limit of 100 deg. C was assumed to prevent changes in clay-based buffer material or clay-rich host rock. Surface decay storage of 50 to 100 years is needed for disposal of high-burnup LWR SNF in 4-PWR packages, or disposal of HLW glass from reprocessing LWR uranium oxide (UOX) fuel. High-level waste (HLW) from reprocessing of metal fuel used in a fast reactor could be disposed after decay storage of 50 years or less. For disposal in salt the rock thermal conductivity is significantly greater, and higher temperatures (200 deg. C) can be tolerated at the waste package surface. Decay storage of 10 years or less is needed for high-burnup LWR SNF in 4-PWR packages, while 12-PWR packages could be emplaced after 40 years or less. HLW from reprocessing LWR UOX fuel or metal fuel from fast reactors, could be disposed of in salt after 10 to 50 years of decay storage depending on the specific composition and other factors. For the deep borehole disposal concept no near-field temperature limits are recognized because no performance credit is taken for waste form or waste package integrity, or containment by the near-field host rock. These results show the key differences in thermal management strategies available to the U.S. repository program, given the range of disposal concepts. A host medium such as salt with greater thermal conductivity and peak temperature tolerance could shorten decay storage by 50 years, or facilitate the use of larger waste packages. The LWR UOX SNF evaluated in this study represents that which could be produced in the coming decades. The existing, lower burnup used fuel that is presently in storage at many LWR locations across the U.S. is significantly cooler, and analyses of this type could be used to show that disposal is possible with less decay storage or larger waste packages. We note that while the temperature limits and waste package capacities used in this study are similar to those used internationally and in past U.S. studies, they might be increased as the result of ongoing research and development activities. This study selected enclosed emplacement modes to conform with disposal concepts developed internationally and previously in the U.S. Open modes (such as that proposed for a repository at Yucca Mountain) afford additional flexibility in waste management and the necessary investment, because the same facility serves both storage and disposal functions. Use of open modes, and combined analysis of storage, transportation, and disposal functions, are appropriate to consider in future studies of this type. (authors)

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Performance Assessment of a Generic Repository for Defense-Related HLW/SNF in Fractured Crystalline Host Rock - 17059

Recently the U.S. made a policy decision to begin R and D for geologic disposal of defense-related HLW/SNF in a facility separate from commercially generated waste. A deep geologic repository for the disposal of DOE-managed HLW, and some thermally cooler DOE-managed SNF, arising from defense and DOE R and D activities, is part of a stepwise, phased approach for disposal of the Nation's nuclear waste, as recommended by the Blue Ribbon Commission on America's Nuclear Future. The work discussed here focuses on post-closure safety (or performance) assessment for such a Defense Waste Repository (DWR), which is divided into four major activities: (1) development of generic reference cases (i.e., knowledge or technical bases for 'generic' or 'non-site-specific' deep geologic repositories); (2) features, events, and processes (FEPs) analyses and screening to support the technical bases and the performance assessment (PA) model; (3) performance evaluation of alternative EBS design concepts; and (4) post-closure safety analyses of the repository system under consideration. Using the known inventory of defense-related SNF, as well as defense-related HLW stored at the Savannah River and Hanford sites, the Geologic Disposal Safety Assessment (GDSA) Framework modeling and software system has been applied to simulate the potential performance of a DWR in crystalline host rock, resulting in a suite of single-realization (i.e., deterministic) and multi-realization (i.e., probabilistic) 3-D post-closure system analyses, over a performance period of one million years. Two types of emplacement concepts are examined, including single-canister vertical-borehole emplacement for the hotter defense SNF waste (KBS-3V concept) and multi-canister horizontal emplacement for defense HLW (similar to Yucca Mountain co-disposal waste packages). Sensitivity analyses examine the effect of key uncertain parameters on repository performance, including the effects of fracture distribution, waste package degradation rate, buffer and disturbed rock zone (DRZ) properties, and sorption parameters. Initial results indicate that a crystalline host rock with a connected fracture system may require additional safety features to ensure robustness of the isolation safety function, such as a deep unsaturated zone, a sufficiently thick sedimentary overburden, and/or a disposal overpack with a very slow corrosion rate. None of these should pose an undue obstacle for successful disposal. (authors)

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Performance assessment modeling of a generic SNF/HLW repository in salt with coupled thermal-hydrologic effects - 15423

This paper describes advances in performance assessment modeling of deep geologic repositories facilitated by a massively parallel, high-performance computing (HPC) environment. Our new Generic Disposal System Analysis (GDSA) Framework utilizes the massively parallel PFLOTRAN multi-physics code to simulate repository performance in the presence of coupled thermal-hydrologic-chemical processes, linked to DAKOTA, an HPC uncertainty sampling and propagation code that provides nested parallelism for multi-realization performance assessment and sensitivity analysis. This enhanced performance assessment (PA) modeling capability is demonstrated with deterministic and probabilistic simulations of a generic repository for SNF and HLW in bedded salt host rock, by comparing repository performance between a case with heat-generating waste ('thermal' case) and a case without heat generation ('isothermal' case). The simulation results provide preliminary insights into the effect of multi-physics processes and thermal-hydrologic coupling on the long-term behavior of a reference-case salt repository. (authors)

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U.S. Senate Bill S.854-IS - A Maladjusted Politicized Maze for Consent-Based Siting of New HLW-Repositories - 16019

At the end of 2015, the USA's HLW-disposal program had been on hold since 2010 pending the enactment of enabling legislation for one or both of: 1) The Yucca Mountain HLW repository; and/or 2) The law proposed in Senate Bill S.854-IS 'to establish a new organization to manage nuclear waste, provide a consensual process for siting nuclear waste facilities, ensure adequate funding for managing nuclear waste, and for other purposes'. But, S.854-IS does not acknowledge the existence of the Yucca Mountain HLW repository, which, if re-enabled, would affect both when another HLW repository would be needed and its disposal capacity. Furthermore, it neither timely nor meaningfully integrates waste generators, facility-host(s) and other directly affected parties with the new 'implementing' organizations deemed to be more susceptible to political influence and interferences than those plaguing the Yucca Mountain HLW repository program since 1987 that resulted in a multitude of contentions, lawsuits, delays, and increased costs. For these and other reasons very compelling and conclusive to the author, the legal status of the YM HLW repository should be 'definitive' before a law based upon S.854-IS is enacted. Instead, the near-term focus should be on: 1. Defining 'consent-based' quantitatively. 2. Promptly siting and opening at least one large, expandable, 'consolidated' HLW-storage facility allowing the government to begin taking title to commercially-generated HLW; most-expeditiously accomplished by amending existing legislation. 3. Updating S.854-IS based on lessons learned about siting, developing, and licensing nuclear-waste-storage and -disposal facilities in the USA and abroad the past 30+ years. (authors)

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Assessment of the potential for criticality in the far field of a used nuclear fuel repository

This study aims to assess the likelihood for criticality in the far field of a repository for direct disposal of commercial light water reactor used nuclear fuel. Two models are used in combination: (1) a neutronics model to estimate the minimum critical masses of spherical, water-saturated depositions of fissile material; (2) a transport model to simulate the dissolution of waste packages arranged in an array and the subsequent transport of fissile solutes through fractured bedrock to a single accumulation location. The neutronics model shows that heavy metals from different types of used fuel present the same minimum critical mass behavior in the parameter space of initial enrichment and burnup, dictated largely by the fissile content. However, the magnitude of the minimum critical mass varies significantly within that parameter space, and secondary effects like the presence of absorbing nuclides play a minor role. Here, the transport model employs various subsurface transport scenarios, and for each scenario the mass of each isotope and the overall fissile content of the accumulation is reported from the time of canister failure up to one hundred million years at various distances from the repository edge. Taking the results of the two models in concert, it is shown that even if the accumulation of a critical mass is possible under conservative conditions, these conditions are unlikely to be present in the vicinity of a carefully engineered repository. Based on the results of each model, recommendations for risk mitigation in terms of waste characteristics and repository design are given.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Autonomous Inspection of Geologic Repositories: Current State of the Art and Future Directions

Geological repositories for nuclear waste, including spent nuclear fuel, present a significant challenge for traditional International Atomic Energy Agency (IAEA) safeguards tools due to their inaccessibility and demanding operational conditions. The IAEA has been working closely with Member State organizations currently involved in repository construction and planning, including Euratom, the Finnish and Swedish regulatory authorities, and relevant facility operators. However, the verification challenge remains unsolved, and there persists an out- standing need for tools and approaches that will help the IAEA verify that no nuclear material is diverted from a repository environment. The challenge is also not static. Activities must encompass verification of the design, prior to and during the construction/operation phase, and post backfill. Throughout these various phases, it is imperative that the IAEA maintains a continuity of knowledge (CoK) of all material including information on material inventory and flow. This paper highlights these challenges and outlines how they might be addressed by using remote or autonomous vehicles. Specifically, we discuss the current state of the art in robotic autonomy for known or partially known environment mapping and patrolling, as well as shared autonomy, where humans collaborate with closed loop autonomation to complete tasks. We explore the feasibility of using rovers for these verification tasks, along with the challenges associated with system implementation. Hardware and software suggestions are provided based on the adoption of similar technologies in other comparable areas and ability to close technical gaps. Lastly, human-robotic interactions are considered based on the challenges of the environment of the repository and effective deployment and continued operation of the robot system.

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Follow-On Status Report on FY2022 Model Development within the Integrated Energy Systems Hybrid Repository

This publication details newly created energy storage and reactor models developed within the HYBRID modeling repository as part of the Department of Energy Office of Nuclear Energy (DOE-NE) Integrated Energy Systems (IES) program, led by Idaho National Laboratory (INL). Model development to-date includes creation of dynamic systems-level models of a pebble bed high temperature gas reactor (HTGR), compressed air energy storage (CAES), and Modelica standard library based two-tank sensible heat storage (SHS) in the IES-based HYBRID repository. Models are developed using the latest publicly available data and incorporate the possibility of control strategy inclusion for use with the existing IES modeling, analysis, and optimization toolset. Simulations showcase the abilities of each technology to flexibly operate in ways consistent with IES operation expectations. When these models are available, they can be utilized within different integrated energy park concepts to understand optimal system operation, control, and dispatching. Moreover, given the generic nature of the models, industrial partner technologies can be quickly added to the repository using the existing models as a basis. Additional dynamic models for thermal energy storage concepts can be developed and added to the HYBRID repository as needed.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Examining Autonomous Inspection of Geologic Repositories

Geological repositories for nuclear waste, including spent nuclear fuel, present a significant challenge for traditional International Atomic Energy Agency (IAEA) safeguards tools due to their inaccessibility and demanding operational conditions. The IAEA has been working closely with Member State organizations currently involved in repository construction and planning including Euratom, the Finnish and Swedish regulatory authorities, and relevant facility operators. However, the verification challenge remains unsolved, and there persists an out-standing need for tools and approaches that will help the IAEA verify that no nuclear material is diverted from a repository environment. The challenge is also not static as activities must encompass verification of the design prior to and during the construction/operation phase, and post backfill. Throughout these various phases, it is imperative that the IAEA maintains a continuity of knowledge (CoK) of all material, including information on material inventory and flow. This paper highlights these challenges and outlines how they might be addressed by using remote or autonomous vehicles. Specifically, it discusses the current state of the art in robotic autonomy for known or partially known environment mapping and patrolling, as well as shared autonomy, where humans collaborate with closed loop autonomation to complete tasks. The feasibility of using rovers for these verification tasks is explored, along with the challenges associated with system implementation. Hardware and software suggestions are provided based on the adoption of similar technologies in other comparable areas and ability to close technical gaps. Finally, human-robotic interactions are considered based on the challenges of the environment of the repository and effective deployment and continued operation of the robot system

autonomous monitoring↗

Portal and Repository for Information on Marine Renewable Energy (PRIMRE)

The Marine Renewable Energy (MRE) industry is in the early stages of development corresponding to low technology readiness levels (TRLs) where the ability of the MRE community (developers, researchers, academics, stakeholders, investors, and regulators) to work together to share knowledge, experience, and lessons learned is critical to the advancement of the entire MRE industry. Through collaboration on solving common problems, the MRE community has the potential to reduce cost and accelerate technology development. Currently, the US Department of Energy (US DOE) Water Power Technologies Office (WPTO) is addressing the challenge of storing, curating, and accessing MRE information by sponsoring development of MRE databases and information portals such as Tethys (https://tethys.pnnl.gov), OpenEI (https://openei.org), the MHK Data Repository (MHKDR, https://mhkdr.openei.org/), and a searchable MRE code catalog and open source code repository (MHKiT, currently under development), to name a few. These sites host scientific papers, news articles, reports, databases, open source codes, and stakeholder engagement information, but they are only a step towards facilitating global discovery and use. In short, there is an abundance of information available online, however it is located on many disparate sites and repositories that make the discovery of those data and information difficult. A DOE national laboratory team from the National Renewable Energy Laboratory (NREL), Pacific Northwest National Laboratory (PNNL), and Sandia National Laboratories (Sandia) is addressing the issues of data discoverability, shared knowledge, and interconnection of existing MRE databases and information portals. To meet the needs of the MRE community, as identified through multiple community outreach and engagement events, and described in this paper, the multi-lab team has developed an implementation plan for PRIMRE, the Portal and Repository for Information on Marine Renewable Energy. PRIMRE will provide broad access to information on engineering and technologies, resource characterization, device performance, and environmental effects of MRE projects. PRIMRE will facilitate the commercial development of the MRE industry by increasing the accessibility and discoverability of this information, integrating the databases and information portals described in this paper, and developing standards and guidelines. Providing consistent, easy access to information can help reduce duplication of effort and enable the MRE community to learn from past failures and build upon the successes of others to innovate and advance the commercialization of MRE technologies.

16 TIDAL AND WAVE POWER↗

Autonomous Monitoring of Nuclear Repositories: Current State of the Art and Future Directions

Geological repositories for nuclear waste, including spent nuclear fuel, present a significant challenge for traditional International Atomic Energy Agency (IAEA) safeguards tools due to their inaccessibility and demanding operational conditions. The IAEA has been working closely with Member State organizations currently involved in repository construction and planning, including Euratom, the Finnish and Swedish regulatory authorities, and relevant facility operators. However, the verification challenge remains unsolved, and there persists an out- standing need for tools and approaches that will help the IAEA verify that no nuclear material is diverted from a repository environment. The challenge is also not static. Activities must encompass verification of the design, prior to and during the construction/operation phase, and post backfill. Throughout these various phases, it is imperative that the IAEA maintains a continuity of knowledge (CoK) of all material including information on material inventory and flow. This paper highlights these challenges and outlines how they might be addressed by using remote or autonomous vehicles. Specifically, we discuss the current state of the art in robotic autonomy for known or partially known environment mapping and patrolling, as well as shared autonomy, where humans collaborate with closed-loop autonomation to complete tasks. We explore the feasibility of using rovers for these verification tasks, along with the challenges associated with system implementation. Hardware and software suggestions are provided based on the adoption of similar technologies in other comparable areas and ability to close technical gaps. Lastly, human-robotic interactions are considered based on the challenges of the environment of the repository and effective deployment and continued operation of the robot system.

geologic repository, safeguards, IAEA, Robotics↗

Challenges for monitoring and data analytics in a leadership public data repository

The availability and disposition of data has assumed increasing importance in large-scale computational science. Data repositories are evolving to meet new classes of requirements: compliance with government access guidelines, support for reproducibility of experimental results, and long-term availability of data products. The Constellation public data repository at the Oak Ridge Leadership Computing Facility faces these issues while being situated in one of the most productive data centers in the world. While monitoring and operational data analysis are ingrained in the operation of the OLCF’s large-scale high performance computing platforms, data repositories do not have this history of support. Problems faced by Constellation range from data size (over 7 petabytes in current holdings) to analytic complexity (detailed curation is both absolutely necessary for many data sets and absolutely impossible for humans to accomplish in any practical manner) to deployment environment (OLCF storage resources are oriented toward the needs of the compute platforms). In this paper we describe some of the challenges for collecting monitoring and analytic data from a leadership public data repository. We also discuss various strategies we are pursuing in order to address these challenges, from manual data collection to plans for introducing machine learning-based curatorial techniques.

Widener, Patrick [ORNL] (ORCID:0000000258820816)↗

Coupled THMC models for bentonite in an argillite repository for nuclear waste: Illitization and its effect on swelling stress under high temperature

Subsurface manipulations such as those expected from the disposal of heat-emanating radioactive waste in deep repositories can induce strongly coupled Thermal (T), hydrological (H), mechanical (M) and chemical (C) processes. Adequate coupled THMC models are highly desirable or even indispensable for performance assessment of such repositories, for examples for the analysis of bentonite-based engineered barrier system (EBS) surrounding the emplaced waste. In this study, we present coupled THMC model simulations of a generic nuclear waste repository in an argillite with a bentonite-based buffer. The objective is to evaluate the chemical changes in the EBS bentonite and their effect on mechanical behavior under high temperature, attempting to shed light on whether EBS bentonite can sustain temperatures higher than 100 °C without significant impact on barrier's performance. Two scenarios were simulated for comparison: a case in which the temperature near the waste canister peaks at 200 °C and a case in which the temperature at the same spot culminate with about 100 °C. Simulations for a generic case with Kunigel-VI bentonite as backfill and Opalinus Clay as host rock were conducted for 1000 years and reported in the previous study (Zheng et al., 2015). In this paper, simulations for 100,000 years have been done for two types of bentonite-based buffer materials: Kunigel-VI and FEBEX bentonite. This enables us to evaluate how different types of bentonite behave in terms of the illitization and its impact on swelling stress and whether we can generalize these results to support decision making. The simulations show the occurrence of illitization in the bentonite buffer and the enhancement of illitization under high temperature. However, FEBEX bentonite undergoes less illitization mainly due to the higher ion concentration in pore water and the lower content of K-feldspar in the bentonite mineral composition. Moreover, the reduction of swelling stress by chemical changes is more pronounced for Kunigel-VI bentonite than for FEBEX bentonite. Furthermore, the results of our model simulations suggest that an argillite repository with a bentonite-based EBS that is similar to FEBEX bentonite could sustain temperatures much higher than 100 °C as far as illitization concerns. Model results also reveal that illitization is stabilized after about 2000 years in bentonite near the waste package, but continues in bentonite near the bentonite-argillite interface, which manifests the strong effect of geochemical interaction between EBS bentonite and host rock on long term illitization in bentonite.

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Enabling pan-repository reanalysis for big data science of public metabolomics data

Public untargeted metabolomics data is a growing resource for metabolite and phenotype discovery; however, accessing and utilizing these data across repositories pose significant challenges. Therefore, here we develop pan-repository universal identifiers and harmonized cross-repository metadata. This ecosystem facilitates discovery by integrating diverse data sources from public repositories including MetaboLights, Metabolomics Workbench, and GNPS/MassIVE. Our approach simplified data handling and unlocks previously inaccessible reanalysis workflows, fostering unmatched research opportunities.

El Abiead, Yasin↗

Evaluation on radiation protection aspect and radiological risk at Mukim Belanja repository

Asian Rare Earth (ARE) is a locally incorporated company that operated a mineral processing operation to extract rare earth element. ARE has received much attention from the public since the beginning of their operation until the work of decommissioning and decontamination of the plant. Due to the existence of Naturally Occurring Radioactive Material (NORM) in the residue, the decommissioning and disposal was done by the company in collaboration with the Perak State Government and the Atomic Energy Licensing Board (AELB). The main objective of this study is to review the level of compliance of the existing Radiation Protection Regulations enforced by AELB particularly in the achievement of allowed exposure dose limit. The next objective was to study the impact of the construction of the Mukim Belanja Repository to workers and public. This study was conducted by analyzing documents that were issued and conducting the area monitoring using a Geiger Muller detector (GM) and Sodium Iodide (NaI(Tl)) survey meters. The measurements were made at 5 cm and 1 m from the ground surface at 27 measurement stations. The external doses measured were within the background levels of the surrounding area. The annual effective dose using the highest reading at 5 cm and 1 m from ground surface by GM detector was calculated to be 1.36 mSv/year and 1.21 mSv/year respectively. Whereas the annual effective dose using the highest reading at 5 cm and 1 m from ground surface by using NaI(Tl) detector was calculated to be 3.31 mSv/year and 2.83 mSv/year respectively. The calculated cancer risks from the study showed that the risk is small compared with the risks derived from natural radiation based on global annual radiation dose to humans. This study therefore indicated that the repository is able to constrain the dose exposure from the disposed NORM waste. The study also revealed that the construction of the repository has complied with all the rules and regulations subjected to it. The exposed dose received by the radiation and the public workers during the construction of the repository were below the annual limit i.e. 20 mSv/year and 1mSv/year respectively.

61 RADIATION PROTECTION AND DOSIMETRY↗

Geological criteria for site selection of an LILW radioactive waste repository in the Philippines

In the selection of sites for disposal facilities involving low- and intermediate-level radioactive waste (LILW), International Atomic Energy Agency (IAEA) recommendations require that 'the region in which the site is located shall be such that significant tectonic and surface processes are not expected to occur with an intensity that would compromise the required isolation capability of the repository'. Evaluating the appropriateness of a site therefore requires a deep understanding of the geological and tectonic setting of the area. The Philippines sits in a tectonically active region frequented by earthquakes and volcanic activity. Its highly variable morphology coupled with its location along the typhoon corridor in the west Pacific region subjects the country to surface processes often manifested in the form of landslides. The Philippine LILW near surface repository project site is located on the north eastern sector of the Island of Luzon in northern Philippines. This island is surrounded by active subduction trenches; to the east by the East Luzon Trough and to the west by the Manila Trench. The island is also traversed by several branches of the Philippine Fault System. The Philippine LILW repository project is located more than 100 km away from any of these major active fault systems. In the near field, the project site is located less than 10 km from a minor fault (Dummon River Fault) and more than 40 km away from a volcanic edifice (Mt. Caguas). This paper presents an analysis of the potential hazards that these active tectonic features may pose to the project site. The assessment of such geologic hazards is imperative in the characterization of the site and a crucial input in the design and safety assessment of the repository. (authors)

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Preliminary safety evaluation of an aircraft impact on a near-surface radioactive waste repository

The aircraft impact accident has become very significant in the design of a nuclear facilities, particularly, after the tragic September 2001 event, that raised the public concern about the potential damaging effects that the impact of a large civilian airplane could bring in safety relevant structures. The aim of this study is therefore to preliminarily evaluate the global response and the structural effects induced by the impact of a military or commercial airplane (actually considered as a 'beyond design basis' event) into a near surface radioactive waste (RWs) disposal facility. The safety evaluation was carried out according to the International safety and design guidelines and in agreement with the stress tests requirements for the security track. To achieve the purpose, a lay out and a scheme of a possible near surface repository, like for example those of the El Cabril one, were taken into account. In order to preliminarily perform a reliable analysis of such a large-scale structure and to determine the structural effects induced by such a types of impulsive loads, a realistic, but still operable, numerical model with suitable materials characteristics was implemented by means of FEM codes. In the carried out structural analyses, the RWs repository was considered a 'robust' target, due to its thicker walls and main constitutive materials (steel and reinforced concrete). In addition to adequately represent the dynamic response of repository under crashing, relevant physical phenomena (i.e. penetration, spalling, etc.) were simulated and analysed. The preliminary assessment of the effects induced by the dynamic/impulsive loads allowed generally to verify the residual strength capability of the repository considered. The obtained preliminary results highlighted a remarkable potential to withstand the impact of military/large commercial aircraft, even in presence of ongoing concrete progressive failure (some penetration and spalling of the concrete wall) of the impacted area. (authors)

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Citing a Data Repository: A Case Study of the Protein Data Bank

The Protein Data Bank (PDB) is the worldwide repository of 3D structures of proteins, nucleic acids and complex assemblies. The PDB’s large corpus of data (> 100,000 structures) and related citations provide a well-organized and extensive test set for developing and understanding data citation and access metrics. In this paper, we present a systematic investigation of how authors cite PDB as a data repository. We describe a novel metric based on information cascade constructed by exploring the citation network to measure influence between competing works and apply that to analyze different data citation practices to PDB. Based on this new metric, we found that the original publication of RCSB PDB in the year 2000 continues to attract most citations though many follow-up updates were published. None of these follow-up publications by members of the wwPDB organization can compete with the original publication in terms of citations and influence. Meanwhile, authors increasingly choose to use URLs of PDB in the text instead of citing PDB papers, leading to disruption of the growth of the literature citations. A comparison of data usage statistics and paper citations shows that PDB Web access is highly correlated with URL mentions in the text. The results reveal the trend of how authors cite a biomedical data repository and may provide useful insight of how to measure the impact of a data repository.

59 BASIC BIOLOGICAL SCIENCES↗

Coupling of Nuclear Waste Form Corrosion and Radionuclide Transports in Presence of Relevant Repository Sediments

Assessments of waste form and disposal options start with the degradation of the waste forms and consequent mobilization of radionuclides. Long-term static tests, single-pass flow-through tests, and the pressurized unsaturated flow test are often employed to study the durability of potential waste forms and to help create models that predict their durability throughout the lifespan of the disposal site. These tests involve the corrosion of the material in the presence of various leachants, with different experimental designs yielding desired information about the behavior of the material. Though these tests have proved instrumental in elucidating various mechanisms responsible for material corrosion, the chemical environment to which the material is subject is often not representative of a potential radioactive waste repository where factors such as pH and leachant composition will be controlled by the near-field environment. Near-field materials include, but are not limited to, the original engineered barriers, their resulting corrosion products, backfill materials, and the natural host rock. For an accurate performance assessment of a nuclear waste repository, realistic waste corrosion experimental data ought to be modeled to allow for a better understanding of waste form corrosion mechanisms and the effect of immediate geochemical environment on these mechanisms. Additionally, the migration of radionuclides in the resulting chemical environment during and after waste form corrosion must be quantified and mechanisms responsible for migrations understood. The goal of this research was to understand the mechanisms responsible for waste form corrosion in the presence of relevant repository sediments to allow for accurate radionuclide migration quantifications. The rationale for this work is that a better understanding of waste form corrosion in relevant systems will enable increased reliance on waste form performance in repository environments and potentially decrease the need for expensive engineered barriers.Our current work aims are 1) quantifying and understanding the processes associated with glass alteration in contact with Fe-bearing materials; 2) quantifying and understanding the processes associated with glass alteration in presence of MgO (example of engineered barrier used in WIPP); 3) identifying glass alteration suppressants and the processes involved to reach glass alteration suppression; 4) quantifying and understanding the processes associated with Saltstone and Cast Stone (SRS and Hanford cementitious waste forms) in various representative groundwaters; 5) investigating positron annihilation as a new tool for the study of glass alteration; and 6) quantifying and understanding the processes associated with glass alteration under gamma irradiation.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗