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Lunar surface processes and cosmic ray histories over the past several million years

Measurements of the Al-26 and Mn-53 in interior portions of lunar rocks have shown that lunar surface processes which move a significant fraction of kilogram size rocks on the lunar surface occur on time scales of a few million years. These measurements, together with noble gas age dating have made it possible to define the history for nine rock samples selected from whole rock counting data because of anomalously low Al-26 relative to Na-22. Six of the rocks from the Apollo 15 and 16 missions showed evidence of movement during the past five million years. Of these six, only two are of an age consistent with their origin from the South Ray Crater Event. In addition, our measurements of Na-22 and Al-26 in Apollo 17 double drive tube 74001-74002 suggest that one to two cm of soil is missing from the top of this core tube. Even with this loss, at least two cm of gardening is indicated in the top portion of 74002.

Fruchter, J. S.

Petrologic variations in Apollo 16 surface soils

Source rock, maturation history and intrasite variation data are derived for the Apollo 16 regolith by comparing modal analyses of 15 surface soils with rake and rock sample data. Triangular source rock component plots show that Apollo 16 soils have similar source rocks that are well homogenized throughout the site. The site can be divided into three soil petrographic provinces. Central site soils are mature, well homogenized, and enriched in glass. They are probably the most typical Cayley Plains materials present. North Ray soils are immature to submature, containing North Ray ejecta. South Ray soils are mature, but contain small amounts of fresh impact melts and plagioclase, due perhaps to the breakdown of blocky South Ray ejecta. The different compositions and physical properties of North and South Ray ejecta support the hypothesis that the latter event excavated Cayley material, while the former excavated Descartes materials.

Houck, K. J.

Magnetic and dielectric properties of lunar samples

Dielectric properties of lunar soil and rock samples showed a systematic character when careful precautions were taken to ensure there was no moisture present during measurement. The dielectric constant (K) above 100,000 Hz was directly dependent on density according to the formula K = (1.93 + or - 0.17) to the rho power where rho is the density in g/cc. The dielectric loss tangent was only slightly dependent on density and had values less than 0.005 for typical soils and 0.005 to 0.03 for typical rocks. The loss tangent appeared to be directly related to the metallic ilmenite content. It was shown that magnetic properties of lunar samples can be used to study the distribution of metallic and ferrous iron which shows systematic variations from soil type to soil type. Other magnetic characteristics can be used to determine the distribution of grain sizes.

Strangway, D. W.

Chemical composition of crystalline rock fragments from Luna 16 and Luna 20 fines

The chemical composition (bulk, rare earth, and trace elements) of the Luna 16 mare regolith and luna 20 highland regolith is discussed. The rock samples considered are 14 basaltic rock fragments (Luna 16) and 13 rock fragments of the ANT suite (Luna 20). On the basis of bulk composition, two types of basaltic rocks have been differentiated and defined in the Luna 16 regolith: mare basalts (fundamental crystalline rocks of Mare Fecunditatis) and high-alumina basalts. The bulk analyses of rock fragments of the ANT suite also enabled distinction of two rock types: anorthositic norites and troctolites and/or spinal-troctolites (the most abundant crystalline rocks of the highland region, the landing site of luna 20), and anorthosites. The chemical compositions of Luna 16 and Luna 20 regolith samples are compared. Differences in the chemistry of the Luna 16 mare regolith and that of mare basalts are discussed. The chemical affinity between the Luna 20 highland regolith and (a) anorthositic norites and (b) troctolites and/or spinel-troctolites has been ascertained.

Cimbalnikova, A.

Electrical properties of Apollo 17 rock and soil samples and a summary of the electrical properties of lunar material at 450 MHz frequency

The dielectric constant and the voltage absorption length was measured for four Apollo 17 soil samples (73241, 74220, 75061, 76501) and for two Apollo 17 rock samples (76315 and 79135) at 450 MHz frequency. The dielectric constant and absorption length measurements made on the lunar samples are reviewed and related to the transition element concentration in these samples. The significance of the laboratory measurements for radar observations is discussed.

Gold, T.

Volatile/mobile trace elements in Bholghati howardite

Ag, Au, Bi, Cd, Co, Cs, Ga, In, Rb, Sb, Se, Te, Tl, U, and Zn by RNAA are determined in two kinds of material from the Bholghati howardite: a carbonaceous chondrite clast (BH-4) that originated by primary nebular condensation/accretion processes; whole-rock samples and clasts resulting from parent-body processes, especially igneous differentiation. Trace element contents in Bholghati whole-rock (matrix) samples and/or white eucritic clasts in it are high for an achondrite, and variable. These characteristics are indicative of random condensation of volcanic emanations admixed with preexisting eucrite, diogenite, and howardite layers in the HED parent body. Other HED samples show similar patterns, and the conclusion that these reflect extensive volcanism in an asteroidal-sized object is supported by other Consortium noble gas and cosmochronologic measurements.

Wang, Ming-Sheng

River Valley pluton, Ontario - A late-Archean/early-Proterozoic anorthositic intrusion in the Grenville Province

This paper presents Nd, Sr, and Pb isotopic data indicating a late-Archean/early-Proterozoic age for the River Valley anorthositic pluton of the southwestern Grenville Province of Sudbury, Ontario. Pb-Pb isotopic data on 10 whole-rock samples ranging in composition from anorthosite to gabbro yield an age of 2560 + or - 155 Ma. The River Valley pluton is thus the oldest anorthositic intrusive yet recognized within the Grenville Province. The Sm-Nd isotopic system records an age of 2377 + or - 68 Ma. High Pb-208/Pb-204 of deformed samples relative to igneous-textured rocks implies Th introduction and/or U loss during metamorphism in the River Valley area. Rb-Sr data from igneous-textured and deformed samples and from mineral separates give an age of 2185 + or - 105 Ma, indicating substantial disturbance of the Rb-Sr isotopic system.

Ashwal, Lewis D.

Mineral and fluid transformation of hydraulically fractured shale: case study of Caney Shale in Southern Oklahoma

This study explores the geochemical reactions that can cause permeability loss in hydraulically fractured reservoirs. The experiments involved the reaction of powdered-rock samples with produced brines in batch reactor system at temperature of 95 °C and atmospheric pressure for 7-days and 30-days respectively. Results show changes in mineralogy and chemistry of rock and fluid samples respectively, therefore confirming chemical reactions between the two during the experiments. The mineralogical changes of the rock included decreases of pyrite and feldspar content, whilst carbonate and illite content showed an initial stability and increase respectively before decreasing. Results from analyses of post-reaction fluids generally corroborate the results obtained from mineralogical analyses. Integrating the results obtained from both rocks and fluids reveal a complex trend of reactions between rock and fluid samples which is summarized as follows. Dissolution of pyrite by oxygenated fluid causes transient and localized acidity which triggers the dissolution of feldspar, carbonates, and other minerals susceptible to dissolution under acidic conditions. The dissolution of minerals releases high concentrations of ions, some of which subsequently precipitate secondary minerals. On the field scale, the formation of secondary minerals in the pores and flow paths of hydrocarbons can cause significant reduction in the permeability of the reservoir, which will culminate in rapid productivity decline. This study provides an understanding of the geochemical rock–fluid reactions that impact long term permeability of shale reservoirs.

58 GEOSCIENCES

Rare gas studies of the galactic cosmic ray irradiation history of lunar rocks.

Average irradiation depths and exposure ages of Tranquillity Base rocks are computed on the basis of eight analyses of the five noble gases in whole rock samples and lunar separates from lunar rocks, in conjunction with available literature data. Correlated variations in He-3/Ne-21 and Ar-38/Ne-21 reflect shielding differences. This correlation cannot be explained by diffusion losses, even though evidence for gas loss is obtained from mineral separate data. A qualitative shielding sequence is constructed which agrees reasonably well with the sequence based on Gd isotopic data.

Huneke, J. C.

Development of Analytical Protocols For Organics and Isotopes Analysis on the 2009 MARS Science Laboratory.

The Mars Science Laboratory, under development for launch in 2009, is designed explore and quantitatively asses a local region on Mars as a potential habitat for present or past life. Its ambitious goals are to (1) assess the past or present biological potential of the target environment, (2) to characterize the geology and geochemistry at the MSL landing site, and (3) to investigate planetary processes that influence habitability. The planned capabilities of the rover payload will enable a comprehensive search for organic molecules, a determination of definitive mineralogy of sampled rocks and fines, chemical and isotopic analysis of both atmospheric and solid samples, and precision isotope measurements of several volatile elements. A range of contact and remote surface and subsurface survey tools will establish context for these measurements and will facilitate sample identification and selection. The Sample Analysis at Mars (SAM) suite of MSL addresses several of the mission's core measurement goals. It includes a gas chromatograph, a mass spectrometer, and a tunable laser spectrometer. These instruments will be designed to analyze either atmospheric samples or gases extracted from solid phase samples such as rocks and fines. We will describe the range of measurement protocols under development and study by the SAM engineering and science teams for use on the surface of Mars.

Mahaffy, P. R.

Petrologic and mineralogic investigation of some crystalline rocks returned by the Apollo 14 mission.

Apollo 14 crystalline rocks (14053 and 14310) and crystalline rock fragments (14001,7,1; 14001,7,3; 14073; 14167,8,1 and 14321,191,X-1) on which Rb/Sr, Ar-40/Ar-39, or cosmic ray exposure ages have been determined by our colleagues were studied with the electron microprobe and the petrographic microscope. Rock samples 14053 and 14310 are mineralogically and petrologically distinct from each other. On the basis of mineralogic and petrologic characteristics all of the fragments, except 14001,7,1, are correlative with rock 14310. Sample 14073 is an orthopyroxene basalt with chemical and mineralogic affinities to ?KREEP,' the ?magic' and ?cryptic' components. Fragment 14001,7,1 is very similar to Luny Rock I.

Gancarz, A. J.

Absolute ages from crater statistics: Using radiometric ages of Martian samples for determining the Martian cratering chronology

In the absence of dates derived from rock samples, impact crater frequencies are commonly used to date Martian surface units. All models for absolute dating rely on the lunar cratering chronology and on the validity of its extrapolation to Martian conditions. Starting from somewhat different lunar chronologies, rather different Martian cratering chronologies are found in the literature. Currently favored models are compared. The differences at old ages are significant, the differences at younger ages are considerable and give absolute ages for the same crater frequencies as different as a factor of 3. The total uncertainty could be much higher, though, since the ratio of lunar to Martian cratering rate which is of basic importance in the models is believed to be known no better than within a factor of 2. Thus, it is of crucial importance for understanding the the evolution of Mars and determining the sequence of events to establish an unambiguous Martian cratering chronology from crater statistics in combination with clean radiometric ages of returned Martian samples. For the dating goal, rocks should be as pristine as possible from a geologically simple area with a one-stage emplacement history of the local formation. A minimum of at least one highland site for old ages, two intermediate-aged sites, and one very young site is needed.

Neukum, G.

Catalog of Apollo 17 rocks. Volume 1: Stations 2 and 3 (South Massif)

The Catalog of Apollo 17 Rocks is a set of volumes that characterize each of 334 individually numbered rock samples (79 larger than 100 g) in the Apollo 17 collection, showing what each sample is and what is known about it. Unconsolidated regolith samples are not included. The catalog is intended to be used by both researchers requiring sample allocations and a broad audience interested in Apollo 17 rocks. The volumes are arranged geographically, with separate volumes for the South Massif and Light Mantle, the North Massif, and two volumes for the mare plains. Within each volume, the samples are arranged in numerical order, closely corresponding with the sample collection stations. The present volume, for the South Massif and Light Mantle, describes the 55 individual rock fragments collected at Stations two, two-A, three, and LRV-five. Some were chipped from boulders, others collected as individual rocks, some by raking, and a few by picking from the soil in the processing laboratory. Information on sample collection, petrography, chemistry, stable and radiogenic isotopes, rock surface characteristics, physical properties, and curatorial processing is summarized and referenced as far as it is known up to early 1992. The intention has been to be comprehensive: to include all published studies of any kind that provide information on the sample, as well as some unpublished information. References which are primarily bulk interpretations of existing data or mere lists of samples are not generally included. Foreign language journals were not scrutinized, but little data appears to have been published only in such journals. We have attempted to be consistent in format across all of the volumes, and have used a common reference list that appears in all volumes. Where possible, ages based on Sr and Ar isotopes have been recalculated using the 'new' decay constants recommended by Steiger and Jager; however, in many of the reproduced diagrams the ages correspond with the 'old' decay constants. In this volume, mg' or Mg' = atomic Mg/(Mg +Fe).

Ryder, Graham