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At least 91 records · Page 5

Pre- and post-launch operation of the Resolve soft X-ray spectrometer onboard the XRISM satellite

Resolve is a high-resolution X-ray spectrometer onboard the X-Ray Imaging and Spectroscopy Mission (XRISM), launched on September 6 (UT), 2023. The Resolve has performed better than its required spectral resolution (7 eV at full width at half maximum at 6 keV), both on the ground and in orbit, and has been confirmed to have comparable performance to the soft X-ray spectrometer onboard the ASTRO-H (Hitomi) satellite. The focal plane is composed of an array of microcalorimeter detectors operated at 50 mK to achieve the required energy resolution, and the cooling system is designed to satisfy the lifetime requirement of over 3 years. The focal plane and cooling system are contained in a vacuum-insulated dewar. The cooling system is equipped with a two-stage adiabatic demagnetization refrigerator (ADR) that uses superfluid liquid helium (LHe) as its heat sink. The system includes a third ADR stage that can be used to provide the heat sink when the helium is exhausted. A Joule–Thomson cooler and several two-stage Stirling coolers are used to reduce the heat load on the LHe. During pre-launch operations, we carried out a superfluid LHe top-off operation. The resultant amount of LHe onboard Resolve was over 35 L before launch, which is sufficient to meet the lifetime requirement. During post-launch operation, the LHe vent valve was opened 5 min after launch during rocket acceleration, and the cryocoolers were turned on after several orbits, as planned, which established stable cooling within the dewar. Pre- and post-launch operations for the Resolve instrument were planned around multiple constraints from launch vehicle operations; all were successfully completed, and the launch requirements were fully met.

X-Ray Imaging and Spectroscopy Mission↗

First estimation of high-resolution solar photovoltaic resource maps over China with Fengyun-4A satellite and machine learning

Fengyun-4A (FY-4A), which is the latest-generation Chinese geostationary meteorological satellite, measures solar reflection and thermal emission with high temporal, spatial, and spectral resolutions. It is expected to be highly beneficial for solar resource assessment and forecasting in China. This study is the first to estimate, using FY-4A and a random forest model, the global horizontal irradiance (GHI) at a 4-km–15-min spatio-temporal resolution over China, as a means to arrive at a solar photovoltaic (PV) resource map. In terms of GHI estimates, the root mean square error and mean bias error between hourly measured and retrieved values are 147.02 (35.2%), –5.64 W/m 2 (–1.4%), respectively, whereas the values of daily estimates are 29.20 (18.0%), –2.97 W/m 2 (–1.3%). The retrieval accuracy is found much better for instances with solar zenith angles smaller than 60°. Relatively larger errors are found at locations in the Sichuan Basin and northeastern China, which can be attributed to bright surfaces and/or strong cloud transients. With the retrieved irradiance, PV resource is derived through a physical model chain. The annual mean PV resource map suggests that, over most of the west areas, the annual mean effective irradiance exceeds 1700 kWh/m 2 , with the highest value found in Tibet (around 2000 kWh/m 2 per annum). Eastern China has an annual effective irradiance of only 1300–1500 kWh/m 2 . In conclusion, the region with poorest solar resource is the Sichuan Basin (less than 1100 kWh/m 2 per annum).

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Current limitations of solid-state NMR in carbohydrate and cell wall research

High-resolution investigation of cell wall materials has emerged as an important application of biomolecular solid-state NMR (ssNMR). Multidimensional correlation experiments have become a standard method for obtaining sufficient spectral resolution to determine the polymorphic structure of carbohydrates and address biochemical questions regarding the supramolecular organization of cell walls. Here, using plant cellulose and matrix polysaccharides as examples, we will review how the multifaceted complexity of polysaccharide structure is impeding the resonance assignment process and assess the available biochemical and spectroscopic approaches that could circumvent this barrier. We will emphasize the ineffectiveness of the current methods in reconciling the ever-growing dataset and deriving structural information. We will evaluate the protocols for achieving efficient and homogeneous hyperpolarization across the cell wall material using magic-angle spinning dynamic nuclear polarization (MAS-DNP). Critical questions regarding the line-broadening effects of cell wall molecules at cryogenic temperature and by paramagnetic biradicals will be considered. Finally, the MAS-DNP method will be placed into a broader context with other structural characterization techniques, such as cryo-electron microscopy, to advance ssNMR research in carbohydrate and cell wall biomaterials.

09 BIOMASS FUELS↗

On the differences in the vertical distribution of modeled aerosol optical depth over the southeastern Atlantic

Abstract. The southeastern Atlantic is home to an expansive smoke aerosol plume overlying a large cloud deck for approximately a third of the year. The aerosol plume is mainly attributed to the extensive biomass burning activities that occur in southern Africa. Current Earth system models (ESMs) reveal significant differences in their estimates of regional aerosol radiative effects over this region. Such large differences partially stem from uncertainties in the vertical distribution of aerosols in the troposphere. These uncertainties translate into different aerosol optical depths (AODs) in the planetary boundary layer (PBL) and the free troposphere (FT). This study examines differences of AOD fraction in the FT and AOD differences among ESMs (WRF-CAM5, WRF-FINN, GEOS-Chem, EAM-E3SM, ALADIN, GEOS-FP, and MERRA-2) and aircraft-based measurements from the NASA ObseRvations of Aerosols above CLouds and their intEractionS (ORACLES) field campaign. Models frequently define the PBL as the well-mixed surface-based layer, but this definition misses the upper parts of decoupled PBLs, in which most low-level clouds occur. To account for the presence of decoupled boundary layers in the models, the height of maximum vertical gradient of specific humidity profiles from each model is used to define PBL heights. Results indicate that the monthly mean contribution of AOD in the FT to the total-column AOD ranges from 44 % to 74 % in September 2016 and from 54 % to 71 % in August 2017 within the region bounded by 25∘ S–0∘ N–S and 15∘ W–15∘ E (excluding land) among the ESMs. ALADIN and GEOS-Chem show similar aerosol plume patterns to a derived above-cloud aerosol product from the Moderate Resolution Imaging Spectroradiometer (MODIS) during September 2016, but none of the models show a similar above-cloud plume pattern to MODIS in August 2017. Using the second-generation High Spectral Resolution Lidar (HSRL-2) to derive an aircraft-based constraint on the AOD and the fractional AOD, we found that WRF-CAM5 produces 40 % less AOD than those from the HSRL-2 measurements, but it performs well at separating AOD fraction between the FT and the PBL. AOD fractions in the FT for GEOS-Chem and EAM-E3SM are, respectively, 10 % and 15 % lower than the AOD fractions from the HSRL-2. Their similar mean AODs reflect a cancellation of high and low AOD biases. Compared with aircraft-based observations, GEOS-FP, MERRA-2, and ALADIN produce 24 %–36 % less AOD and tend to misplace more aerosols in the PBL. The models generally underestimate AODs for measured AODs that are above 0.8, indicating their limitations at reproducing high AODs. The differences in the absolute AOD, FT AOD, and the vertical apportioning of AOD in different models highlight the need to continue improving the accuracy of modeled AOD distributions. These differences affect the sign and magnitude of the net aerosol radiative forcing, especially when aerosols are in contact with clouds.

54 ENVIRONMENTAL SCIENCES↗

A VIPA Spectrograph with Ultra-high Resolution and Wavelength Calibration for Astronomical Applications

A prototype spectrograph using a Virtually Imaged Phased Array (VIPA) as the main dispersion element is presented, and its performance is fully examined in our laboratory. The single-mode, fiber-fed spectrograph with simultaneous wavelength calibration possesses a spectral resolution well in excess of R≈1.12×10{sup 6} while the size of the VIPA is several orders of magnitude smaller than that of a conventional échelle with comparable resolution. In laboratory tests, the VIPA-based instrument with a homemade Yb:fiber ring laser frequency comb demonstrates a mode-to-mode tracking stability of 41 cm s{sup −1} over a period of 6 hr. The VIPA spectrograph has promising applications in various astronomical observations in which ultra-high resolution and calibration precision are imperative, such as solar physics research, exoplanet searching with the radial velocity method, and O{sub 2} detection in the atmosphere of Earth-like planets. Ultimately, feasible optimizations for night-sky observations under seeing limited conditions are discussed.

79 ASTRONOMY AND ASTROPHYSICS↗

Exoplanet Sciences with Nulling Interferometers and a Single-mode Fiber-fed Spectrograph

Understanding the atmospheres of exoplanets is a milestone to decipher their formation history and potential habitability. High-contrast imaging and spectroscopy of exoplanets is the major pathway toward the goal. Direct imaging of an exoplanet requires high spatial resolution. Interferometry has proven to be an effective way of improving spatial resolution. However, means of combining interferometry, high-contrast imaging, and high-resolution spectroscopy have been rarely explored. To fill in the gap, we present the dual-aperture fiber nuller (FN) for current-generation 8–10 m telescopes, which provides the necessary spatial and spectral resolution to (1) conduct follow-up spectroscopy of known exoplanets and (2) detect planets in debris-disk systems. The concept of feeding an FN to a high-resolution spectrograph can also be used for future space and ground-based missions. We present a case study of using the dual-aperture FN to search for biosignatures in rocky planets around M stars for a future space interferometry mission. Moreover, we discuss how an FN can be equipped on future extremely large telescopes by using the Giant Magellan Telescope as an example.

79 ASTRONOMY AND ASTROPHYSICS↗

Effects of Molecular Size on Resolution in Charge Detection Mass Spectrometry

Instrumental resolution of Fourier transform-charge detection mass spectrometry instruments with electrostatic ion trap detection of individual ions depends on the precision with which ion energy is determined. Energy can be selected using ion optic filters or from harmonic amplitude ratios (HARs) that provide Fellgett’s advantage and eliminate the necessity of ion transmission loss to improve resolution. Unlike the ion energy-filtering method, the resolution of the HAR method increases with charge (improved S/N) and thus with mass. An analysis of the HAR method with current instrumentation indicates that higher resolution can be obtained with the HAR method than the best resolution demonstrated for instruments with energy-selective optics for ions in the low MDa range and above. However, this gain is typically unrealized because the resolution obtainable with molecular systems in this mass range is limited by sample heterogeneity. Here, this phenomenon is illustrated with both tobacco mosaic virus (0.6–2.7 MDa) and AAV9 (3.7–4.7 MDa) samples where mass spectral resolution is limited by the sample, including salt adducts, and not by instrument resolution. Nevertheless, the ratio of full to empty AAV9 capsids and the included genome mass can be accurately obtained in a few minutes from 1× PBS buffer solution and an elution buffer containing 300+ mM nonvolatile content despite extensive adduction and lower resolution. Empty and full capsids adduct similarly indicating that salts encrust the complexes during late stages of droplet evaporation and that mass shifts can be calibrated in order to obtain accurate analyte masses even from highly salty solutions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The XRISM/Resolve View of the Fe K Region of Cyg X-3

The X-ray binary system Cygnus X-3 (4U 2030+40, V1521 Cyg) is luminous but enigmatic owing to the high intervening absorption. High-resolution X-ray spectroscopy uniquely probes the dynamics of the photoionized gas in the system. In this Letter, we report on an observation of Cyg X-3 with the XRISM/Resolve spectrometer, which provides unprecedented spectral resolution and sensitivity in the 2–10 keV band. We detect multiple kinematic and ionization components in absorption and emission whose superposition leads to complex line profiles, including strong P Cygni profiles on resonance lines. The prominent Fe xxv Heα and Fe xxvi Lyα emission complexes are clearly resolved into their characteristic fine-structure transitions. Self-consistent photoionization modeling allows us to disentangle the absorption and emission components and measure the Doppler velocity of these components as a function of binary orbital phase. We find a significantly higher velocity amplitude for the emission lines than for the absorption lines. The absorption lines generally appear blueshifted by ∼−500–600 km s −1 . We show that the wind decomposes naturally into a relatively smooth and large-scale component, perhaps associated with the background wind itself, plus a turbulent, denser structure located close to the compact object in its orbit.

Audard, Marc (ORCID:000000034721034X)↗

Resolved H i in two ultra-diffuse galaxies from contrasting non-cluster environments

ABSTRACT We report on the first resolved H i observations of two blue ultra-diffuse galaxies (UDGs), using the Giant Metrewave Radio Telescope (GMRT). These observations add to the so-far limited number of UDGs with resolved H i data. The targets are from contrasting non-cluster environments: UDG-B1 is projected in the outskirts of Hickson Compact Group 25 and Secco-dI-2 (SdI-2) is an isolated UDG. These UDGs also have contrasting effective radii with Re of 3.7 kpc (similar to the Milky Way) and 1.3 kpc, respectively. SdI-2 has an unusually large $\frac{M_{\rm H\,{\small I}}}{M_*}$ ratio = 28.9, confirming a previous single dish H i observation. Both galaxies display H i morphological and kinematic signatures consistent with a recent tidal interaction, which is also supported by observations from other wavelengths, including optical spectroscopy. Within the limits of the observations’ resolution our analysis indicates that SdI-2 is dark matter dominated within its H i radius and this is also likely to be the case for UDG-B1. Our study highlights the importance of high spatial and spectral resolution H i observations for the study of the dark matter properties of UDGs.

Scott, T. C.↗

On-chip pulse shaping of entangled photons

The miniaturization of optical systems via integrated photonics is critical to the ultimate scalability and performance of photonic quantum processors, yet many longstanding optical signal processing capabilities—such as Fourier-transform pulse shaping—remain unrealized on chip. In this work, we demonstrate on-chip spectral shaping of entangled photons using a multichannel microring-resonator-based silicon photonic pulse shaper. Achieving line-by-line phase control on a 3 GHz grid for two frequency-bin-entangled qudits, the pulse shaper's fine spectral resolution enables control of nanosecond-scale temporal features, which are observed by direct coincidence detection of biphoton correlation functions that show excellent agreement with theory. This work marks a demonstration of biphoton pulse shaping using an integrated spectral shaper and holds significant promise for applications in photonic quantum information processing.

Entanglement manipulation↗

$t_1$-Noise eliminated dipolar heteronuclear multiple-quantum coherence solid-state NMR spectroscopy

Heteronuclear correlation (HETCOR) spectroscopy is one of the key tools in the arsenal of the solid-state NMR spectroscopist to probe chemical and spatial proximities between two different nuclei and enhance spectral resolution. Dipolar heteronuclear multiple-quantum coherence (D-HMQC) is a powerful technique that can be potentially utilized to obtain 1 H detected 2D HETCOR solid-state NMR spectra of any NMR active nucleus. A long-standing problem in 1 H detected D-HMQC solid-state NMR experiments is the presence of t 1 -noise which reduces sensitivity and impedes spectral interpretation. In this contribution, we describe novel pulse sequences, termed t 1 -noise eliminated (TONE) D-HMQC, that minimize t 1 -noise and can provide higher sensitivity and resolution than conventional D-HMQC. Monte-Carlo and numerical simulations confirm that t 1 -noise in conventional D-HMQC primarily occurs because random MAS frequency fluctuations cause variations in the NMR signal amplitude from scan to scan, leading to imperfect cancellation of uncorrelated signals by phase cycling. The TONE D-HMQC sequence uses 1 H π-pulses to refocus the evolution of 1 H CSA across each SR4 2 1 recoupling block, improving the stability of the pulse sequence to random MAS frequency fluctuations. The 1 H refocusing pulses also restore the orthogonality of in-phase and anti-phase magnetization for all crystallite orientations at the end of each recoupling block, enabling the use of 90° flip-back or LG spin-lock trim pulses to reduce the intensity of uncorrelated signals. We demonstrate the application of these methods to acquire 1 H detected 2D 1 H{ 35 Cl} and 1 H{ 13 C} HETCOR spectra of histidine·HCl·H 2 O with reduced t 1 -noise. To show generality, we also apply these methods to obtain 2D 1 H{ 17 O} spectra of 20%- 17 O fmoc-alanine and for the first time at natural abundance, 2D 1 H{ 25 Mg} HETCOR spectra of magnesium hydroxide. The TONE D-HMQC sequences are also used to probe 1 H– 25 Mg and 1 H– 27 Al proximities in Mg–Al layered double hydroxides and confirm the even mixing of Mg and Al in these materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

iMaNGA: mock MaNGA galaxies based on IllustrisTNG and MaStar SSPs – I. Construction and analysis of the mock data cubes

ABSTRACT Galaxy formation and evolution simulations are essential tools to probe poorly known astrophysics processes, but particular care is needed to compare simulations with galaxy observations, as observed data need to be modelled as well. We present a method to generate mock galaxies from the hydro-dynamical IllustrisTNG simulations which are suited to compare with integral field spectroscopic observation of galaxies from the SDSS-IV/Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey. First, we include the same instrumental effects and procedures as adopted in the acquisition and analysis of real data. Furthermore, we generate the galaxy spectra from the simulations using new stellar population models based on the MaNGA stellar library (MaStar). In this way, our mock data cubes have the same spatial sampling, cover the same wavelength range (3600–10 300 Å), and share the same spectral resolution (R ≈ 1800) and flux calibration of real MaNGA galaxy spectra. In this first paper, we demonstrate the method over an early- and a late-type simulated galaxy from TNG50. We analyse the correspondent mock MaNGA-like data cubes with the same full spectral fitting code, firefly, which was used for the observed spectra. We find that the intrinsic and recovered age and metallicity gradients are consistent within 1σ, with residuals over all tassels consistent with 0 at the 68 ${{\ \rm per\ cent}}$ confidence level. We also perform the challenging test at comparing intrinsic and recovered star formation histories, finding a close resemblance between input and output. In follow-up papers, we will present a full simulated MaNGA-like catalogue (≈10 000 galaxies) with a comprehensive comparison of TNG50 simulations to MaNGA observational results.

79 ASTRONOMY AND ASTROPHYSICS↗

High-resolution x-ray spectrometer for x-ray absorption fine structure spectroscopy

Two extended x-ray absorption fine structure flat crystal x-ray spectrometers (EFX’s) were designed and built for high-resolution x-ray spectroscopy over a large energy range with flexible, on-shot energy dispersion calibration capabilities. The EFX uses a flat silicon [111] crystal in the reflection geometry as the energy dispersive optic covering the energy range of 6.3–11.4 keV and achieving a spectral resolution of 4.5 eV with a source size of 50 μm at 7.2 keV. A shot-to-shot configurable calibration filter pack and Bayesian inference routine were used to constrain the energy dispersion relation to within ±3 eV. The EFX was primarily designed for x-ray absorption fine structure (XAFS) spectroscopy and provides significant improvement to the Laboratory for Laser Energetics’ OMEGA-60 XAFS experimental platform. The EFX is capable of performing extended XAFS measurements of multiple absorption edges simultaneously on metal alloys and x-ray absorption near-edge spectroscopy to measure the electron structure of compressed 3d transition metals.

47 OTHER INSTRUMENTATION↗

Advanced Simulation of ITER Core X-ray Crystal Spectroscopy

X-Ray Simulation Analysis (XRSA) is an analytical ray-tracing mixed code developed specifically for the ITER Core X-Ray Crystal Spectroscopy (XRCS-Core) diagnostic, which employs a dual-reflection configuration incorporating multiple pre-reflectors made of Highly Oriented Pyrolytic Graphite (HOPG) and spherically curved analyzing crystals. The ITER XRCS-Core is designed for high spectral resolution measurement in specific wavelength ranges, including narrow bands around 1.354 Å for W 64+ , 2.19 Å for Xe 51+ , and 2.555 Å for Xe 44+ and Xe 47+ , enabling diagnostic capability across a broad electron temperature range in the ITER plasma. XRSA facilitates efficient simulation of the spectral performance of this complex X-ray spectroscopic system. Recent updates to the XRSA code have incorporated two critical effects: auto-focusing, which specifically applies to HOPG, and polarization. These two effects are particularly important in the dual-reflection configuration used in the ITER XRCS-Core system to provide more accurate modeling results. Here, simulations conducted with the updated code demonstrate that polarization has a substantial impact on the performance of the dual-reflection system. Additionally, the combined influence of polarization and system layout introduces performance variations across channels through the same crystal.

Computer graphics↗

Analysis of Hybrid Gas–Dust Outbursts Observed at 67P/Churyumov–Gerasimenko

Cometary outbursts offer a valuable window into the composition of comet nuclei with their forceful ejection of dust and volatiles in explosive events, revealing the interior components of the comet. Understanding how different types of outbursts influence the dust properties and volatile abundances, to better interpret what signatures can be attributed to primordial composition and what features are the result of processing, is an important task best undertaken with a multi-instrument approach. The European Space Agency Rosetta mission to 67P/Churyumov–Gerasimenko carried a suite of instruments capable of carrying out this task in the near-nucleus coma with unprecedented spatial and spectral resolution. In this work, we discuss two outbursts that occurred 2015 November 7 and were observed by three instruments on board: the Alice ultraviolet spectrograph, the Visual Infrared and Thermal Imaging Spectrometer, and the Optical, Spectroscopic, and Infrared Remote Imaging System. Together, the observations show that mixed gas and dust outbursts can have different spectral signatures representative of their initiating mechanisms, with the first outburst showing indicators of a cliff collapse origin and the second more representative of fresh volatiles being exposed via a deepening fracture. This analysis opens up the possibility of remote spectral classification of cometary outbursts with future work.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Characterization of the Atmosphere of Super-Earth 55 Cancri e Using High-resolution Ground-based Spectroscopy

The nearby super-Earth 55 Cnc e orbits a bright (V = 5.95 mag) star with a period of -18 hr and a mass of -8M {sub ⊕}. Its atmosphere may be water-rich and have a large-scale height; though, attempts to characterize it have yielded ambiguous results. Here we present a sensitive search for water and TiO in its atmosphere at high spectral resolution using the Gemini North telescope and the GRACES spectrograph. We combine observations with previous observations from Subaru and CFHT, improving the constraints on the presence of water vapor. We adopt parametric models with an updated planet radius based on recent measurements, and use a cross-correlation technique to maximize sensitivity. Our results are consistent with atmospheres that are cloudy or contain minimal amounts of water and TiO. Using these parametric models, we rule out a water-rich atmosphere (VMR ≥ 0.1%) with a mean molecular weight of ≤ 15 g mol{sup -1} at a 3σ confidence level, improving on the previous limit by a significant margin. For TiO, we rule out a mean molecular weight of ≤ 5 g mol{sup -1} with a 3σ confidence level for a VMR greater than 10{sup -8}; for a VMR of greater than 10{sup -7}, the limit rises to a mean molecular weight of ≤ 10 g mol{sup -1}. We can rule out low mean-molecular-weight chemical equilibrium models both including and excluding TiO/VO at very high confidence levels (>10σ). Overall, our results are consistent with an atmosphere with a high mean molecular weight and/or clouds, or no atmosphere.

79 ASTRONOMY AND ASTROPHYSICS↗

High-resolution inelastic x-ray scattering at the high energy density scientific instrument at the European X-Ray Free-Electron Laser

We introduce a setup to measure high-resolution inelastic x-ray scattering at the High Energy Density scientific instrument at the European X-Ray Free-Electron Laser (XFEL). The setup uses the Si (533) reflection in a channel-cut monochromator and three spherical diced analyzer crystals in near-backscattering geometry to reach a high spectral resolution. An energy resolution of 44 meV is demonstrated for the experimental setup, close to the theoretically achievable minimum resolution. The analyzer crystals and detector are mounted on a curved-rail system, allowing quick and reliable changes in scattering angle without breaking vacuum. The entire setup is designed for operation at 10 Hz, the same repetition rate as the high-power lasers available at the instrument and the fundamental repetition rate of the European XFEL. Among other measurements, it is envisioned that this setup will allow studies of the dynamics of highly transient laser generated states of matter.

47 OTHER INSTRUMENTATION↗

Multi-cone x-ray imaging Bragg crystal spectrometer

Embodiments provide a multi-cone X-ray imaging Bragg crystal spectrometer for spectroscopy of small x-ray sources with a well-defined spectral resolution. The spectrometer includes a glass substrate machined to a multi-cone form; and a thin crystal slab attached to the glass substrate, whereby the multi-cone X-ray imaging Bragg crystal spectrometer provides rotational symmetry of a ray pattern, providing for accurate imaging, for each wavelength in the spectral range of interest. One or more embodiments include a streak camera and/or a gated strip detector.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗