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At least 91 records · Page 5

Analysis of Pt/SnO(sub x) during catalysis of CO oxidation

Temperature-programmed reduction using 6kPaH2 suggests that a sample consisting of 3 percent Pt supported directly on SnO2 is, under conditions of catalysis of CO oxidation used here, best represented as 3 percent Pt/SnO sub x, since the support is likely to partially reduced, probably in the vicinity of the metal/oxide interface. Catalytic measurements at 421 to 424 K show that this 3 percent Pt/SnO sub x is significantly more active per unit area of Pt than 6 percent Pt/SiO2 in catalyzing the oxidation of CO. In situ micro-FTIR reveals that while the latter has predominantly linearly bound CO on the surface under reaction conditions, the Pt/SnO sub x also has a species absorbing at 2168 cm(exp -1) which may be CO upon Pt in a positive oxidation state or weakly chemisorbed CO on zero-valent Pt. This may be directly involved in the low temperature oxidation of CO on the Pt/SnO sub x, since being weakly held the activation energy for its surface diffusion to the metal/oxide interface will be low; such mobile species could allow the high rates of surface transport and an increase in the fraction of the surface over which the CO oxidation occurs. FTIR also reveals carbonate-type species on the P/SnO sub c surface.

Sermon, Paul A.↗

Improved diffusion welding and roll welding of titanium alloys

Auto-vacuum cleaning technique was applied to titanium parts prior to welding. This provides oxide-free welding surfaces. Diffusion welding can be accomplished in as little as five minutes of hot pressing. Roll welding can be accomplished with only ten percent deformation.

Holko, K. H.↗

Surface and Atmospheric Shortwave Radiative Fluxes From ISCCP Data and Fu-Liou Algorithm at Higher Spatial and Vertical Resolution

NASA/GEWEX Surface Radiation Budget (SRB) has provided surface and TOA shortwave and longwave radiative fluxes using International Satellite Cloud Climatology data as the primary input. Release 4.0 came out in 2019, with data from July 1983 through June 2017, and improved validation stats relative to Release 3.0 (Stackhouse et al., 2012). Release 4.0 used the newly reprocessed ISCCP H data set. The shortwave algorithm for versions 3 and 4 has been based on the Pinker and Laszlo (1992) algorithm, which relies on the satellite-measured shortwave radiance to produce a TOA albedo. This background TOA albedo is made utilizing the background clear-sky visible radiance (called clear-sky composite radiance in the ISCCP data) and applying narrowband-to-broadband angular distribution models. Using a climatological aerosol assumption, the surface albedo is estimated using radiative transfer based (i.e., Fu/Liou radiative transfer model; Fu and Liou, 1993) look-up tables. Using this surface albedo and an instantaneous TOA albedo, the look-up tables are used to adjust both the aerosol optical depth (for clear sky) and cloud optical depth (for cloudy sky) for each scene. These properties and look up tables are then used to generate surface fluxes. While this has worked well to provide useful fluxes, it has occasionally resulted in inaccurate direct and diffuse surface SW fluxes due to the overreliance on aerosol optical depth. With increased computational power and storage now available, a more direct approach is now possible. Here we present a different approach for a future high resolution SRB Release 5.0. We replace the Pinker-Laszlo lookup table approach with a forward call to the Fu-Liou radiative transfer model as modified by the CERES team (Rose et al., 2006). In addition to being a proven radiation code, Fu-Liou allows the calculation of fluxes at different atmospheric levels and spectral bands, which will provide more insight into the surface radiation budget, its variability and attribution. It is expected that horizontal resolution will increase to at least 0.5°x0.5° from the current 1°x1°. Here we demonstrate a preliminary look at the next SRB, and show comparisons with the current release.

Earth Radiation Budget↗

A Wind Tunnel Investigation of Three NACA 1-Series Inlets at Mach Numbers up to 0.92

Pressure distributions on three NACA 1-series inlets have been obtained in the Langley 16-Foot Transonic Tunnel. The cowl diameter ratio (ratio of cowl highlight diameter to cowl maximum diameter) was 0.85 for all three inlets. The cowl length ratio (ratio of cowl length to cowl maximum diameter) was 1.0 for two of the inlets (NACA 1-85-100) and 0.439 for the other (NACA 1-85-43.9) inlet. One of the inlets with a cowl length ratio of 1.0 had an internal contraction ratio (ratio of highlight area to throat area) of 1.009 and the other had a contraction ratio of 1.250. The inlet with a cowl length ratio of 0.439 also had an internal contraction ratio of 1.250. All three inlets had longitudinal rows of static pressure orifices on the top and bottom external cowl surfaces. The inlet with a contraction ratio of 1.009 also had a row of static pressure orifices on the side of the cowl (external surface). The two inlets with a contraction ratio of 1.250 had a longitudinal row of static pressure orifices on the diffuser surface.

Re, Richard J.↗

Prediction of laminar and turbulent boundary layer flow separation in V/STOL engine inlets

The paper provides a theoretical description of the development of the boundary layer on the lip and diffuser surface of a subsonic inlet at arbitrary operating conditions of mass flow rate, freestream velocity and incidence angle. Both laminar separation on the lip and turbulent separation in the diffuser are discussed. The agreement of the theoretical results with model experimental data illustrates the capability of the theory to predict separation. The effects of throat Mach number, inlet size, and surface roughness on boundary-layer development and separation are illustrated.

Chou, D. C.↗

Prediction of Laminar and Turbulent Boundary Layer Flow Separation in V/STOL Engine Inlets

A description is presented of the development of the boundary layer on the lip and diffuser surface of a subsonic inlet at arbitrary operating conditions of mass flow rate, free stream velocity and incidence angle. Both laminar separation on the lip and turbulent separation in the diffuser are discussed. The agreement of the theoretical results with model experimental data illustrates the capability of the theory to predict separation. The effects of throat Mach number, inlet size, and surface roughness on boundary layer development and separation are illustrated.

Chou, D. C.↗

Three-dimensional radiative exchange factors for nongray, nondiffuse surfaces

A computer program using a variation of the Monte Carlo method was developed to predict radiative exchange factors in three-dimensional configurations with curved surfaces. The model allows for arbitrary emission, absorption, and reflection characteristics and for radiation exchange between surfaces as well as external irradiation through openings. It was shown that exchange factors can be determined efficiently by using the normal Monte Carlo method for closed configurations and/or high surface emissivities, while energy partitioning is vastly superior in the case of open configurations and/or low surface emissivities. Comparison with some experiments performed on the Space Shuttle heat rejection system demonstrates the model's accuracy as well as its superiority over a simplified diffuse-surface analysis, which requires similar amounts of computer time.

Modest, M. F.↗

Physics of pitch angle scattering and velocity diffusion. I - Theory

A general theory for the pitch angle scattering and velocity diffusion of particles in the field of a spectrum of waves in a magnetized plasma is presented. The test particle theory is used to analyze the particle motion. The form of diffusion surfaces is examined, and analytical expressions are given for the resonance width and bounce frequency. The resonance widths are found to vary strongly as a function of harmonic number. The resulting diffusion can be quite asymmetric with respect to pitch angle of 90 deg. The conditions for the onset of pitch angle scattering and energy diffusion are explained in detail. Some of the known shortcomings of the standard quasi-linear theory are also addressed, and ways to overcome them are shown. In particular, the often stated quasi-linear gap at 90 deg is found to exist only under very special cases. For instance, oblique wave propagation can easily remove the gap. The conditions for the existence of the gap are described in great detail. A new diffusion equation which takes into account the finite resonance widths is also discussed. The differences between this new theory and the standard resonance broadening theory is explained.

Karimabadi, H.↗

Performance of Compressor of XJ-41-V Turbojet Engine II - Static-Pressure Ratios and Limitation of Maximum Flow at Equivalent Compressor Speed of 8000 rpm

At the request of the Air Material Command, Army Air Forces, an investigation was conducted by the NACA Cleveland laboratory to determine the performance characteristics of the compressor of the XJ-41-V turbojet engine. This report is the second in a series presenting the compressor performance and analysis of flow conditions in the compressor. The static-pressure variation in the direction of flow through the compressor and the location and the cause of the maximum flow restriction at an equivalent speed of 8000 rpm are presented. After the initial runs were reported, the leading edges of the impeller blades and the diffuser surfaces were found to have been roughened by steel particles from a minor failure of auxiliary equipment. The leading edges of the impeller blades were refinished and all high spots resulting from scratches in the diffuser and the accessible parts of the vaned collector passages were removed. The initial overall performance and that obtained with the refinished blades are presented.

Dildine, Dean M.↗

Flow downstream of the heliospheric terminal shock - The magnetic field on the heliopause

Modeling the kinematic magnetic field in the solar wind beyond the terminal shock shows that a ridge of magnetic pressure is produced just inside the heliopause. This ridge is sufficiently large that it will cause the layer immediately inside the heliopause to thicken, pushing the heliopause outward and slightly affecting its position relative to the terminal shock. However, the ridge is far too thin to cause an important change in the distance of the terminal shock from the sun. We show that these conclusions are a simple consequence of geometrical arguments for incompressible, steady, laminar flows. Moreover, the heliopause magnetic field originates on the terminal shock near the substagnation point. Consequently, the heliospheric current sheet field reversals are painted onto the inside surface of the heliopause. Alternate magnetic polarity strips will be oppositely directed relative to the interstellar magnetic field, implying that reconnection inevitably occurs on a fine some near the nose of the heliosphere. This suggests that the heliopause is a leaky, diffuse surface.

Nerney, Steven↗

Surface migration and volume diffusion in the AgGaSe2-Ag2Se system

Surface migration and volume diffusion in the Ag2Se-AgGaSe2 system were investigated using reactive diffusion couples which were analyzed by X-ray diffraction, optical microscopy, and electron probe microanalysis. The surface diffusivities of all mobile species are found to be much larger than volume diffusivities. The results of the study suggest that Se moves together with Ag and Ga to maintain binary (Ag2Se and Ga2Se3) stoichiometry and electroneutrality. The dominance of surface migration kinetics can account for the uniform annihilation of second-phase precipitates during heat treatments.

Kim, N.-H.↗

MODIS Solar Diffuser Attenuation Screen Modeling Results

On-orbit calibration of the reflected solar bands on the EOS Moderate Resolution Imaging Spectroradiometer (MODIS) is accomplished by have the instrument view a high reflectance diffuse surface illuminated by the sun. For some of the spectral bands this proves to be much too bright a signal that results in the saturation of detectors designed for measuring low reflectance (ocean) surfaces signals. A mechanical attenuation device in the form of a pin hole screen is used to reduce the signals to calibrate these bands. The sensor response to solar illumination of the SD with and without the attenuation screen in place will be presented. The MODIS detector response to the solar diffuser is smooth when the attenuation screen is absent, but has structures up to a few percent when the attenuation screen is present. This structure corresponds to non-uniform illumination from the solar diffuser. Each pin hole produces a pin-hole image of the sun on the solar diffuser, and there are very many pin hole images of the sun on the solar diffuser for each MODIS detector. Even though there are very many pin-hole images of the sun on the solar diffuser, it is no longer perfectly uniformly illuminated. This non-uniformly illuminated solar diffuser produces intensity variation on the focal planes. The results of a very detailed simulation will be discussed which show how the illumination of the focal plane changes as a result of the attenuation, and the impacts on the calibration will be discussed.

Waluschka, Eugene↗

Epitaxial solar-cell fabrication, phase 2

Dichlorosilane (SiH2Cl2) was used as the silicon source material in all of the epitaxial growths. Both n/p/p(+) and p/n/n(+) structures were studied. Correlations were made between the measured profiles and the solar cell parameters, especially cell open-circuit voltage. It was found that in order to obtain consistently high open-circuit voltage, the epitaxial techniques used to grow the surface layer must be altered to obtain very abrupt doping profiles in the vicinity of the junction. With these techniques, it was possible to grow reproducibly both p/n/n(+) and n/p/p(+) solar cell structures having open-circuit voltages in the 610- to 630-mV range, with fill-factors in excess of 0.80 and AM-1 efficiencies of about 13%. Combinations and comparisons of epitaxial and diffused surface layers were also made. Using such surface layers, we found that the blue response of epitaxial cells could be improved, resulting in AM-1 short-circuit current densities of about 30 mA/cm sq. The best cells fabricated in this manner had AM-1 efficiency of 14.1%.

Daiello, R. V.↗

Photophysics of Laser Dye-Doped Polymer Membranes for Laser-Induced Fluorescence Photogrammetry

Laser-induced fluorescence target generation in dye-doped polymer films has recently been introduced as a promising alternative to more traditional photogrammetric targeting techniques for surface profiling of highly transparent or reflective membrane structures. We investigate the photophysics of these dye-doped polymers to help determine their long-term durability and suitability for laser-induced fluorescence photogrammetric targeting. These investigations included experimental analysis of the fluorescence emission pattern, spectral content, temporal lifetime, linearity, and half-life. Results are presented that reveal an emission pattern wider than normal Lambertian diffuse surface scatter, a fluorescence time constant of 6.6 ns, a pump saturation level of approximately 20 micro J/mm(exp 2), and a useful lifetime of more than 300,000 measurements. Furthermore, two demonstrations of photogrammetric measurements by laser-induced fluorescence targeting are presented, showing agreement between photogrammetric and physically measured dimensions within the measurement scatter of 100 micron.

Dorrington, Adrian A.↗

Zenith angle effects in multichannel infrared sea surface remote sensing

Several approaches to infrared multichannel sea surface temperature retrievals propose using a universal set of constants. It is shown that the single-channel multiangle technique (i.e., GOES and NOAA) and the multichannel single-angle technique (NOAA-n) are similar concepts with a common derivation from radiative transfer theory. It is also shown that the linear correlation factor between surface temperature minus satellite temperature in one channel versus the difference in satellite temperatures in two channels is not independent of the difference in satellite sensed equivalent blackbody temperature. The 3.7-micron, 11-micron, and 12-micron channels on the NOAA-n AVHRR can be used in combination to compute atmospheric transmissivity and average atmospheric temperature, but a better combination would be substituting three 0.5-micron-wide channels centered on 11.25 micron, 11.75 micron, and 12.25 micron. A triple window multispectral scanner in the 11-12.5 micron region allows determination of diffuse surface reflectance which can bias sea surface temperatures - 0.4 K + or - 0.3 K.

Maul, G. A.↗

Metrology of Large Parts

As discussed in the first chapter of this book, there are many different methods to measure a part using optical technology. Chapter 2 discussed the use of machine vision to measure macroscopic features such as length and position, which was extended to the use of interferometry as a linear measurement tool in chapter 3, and laser or other trackers to find the relation of key points on large parts in chapter 4. This chapter looks at measuring large parts to optical tolerances in the sub-micron range using interferometry, ranging, and optical tools discussed in the previous chapters. The purpose of this chapter is not to discuss specific metrology tools (such as interferometers or gauges), but to describe a systems engineering approach to testing large parts. Issues such as material warpage and temperature drifts that may be insignificant when measuring a part to micron levels under a microscope, as will be discussed in later chapters, can prove to be very important when making the same measurement over a larger part. In this chapter, we will define a set of guiding principles for successfully overcoming these challenges and illustrate the application of these principles with real world examples. While these examples are drawn from specific large optical testing applications, they inform the problems associated with testing any large part to optical tolerances. Manufacturing today relies on micrometer level part performance. Fields such as energy and transportation are demanding higher tolerances to provide increased efficiencies and fuel savings. By looking at how the optics industry approaches sub-micrometer metrology, one can gain a better understanding of the metrology challenges for any larger part specified to micrometer tolerances. Testing large parts, whether optical components or precision structures, to optical tolerances is just like testing small parts, only harder. Identical with what one does for small parts, a metrologist tests large parts and optics in particular to quantify their mechanical properties (such as dimensions, mass, etc); their optical prescription or design (i.e. radius of curvature, conic constant, vertex location, size); and their full part shape. And, just as with small parts, a metrologist accomplishes these tests using distance measuring instruments such as tape measures, inside micrometers, coordinate measuring machines, distance measuring interferometers; angle measuring instruments such as theodolites, autocollimators; and surface measuring instruments including interferometers, stylus profilers, interference microscopes, photogrammetric cameras, or other tools. However, while the methodology may be similar, it is more difficult to test a large object for the simple reason that most metrologists do not have the necessary intuition. The skills used to test small parts or optics in a laboratory do not extrapolate to testing large parts in an industrial setting any more than a backyard gardener might successfully operate a farm. But first, what is a large part? A simple definition might be the part's size or diameter. For optics and diffuse surface parts alike, the driving constraint is ability to illuminate the part's surface. For reflective convex mirrors, large is typically anything greater than 1 meter. But, for refractive optics, flats or convex mirrors, large is typically greater than 0.5 meter. While a size definition is simple, it may be less than universal. A more nuanced definition might be that a large part is any component which cannot be easily tested in a standard laboratory environment, on a standard vibration isolated table using standard laboratory infrastructure. A micro-switch or a precision lens might be easily measured to nanometer levels under a microscope in a lab, but a power turbine spline or a larger telescope mirror will not fit under that microscope and may not even fit on the table.

Stahl, H. Philip↗

Multicomponent Gas Diffusion and an Appropriate Momentum Boundary Condition

Multicomponent gas diffusion is reviewed with particular emphasis on gas flows near solid boundaries-the so-called Kramers-Kistemaker effect. The aim is to derive an appropriate momentum boundary condition which governs many gaseous species diffusing together. The many species' generalization of the traditional single gas condition, either as slip or stick (no-slip), is not obvious, particularly for technologically important cases of lower gas pressures and very dissimilar molecular weight gases. No convincing theoretical case exists for why two gases should interact with solid boundaries equally but in opposite flow directions, such that the total gas flow exactly vanishes. ln this way, the multicomponent no-slip boundary requires careful treatment The approaches discussed here generally adopt a microscopic model for gas-solid contact. The method has the advantage that the mathematics remain tractable and hence experimentally testable. Two new proposals are put forward, the first building in some molecular collision physics, the second drawing on a detailed view of surface diffusion which does not unphysically extrapolate bulk gas properties to govern the adsorbed molecules. The outcome is a better accounting of previously anomalous experiments. Models predict novel slip conditions appearing even for the case of equal molecular weight components. These approaches become particularly significant in view of a conceptual contradiction found to arise in previous derivations of the appropriate boundary conditions. The analogous case of three gases, one of which is uniformly distributed and hence non-diffusing, presents a further refinement which gives unexpected flow reversals near solid boundaries. This case is investigated alone and for aggregating gas species near their condensation point. In addition to predicting new physics, this investigation carries practical implications for controlling vapor diffusion in the growth of crystals used in medical diagnosis (e.g. mercuric iodide) and semiconductors.

Noever, David A.↗

Actinic Flux Calculations: A Model Sensitivity Study

calculate direct and diffuse surface irradiance and actinic flux (downwelling (2p) and total (4p)) for the reference model. Sensitivity analysis has shown that the accuracy of the radiative transfer flux calculations for a unit ETS (i.e. atmospheric transmittance) together with a numerical interpolation technique for the constituents' vertical profiles is better than 1% for SZA less than 70(sub o) and wavelengths longer than 310 nm. The differences increase for shorter wavelengths and larger SZA, due to the differences in pseudo-spherical correction techniques and vertical discretetization among the codes. Our sensitivity study includes variation of ozone cross-sections, ETS spectra and the effects of wavelength shifts between vacuum and air scales. We also investigate the effects of aerosols on the spectral flux components in the UV and visible spectral regions. The "aerosol correction factors" (ACFs) were calculated at discrete wavelengths and different SZAs for each flux component (direct, diffuse, reflected) and prescribed IPMMI aerosol parameters. Finally, the sensitivity study was extended to calculation of selected photolysis rates coefficients.

Krotkov, Nickolay A.↗