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At least 91 records · Page 5

NASA Tech Briefs, November 2007

Topics include: Wireless Measurement of Contact and Motion Between Contact Surfaces; Wireless Measurement of Rotation and Displacement Rate; Portable Microleak-Detection System; Free-to-Roll Testing of Airplane Models in Wind Tunnels; Cryogenic Shrouds for Testing Thermal-Insulation Panels; Optoelectronic System Measures Distances to Multiple Targets; Tachometers Derived From a Brushless DC Motor; Algorithm-Based Fault Tolerance for Numerical Subroutines; Computational Support for Technology- Investment Decisions; DSN Resource Scheduling; Distributed Operations Planning; Phase-Oriented Gear Systems; Freeze Tape Casting of Functionally Graded Porous Ceramics; Electrophoretic Deposition on Porous Non- Conductors; Two Devices for Removing Sludge From Bioreactor Wastewater; Portable Unit for Metabolic Analysis; Flash Diffusivity Technique Applied to Individual Fibers; System for Thermal Imaging of Hot Moving Objects; Large Solar-Rejection Filter; Improved Readout Scheme for SQUID-Based Thermometry; Error Rates and Channel Capacities in Multipulse PPM; Two Mathematical Models of Nonlinear Vibrations; Simpler Adaptive Selection of Golomb Power-of- Two Codes; VCO PLL Frequency Synthesizers for Spacecraft Transponders; Wide Tuning Capability for Spacecraft Transponders; Adaptive Deadband Synchronization for a Spacecraft Formation; Analysis of Performance of Stereoscopic-Vision Software; Estimating the Inertia Matrix of a Spacecraft; Spatial Coverage Planning for Exploration Robots; and Increasing the Life of a Xenon-Ion Spacecraft Thruster.

Source record↗

Portable Cathode-Air Vapor-Feed Electrochemical Medical Oxygen Concentrator (OC)

Missions on the International Space Station and future space exploration will present significant challenges to crew health care capabilities, particularly in the efficient utilization of onboard oxygen resources. Exploration vehicles will require lightweight, compact, and portable oxygen concentrators that can provide medical-grade oxygen from the ambient cabin air. Current pressure-swing adsorption OCs are heavy and bulky, require significant start-up periods, operate in narrow temperature ranges, and require a liquid water feed. Lynntech, Inc., has developed an electrochemical OC that operates with a cathode-air vapor feed, eliminating the need for a bulky onboard water supply. Lynntech's OC is smaller and lighter than conventional pressure-swing OCs, is capable of instant start-up, and operates over a temperature range of 5-80 C. Accomplished through a unique nanocomposite proton exchange membrane and catalyst technology, the unit delivers 4 standard liters per minute of humidified oxygen at 60 percent concentration. The technology enables both ambient-pressure operating devices for portable applications and pressurized (up to 3,600 psi) OC devices for stationary applications.

Balasubramanian, Ashwin↗

Virtual Power Plants and Distributed Energy Resource Management Systems

Virtual Power Plants (VPPs) are aggregations of DERs that can balance electrical loads and provide utility-scale and utility-grade grid services like a traditional power plant. This presentation covers VPP definition, State-of-the-Art, Grid Architectures, Example VPP studies, VPP Standards, and VPP Roadmap.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Reactor Fundamentals Handbook

The objective of the Knowledge Transfer Workshop is to transfer selected fundamental nuclear energy technology knowledge and experience to the nuclear industry’s next generation of leaders. The course provides the original bases for fundamental safety concepts, design features, and reactor technologies. The course discusses the “why” and the “how” for decisions that led to the current commercial nuclear reactor designs and regulatory framework. Various accidents and their attributes as well as other events that have strongly affected the evolution of the safety case, plant design, and operations are discussed. To prepare the course participant for the topics discussed, this handbook provides a crash course into the current state of commercialized Light Water Reactor technology. The material is introductory for the interested layperson and also serves as a refresher for scientists and engineers that may have studied Light Water Reactors at one time, but are currently not an expert in this field of nuclear engineering. This handbook is a brief tutorial and refresher training material on basic Light Water Reactor (LWR) core physics and plant systems. It is reference material for attendees of the Knowledge Transfer Workshop. There are two types of LWR technologies, Pressurized Water Reactor (PWR) and Boiling Water Reactors (BWR). This handbook discusses fundamental design traits of each providing contrasts between performance and safety features. The intent is to provide the participants with an understanding of nuclear terminology associated with LWR technology, including fundamentals, systems, safety, and regulations. This handbook is not an original textbook. Many authors have contributed collegiate level introduction to nuclear engineering texts. Rather, this material is intended to be a graded summary of important aspects of LWR reactor core and plant systems. It draws heavily on other resources. The interested reader is encouraged to follow citations made in this handbook to more thorough or detailed public references.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Solution of resource allocation problem for identification of cost-effective measures to reduce nuclear proliferation risks

This report presents a methodology of selection of cost-effective measures to reduce nuclear proliferation risks. The methodology relies on a graded security model used in practice in different applications. The method is based on the controlled finite Markov chain approach set in combination with discrete dynamic programming and MCDM (Multi Criteria Decision Making) techniques that enables the expert to select the cost-effective measures to reduce nuclear proliferation risks depending on availability of resources. The analysis performed with different number of possible measures confirms the conclusions that the implementation of extra-large costs may not produce the required effect, and the increase in resources above a certain level does not appear sensitive. Diversification in improving the effectiveness of other measures seems more rational and efficient for the whole system than the unlimited improvement of the effectiveness of only one measure.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Low-dose-rate Brachytherapy for Prostate Cancer in Low-resource Settings

Purpose: In areas with limited health care, it is important to identify and implement effective treatment methods and to optimize available resources. We investigated the implementation of a low-dose-rate (LDR) brachytherapy program for the treatment of prostate cancer (PCa) in a low-resource setting such as Puerto Rico (PR), where PCa is the main cause of cancer-associated death. Methods and Materials: After institutional approval, the medical records of patients with nonmetastatic PCa undergoing LDR brachytherapy from 2008 to 2013 were reviewed from PR. The factors analyzed included adequate D{sub 90} (radiation dose delivered to 90% of the target volume) coverage (≥140 Gy), early and late toxicity (Common Terminology Criteria for Adverse Events grade >2), and prostate-specific antigen failure. Freedom from biochemical failure was evaluated using Kaplan-Meier analysis. Results: The barriers to implementation of LDR brachytherapy in a country with limited resources were identified. These included lack of access to funding for startup costs, specific referral patterns, lack of trained support staff, such as dosimetrists and physicists, and initial opposition from insurance companies for reimbursement. The initial results from 191 patients were included in the present study with a median follow-up period of 26 months. Prostate-specific antigen failure occurred in 6 patients (3%). No early or late gastrointestinal toxicity (grade >2) developed. Only 3 (2%) and 2 (1%) patients experienced early and late genitourinary toxicity (grade >2), respectively. The 2- and 3-year freedom from biochemical failure in this population was 97% and 95.9%, respectively. Conclusions: At present, limited data are available delineating the barriers faced by low-resource settings in the implementation of LDR brachytherapy. Our data highlight the issues unique to this environment and support the use of LDR brachytherapy as a reliable and effective treatment modality for patients with PCa in low-resource settings.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

NASA Tech Briefs, December 2003

Topics covered include: Organic/Inorganic Hybrid Polymer/Clay Nanocomposites; Less-Toxic Coatings for Inhibiting Corrosion of Aluminum; Liquid Coatings for Reducing Corrosion of Steel in Concrete; Processable Polyimides Containing APB and Reactive End Caps; Rod/Coil Block Copolyimides for Ion-Conducting Membranes; Techniques for Characterizing Microwave Printed Antennas; Cylindrical Antenna With Partly Adaptive Phased-Array Feed; Command Interface ASIC - Analog Interface ASIC Chip Set; Predicting Accumulations of Ice on Aerodynamic Surfaces; Analyzing Aeroelasticity in Turbomachines; Software for Allocating Resources in the Deep Space Network; Expert Seeker; High-Speed Recording of Test Data on Hard Disks; Functionally Graded Nanophase Beryllium/Carbon Composites; Thin Thermal-Insulation Blankets for Very High Temperatures; Aerostructures Test Wing; Flight-Test Evaluation of Flutter-Prediction Methods; Piezoelectrically Actuated Microvalve for Liquid Effluents; Larger-Stroke Piezoelectrically Actuated Microvalve; Innovative, High-Pressure, Cryogenic Control Valve: Short Face-to-Face, Reduced Cost; Safer Roadside Crash Walls Would Limit Deceleration; Improved Interactive Medical-Imaging System; Scanning Microscopes Using X Rays and Microchannels; Slotting Fins of Heat Exchangers to Provide Thermal Breaks; Methane Clathrate Hydrate Prospecting; Automated Monitoring with a BSP Fault-Detection Test; Automated Monitoring with a BCP Fault-Decision Test; Vector-Ordering Filter Procedure for Data Reduction; Remote Sensing and Information Technology for Large Farms; Developments at the Advanced Design Technologies Testbed; Spore-Forming Bacteria that Resist Sterilization; and Acoustical Applications of the HHT Method.

Source record↗

Physics is Fun

This document is a potential resource for teachers and outlines a series of activities and experiments that introduce concepts in physics and astronomy, to students grades 1-6.

79 ASTRONOMY AND ASTROPHYSICS↗

Discovering Blind Geothermal Systems in the Great Basin Region: An Integrated Geologic and Geophysical Approach for Establishing Geothermal Play Fairways: All Phases

Most geothermal resources in the Great Basin region of the western USA are blind, and thus the discovery of new commercial-grade systems requires synthesis of favorable characteristics for geothermal activity. The geothermal play fairway concept involves integration of multiple parameters indicative of geothermal activity to identify promising areas for new development. This project integrated multiple datasets to apply the play fairway concept and assess geothermal potential in a large region of the Great Basin in Nevada. It is therefore referred to as the Nevada play fairway project. This project was a strong collaborative effort between several organizations, led by the Nevada Bureau of Mines and Geology at the University of Nevada, Reno, but with key support from the U.S. Geological Survey, ATLAS Geosciences, Inc,, Hi-Q Geophysical, Inc., Lawrence Berkeley National Laboratory, Utah Geological Survey, and Innovative Geothermal Ltd. In Budget Period 1 of this project, available data for nine geologic, geochemical, and geophysical parameters were initially synthesized to produce a new detailed geothermal potential map of 96,000 km2 from west-central to eastern Nevada. These parameters were grouped into subsets and individually weighted to delineate rankings for local permeability, intermediate permeability, regional permeability, and thermal potential, which collectively defined geothermal play fairways (i.e., most likely locations for significant geothermal fluid flow). This initial work was aimed at reducing the risks in regional exploration and therefore facilitating discovery of new commercial-grade systems in blind settings, as well as in areas with surface expressions of geothermal activity. Budget Period 2 of the project involved detailed analysis of some of the most promising areas identified in Phase 1. Twenty-four highly prospective areas, including both known undeveloped systems and previously undiscovered potential blind systems, were identified for further analysis. After reconnaissance of these areas, five of the most promising sites were selected for detailed studies. Multiple techniques were employed in the detailed studies, including geologic mapping, shallow temperature surveys, gravity surveys, Lidar, geochemical studies, seismic reflection analysis, and 3D modeling. The goal of the detailed studies was to identify specific areas with the highest likelihood for high permeability and thermal fluids, such that drill sites could be targeted. Three main sets of predictive maps were generated for each detailed study area: 1) play fairway maps, 2) play fairway error maps, and 3) direct evidence maps. Local- and intermediate-scale permeability models were revised to reflect results of the detailed geologic, geophysical, and geochemical analyses. Budget Period 3 of the project involved more detailed geophysical analyses and temperature-gradient (TG) drilling in southeastern Gabbs Valley and northern Granite Springs Valley, deemed the two most promising sites, with the goal of providing preliminary validation of the play fairway methodology. In southeastern Gabbs Valley, the collocation of a favorable structural setting (displacement transfer zone and fault intersections), Quaternary faults, intersecting and terminating gravity gradients, magnetic low, shallow (2 m) temperature anomaly, low resistivity anomaly, and promising geothermometry from nearby water wells provided evidence for a blind system. Drilling of six TG holes defines an apparent geothermal system at this locality with temperatures as high as 124°C at 152 m. This system is blind, with no surface hot springs, fumaroles, or paleo-geothermal deposits. For northern Granite Springs Valley, a favorable structural setting (termination of a major Quaternary normal fault), terminating gravity gradient, magnetic gradient, newly discovered sinter deposits, nearby warm water wells, previously drilled TG holes in the vicinity, and promising geothermometry suggest a hidden system. Drilling of six new TG holes yields temperatures of ~96°C at ~250 m, suggesting the presence of a geothermal system. Major lessons learned in the course of this project include: 1) initially identified sites commonly include multiple favorable structural settings at a finer scale; 2) promising sites in Cenozoic basins cannot be recognized without detailed geophysical surveys; and 3) play fairway analysis should be refined as the exploration program vectors into the most promising sites and finer-scale data are acquired. In addition to producing copious amounts of data, this project resulted in 16 published papers, 10 abstracts, more than 40 presentations across the U.S. and abroad (including several keynote addresses), 2 Masters theses, and 7 media reports.

15 GEOTHERMAL ENERGY↗

Land use maps of the Tanana and Purcell Mountain areas, Alaska, based on Earth Resources Technology Satellite imagery

The author has identified the following significant results. ERTS imagery in photographic format was used to make land use maps of two areas of special interest to native corporations under terms of the Alaska Native Claims Settlement Act. Land selections are to be made in these areas, and the maps should facilitate decisions because of their comprehensive presentation of resource distribution information. The ERTS images enabled mapping broadly-defined land use classes in large areas in a comparatively short time. Some aerial photography was used to identify colors and shades of gray on the various images. The 14 mapped land use categories are identified according to the classification system under development by the U.S. Geological Survey. These maps exemplify a series of about a dozen diverse Alaskan areas. The principal resource depicted is vegetation, and clearly shown are vegetation units of special importance, including stands possibly containing trees of commercial grade and stands constituting wildlife habitat.

Anderson, J. H.↗

Incorporating Forecast Uncertainty in Utility Control Center

Uncertainties in forecasting the output of intermittent resources such as wind and solar generation, as well as system loads are not adequately reflected in existing industry-grade tools used for transmission system management, generation commitment, dispatch and market operation. There are other sources of uncertainty such as uninstructed deviations of conventional generators from their dispatch set points, generator forced outages and failures to start up, load drops, losses of major transmission facilities and frequency variation. These uncertainties can cause deviations from the system balance, which sometimes require inefficient and costly last minute solutions in the near real-time timeframe. This Chapter considers sources of uncertainty and variability, overall system uncertainty model, a possible plan for transition from deterministic to probabilistic methods in planning and operations, and two examples of uncertainty-based fools for grid operations.This chapter is based on work conducted at the Pacific Northwest National Laboratory (PNNL)

wind generation, solar generation, Energy managmen↗

Experimental Investigation of a Novel High Energy Density Mobile Sorption–based Thermal Battery

Around 20% of the total primary energy use in the United States is for thermal demands of buildings, such as space cooling, dehumidification, and space heating. Low-grade geothermal energy is abundant and could effectively satisfy these thermal demands. However, low-grade geothermal energy is underused because geothermal fluids have an energy density too low to justify transportation between the existing resources and buildings. The mobile sorption-based thermal battery (MSTB) system was thus developed to store the low-temperature heat using three-phase (vapor-liquid solution-solid crystal) sorption technology with a much higher energy density than a geothermal fluid provides. The energy density of an MSTB is over 6 times that of conventional hot water, enabling economical long-distance transport of low-temperature heat for thermal end uses. This can alleviate peak demand on the electricity grid by offsetting space-conditioning loads, improving the reliability and resilience of US energy systems. High energy density, fast crystallization, and crystal dissolution of the sorption material are critical to the viability and performance of the MSTB system. Therefore, the design and operation of MSTB systems must ensure effective generation and dissolution of the salt crystals inside the MSTB. To achieve this target, this study developed a prototype MSTB and its testing apparatus, and experimentally investigated the prototype MSTB. The crystallization and dissolution performance were also theoretically defined and quantified. The experimental results showed that the prototype MSTB was able to achieve an energy storage density of 903.0 kJ/kg and a maximum discharge rate of 1.3 kW. This study proves the feasibility and high performance of the MSTB concept, which is helpful to further study and development of the MSTB system.

Wang, Lingshi↗

A Systematic Evidence Based Performance Approach to Regulation of Nuclear Sites in England and Wales - 20058

The Environment Agency for England has developed a systematic evidence-based approach to pursue our strategic environmental objectives for the regulation of nuclear sites. We use an annual evidence review process to ensure effective and efficient targeting of limited resources to achieve those objectives. Over the last 8 years, we have been developing and refining this approach to ensure risk-based and value driven regulation. The approach comprises nuclear site and nuclear sector review processes known as Site Environment Review (SER) and Nuclear Environment Review (NER). This approach complements our regulation of nuclear site permit holders under the Environmental Permitting Regulations (EPR). We deliver our regulation of nuclear sites in England and Wales alongside the Office for Nuclear Regulation. The SER process involves the lead regulator for each nuclear site assessing the permit holder's environmental performance across 14 themes, set within the context of the site's main activities and associated waste disposals. Our themes include environmental leadership, resources and climate change, radioactive waste management, facility management and decommissioning, groundwater, and environmental radiological protection. We use evidence from site inspections and working within our subject matter groups to grade current and predicted future environmental performance. We are particularly interested in sustainability and the application of Best Available Techniques (BAT) to prevent the creation, and minimise the disposal, of radioactive wastes. We use risk analysis (strengths, weaknesses, threats and opportunities) to examine performance against our strategic environmental objectives, which are set out, in our 5-year Nuclear Delivery Plan (NDP). The output supports the targeting of our resources at each nuclear site. We consult the relevant permit holders on the SER priorities and use their feedback to refine our plans. We expect all permit holders to take account of our priorities when considering their own programmes of work, objectives and plans. The NER process brings together what we learn and achieve through regulation across the sector. It provides input to planning priorities, supported by qualitative and semi-quantitative evidence. It covers the 28 nuclear sites in England and Wales and spans the same 14 environmental themes. During the process we collate, compile and summarise evidence from the SERs and other sources such as inspection reports and evidence from our other nuclear work programmes. The output is the NER annual report. This provides a snapshot of the status of the nuclear sector and gives insights to enable us to regulate more efficiently and effectively. It also takes account of cross-cutting issues and risks such as changes in international standards, domestic policy, regulatory framework, domestic standards and guidance, learning from experience such as incidents, events and good practice, and innovation, research and development. It provides graphics that illustrate the grading of environmental performance for the nuclear sector across the fourteen environmental themes. This analysis allows benchmarking of nuclear site's environmental performance and the visualisation provides a convenient comparison of performance across themes, sites, and over time. We use this intelligence to inform our investment in training and development of our staff, and our cross-cutting engagement on strategic issues with government, the Nuclear Decommissioning Authority (NDA) and other corporate organisations. Adopting this approach can provide benefits with organisational reputation, stakeholder participation and ensuring value from the public investment. This paper describes the history of the SER/NER process, a selection of outputs from the process and ideas for improvement. The paper will be of interest to other regulators and organisations across the world that are interested in supporting continuous improvement. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Planet X probe: A fresh new look at an old familiar place

Planet X Probe utilizes a Get Away Special (GAS) payload to provide a large student population with a remote Earth sensing experimental package. To provide a cooperative as well as a competitive environment, the effort is targeted at all grade levels and at schools in different geographical regions. LANDSAT capability allows students to investigate the Earth, its physical makeup, its resources, and the impact of man. This project also serves as an educational device to get students to stand back and take a fresh look at their home planet. The key element is to treat the familiar Earth as an unknown planet with knowledge based only on what is observable and provable from the images obtained. Through participation, a whole range of experiences will include: (1) mission planning; (2) research and pilot projects to train teams; (3) identification and recruitment of scientific mentors and dialogue; (4) selection of a student advisory team to be available during the mission; (5) analysis of data and compilation of findings; (6) report preparation, constucted along sound scientific principles; and (7) presentation and defense of findings before a meeting of competitive student groups and scientist in the field.

Nicholson, James↗

Synchrophasor Visual Integration and Event Evaluation for Utilities (SynchroVIEEU) with High Penetration of Renewables

The Hawaiian Electric Companies (Companies), operating independent grid systems on the islands of Oahu, Hawaii, Maui, Molokai and Lanai, have been contending with some of the highest levels of renewable generation from both utility-scale and distributed generation resources. Renewable penetration levels exceeding 50% of generation are some of the highest in the nation and are changing the system characteristics and requiring operational changes to grid management. The Companies have aggressively leveraged federal, multi-state and industry grant funding to demonstrate new technologies for monitoring, visualization, forecasting and analysis to inform transformation needs and to improve operational awareness, especially at the distribution level. As part of the American Recovery and Reinvestment Act (ARRA) supported efforts to facilitate integration of renewables, synchrophasor devices were deployed on the islands of Hawaii and Maui in 2010. The devices have potential to provide Hawaii Electric Light Company (HELCO) on Hawaii Island and Maui Electric Company (MECO) with additional information to support post-event analysis and to help quantify observed area-wide changes in voltage and frequency on the systems. Consistent with the U.S. Department of Energy’s (DOE) Office of Electricity Delivery and Energy Reliability (OE) FOA objectives, the goal of this project was to accelerate the integration of synchrophasor information into production grade data visualization and analysis platforms/models to inform timely, efficient and reliable operations of a modern grid in light of high penetrations of renewable resources. The project comprised a two-year development effort to investigate the integration and visualization of synchrophasor field data into production-ready transmission and distribution proactive modeling efforts and a common data analysis platform application currently being used by the Companies. Conceptually, the project was about getting the right data to the right people at the right time in an easily accessible and timely environment.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Flash Recycling of Graphite Anodes

The ever-increasing production of commercial lithium-ion batteries (LIBs) will result in a staggering accumulation of waste when they reach their end of life. A closed-loop solution, with effective recycling of spent LIBs, will lessen both the environmental impacts and economic cost of their use. Presently, <5% of spent LIBs are recycled and the regeneration of graphite anodes has, unfortunately, been mostly overlooked despite the considerable cost of battery-grade graphite. Here, in this work, an ultrafast flash recycling method to regenerate the graphite anode is developed and valuable battery metal resources are recovered. Selective Joule heating is applied for only seconds to efficiently decompose the resistive impurities. The generated inorganic salts, including lithium, cobalt, nickel, and manganese, can be easily recollected from the flashed anode waste using diluted acid, specifically 0.1 M HCl. The flash-recycled anode preserves the graphite structure and is coated with a solid-electrolyte-interphase-derived carbon shell, contributing to high initial specific capacity, superior rate performance, and cycling stability, when compared to anode materials recycled using a high-temperature-calcination method. Life-cycle-analysis relative to current graphite production and recycling methods indicate that flash recycling can significantly reduce the total energy consumption and greenhouse gas emission while turning anode recycling into an economically advantageous process.

36 MATERIALS SCIENCE↗

Conversion Of Coal To Li-Ion Battery Grade (Potato) Graphite (Final Technical Report)

It was previously shown that biomass could be readily transformed to Li-ion battery grade graphite with performance that is equivalent to commercial graphite. This project extended that result to lignite coal, an abundant and inexpensive resource in the United States. It was found that lignite from North Dakota (ND), following charring and exposure to near-infrared light from a laser in the presence of an iron metal catalyst, graphitizes with high yield, crystallinity and purity. Furthermore, spheroidal (“potato”) shaped graphite agglomerates can be produced from ND lignite with performance that rivals that of commercial graphite. Finally, the process was found to be potentially economical, to that extent that it may be able to disrupt the current market, if the laboratory results obtained under this project can be successfully translated to industrial scale.

01 COAL, LIGNITE, AND PEAT↗

Expanding the horizon of bio-naphtha beyond gasoline blend: property characterization and conversion opportunity assessment through technoeconomic and life-cycle analyses

Bio-naphtha, a common by-product of biorefineries, is expected to experience substantial growth in supply due to increasing demands for renewable diesel and synthetic aviation fuel (SAF). However, demand for bio-naphtha itself as a gasoline blendstock is limited because of the electrification of light-duty vehicles. This work investigated valorization opportunities for bio-naphtha from catalytic fast pyrolysis, hydrothermal liquefaction, Fischer–Tropsch synthesis, and hydrotreated esters and fatty acids pathways. These opportunities include producing polymer-grade olefin via steam cracking, SAF via steam cracking followed by olefin oligomerization, and renewable aromatics benzene, toluene, and xylene (BTX) and hydrogen via catalytic reforming. Process models were developed in Aspen Plus V14 and Aspen HYSYS V14 to calculate the mass and energy balances for each conversion step. Technoeconomic assessment and life-cycle analysis were conducted to evaluate the minimum fuel/product selling price, conversion cost, and life-cycle CO2 equivalent (CO2e) emission reduction. Technoeconomic assessment results suggest a minimum fuel/product selling price as low as $1.9/kg of olefins, $6.30/gal of gasoline-equivalent SAF, and $1.2/kg of BTX without any incentives. For all pathways, these prices are dominated by bio-naphtha feedstock costs, which account for at least 76% of the total cost. Compared with petroleum baselines, bio-naphtha-derived SAF, olefins, and BTX can achieve significant CO2e emission reductions from the use of renewable carbon resources. The results of life-cycle analysis and subsequent technoeconomic assessment, incorporating carbon credits, indicate the economic viability of using bio-naphtha for polymer-grade olefin and BTX production, with product costs comparable to market prices.

Xu, Shuang↗