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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Pressure Relief Devices for High-Pressure Gaseous Storage Systems: Applicability to Hydrogen Technology

Pressure relief devices (PRDs) are viewed as essential safety measures for high-pressure gas storage and distribution systems. These devices are used to prevent the over-pressurization of gas storage vessels and distribution equipment, except in the application of certain toxic gases. PRDs play a critical role in the implementation of most high-pressure gas storage systems and anyone working with these devices should understand their function so they can be designed, installed, and maintained properly to prevent any potentially dangerous or fatal incidents. As such, the intention of this report is to introduce the reader to the function of the common types of PRDs currently used in industry. Since high-pressure hydrogen gas storage systems are being developed to support the growing hydrogen energy infrastructure, several recent failure incidents, specifically involving hydrogen, will be examined to demonstrate the results and possible mechanisms of a device failure. The applicable codes and standards, developed to minimize the risk of failure for PRDs, will also be reviewed. Finally, because PRDs are a critical component for the development of a successful hydrogen energy infrastructure, important considerations for pressure relief devices applied in a hydrogen gas environment will be explored.

08 HYDROGEN↗

Suitability of Exoseal Vascular Closure Device for Antegrade Femoral Artery Puncture Site Closure

Purpose. To assess the efficacy and safety of the Exoseal vascular closure device for antegrade puncture of the femoral artery. Methods. In a prospective study from February 2011 to January 2012, a total of 93 consecutive patients received a total of 100 interventional procedures via an antegrade puncture of the femoral artery. An Exoseal vascular closure device (6F) was used for closure in all cases. Puncture technique, duration of manual compression, and use of compression bandages were documented. All patients were monitored by vascular ultrasound and color-coded duplex sonography of their respective femoral artery puncture site within 12 to 36 h after angiography to check for vascular complications. Results. In 100 antegrade interventional procedures, the Exoseal vascular closure device was applied successfully for closure of the femoral artery puncture site in 96 cases (96 of 100, 96.0 %). The vascular closure device could not be deployed in one case as a result of kinking of the vascular sheath introducer and in three cases because the bioabsorbable plug was not properly delivered to the extravascular space adjacent to the arterial puncture site, but instead fully removed with the delivery system (4.0 %). Twelve to 36 h after the procedure, vascular ultrasound revealed no complications at the femoral artery puncture site in 93 cases (93.0 %). Minor vascular complications were found in seven cases (7.0 %), with four cases (4.0 %) of pseudoaneurysm and three cases (3.0 %) of significant late bleeding, none of which required surgery. Conclusion. The Exoseal vascular closure device was safely used for antegrade puncture of the femoral artery, with a high rate of procedural success (96.0 %), a low rate of minor vascular complications (7.0 %), and no major adverse events.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Development and testing of a fission-like neutron field for dosimetry and instrument calibrations based on deuterium-tritium generator

For nearly five decades 252 Cf sources have been used for testing and calibration over a wide range of neutron detection devices used for nuclear safety and radiation protection. However, the vastly increased cost of 252 Cf sources, its short half-life, and concerns about future shortage have prompted nuclear facilities and radiological calibration laboratories that rely on high-intensity neutron sources to seek alternatives. There appear to be no other radionuclide neutron sources that would match “like-to-like” 252 Cf performance characteristics. Alternatives of producing a fission-like neutron spectrum based on commercially available deuterium-tritium (D-T) generators, and without any fissionable materials or beryllium, have been explored. This paper describes efforts of designing the spectrum shaping assembly, its construction and installation. The produced neutron field was evaluated both from the perspective of the neutron fluence spectrum and the resulting dosimetric outcome. Finally, it was tested for practical application by examining response of various health physics instruments and personal monitoring devices in comparison to the response of those devices when exposed to 252 Cf. In conclusion, the response of survey-type instruments tested within the prototype, surrogate fission, reference field are acceptably close to their response in the targeted 252 Cf field.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Progress in the development of the neutron flux monitoring system of the French GEN-IV SFR: simulations and experimental validations [ANIMMA--2015-IO-392]

France has a long experience of about 50 years in designing, building and operating sodium-cooled fast reactors (SFR) such as RAPSODIE, PHENIX and SUPER PHENIX. Fast reactors feature the double capability of reducing nuclear waste and saving nuclear energy resources by burning actinides. Since this reactor type is one of those selected by the Generation IV International Forum, the French government asked, in the year 2006, CEA, namely the French Alternative Energies and Atomic Energy Commission, to lead the development of an innovative GEN-IV nuclear- fission power demonstrator. The major objective is to improve the safety and availability of an SFR. The neutron flux monitoring (NFM) system of any reactor must, in any situation, permit both reactivity control and power level monitoring from startup to full power. It also has to monitor possible changes in neutron flux distribution within the core region in order to prevent any local melting accident. The neutron detectors will have to be installed inside the reactor vessel because locations outside the vessel will suffer from severe disadvantages; radially the neutron shield that is also contained in the reactor vessel will cause unacceptable losses in neutron flux; below the core the presence of a core-catcher prevents from inserting neutron guides; and above the core the distance is too large to obtain decent neutron signals outside the vessel. Another important point is to limit the number of detectors placed in the vessel in order to alleviate their installation into the vessel. In this paper, we show that the architecture of the NFM system will rely on high-temperature fission chambers (HTFC) featuring wide-range flux monitoring capability. The definition of such a system is presented and the justifications of technological options are brought with the use of simulation and experimental results. Firstly, neutron-transport calculations allow us to propose two in-vessel regions, namely the above-core and under-core structures. We verify that they comply with the main objective, that is the neutron power and flux distribution monitoring. HTFC placed in these two regions can detect an inadvertent control rod withdrawal that is a postulated initiating event for safety demonstration. Secondly, we show that the HTFC reliability is enhanced thanks to a more robust physical design and the fact that it has been justified that the mineral insulation is insensitive to any increase in temperature. Indeed, the HTFC insulation is subject to partial discharges at high temperature when the electric field between their electrodes is greater than about 200 V/mm or so. These discharges give rise to signals similar to the neutron pulses generated by a fission chamber itself, which may bias the HTFC count rate at start-up only. However, as displayed in Figure 1, we have experimentally verified that one can discriminate neutron pulses from partial discharges using online estimation of pulse width. Thirdly, we propose to estimate the count rate of a HTFC using the third order cumulant of its signal that is described by a filtered Poisson process. For such a statistic process, it is known that any cumulant, also called cumulative moment, is proportional to the process intensity that is here the count rate of a fission chamber. One recalls that the so-called Campbelling mode of such a detector is actually based on the signal variance, which is the second-order cumulant as well. The use of this extended Campbelling mode based on the third-order cumulant will permit to ensure the HTFC response linearity over the entire neutron flux range using a signal processing technique that is simple enough to satisfy design constraints on electric devices important for nuclear safety. We also show that this technique, named high order Campbelling method (HOC), is significantly more robust than another technique based on the change in the HTFC filling gas, which consists in adding a few percent of nitrogen. Finally, we also present an experimental campaign devoted to the required calibration process of the so-called HOC method. The Campbelling results show a good agreement with the simple pulse counting estimation at low count rates. It is also shown that the HOC technique provides a linear estimation of the count rates at higher power levels as well.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Kink modes and surface currents associated with vertical displacement events

The fast termination phase of a vertical displacement event (VDE) in a tokamak is modeled as a sequence of shrinking equilibria, where the core current profile remains constant so that the safety-factor at the axis, q{sub axis}, remains fixed and the q{sub edge} systematically decreases. At some point, the n = 1 kink mode is destabilized. Kink modes distort the magnetic field lines outside the plasma, and surface currents are required to nullify the normal component of the B-field at the plasma boundary and maintain equilibrium at finite pressure. If the plasma touches a conductor, the current can be transferred to the conductor, and may be measurable by the halo current monitors. This report describes a practical method to model the plasma as it evolves during a VDE, and determine the surface currents, needed to maintain equilibrium. The main results are that the onset conditions for the disruption are that the growth-rate of the n = 1 kink exceeds half the Alfven time and the associated surface current needed to maintain equilibrium exceeds one half of the core plasma current. This occurs when q{sub edge} drops below a low integer, usually 2. Application to NSTX provides favorable comparison with non-axisymmetric halo-current measurements. The model is also applied to ITER and shows that the 2/1 mode is projected to be the most likely cause of the final disruption.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Meeting the imperative to accelerate environmental bioelectromagnetics research

Highlights: • Concerns mount about adverse health effects of low-level radiofrequency (RF) radiation. • Bioelectronics and environmental RF effects research both need an omics platform. • Standard bioelectromagnetic data models would advance dosimetry and omics work. • Steps toward developing standards and a shared research platform are proposed. In this article, the author draws on his experience in the world of geospatial information technology standards to suggest a path toward acceleration of bioelectromagnetics science. Many studies show biological effects of extremely low frequency (ELF) and radiofrequency (RF) radiation despite that fact that the radiation is too weak to cause temperature changes in biological features. Considered together in worst case scenarios, such effects, many of which appear to have long latencies, could have potentially disastrous consequences for the health and safety of humans and wildlife. Other studies show no such effects, and in both cases, often there are significant research quality deficits that make it difficult to draw firm conclusions from the data. The progress of bioelectromagnetics science is retarded by a lack of standard data models and experimental protocols that could improve the overall quality of research and make it easier for researchers to benefit from omics-related bioinformatics resources. {sup C}ertainty of safety{sup }of wireless devices used in digital communications and remote sensing (radar) is impossible without dosimetry standards that reflect the effects of non-thermal exposures. Electrical signaling in biological systems, a poorly funded research domain, is as biologically important as chemical signaling, a richly funded research domain, and these two types of signaling are inextricably connected. Entreprenuerial scientists pursuing bioelectronic innovations have begun to attract new funding. With appropriate institutional coordination, this new funding could equally benefit those investigating environmental effects of ELF and RF radiation. The author proposes a concerted effort among both bioelectronics technology stakeholders and environmental bioelectromagnetics science researchers to collaborate in developing institutional arrangements and standard data models that would give the science a stronger bioinformatics platform and give researchers better access to omics data. What is proposed here is essentially a bioelectromagnetics omics initiative.

54 ENVIRONMENTAL SCIENCES↗

Peripheral white blood cells profile of biodegradable metal implant in mice animal model

Biocompatibility or safety of the medical device is considered important. It can be determined by blood profile examination. The aim of this study was to assess the biocompatibility of biodegradable metal implant through peripheral white blood cells (WBCs) profile approach. Forty eight male ddy mice were divided into four groups according to the materials implanted: iron wire (Fe), magnesium rod (Mg), stainless steel surgical wire (SS316L) and control with sham (K). Implants were inserted and attached onto the right femoral bone on latero-medial region. In this study, peripheral white blood cells and leukocyte differentiation were the parameters examined. The result showed that the WBCs value of all groups were decreased at the first day after implantation, increased at the 10th day and continued increasing at the 30th day of observation, except Mg group which has decreased. Neutrophil, as an inflammatory cells, was increased at the early weeks and decreased at the day-30 after surgery in all groups. Despite, these values during the observation were still within the normal range. As a conclus ion, biodegradable metal implants lead to an inflammatory reaction, with no adverse effect on WBC value found.

60 APPLIED LIFE SCIENCES↗

Concept of a demonstrational hybrid reactor—a tokamak with molten-salt blanket for {sup 233}U fuel production: 1. Concept of a stationary Tokamak as a neutron source

On the basis of current understanding of physical processes in tokamaks and taking into account engineering constraints, it is shown that a low-cost facility of a moderate size can be designed within the adopted concept. This facility makes it possible to achieve the power density of neutron flux which is of interest, in particular, for solving the problem of {sup 233}U fuel production from thorium. By using a molten-salt blanket, the important task of ensuring the safe operation of such a reactor in the case of possible coolant loss is accomplished. Moreover, in a hybrid reactor with the blanket based on liquid salts, the problem of periodic refueling that is difficult to perform in solid blankets can be solved.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

A Fission-like Neutron Spectrum Shaping Assembly based on D-T Generator

For nearly five decades, 252 Cf sources have been used for testing and calibration over a wide range of neutron detection devices used for nuclear safety and radiation protection. However, the vastly increased cost of 252 Cf sources, its short half-life, and concerns about future shortage have prompted nuclear facilities and radiological calibration laboratories that rely on high-intensity neutron sources to seek alternatives. While there appear to be no other radionuclide neutron sources that would match the 252 Cf performance characteristics, all of them, including 252 Cf, present similar concerns in terms of hazards, safety, and security. As a possible solution to this issue, the Pacific Northwest National Laboratory (PNNL) developed a low-risk, cost-efficient alternative to produce fission-like spectra based on commercially available deuterium-tritium (D-T) neutron generators. The alternative of producing a fission-like neutron spectrum without any fissionable materials or beryllium would enable the nuclear facilities across the entire complex to eliminate their reliance on high intensity 252 Cf sources for nuclear safety and radiation protection applications, substantially reducing risks and associated costs. This report describes efforts of designing the spectrum shaping assembly, its construction and characterization of the neutron field produced. Performance of this newly developed D-T generator based neutron field is demonstrated via calibration of a criticality detector, neutron survey instruments, and personal dosimeters verified against current standardized fields produced by 252 Cf spontaneous fission sources.

42 ENGINEERING↗

Thermally switchable dielectrics

Precursor polymers to conjugated polymers, such as poly(phenylene vinylene), poly(poly(thiophene vinylene), poly(aniline vinylene), and poly(pyrrole vinylene), can be used as thermally switchable capacitor dielectrics that fail at a specific temperature due to the non-conjugated precursor polymer irreversibly switching from an insulator to the conjugated polymer, which serves as a bleed resistor. The precursor polymer is a good dielectric until it reaches a specific temperature determined by the stability of the leaving groups. Conjugation of the polymer backbone at high temperature effectively disables the capacitor, providing a `built-in` safety mechanism for electronic devices.

36 MATERIALS SCIENCE↗

Deployment of Rapid Assay Systems for Real-time Sorting of Excavation Spoil on Contaminated Land - 19258

To optimise segregation at source, and hence minimise waste production, NUVIA have developed and utilised the Gamma Excavation Monitor (GEM) system. The GEM was designed for land remediation projects, to provide a rapid screening tool for excavator buckets of material. Following successful deployment in the UK, including the Olympic Park site in London, and two major Magnox land remediation projects, the first GEM unit was deployed to Canadian Nuclear Laboratories' (CNL) Chalk River Laboratory (CRL) in 2016. The GEM unit was fitted with a plastic scintillator detector; recent developments have included the utilisation of a sodium iodide. The system is initiated by the presence of an excavator bucket above the detector which triggers proximity switches that automatically start the counting routine. At the end of a short count time, typically 10 seconds, the materials category is indicated by means of a traffic light system, based on either the gross gamma activity or a photo-peak. Using this instrument, material determined not to be radioactive can be re-used on-site. In addition to the traffic light system, results are also transmitted wirelessly to a tablet device. These combined features allow operation of the system without the need to have operatives near the mechanical excavator bucket; therefore, eliminating a significant industrial hazard. Deployments of the GEM on the CRL site have included Storm Water Management project, within the CRL controlled area, and the Foundation Road Landfill Project. The use of the GEM in these projects enabled in-situ decisions to be made regarding the segregation and sentencing of soil rather than having to wait for the analysis of samples; saving time and cost to the project. The Building 492 project involved the excavation of soil within a supervised area to prepare for the installation of modular trailer units. For this specific job, the GEM was calibrated to ensure soil met clearance criteria as stipulated in the Nuclear Substances and Radiation Devices Regulations (Canadian Nuclear Safety Commission; SOR/2000-207). A total of 326 loads of soil were monitored during this project and re-assurance sampling conducted by CNL corroborated the results produced by the GEM system. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Single‐Ion Conducting Borate Network Polymer as a Viable Quasi‐Solid Electrolyte for Lithium Metal Batteries

Abstract Lithium‐ion batteries have remained a state‐of‐the‐art electrochemical energy storage technology for decades now, but their energy densities are limited by electrode materials and conventional liquid electrolytes can pose significant safety concerns. Lithium metal batteries featuring Li metal anodes, solid polymer electrolytes, and high‐voltage cathodes represent promising candidates for next‐generation devices exhibiting improved power and safety, but such solid polymer electrolytes generally do not exhibit the required excellent electrochemical properties and thermal stability in tandem. Here, an interpenetrating network polymer with weakly coordinating anion nodes that functions as a high‐performing single‐ion conducting electrolyte in the presence of minimal plasticizer, with a wide electrochemical stability window, a high room‐temperature conductivity of 1.5 × 10 −4 S cm −1 , and exceptional selectivity for Li‐ion conduction ( t Li+ = 0.95) is reported. Importantly, this material is also flame retardant and highly stable in contact with lithium metal. Significantly, a lithium metal battery prototype containing this quasi‐solid electrolyte is shown to outperform a conventional battery featuring a polymer electrolyte.

Shin, Dong‐Myeong↗

The Use of ExoSeal Vascular Closure Device for Direct Antegrade Superficial Femoral Artery Puncture Site Hemostasis

PurposeThis study was designed to assess the efficacy and safety of the ExoSeal vascular closure device (VCD) to achieve hemostasis in antegrade access of the superficial femoral artery (SFA).MethodsWe retrospectively reviewed the outcome of ExoSeal VCD used for hemostasis in 110 accesses to the SFA in 93 patients between July 2011 and July 2013. All patients had patent proximal SFA based on computer tomography angiography or ultrasound duplex. Arterial calcifications at puncture site were graded using fluoroscopy. The SFA was accessed in an antegrade fashion with ultrasound or fluoroscopic guidance. In all patients, 5–7F vascular sheaths were used. The ExoSeal VCD was applied to achieve hemostasis at the end of the procedure. All patients were clinically examined and had ultrasound duplex exam for any puncture site complications during the 24 h postprocedure.ResultsIn all procedures, the ExoSeal was applied successfully. We did not encounter any device-related technical failure. There were four major complications in four patients (3.6 %): three pseudoaneurysms, which were treated with direct thrombin injection, and one hematoma, which necessitated transfusion of two blood units. All patients with complications were treated with anticoagulation preprocedure or received thrombolytic therapy.ConclusionsThe ExoSeal VCD can be safely used for antegrade puncture of the SFA, with a high procedural success rate (100 %) and a low rate of access site complications (3.6 %)

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Enhancing Staging Capabilities at the Device Assembly Facility

The radioactive material limits allowed by the Documented Safety Analysis (DSA) at the Nevada National Security Site (NNSS) Device Assembly Facility (DAF) can support larger quantities than the floor space will accommodate. In order to maximize the full staging bunker capability, National Security Technologies, LLC, (NSTec) is developing a plan to take advantage of these high inventory limits and evaluate staging options such as shelves, racks, and mezzanines. This plan will investigate cost and evaluate U.S. Department of Energy (DOE) complex-wide alternatives used at other sites (Highly Enriched Uranium Manufacturing Facility, Pantex, Los Alamos National Laboratory, Sandia National Laboratories, etc.) that addressed similar situations.

staging, NMMP, nuclear material, DAF↗

Material Selection and Heat Transfer Model for PTUHS Device

The Path to Ultimate Heat Sink Device (PTUHS) is a passive safety system that utilizes a radiative heat transfer valve to control the rate at which heat is removed from a nuclear reactor pressure vessel (RPV) and dispersed into surrounding soil. The material selection for the PTUHS device is investigated, where the thermophysical properties are either maximized or minimized bases on what section of the PTUHS that material is being used for. Final recommendations of material choice are then presented. The heat transfer model of the PTUHS device is solved in ABAQUS, where a normal operating conditions and SCRAM conditions are solved. These temperature maps and heat flux of the system show the system's ability, where minimal heat is lost during normal operating conditions and system failure in a SCRAM scenario due to temperatures that were reached.

42 - ENGINEERING↗

Effect of rapid thermal annealing of copper indium aluminium gallium diselenide solar cell devices and its deposition challenges

Thin-film photovoltaic research based on ternary or quaternary absorber materials has mainly concentrated on copper (indium/gallium) diselenide, CuIn x Ga 1-x Se 2 (CIGS). This material has demonstrated exceptional energy conversion efficiencies. By altering the In/Ga ratio the band gap can be varied from 1.02 eV (for CuInSe 2 ) to 1.68 eV (for CuGaSe 2 ). However, research from leading groups showed that cells have maximum efficiency at or below 1.35 eV. This paper reports the challenges of using aluminium alloyed CIGS deposited with a single step co-evaporation method. Adding aluminium is found to reduce the bulk trap state density for wide gap devices. However, it created significant safety issues when compared to conventional CIGS co-evaporation deposition systems. The release of H 2 Se when moisture comes in contact with aluminium selenide was resolved by placing exhaust lines at various places of the deposition chamber. A single phase CIAGS device with a bandgap of 1.30 eV was prepared using a co-evaporation method. The fabricated solar cell devices with CIAGS absorber layers and resulted in a photoconversion efficiency of 10.3%. A progressive rapid thermal annealing at various temperature resulted in a 10% increase in the overall efficiency at 300 °C. The efficiencies were reduced when the RTA temperature increased above 300 °C.

14 SOLAR ENERGY↗