Positive and negative ion-molecule reactions and the proton affinity of ethyl nitrate
Ethyl nitrate positive and negative ion-molecule chemistry investigated by ion cyclotron single/ double resonance techniques
Buttrill, S. E., Jr.↗
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Blood velocity measurements in intact subjects
Intact human forearms venous blood velocity measurements, using nuclear magnetic resonance techniques
Morse, O. C.↗
Ordering of V/2 plus/, Mn/2 plus/, and Fe/3 plus/ ions in zoisite, Ca2Al3Si3O12/OH/
Manganese, iron and vanadium ion ordering in orthorhombic zoisite structure by electron paramagnetic resonance technique
Ghose, S.↗
Thermomechanical and Thermochemical Behavior of a Hafnium-20 Percent Tantalum Alloy
An investigation was conducted to determine the thermomechanical and thermochemical behavior of a high temperature, oxidation resistant, hafnium-20 percent tantalum alloy. The elastic and shear moduli of this alloy were determined in air up to 1000 C and in vacuum up to 2000 C using a mechanical resonance technique. The internal friction of the alloy was measured up to temperatures greater than 1400 C. Room temperature stress-strain behavior of the oxidized and unoxidized alloy was established. The effect of annealing on the elastic and shear moduli of the extruded rod material was investigated. The martensitic-type phase transformation occurring in the alloy was studied using hot stage metallography and electron microscopy. Static oxidation tests were conducted on the alloy at temperatures from 1000 C to 1700 C with weight gain measurements made as a function of time and temperatures. Surface morphology studies were conducted on the oxide coatings formed at the different temperatures using scanning electron microscopy and X-ray diffraction techniques.
Howell, J. P.↗
Remote double resonance coupling of radar energy to ionospheric irregularities
Experimental results indicate that low frequency modulation of a high power radar beam, tuned to one of the critical frequencies of the ionosphere, may produce field-aligned density irregularities when the modulation frequency matches an ionospheric eigenfrequency. By choosing the radar carrier frequency and polarization, a number of interaction layers were selected. The variety of possible excitations shows that the double resonance technique may be adaptable to a number of different objectives.
Kennel, C. F.↗
Concerning the production of free radicals in proteins by ultraviolet light.
The response to UV light of several solid proteins and model compounds has been studied in vacuum and at low temperature, using electron paramagnetic resonance techniques. The results indicate that the details of amino acid composition and sequence, and the tertiary structure of a protein are important in determining both the rate of, and the mechanism for, the production of free radicals, and in determining the conditions under which sulfur-type radicals can be produced. The results presented are related to enzyme inactivation and to the UV stability of proteins generally.
Androes, G. M.↗
Passivation of pigment particles for thermal control coatings
Various redox couple surface additives are studied which increase the photostability of coprecipitated zinc orthotitanate pigment. The electron spin resonance technique was used to examine the characteristic photodamage centers. Results indicate that cerium surface redox additive completely passivates the pigment at the surface concentrations studied. Less passivation occurs with the iridium chloride and the iron cyanide redox couples.
Sancier, K. M.↗
Molecular correlations with fracture in fibers and granular-filled composites
Results are presented for an experimental electron spin resonance study of chain-scission kinetics in oriented nylon fibers and in granular-filled elastomer composites. A reaction-rate molecular model is proposed as a tool to predict failure under various loadings. The model assumes a statistical distribution in stress on the polymeric chain structure. Interfacial failure in the filled composites is examined. Failure at the interface between the filler and the matrix may be largely adhesive or cohesive, depending on the magnitude of the interactive forces. It appears that the mechanical behavior of both single-component and filled composites depends on the composite nature of the structure. The electron spin resonance technique is shown to be suitable for experimental observation of phenomena directly related to atomic occurrences.
Devries, K. L.↗
Measurement and significance of the equilibrium reaction C-13/+/ + /C-12/O yields C-12/+/ + /C-13/O for alteration of the C-13/C-12 ratio in interstellar molecules
Laboratory measurements using the ion-cyclotron resonance technique yield a rate constant of 2 by 10 to the -10th power cu cm/sec at 300 K for the isotope exchange C-13(+) + (C-12)O yields C-12(+) + (C-13)O. According to the usual ideas about ion-molecule reactions, this rate constant should also be appropriate at temperatures not exceeding about 100 K. Then the observed C-13/C-12 ratio obtained from radio observation of interstellar molecules may be either larger or smaller than the actual value in the interstellar medium by factors of 2 or so. If the ratio is altered from the actual interstellar value, it will not be the same in all molecules, and CO will tend to have the highest value. The chief astronomical uncertainty for the occurrence of this isotope fractionation is the abundance of 'unobservable' molecules which can react rapidly with C(+): e.g., O2, H2O, CO2, and CH4. If their abundance is greater than about one-tenth that of CO, the isotope fractionation will be inhibited.
Watson, W. D.↗
Flight-control/navigation inertial reference system
The preliminary design of a redundant strapdown navigation system for integrated flight-control/navigation use has been completed. Based on application of tuned-gimbal gyros, a compact configuration (13 in x 13 in x 14 in) has been achieved for fail-operational/fail-operational redundancy. Test data are presented for strapdown system test programs including flight testing of the LN-50 tuned-gimbal gyro system. Testing of a redundant sensor configuration is currently in process. Strapdown gyro development also includes ring laser and nuclear magnetic resonance techniques.
Ebner, R. E.↗
An ICR study of an association reaction at low pressure
The reactions of the gaseous ion CH3+ with HCN are investigated, using the ion cyclotron resonance technique. The pressure range of the experiment was 1 x 10 to the -6 to 3 x 10 to the -4 Torr with a rate coefficient of 2 x 10 to the -10 cu cm/sec. Good agreement was found between rate coefficients determined in the trapping mode at the low end of the pressure range and the drift mode at the high end of the pressure range. It is shown that the association reaction of CH3 with HCN follows second order kinetics throughout the entire pressure range of the experiment. The reaction is interpreted in terms of both a saturated three-body and a radiative association mechanism. Some explanations for the disagreement of the rate coefficient with that reported previously are also given.
Mcewan, M. J.↗
An ICR investigation of ion-molecule reactions of HCN
Laboratory reaction rates and product distributions measured by the ion cyclotron resonance technique are reported for a series of reactions of HCN(+) ions with the neutral molecules HCN, CH4, NH3, H2O, CO, CO2, N2 and O2. Rate coefficients are also reported for reactions of positive ions derived from these molecules with HCN. A comparison of the results with a survey of literature values for rate coefficients of HCN(+) reactions shows some exothermic proton transfers from HCN(+) to be inefficient.
Mcewan, M. J.↗
Origins and size distribution of metallic iron particles in the lunar regolith
The metallic iron concentration has been measured in three ranges of metal particle diameters for 79 lunar soils by a combination of static magnetic and ferromagnetic resonance techniques. Based on these measurements, a model has been developed which apportions the total metallic iron content of lunar soils between three components: (1) metallic iron particles produced from the exposure-induced reduction of ferrous iron; they range from 40 to 330 A in diameter and are predominantly associated with agglutinate glass; (2) metallic iron particles derived from the metallic phases of the micrometeorites involved in the formation of agglutinate glass; these particles are mostly greater than 300 A in diameter; and (3) metallic iron particles in the source materials such as bedrock and breccias; these are usually greater than 330 A in diameter. The maximum concentration of metallic iron in lunar regolith is estimated at about 0.7 equiv. wt% in highland regions (approximately 5.0 wt% FeO) and about 1.0 equiv. wt% in mare regions (approximately 15.0 wt% FeO).
Morris, R. V.↗
Narrow 87Rb and 133Cs hyperfine transitions in evacuated wall-coated cells
An extension of work on wall-coated cells was made to include observation by a triple resonance technique of the 0-0 hyperfine transitions in 87Rb and 133Cs. Conventional RF excited lamps were used. Interest in such cells is for possible application in atomic clocks. The Rb cell would appear to remain especially promising in this respect.
Robinson, H. G.↗
An ICR study of ion-molecule reactions of PH(n)+ ions
The reactions of PH(n)+ ions (n = 0-3) were examined with a number of neutrals using ion-cyclotron-resonance techniques. The reactions examined have significance for the distribution of phosphorus in interstellar molecules. The results indicate that interstellar molecules containing the P-O bond are likely to be more abundant than those containing the P-H bond.
Thorne, L. R.↗
Binding constants of phenylalanine for the four mononucleotides
Earlier work has shown that several properties of amino acids correlate directly with properties of their anticodonic nucleotides. Furthermore, in precipitation studies with thermal proteinoids and homopolyribonucleotides, an anticodonic preference was displayed between Lys-rich, Pro-rich and Gly-rich thermal proteinoids and their anticodonic polyribonucleotides. However, Phe-rich thermal proteinoid displayed a preference for its codonic nucleotide, poly U. This inconsistency seemed to be explained by a folding in of the hydrophobic residues of Phe causing the proteinoid to appear more hydrophilic. The present work used nuclear magnetic resonance techniques to resolve a limited question: to which of the four nucleotides does Phe bind most strongly? The results show quite clearly that Phe binds most strongly to its anticodonic nucleotide, AMP.
Khaled, M. A.↗
Analysis of glow discharges for understanding the process of film formation
The physical and chemical processes which occur during the formation of different types of films in a variety of glow discharge plasmas are discussed. Emphasis is placed on plasma diagnostic experiments using spectroscopic methods, probe analysis, mass spectrometric sampling and magnetic resonance techniques which are well suited to investigate the neutral and ionized gas phase species as well as some aspects of plasma surface interactions. The results on metallic, semi-conducting and insulating films are reviewed in conjunction with proposed models and the problem encountered under film deposition conditions. It is concluded that the understanding of film deposition process requires additional experimental information on plasma surface interactions of free radicals and the synergetic effects where photon, electron and ion bombardment change the reactivity of the incident radical with the surface.
Venugopalan, M.↗
An approach to operating system testing
To ensure the reliability and performance of a new system, it must be verified or validated in some manner. Currently, testing is the only resonable technique available for doing this. Part of this testing process is the high level system test. System testing is considered with respect to operating systems and in particular UNIX. This consideration results in the development and presentation of a good method for performing the system test. The method includes derivations from the system specifications and ideas for management of the system testing project. Results of applying the method to the IBM System/9000 XENIX operating system test and the development of a UNIX test suite are presented.
Sum, R. N., Jr.↗