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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

In situ stress measurements during electrochemical cycling of lithium-rich cathodes

Layered lithium transition metal oxides (Li 1+x M 1-x O 2 , M= Ni, Mn, Co) are attractive cathode materials for lithium-ion batteries due to their high reversible capacity but suffer from structural changes and voltage fade. In this study, we use stress as a novel way to track irreversible changes in Li 1.2 Mn 0.55 Ni 0.125 Co 0.125 O 2 (LR-NMC) cathodes. A unique and unpredicted stress signature is observed during the first delithiation. Initially, a tensile stress is observed, consistent with volume contraction from lithium removal, however, the stress reverses and becomes compressive with continued charging beyond 4 V vs Li/Li + , indicating volume expansion; this phenomenon is present in the first cycle only. The origin of this irreversible stress during delithiation is likely oxygen loss and the resulting cation rearrangement. Here, Raman spectroscopy provides evidence of the layered-to-spinel phase transition after cycling in the LR-NMC films, as well as recovery of the original spectra upon re-annealing in an oxygen environment.

25 ENERGY STORAGE↗

Review of magnetoacoustic residual stress measurement technique for iron-like ferromagnetic alloys

It is shown that the elastic moduli of ironlike ferromagnetics depends explicitly on the state of 90 deg domain walls: the more 90 deg domain wall area available, the lower the elastic modulus. New experimental results obtained for three types of carbon and pure iron samples are presented. The magnetoacoustic response due to magnetization perpendicular to the uniaxial stress axis is considered as well as the magnetoacoustic response due to magnetization parallel to the uniaxial stress axis.

Namkung, M.↗

Residual Stress Measurements of Cr-coated Cladding

Accident-tolerant fuel concepts for light-water reactor applications have been developed and tested in diverse research programs around the world. Industry teams have developed coated cladding concepts using different coating application methods, such as physical vapor deposition and coldspraying. Recently, variations in thickness and application method were investigated, and their effects on the microstructure and mechanical properties were reported. The results suggest an increase in performance in an unirradiated state, however, it remains unclear what phenomenon drove this performance. One explanation to this performance is associated with the coating process imparting a residual stress. Residual stress analysis was performed on coatings produced with various process parameters to understand how a thin layer of Cr impacts the mechanical properties after coating application and after simulated operating conditions. The gathered information is intended to address safety concerns or support margin identification related to accident-tolerant fuels and to support subsequent modeling and simulation efforts.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Modeling slip system strength evolution in Ti-7Al informed by in-situ grain stress measurements

In this work, far-field high-energy X-ray diffraction microscopy is used to asses the evolution of slip system strengths in hexagonal close-packed (HCP) Ti-7Al during tensile deformation in-situ. The following HCP slip system families are considered: basal $\langle$a$\rangle$, prismatic $\langle$a$\rangle$, pyramidal$\langle$a$\rangle$, and first-order pyramidal $\langle$c + a$\rangle$. A 1 mm length of the specimen's gauge section, marked with fiducials and comprised of an aggregate of over 500 grains, is tracked during continuous deformation. The response of each slip system family is quantified using ‘slip system strength curves’ that are calculated from the average stress tensors of each grain over the applied deformation history. These curves, which plot the average resolved shear stress for each slip system family versus macroscopic strain, represent a mesoscopic characterization of the aggregate response. A short time-scale transient softening is observed in the basal $\langle$a$\rangle$, prismatic $\langle$a$\rangle$, and pyramidal $\langle$a$\rangle$ slip systems, while a long time-scale transient hardening is observed in the pyramidal $\langle$c + a$\rangle$ slip systems. These results are used to develop a slip system strength model as part of an elasto-viscoplastic constitutive model for the single crystal behavior. A suite of finite element simulations is performed on a virtual polycrystal to demonstrate the relative effects of the different parameters in the slip system strength model. The model is shown to accurately capture the macroscopic stress-strain response using parameters that are chosen to capture the mesoscopic slip system responses.

36 MATERIALS SCIENCE↗

Evaluation of a self-equilibrium cutting strategy for the contour method of residual stress measurement

An assessment of cutting-induced plasticity (CIP) is performed, by finite element (FE) prediction of the plastic strain accumulation along the cut tip when the EDM wire sections the NeT TG4 weld benchmark specimen along two cutting directions. The first direction corresponds to a conventional (C) cutting strategy, whereby the EDM wire cuts through the thickness of the weld specimen and travels in a direction transverse to the weld. The second direction corresponds to a self-equilibrating cutting (SE) strategy, whereby the EDM wire cuts across the transverse direction of the weld specimens and travels through the thickness of the plate. The cutting thus progresses simultaneously through the compression-tension-compression regions of present weld residual stress (WRS) field. This type of cutting strategy is believed to minimize the CIP by minimising residual stress redistribution during cutting, due to stress equilibration across the sectioned material. The simulated cutting procedures are conducted under a range of clamping conditions to assess whether mechanical restraint has a primary or secondary influence on CIP accumulation. Both predictions of CIP and the resultant back-calculated WRS demonstrate that (i) mechanical restraint is the primary variable influencing CIP development, and (ii) under no circumstance does a self-equilibrating cutting strategy perform significantly better than a conventional cutting approach. Furthermore, the reason that self-equilibrating cuts are not effective is illustrated by calculating the Mode I (K I ) stress intensity factor (SIF) along the cut tip, and correlating trends in K I to CIP development.

36 MATERIALS SCIENCE↗

Stress measurements of planar dielectric elastomer actuators

Dielectric elastomer actuator (DEA) micro- and nano-structures are referred to artificial muscles because of their specific continuous power and adequate time response. The bending measurement of an asymmetric, planar DEA is described. The asymmetric cantilevers consist of 1 or 5 μm-thin DEAs deposited on polyethylene naphthalate (PEN) substrates 16, 25, 38, or 50 μm thick. The application of a voltage to the DEA electrodes generates an electrostatic pressure in the sandwiched silicone elastomer layer, which causes the underlying PEN substrate to bend. Optical beam deflection enables the detection of the bending angle vs. applied voltage. Bending radii as large as 850 m were reproducibly detected. DEA tests with electric fields of up to 80 V/μm showed limitations in electrode’s conductivity and structure failures. The actuation measurement is essential for the quantitative characterization of nanometer-thin, low-voltage, single- and multi-layer DEAs, as foreseen for artificial sphincters to efficiently treat severe urinary and fecal incontinence.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Calibration of X-Ray Diffraction Instruments for Residual-Stress Measurement

The deficiencies of existing standard iron and nickel samples for calibration by means of X-ray diffraction are noted. These standards cannot be used in calibration by magnetic noise recording. A new calibration method based on X-ray diffraction is proposed, using plane samples of the material employed in the manufacture of the actual structures. Theoretical analysis provides the basis for the development of null standards in which a plane sample is deformed by pure flexure or in a cantilever-beam configuration.

42 ENGINEERING↗

Differential temperature stress measurement employing array sensor with local offset

The instrument has a focal plane array of infrared sensors of the integrating type such as a multiplexed device in which a charge is built up on a capacitor which is proportional to the total number of photons which that sensor is exposed to between read-out cycles. The infrared sensors of the array are manufactured as part of an overall array which is part of a micro-electronic device. The sensor achieves greater sensitivity by applying a local offset to the output of each sensor before it is converted into a digital word. The offset which is applied to each sensor will typically be the sensor's average value so that the digital signal which is periodically read from each sensor of the array corresponds to the portion of the signal which is varying in time. With proper synchronization between the cyclical loading of the test object and the frame rate of the infrared array the output of the A/D converted signal will correspond to the stress field induced temperature variations. A digital lock-in operation may be performed on the output of each sensor in the array. This results in a test instrument which can rapidly form a precise image of the thermoelastic stresses in an object.

Lesniak, Jon R.↗

A borehole jack for deformability, strength, and stress measurements in a 2-inch borehole

A borehole jack devised for lunar exploration is described and results of its use in simulated lunar solids are presented. A hydraulic cylinder mounted between two stiff plates acts to spread the plates apart against the borehole walls when pressured. The spreading is measured by a displacement transducer and the load is measured hydraulically. The main improvement over previous instruments is the increased stroke, which allows large deformations of the borehole. Twenty-eight pistons are used to obtain a high hydraulic efficiency, and three return pistons are also provided. Pressure-deformation curves were obtained for each test on Lunar Soil Simulant No. 2, a light gray silty basalt powder.

Goodman, R. E.↗