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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Potassium Rankine cycle vapor chamber (heat pipe) radiator study

A structurally integrated vapor chamber fin (heat pipe) radiator is defined and evaluated as a potential candidate for rejecting waste heat from the potassium Rankine cycle powerplant. Several vapor chamber fin geometries, using stainless steel construction, are evaluated and an optimum is selected. A comparison is made with an operationally equivalent conduction fin radiator. Both radiators employ NaK-78 in the primary coolant loop. In addition, the Vapor Chamber Fin (VCF) radiator utilizes sodium in the vapor chambers. Preliminary designs are developed for the conduction fin and VCF concepts. Performance tests on a single vapor chamber were conducted to verify the VCF design. A comparison shows the conduction fin radiator easier to fabricate, but heavier in weight, particularly as meteoroid protection requirements become more stringent. While the analysis was performed assuming the potassium Rankine cycle powerplant, the results are equally applicable to any system radiating heat to space in the 900 to 1400 F temperature range.

Gerrels, E. E.↗

Vapor chamber fin radiator study for the potassium Rankine cycle.

A structurally integrated vapor chamber fin (heat pipe) radiator is defined and evaluated as a potential candidate for rejecting waste heat from the potassium Rankine cycle powerplant. Several vapor chamber fin geometries, using stainless steel construction, are evaluated and an optimum is selected. A comparison is made with an operationally equivalent conduction fin radiator. Both radiators employ NaK-78 in the primary coolant loop. In addition, the Vapor Chamber Fin (VCF) radiator utilizes sodium in the vapor chambers. Preliminary designs are developed for the conduction fin and VCF concepts. Performance tests on a single vapor chamber were conducted to verify the VCF design.

Gerrels, E. E.↗

Shock tube study of ionization rates of NaCl-contaminated argon

Electron density, electron temperature, and concentration of excited sodium atoms are measured in the weakly ionized regime behind a shock wave in impure argon in a shock tube using microwave techniques and spectrally resolved radiometry. Evidence is presented to show that an apparent increase in the rate of ionization is due to electron detachment of negative chlorine ions produced from sodium chloride vapor contained as an impurity. To be consistent with this chemical model, rate coefficients are found in the temperature range between 5500 and 8600 K for the dissociation of NaCl into an ion pair, dissociation of NaCl into a neutral pair, and electron detachment of a negative chlorine ion. Electron temperature is lower than heavy-particle temperature by roughly 1000 K. The electron-argon impact-ionization rate coefficient is a weak function of electron temperature in contradiction to expectation.

Schneider, K.-P.↗

Shock tube study of ionization rates of NaCl-contaminated argon

Spectrally resolved radiometry and a microwave technique were used to measure the electron density, electron temperature, and concentration, and the concentration of sodium atoms in the weakly ionized region behind a shock wave in an argon shock tube. It is shown that the observed increase in the ionization rate is due to electron detachment of negative chlorine ions produced from sodium chloride vapor contained as an impurity in the argon gas. The observed behavior of the electron temperature in time and the reactions controlled by the electron temperature are analyzed in the light of the impurity reaction scheme.

Scheneider, C.-P.↗

Real-time observation of dynamic structure of liquid-vapor interface at nanometer resolution in electron irradiated sodium chloride crystals

The dynamics and structure of the liquid and vapor interface has remained elusive for decades due to the lack of an effective tool for directly visualization beyond micrometer resolution. Here, we designed a simple liquid-cell for encapsulating the liquid state of sodium for transmission electron microscopic (TEM) observation. The real-time dynamic structure of the liquid-vapor interface was imaged and videoed by TEM on the sample of electron irradiated sodium chloride (NaCl) crystals, a well-studied sample with low melting temperature and quantum super-shells of clusters. The nanometer resolution images exhibit the fine structures of the capillary waves, composed of first-time observed three zones of structures and features, i.e. flexible nanoscale fibers, nanoparticles/clusters, and a low-pressure area that sucks the nanoparticles from the liquid to the interface. Although the phenomenons were observed based on irradiated NaCl crystals, the similarities of the phenomenons to predictions suggest our real-time ovserved dynamic structure might be useful in validating long-debated theoretical models of the liquid-vapor interface, and enhancing our knowledge in understanding the non-equilibrium thermodynamics of the liquid-vapor interface to benefit future engineering designs in microfluidics.

36 MATERIALS SCIENCE↗

Third harmonic generation in phase-matched alkali metal vapors

We report improvements in conversion efficiency for third harmonic generation in sodium and rubidium vapor. 30-psec pulses of radiation at 1.064 micron have been converted to 0.3547 micron with an energy conversion efficiency of 10%. Factors limiting conversion efficiency are discussed.

Bloom, D. M.↗

Sodium Fluid Properties

This software is used to compute numerous properties for the liquid and vapor phases of sodium.

Andrs, David↗

Liquid-to-gas transfer of sodium in a liquid anode glow discharge

Solute transfer from the liquid to the gas phase in plasmas has been widely used in analytical chemistry often focused on liquid cathode discharges. In this study, we report on time-resolved absolute density measurements of sodium in a glow discharge plasma with a NaCl solution anode using two-photon absorption laser induced fluorescence. The averaged maximum sodium density is found to be similar to the electron density in the discharge consistent with plasma-induced vapor generation. Random sodium flashes were also observed extending into the plasma afterglow and are attributed to sodium particles falling back on the liquid surface. Cataphoresis can explain the location of the maximum sodium density near the cathode side of the electrode gap rather than near the liquid anode region.

chemical vapor generation↗

Mixed metal vapor phase matching for third-harmonic generation

Phase matching for frequency tripling of 1.06 microns is demonstrated in a homogeneous mixture of sodium and magnesium vapor. The ratio of Mg to Na vapor pressures required for phase matching is 2:1. This ratio is about 1/75 of that required to phase match Na with Xe.

Bloom, D. M.↗

Simulating Ordinary Chondrite (Tamdakht) Ablation at the Hypersonic Materials Environmental Test System (HyMETS) Facility.

NASA’s Science Mission Directorate (SMD) created the Asteroid Threat Assessment Project (ATAP) to inform decision-makers of risks associated with Potentially Hazardous Objects (PHOs), which may pose an existential threat to human civilization. ATAP assesses risk, in part, by developing analytical physics-based damage models which draw upon data collected during material property characterization efforts, entry simulations, hazard simulations, and ground-based arc-jet testing. Therefore, a pathfinder test campaign was con-ducted at the Hypersonic Materials Environmental Test System (HyMETS) at the NASA Langley Re-search Center to investigate the ablation mechanisms of an ordinary chondrite (Tamdakht H5) and a terrestrial analog (basalt). The HyMETS facility is a 400 kW constricted arc heater used to screen material performance under simulated aerothermal conditions of hypersonic flow.1 Facility conditions were chosen to simulate Earth entry conditions be-tween the upper-mesosphere and the lower thermo-sphere. The ablation mechanisms of Tamdakht and bas-alt are illustrated with still images collected from high-speed video cameras (fig. 1, Tamdakht). Tamdakht produces a relatively stable melt flow, as evidenced by the perpetual growth of a flange at the sidewall and the exiguous detachment of molten material into the flow. Furthermore, an inspection of high-speed video and chemical analysis of the post-test melt layer suggests that the dominant mode of mass loss for Tamdakht, at these test conditions, is expressed through the vaporization of volatiles (e.g., iron, potassium, sodium, phosphorus, and sulfur). The vaporization rates of Tamdakht are greater than basalt under the most extreme test conditions, which leads to an enhanced blowing layer, in-creased thermal shielding, and reduced recession. The ablation mechanisms of basalt are markedly different from Tamdakht and are attributed to the presence of hydrated minerals dispersed at irregular intervals throughout the silicate matrix. Rapid de-composition of secondary minerals and the subsequent formation of water lead to the ejection of the subsurface and overlying melt layer. Furthermore, the presence of water is suspected of lowering the viscosity of the melt layer resulting in increased mass loss near the edge of the test article where drag forces overcome rheological properties (fig. 1, bas-alt). Finally, the results will be discussed in the broader context of meteorite-based material response model development and the potential impact on the Asteroid Threat Assessment Project (ATAP).

Brody K. Bessire↗

Sodium and potassium in the lunar atmosphere

The discovery that sodium and potassium vapor can be observed in the lunar atmosphere using ground-based telescopes has opened up a field of investigation that was closed after the last Apollo mission to the Moon. Sodium has been detected at altitudes up to 1500 km above the surface. This implies a high effective temperature for sodium, of the order of 1000 K. However, there is some evidence for two populations of sodium and potassium, one at temperatures corresponding to the surface, and another corresponding to high temperatures. The sources for the lunar atmosphere are not understood. Meteoric bombardment of the surface, solar wind sputtering of the surface, and photo-sputtering of the surface have all been suggested as possible sources for the lunar atmosphere. One of the objectives of the current research is to test different hypotheses by measurements of the atmosphere under different conditions of solar illumination and shielding from the solar wind by the Earth.

Potter, A. E.↗

Volatility of sodium, potassium, and cesium perrhenates determined by thermogravimetry

Here, in this study, we investigated the volatility of sodium, potassium, and cesium perrhenates using thermogravimetry (TG) performed on single salts and their binary mixed salts. We performed simultaneous TG and differential scanning calorimetry under a ramp heating condition at 10°C/min up to 1200°C to characterize volatilization behavior as a function of temperature. We also performed isothermal TG over a temperature range of 700 to 975°C to estimate the vapor pressures of the alkali perrhenates based on a modified Langmuir equation that relates the rate of free evaporation from the open surface to vapor pressure. In this paper, we discuss the results of our study on the temperature of evaporation and temperature-dependent vapor pressure of sodium, potassium, and cesium perrhenates in relation to rhenium volatilization behavior observed during melting of simulated waste glass.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Calculation of Friction Factors in Heat Pipes Using CFD in Support of the Sockeye Code

A heat pipe is two-phase heat transfer device which relies on surface tension and capillary pressure to provide a very efficient heat transfer mechanism. Currently, there is interest in designing micro nuclear power reactors using high temperature heat pipes to provide totally passive cooling. To support this, Sockeye is being developed as a heat pipe simulation capability. To support the development of Sockeye, individual phenomena must be tested. This work focuses on applying a CFD model to evaluate friction factors for use in Sockeye. A CFD model has been developed in Nek5000 which simulates each component fluid, i.e. sodium liquid and vapor, independently and captures the effects of the wick on friction factor. The model tests the effect of the wick permeability and the thickness of the wick occupied by each fluid component. The thickness of the wick occupied by each component can be directly related to the local vapor volume fraction from the Sockeye heat pipe model. Results from the CFD model indicate that friction factor in the liquid flow decreases with increasing wick permeability, while the friction factor in the vapor flow increases with increasing wick permeability. In the liquid, this is likely a direct result of the increased cross sectional area available for the flow. For the vapor, this is explained as the wick acting like a rough wall, while the increased area has only a negligible impact. Results for the tests of the thickness of the wick occupied by each fluid showed a thresholding behavior for both liquid and vapor. When the thickness of the wick occupied by each fluid was increased, it increased the effect of the wick, but only up to a certain point. Once a certain thickness was reached, the friction factors remained constant. When the fluid occupied only a very small fraction of the wick, friction factors returned to nominal values.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Hanover LED Streetlight Conversion

On May 8, 2017, Hanover residents voted overwhelmingly to transition to 100% renewable electricity by 2030 and heating, cooling and transportation by 2050. In so doing, we became the first municipality in the country to make this commitment by popular vote. To accomplish these goal town leaders developed a plan to address first transitioning municipal energy uses to renewable forms of energy, through on-site generation of the municipal electrical load, load reduction through energy efficiency improvements to town facilities and infrastructure. Significant progress has been accomplished in the generation of energy with 90%+ of the 2024 municipal load being offset by generation and through various energy efficiency projects. The utility owned street lighting was identified as a large energy consumer of 165 MWh annually (7% of the annual municipal load) due to old inefficient high-pressure sodium and mercury vapor streetlights with no ability to reduce wattage during periods with low lighting needs. The Hanover LED Streetlight Replacement Project replaced utility owned streetlights with town owned controllable (dimmable and trimmable) LED lights that can be adjusted by location and time of night. Coupled with ownership of the streetlights transfer to the town, the town’s share of the project pay back is 11 months and for the complete project including federal share the payback is approximately 3 years. With the completion of lighting upgrade, the annual streetlighting energy load has dropped by 60% to 67 MWh in the first year of operation (7/1/24 - 6/30/25). This amounts to an approximate $90,000 annual savings or a local 1% tax rate impact. Additionally, over 200,000 pounds of CO2 will be saved annually.

99 GENERAL AND MISCELLANEOUS↗

Heat pipe reactors for space power applications

A family of heat pipe reactors design concepts has been developed to provide heat to a variety of electrical conversion systems. Three power plants are described that span the power range 1-500 kWe and operate in the temperature range 1200-1700 K. The reactors are fast, compact, heat-pipe cooled, high-temperature nuclear reactors fueled with fully enriched refractory fuels, UC-ZrC or UO2. Each fuel element is cooled by an axially located molybdenum heat pipe containing either sodium or lithium vapor. Virtues of the reactor designs are the avoidance of single-point failure mechanisms, the relatively high operating temperature, and the expected long lifetimes of the fuel element components.

Koenig, D. R.↗

AMTEC cell testing, optimization of rhodium/tungsten electrodes, and tests of other components

Electrodes, current collectors, ceramic to metal braze seals, and metallic components exposed to the high 'hot side' temperatures and sodium liquid and vapor environment have been tested and evaluated in laboratory cells running for hundreds of hours at 1100-1200 K. Rhodium/tungsten electrodes have been selected as the optimum electrodes based on performance parameters and durability. Current collectors have been evaluated under simulated and actual operating conditions. The microscopic effects of metal migration between electrode and current collector alloys as well as their thermal and electrical properties determined the suitability of current collector and lead materials. Braze seals suitable for long term application to AMTEC devices are being developed.

Williams, Roger M.↗