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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

A Unified Mechanism on the Formation of Acenes, Helicenes, and Phenacenes in the Gas Phase

A unified low-temperature reaction mechanism on the formation of acenes, phenacenes, and helicenes—polycyclic aromatic hydrocarbons (PAHs) that are distinct via the linear, zigzag, and ortho-condensed arrangements of fused benzene rings—is illustrated. This mechanism is mediated through a barrierless, vinylacetylene mediated gas-phase chemistry utilizing tetracene, [4]phenacene, and [4]helicene as benchmarks contesting established ideas that molecular mass growth processes to PAHs transpire at elevated temperatures. This mechanism opens up an isomer-selective route to aromatic structures involving submerged reaction barriers, resonantly stabilized free-radical intermediates, and systematic ring annulation potentially yielding molecular wires along with racemic mixtures of helicenes in deep space. Thus, connecting helicene templates to the Origins of Life ultimately changes our hypothesis on interstellar carbon chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

A Free-Radical Prompted Barrierless Gas-Phase Synthesis of Pentacene

A representative, low-temperature gas-phase reaction mechanism synthesizing polyacenes via ring annulation exemplified by the formation of pentacene (C 22 H 14 ) along with its benzo[ a ]tetracene isomer (C 22 H 14 ) is unraveled by probing the elementary reaction of the 2-tetracenyl radical (C 18 H 11 . ) with vinylacetylene (C 4 H 4 ). The pathway to pentacene—a prototype polyacene and a fundamental molecular building block in graphenes, fullerenes, and carbon nanotubes—is facilitated by a barrierless, vinylacetylene mediated gas-phase process thus disputing conventional hypotheses that synthesis of polycyclic aromatic hydrocarbons (PAHs) solely proceeds at elevated temperatures. This low-temperature pathway can launch isomer-selective routes to aromatic structures through submerged reaction barriers, resonantly stabilized free-radical intermediates, and methodical ring annulation in deep space eventually changing our perception about the chemistry of carbon in our universe.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Covariance generation for the prompt neutron multiplicity of 239 Pu including the (n, γ f) process

Fission cross section of 239 Pu can be seen as a sum of the “immediate" fission and “two-step" (n,γf) reactions. In the Resolved Resonance Range of the reaction cross sections, the contribution of the (n,γf) process has an impact on the determination of the partial widths magnitude involved in the Reich-Moore approximation of the R-matrix theory. The present work aims to investigate this impact by using the CONRAD code and the partial width Γ γf for the (n,γf) reaction calculated by Lynn et al. A special attention will be paid to the covariance matrix obtained on ν p .

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

Aqueous harvesting of 88 Zr at a radioactive-ion-beam facility for cross-section measurements

Isotope harvesting is a method of collecting the long-lived radioisotopes that build up during the operation of ion-beam facilities in a way that is useful for subsequent research. As a demonstration of this method for the collection of a group IV metal at a fragmentation facility, the high-energy Zr 88 secondary beam produced from a 140-MeV/u Mo 92 primary beam at the National Superconducting Cyclotron Laboratory (NSCL) was stopped in a water target. The setup aimed to mimic the aqueous beam dump that will be implemented at the Facility for Rare Isotope Beams (FRIB). The collected Zr 88 and accompanying Y 88 decay daughter were radiochemically extracted from the solution and made into target samples suitable for neutron-capture cross-section measurements. These samples were then irradiated at two reactor facilities, and the Zr 88 average thermal-neutron-capture cross section ( σ T ) and resonance integral ( I ) were determined to be σ T = ( 8.04 ± 0.63 ) × 10 5 b and I = ( 2.53 ± 0.28 ) × 10 6 b. The σ T value agrees well with previous results and I , determined for the first time here, was found to be the largest measured resonance integral by two orders of magnitude. The Y 88 thermal-neutron-capture cross section was determined to be less than 1.8 × 10 4 b. This work demonstrates the steps needed to make cross-section measurements with samples produced via aqueous isotope harvesting.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗
DOE OSTI2021

Properties of isoscalar giant multipole resonances in medium-heavy closed-shell nuclei: A semimicroscopic description

The semimicroscopic particle-hole dispersive optical model (PHDOM) is implemented to describe main properties of Isoscalar Giant Multipole Resonances (up to L=3) in medium-heavy closed-shell nuclei. Here, the main properties are characterized by the strength distribution, transition density, partial and total probabilities of direct one-nucleon decay. Calculation results obtained for the 208 Pb nucleus are compared with available experimental data.

190 ≤ A ≤ 219↗
DOE OSTI2023

Semimicroscopic description of isoscalar giant multipole resonances in medium-mass closed-shell nuclei

Main properties of isoscalar giant multipole resonances (up to L=3), including L=0,and 2 overtones, in medium-mass closed-shell nuclei are described within the semimicroscopic particle-hole dispersive optical model. Further, main properties are characterized by the energy-averaged strength distribution, projected (one-body) transition density, and probabilities of direct one-nucleon decay. Calculation results obtained for characteristics of the mentioned resonances in the 48 Ca, 90 Zr, and 132 Sn nuclei are compared with available experimental data.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

Complex scaling in finite volume

Quantum resonances, i.e., metastable states with a finite lifetime, play an important role in nuclear physics and other domains. Describing this phenomenon theoretically is generally a challenging task. In this work, we combine two established techniques to address this challenge. Complex scaling makes it possible to calculate resonances with bound-state-like methods. Finite-volume simulations exploit the fact that the infinite-volume properties of quantum systems are encoded in how discrete energy levels change as one varies the size of the volume. Herein we apply complex scaling to systems in finite periodic boxes and derive the volume dependence of states in this scenario, demonstrating with explicit examples how one can use these relations to infer infinite-volume resonance energies and lifetimes.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

Investigation of post-breakup Coulomb acceleration using a trajectory model

Intermediate mass fragments ejected during the deexcitation of excited projectilelike fragments may promptly decay following ejection; the daughter particles that are subsequently produced are subject to interactions with the residual nucleus that affect final-state observables, a process herein referred to as post-breakup Coulomb acceleration. A simple classical Coulomb interaction model was used to study modification of 8 Be (2 + ), 5 Li (3/2 – ), 7 Li (7/2 – ), 7 Be (7/2 – ), and states in 12 B emitted following heavy-ion collisions of 28 Si + 12 C at 35 MeV/nucleon. Here, in contrast to previous work studying 8 Be (2 + ), excellent agreement between simulation and experiment was obtained using only Coulomb forces when either a Lorentzian or R-matrix line shape was used to describe the initial relative energy rather than a Gaussian. In consideration of the obtained results, improvements to the model and evaluation of experimental data are discussed as future directions, but it was concluded that the effects observed in the present data can be accurately described using only elements of classical mechanics and that the process is largely understood for a wide range of state lifetimes and mass and charge (a)symmetries.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1973

The depth distribution of hydrogen in lunar materials.

A technique employing the resonant nuclear reaction H-1(F-19, alpha gamma)O-16 has been used to measure hydrogen concentration versus depth in selected coarse fine fragments from the Apollo 11 and Apollo 15 missions, and in glass coated surface chips from two Apollo 15 rocks. The highly variable hydrogen content in the coarse fine fragments is concentrated mainly in a layer extending from the surface to a depth of 2000 plus or minus 500 A. The hydrogen content of the surface region of the Apollo 15 rock chips is comparable to that of the coarse fine samples, but is concentrated mainly within a few hundred angstroms of the surface. The hydrogen depth distribution in a piece of platinum foil from the Apollo 16 Lunar surface Cosmic Ray Experiment was also measured in an attempt to place a limit on the flux of 10- to 40-keV protons associated with a solar flare event.

Leich, D. A.↗
NASA NTRS1974

Quantitative multielement analysis using high energy particle bombardment

Charged particles ranging in energy from 0.8 to 4.0 MeV are used to induce resonant nuclear reactions, Coulomb excitation (gamma X-rays), and X-ray emission in both thick and thin targets. Quantitative analysis is possible for elements from Li to Pb in complex environmental samples, although the matrix can severely reduce the sensitivity. It is necessary to use a comparator technique for the gamma-rays, while for X-rays an internal standard can be used. A USGS standard rock is analyzed for a total of 28 elements. Water samples can be analyzed either by nebulizing the sample doped with Cs or Y onto a thin formvar film or by extracting the sample (with or without an internal standard) onto ion exchange resin which is pressed into a pellet.

Clark, P. J.↗
NASA NTRS1975

Quantitative multielement analysis using high energy particle bombardment

Charged particles ranging in energy from 0.8 to 4.0 MeV are used to induce resonant nuclear reactions, Coulomb excitation (gamma-rays), and X-ray emission in both thick and thin targets. Quantitative analysis is possible for elements from Li to Pb in complex environmental samples, although the matrix can severely reduce the sensitivity. It is necessary to use a comparator technique for the gamma-rays while for X-rays an internal standard can be used. A USGS standard rock is analyzed for a total of 28 elements. Water samples can be analyzed either by nebulizing the sample doped with Cs or Y a thin Formvar film or by extracting the sample onto ion exchange resin which is pressed into a pellet.

Clark, P. J.↗
NASA NTRS1977

Fluorine in meteorites

Microanalysis using a resonant nuclear reaction was used to measure F concentrations in USGS standard rocks and 21 meteorites. The F appears to be a moderately depleted element, but there were significant variations within each sample. Measurements on separated metal phases suggest that about 20% of meteoritic F is in the metal or in a phase closely associated with it. Simultaneous measurements of F, Mg, Na, Al and Si in the nonmagnetic fractions of meteorites suggest plagioclase as a F containing phase.

Allen, R. O., Jr.↗
NASA NTRS1976

Fluorine as a constituent in lunar magmatic gases

Fluorine surface deposits on Apollo 15 green glass, Apollo 17 orange glass, and on vesicle linings from Apollo 15 basalts were studied by a resonant nuclear reaction technique. Surface layers of about 10 to the 15th F atoms/sq cm were observed on unbroken spheroidal glass surfaces, whereas thinner (about 10 to the 14th atoms/sq cm) deposits were found on the vesicle linings.

Goldberg, R. H.↗
DOE OSTI2021

Evaluation of alkali–silica reaction damage in concrete using linear and nonlinear resonance techniques

Here in this study, the initiation and development of alkali–silica reaction (ASR) in concrete prisms containing reactive coarse (RCA) and reactive fine (RFA) aggregates were monitored over one year using linear and nonlinear resonance techniques. Although the linear resonance test could detect initiation and development of ASR damage in RCA specimens, it failed in the RFA specimens. Petrographic analysis confirmed the presence of early-stage ASR damage and the presence of different microcracking patterns in the RFA and RCA specimens, which may explain differences in the linear resonance data. For both RCA and RFA specimens, the nonlinear resonance test results were able to detect the initiation of ASR damage and showed a strong correlation with the ASR expansion for all specimens from different mix designs. The results demonstrate the high sensitivity of the nonlinear resonance test and its potential for quantitative evaluation of the ASR damage state of concrete specimens without a baseline measurement.

36 MATERIALS SCIENCE↗