Search NASA⌕ Search

SEARCH · Search NASA

Results for “STRESS CORROSION”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 91 records · Page 5

Stress-corrosion behavior of aluminum-lithium alloys in aqueous salt environments

The stress corrosion susceptibility of two powder metallurgy (P/M) alloys, Al-Li-Cu and Al-Li-Cu-Mg; two mechanically attrited (M/A) alloys, Al-Li-Cu and Al-Li-Mg; and two wrought, ingot alloys, X-2020 and AA7475, are compared. Time-dependent fracture in an aqueous sodium chloride environment under alternate immersion condition was found to vary significantly between alloys. The stress corrosion behavior of the two powder metallurgy processed alloys was studied in detail under conditions of crack initiation, static crack growth, and fatigue crack growth. A variety of stress corrosion tests were performed including smooth surface, time-to-failure tests; potentiostatic tests on smooth surfaces exposed to constant applied strain rates; and fracture mechanics-type tests under static and cyclic loads. Both alloys show surface pitting and subsequent intergranular corrosion. Pitting is more severe in the magnesium-bearing alloy and is associated with stringer particles strung along the extrusion direction as a result of P/M processing.

Pizzo, P. P.↗

Nondestructive Evaluation of Stress Corrosion Cracking in a Welded Steel Plate Using Guided Ultrasonic Waves

Stress corrosion cracking (SCC) had occurred in early-generation high-level nuclear waste tanks constructed by welding carbon steel. This paper describes an ultrasonic inspection system and its fundamental ability to detect and quantify the length of SCC on thick welded steel plates. The finite element method (FEM) was applied to simulate the welding process to estimate the welding residual stress field. Growth of stress corrosion cracks is driven by crack stress intensities exceeding the subcritical cracking threshold intensity. The subject plate was experimentally inspected with ultrasonic nondestructive evaluation (NDE) techniques to characterize the extent of SCC. The NDE system uses a piezoelectric transducer to generate guided waves in the thick steel plate, and a scanning laser Doppler vibrometer (SLDV) to measure multidimensional time–space wavefield data over a user-defined scanning area in the plate surface. The measured wavefield data can show wave interactions in a localized area in the plate due to the presence of the discontinuities of the SCC. To generate an inspection image that can precisely show the crack’s location and/or the dimension, the wavefield data are further processed to generate inspection image that maps the entire sample plate so the crack can be clearly identified in the plate while its length can be readily estimated. In conclusion, the ultrasonic test results for crack length agree well with the visually estimated length and are close to that predicted by the FEM for cracks in the weld residual stress field.

36 MATERIALS SCIENCE↗

Stress corrosion cracking of titanium alloys.

Stress corrosion cracking of titanium alloys noting tensile test data, crack propagation in salt solution and in pure solvents and metallurgical and electrochemical factors

Beck, T. R.↗

Role of pH on the stress corrosion cracking of titanium alloys

Stress corrosion cracking (SCC) experiments were conducted on Ti-8-1-1 wire specimens in hydrochloric and sulfuric acids of variable pH in order to determine the effect of pH on the susceptibility to cracking. The alloy exhibited increasing susceptibility with decreasing pH. By varying the applied potential, it was observed that susceptibility zones exist both in the cathodic and the anodic ranges. In the cathodic range, susceptibility also increased with decreasing applied potential. Corrosion potential-time data in hydrochloric acid (pH 1.7) and sulfuric acid (pH 1.7) indicate that chloride ions lower the corrosion potential of the specimen which, in turn, increases the susceptibility.

Khokhar, M. I.↗

Stress-corrosion cracking due to hydrazine

Stress corrosion cracking susceptability in presence of hydrazine is examined for 6061-T6, Ti-6A1-4V(STA), Inconel 718, 410 stainless steel, and 4130 steel alloys.

Adamson, M. J.↗

Surface aspects of pitting and stress corrosion cracking

The pitting and stress corrosion cracking of a stable austenitic stainless steel in aqueous chloride environments were investigated using a secondary ion mass spectrometer as the primary experimental technique. The surface concentration of hydrogen, oxygen, the hydroxide, and chloride ion, magnesium or sodium, chromium and nickel were measured as a function of potential in both aqueous sodium chloride and magnesium chloride environments at room temperature and boiling temperatures. It was found that, under anodic conditions, a sharp increase in the chloride concentration was observed to occur for all environmental conditions. The increase may be associated with the formation of an iron chloride complex. Higher localized chloride concentrations at pits and cracks were also detected with an electron microprobe.

Truhan, J. S., Jr.↗

Probability of stress-corrosion fracture under random loading.

A method is developed for predicting the probability of stress-corrosion fracture of structures under random loadings. The formulation is based on the cumulative damage hypothesis and the experimentally determined stress-corrosion characteristics. Under both stationary and nonstationary random loadings, the mean value and the variance of the cumulative damage are obtained. The probability of stress-corrosion fracture is then evaluated using the principle of maximum entropy. It is shown that, under stationary random loadings, the standard deviation of the cumulative damage increases in proportion to the square root of time, while the coefficient of variation (dispersion) decreases in inversed proportion to the square root of time. Numerical examples are worked out to illustrate the general results.

Yang, J.-N.↗

Stress corrosion cracking evaluation of martensitic precipitation hardening stainless steels

The resistance of the martensitic precipitation hardening stainless steels PH13-8Mo, 15-5PH, and 17-4PH to stress corrosion cracking was investigated. Round tensile and c-ring type specimens taken from several heats of the three alloys were stressed up to 100 percent of their yield strengths and exposed to alternate immersion in salt water, to salt spray, and to a seacoast environment. The results indicate that 15-5PH is highly resistant to stress corrosion cracking in conditions H1000 and H1050 and is moderately resistant in condition H900. The stress corrosion cracking resistance of PH13-8Mo and 17-4PH stainless steels in conditions H1000 and H1050 was sensitive to mill heats and ranged from low to high among the several heats included in the tests. Based on a comparison with data from seacoast environmental tests, it is apparent that alternate immersion in 3.5 percent salt water is not a suitable medium for accelerated stress corrosion testing of these pH stainless steels.

Humphries, T. S.↗

On the Problem of Stress Corrosion

The object of the present work is first to investigate accurately the processes during stress corrosion, in particular, for light metal alloys and, as the first part of the investigation, to determine its laws; and secondly to explain its causes for various alloys and thereby find means for its partial or complete elimination and thus make possible the production of light metal alloys free from any stress corrosion. In the present paper some of the results of the investigation are given and the fundamental problems of stress corrosion discussed.

Graf, L.↗

Irradiation Assisted Stress Corrosion Cracking Susceptibility of Alloy X-750 exposed to BWR environments

The effect of irradiation on stress corrosion cracking susceptibility and fracture toughness of alloy X-750 has been investigated. The material has been irradiated at a target temperature of 288°C in the Advanced Test Reactor at Idaho National Laboratory to a fluence of approximately 1.93x1020 n/cm2 (E > 1 MeV). Stress corrosion cracking crack growth rates were determined in both unirradiated and irradiated materials in normal water chemistry and hydrogen water chemistry environments. Although the effect of irradiation on tensile properties and fracture toughness was observed, there was no significant effect of irradiation observed on the propagation rate of stress corrosion cracks.

36 MATERIALS SCIENCE↗

Hot-salt stress-corrosion of titanium alloys as related to turbine engine operation.

Demonstration that the major variables influencing hot-salt stress-corrosion of titanium alloys are alloy processing conditions, heat-to-heat variations and composition, surface condition, and cyclic exposures. Under simulated compressor environmental conditions the commonly used 64 alloy is creep limited and not stress-corrosion limited. Cyclic exposures to stress-corrosion conditions are not as detrimental as continuous exposures for equivalent total times.

Gray, H. R.↗

In situ synchrotron X-ray tomography of 304 stainless steels undergoing chlorine-induced stress corrosion cracking

To understand the mechanisms behind chlorine-induced stress corrosion cracking (CISCC) in 304 stainless steel, synchrotron high energy x-rays were used to perform in-situ x-ray microtomography on a pre-cracked sample under load in a corrosive simulated marine environment. The tomography scans showed the crack morphology evolving into a branching crack around the surface of the sample. Finite element analysis and stress intensity analysis are conducted to explain the observed crack branching.

304 Stainless Steel↗

Analysis of stress corrosion cracking in alloy 718 following commercial reactor exposure

Alloy 718 is generally considered a highly corrosion-resistant material but can still be susceptible to stress corrosion cracking (SCC). The combination of factors leading to SCC susceptibility in the alloy is not always clear enough. In this paper, alloy 718 leaf spring (LS) materials that suffered stress corrosion damage during two 24-month cycles in pressurized water reactor service, operated to >45 MWd/mtU burn-up, was investigated. Compared to archival samples fabricated through the same processing conditions, little microstructural and property changes occurred in the material with in-service irradiation, contrary to high dose rate laboratory-based experiments reported in literature. Though the lack of delta phase formation along grain boundaries would suggest a more SCC resistant microstructure, grain boundary cracking in the material was extensive. Crack propagation routes were explored through focused ion beam milling of specimens near the crack tip for transmission electron microscopy as well as in polished plan view and cross-sectional samples for electron backscatter diffraction analysis. It has been shown in this study that cracks propagated mainly along random high-angle grain boundaries, with the material around cracks displaying a high local density of dislocations. The slip lines were produced through the local deformation of the leaf spring material above their yield strength. Also, the cause for local SCC appears to be related to oxidation of both slip lines and grain boundaries, which under the high in-service stresses resulted in crack development in the material.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Effect of initial hydrogen content of a titanium alloy on susceptibility to hot salt stress corrosion.

The influence of the initial hydrogen content of a titanium alloy on subsequent resistance to hot salt stress corrosion embrittlement and cracking was investigated. A Ti-8Al-1Mo-1V alloy was tested in four conditions: mill annealed (70 ppm H), duplex annealed (70 ppm H), vacuum annealed to an intermediate (36 ppm H) and a low (9 ppm H) hydrogen level. Material annealed at 650 C (duplex condition) exhibited resistance to hot salt stress corrosion superior to that exhibited by material in the mill annealed condition. Reduction of the alloy hydrogen content from 70 to as low as 9 ppm did not influence resistance to hot salt stress corrosion embrittlement or cracking.

Gray, H. R.↗

Precursor Evolution and Stress Corrosion Cracking Initiation of Cold-Worked Alloy 690 in Simulated Pressurized Water Reactor Primary Water

Stress corrosion crack initiation of two thermally-treated, cold-worked (CW) alloy 690 (UNS N06690) materials was investigated in 360oC simulated PWR primary water using constant load tensile (CLT) tests and blunt notch compact tension (BNCT) tests equipped with direct current potential drop (DCPD) for in-situ detection of cracking. SCC initiation was not detected by DCPD for either the 21% or 31%CW CLT specimens loaded at their yield stress after ~9,220 hours, however intergranular (IG) precursor damage and isolated surface cracks were observed on the specimens. The two 31%CW BNCT specimens loaded at moderate stress intensity after several cyclic loading ramps showed DCPD-indicated crack initiation after 10,400 hours of exposure at constant stress intensity, which was resulted from significant growth of IG cracks. The 21%CW BNCT specimens only exhibited isolated small IG surface cracks and showed no apparent DCPD change throughout the test. Post-test cross-section examinations revealed many grain boundary (GB) nano-cavities in the bulk of all the CLT and BNCT specimens particularly for the 31%CW materials. Cavities were also found along GBs extending to the surface suggesting an important role in crack nucleation. This paper provides an overview of the evolution of GB cavities and discusses their effects on crack initiation in CW alloy 690.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Relative susceptibility of titanium alloys to hot-salt stress-corrosion

Susceptibility of titanium alloys to hot-salt stress-corrosion cracking increased as follows: Ti-2Al-11Sn-5Zr-0.2Si(679), Ti-6Al-2Sn-4Zr-2Mo(6242), Ti-6Al-4V(64), Ti-6Al-4V-3Co(643), Ti-8Al-1Mo-1V(811), and Ti-13V-11Cr-3A1(13-11-3). The Ti-5Al-6Sn-2Zr-1Mo-0.25Si(5621S) alloy was both the least and most susceptible depending on heat treatment. Such rankings can be drastically altered by heat-to-heat and processing variations. Residual compressive stresses and cyclic exposures also reduce susceptibility to stress-corrosion. Simulated turbine-engine compressor environmental variables such as air velocity, pressure, dewpoint, salt concentration, and salt deposition temperature have only minor effects. Detection of substantial concentrations of hydrogen in all corroded alloys confirmed the existence of a hydrogen embrittlement mechanism.

Gray, H. R.↗