Aerospace castings produced from magnesium- lithium-silicon alloy.
Aerospace castings from light ternary Mg-Li-Si alloy, discussing fabrication development
AEROSPACE TECHNOLOGY↗
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Infrared response measurements on radiation-damaged Si/Li/ detectors.
The improved infrared response (IRR) technique has been used to qualitatively compare radiation effects on Si(Li) detectors with energy levels reported for silicon in the literature. Measurements have been made on five commercial silicon detectors and one fabricated in-house, both before and after irradiation with fast neutrons, 1.9-MeV protons, and 1.6-MeV electrons. Effects dependent upon the extent of radiation damage have been observed. It seems likely that the photo-EMF, or photo-voltage, effect is the basic mechanism for the observation of IRR in p-i-n diodes with a wide i-region. Experimental characteristics of the IRR measurement are in agreement with those of the photovoltage effect.
Sher, A. H.↗
Si/Li/ X-ray astronomical spectroscopy
The principles of operation of solid state nondispersive spectrometers are reviewed. Si(Li) is shown to be the preferred nondispersive X-ray spectrometer because of its inherent resolution advantages and its adaptability to the constraints and philosophy of the HEAO-B observatory. A schematic diagram is presented of the geometry of the HEAO-B solid state detector assembly as a block diagram of the primary logic mode of the HEAO-B X-ray spectrometer.
Holt, S. S.↗
First detection of line emission from the hot interstellar medium with solid state detectors
Previously reported enhanced soft X-ray emission from the North-Galactic Polar region supports the theory of a hot interstellar component. This paper reports the first detection of line emission from the hot interstellar component in the North-Galactic-Polar region. Measurements were made with solid state Si(Li) detectors aboard a spin-stabilized rocket launched from the White Sands Missile Range on March 22, 1980. Two features are clearly present in the low energy portion of the spectrum derived from the data. They correspond to emission lines from C V (300 eV) and C VI (360 eV), and from O VII (560 eV) and O VIII (650 eV). The detection of emission lines coming from these highly stripped ions is direct evidence for the thermal origin of the emission and confirms the presence of a hot (1-million K) component in the interstellar medium.
Schnopper, H. W.↗
Broad band X-ray telescope (BBXRT)
An approach along with corroborating measurements for significantly enhancing the potential of Si(Li) spectrophotometry in X-ray astronomy is presented. The key new element is an unconventional X-ray mirror that meets qualifications of low cost, light weight, and large throughput over a broad energy band at moderate angular resolution. The potential for other applications is also discussed.
Serlemitsos, P. J.↗
Broad band X-ray astronomical spectroscopy
The Broad Band X-Ray Telescope (BBXRT) experiment has been designed for high sensitivity, moderate resolution spectrophotometry of cosmic sources in the range 0.5 to 12 keV. Principal elements are two co-aligned imaging telescopes with cooled Si(Li) detectors at each focus. The mirror design uses an approximate geometry of tightly nested, conical, foil reflectors that allow a large filling factor (high throughput) at small grazing angles (high energy response). Each detector consists of a cluster of five elements defined with grooves on a single crystal. This arrangement affords some spatial resolution as well as a means of substantial background reduction. Shuttle borne measurements will typically be of 2000 s duration for sources with a flux of 10 to the -12 erg/sq cm-s.
Serlemitsos, P. J.↗
An accelerator test of semi-empirical cross-sections
Experimentally measured yields of isotopes of elements from Mg to K resulting from the fragmentation of Ar-40 are compared with calculated yields based on semiempirical cross-section formulas. Excellent mass resolution is obtained in measurements using a beam of 287 MeV/amu Ar-40 incident on a CH2 target. The resolution is made possible by an Si(Li) detector telescope. Whereas the general agreement between calculation and experiment is good, with an rms difference of approximately 24 percent, attention is called to certain significant differences. It is found that important information for refining the semiempirical calculation of fragmentation cross sections can be obtained from data collected during the calibration of cosmic ray detector systems when such calibrations are performed under suitable conditions.
Lau, K. H.↗
Spectral observations of the soft X-ray background with solid-state detectors - Evidence for line emissions
The soft X-ray radiation from several regions of the sky was observed with solid-state detectors Si(Li) between 0.3 and 1.2 keV during two rocket flights. The thermal nature of the diffuse emission coming from the hot bubble surrounding the solar system is confirmed by the observation of C V-C VI and O VII lines which are typical of a temperature of about 10 to the 6th K. Evidence for the existence of a weak component at a higher temperature is given. This component, well visible in the high latitude spectra, could be produced by a hot galactic halo. In the direction of the enhancement region centered on the North Polar Spur, the radiation excess spectra are well represented by a two-temperature plasma model with rather standard abundances. The two components have temperatures of 10 to the 6th and 4.7 x 10 to the 6th K.
Rocchia, R.↗
An accelerator test of semi-empirical cross-sections
Experimentally measured yields of isotopes of elements from Mg-12 to K-19 resulting from the fragmentation of Ar-40 are compared with calculated yields based on semiempirical cross-section formulae. The measurements, made at the LBL Bevalac using a beam of 287 MeV/amu Ar-40 incident on a CH2 target, achieve excellent mass resolution (up to 0.2 amu) through the use of a Si(Li) detector telescope. The general agreement between calculation and experiment is good (rms difference of about 24 percent), but some significant differences are reported.
Lau, K. H.↗
The Broad Band X-ray telescope
The Broad-Band X-ray Telescope (BBXRT) has been designed to perform high sensitivity, moderate resolution spectrophotometry of X-ray sources in the 0.3-12 keV band from the Shuttle. It consists of a coaligned pair of high throughput conical X-ray imaging mirrors, with a cryogenically cooled multiple element Si(Li) spectrometer at the focus of each. On axis, BBXRT will have an effective area of 580 sq cm at 2 keV and 250 sq cm at 7 keV, and a spectral resolution of 110 eV at 2 keV and 150 eV at 7 keV. A 10,000-s observation with BBXRT will allow a determination of the continuum spectral shape for sources near the Einstein deep survey limit.
Petre, R.↗
Molecular and Elemental Dust Analyzer (MEDA) for the comet rendezvous asteroid flyby mission
Comets are some to the most primitive bodies in the solar system and therefore should contain elemental, chemical, and isotopic records of the early history of the solar system. An opportunity to perform in situ analyses of a comet nucleus exists with the Comet Rendezvous Asteroid Flyby (CRAF) mission. An integrated gas chromatograph/X-ray fluorescence instrument (MEDA), being proposed for inclusion onboard the CRAF spacecraft, will measure the molecular and elemental constituents of collected dust grains and ices. The gas chromatograph, employing helium ionization detectors and three columns designed to separate light gases, polar gases, and hydrocarbons will measure the volatile compounds of the biogenic elements thermally released from collected dust grains. The sensitivity of the GC for compounds of interest is at the picogram level. X-ray fluorescence utilized cryogenically cooled Si(Li) solid state detectors of nominal 150 eV resolution at 5.9 keV. Based on laboratory work with carbonaceous meteorites, both the GC and XRF can perform meaningful analyses with a few micrograms of collected comet dust.
Ohara, B. J.↗
Modifications of the X-ray source and monitor at the X-ray Calibration Facility
In order to test the instruments aboard the Advanced X-ray Astrophysics Facility (AXAF) some modifications will need to be made in the X-ray Calibration Facility at Marshall. Several of these modifications involve the X-ray source and the monitor. The source was redesigned to increase the spectral purity of the beam and decrease its polarization by minimizing the number of bremsstrahlung photons in the beam. This was accomplished by utilizing an annular electron gun which allowed the beam to take off antiparallel to the direction at which electrons are incident on the anode. Two other features of the source are the conical anode which decreases the effective spot size and a rotatable anode and filter wheel which allow the operator to change targets without breaking vacuum. The monitor is an important part of the facility because it is used to determine the X-ray flux at the target. A commercially available solid-state detector, Si(Li), should be used along with appropriate proportional counters for monitoring. This detector will be particularly useful when energy or wavelength dispersive instruments are tested because of its good resolution.
Newbolt, W. Barlow↗
Use of mercuric iodide X-ray detectors with alpha backscattering spectrometers for space applications
The authors present X-ray fluorescence (XRF) spectra of different extraterrestrial samples taken with a mercuric iodide (HgI2) spectrometer inserted into an alpha backscattering instrument identical to that used in the Soviet Phobos mission. The results obtained with the HgI2 ambient temperature detector are compared with those obtained using an Si(Li) cryogenically cooled detector. Efforts to design an optimized instrument for space application are also described. The results presented indicate that the energy resolution and sensitivity of HgI2 detectors are adequate to meet the performance needs of a number of proposed space applications, particularly those in which cooled silicon X-ray detectors are impractical or even not usable, such as for the target science programs on geoscience opportunities for lunar surface, Mars surface, and other comet and planetary missions being planned by NASA and ESA.
Iwanczyk, J. S.↗
In-flight performance of the Broad-Band X-Ray Telescope
The Broad-Band X-Ray Telescope (BBXRT) was designed to carry out moderate resolution spectrophotometry of cosmic X-ray sources in the 0.3-12 keV band from the Space Shuttle. It consists of a pair of coaligned conical foil telescopes, with cryogenically cooled Si(Li) spectrometers as focal instruments. It was flown as part of the Astro-1 mission in December, 1990. The in-flight performance of the instrument was essentially as predicted on the basis of ground calibration and modelling. We discuss the performance of the system, with emphasis on the conical mirror systems, and present some preliminary scientific results which illustrate the power of broad band, high sensitivity X-ray spectrophotometry.
Petre, R.↗
Calibrating the broad band X-ray telescope
This paper describes the calibration of the two solid-state Si(Li) X-ray detectors and the X-ray telescopes that flew as part of Goddard Space Flight Center's Broad Band X-Ray Telescope (BBXRT) experiment on board the space shuttle Columbia in 1990 December. During the 9 day shuttle mission, BBXRT performed approximately 150 observations of 82 celestial sources. The content of the archive is summarized here. Although BBXRT had a relatively short life, it stands as a milestone in X-ray astronomy as being the first instrument to offer moderate spectral resolution over a wide bandpass (0.3-12.0 keV). Among other things, this paper discusses the effective area calibration of the instrument, the flux calibration and flux corrections for off-axis observations, the detector background, and optimal background subtraction techniques. The on-axis effective area calibration for the central detector elements was performed using data from the Crab Nebula, while other carefully selected targets were used for calibration of the outer detector elements. The remaining systematic uncertainties in the effective area calibration for point sources observed both on and off axis are generally less than 5%-10%. The energy scale is known to better than 0.5% at 6.0 keV for both detectors. The results presented here have an impact on the calibration of other medium resolution X-ray experiments such as the CCDs on board ASCA (Astro-D) as well as the Advanced X-Ray Astrophysics Facility detectors.
Weaver, K. A.↗
Magnetospheric Atmospheric X-ray Imaging Experiment (MAXIE)
This report summarizes the activities sponsored by the Office of Naval Research for the Magnetospheric Atmospheric X-ray Imaging Experiment (MAXIE). The MAXIE instrument was developed as a joint activity of Lockheed, The Aerospace Corporation, and the University of Bergen, Norway. Lockheed was responsible for the overall management of the program, interfacing with the appropriate government agencies, the overall electrical and mechanical design, flight software, environmental testing, spacecraft integration activities, on orbit checkout, and data processing activities. The Magnetospheric Atmospheric X-ray Imaging Experiment (MAXIE), the ONR 401 experiment, is the first in a new class of satellite-borne remote sensing instruments. The primary innovation is the ability to obtain rapid, sequential, images with high sensitivity of the earth's X ray aurora from a low altitude polar orbiting satellite. These images can be used to identify dynamic temporal variations in the three-dimensional (energy and position) distribution of electron precipitation into the atmosphere. MAXIE was launched on the TIROS NOAA-13 satellite on 9 August 1993. The experiment performed well during its turn-on sequence; however, the spacecraft bus failed on 21 August 1993. New spacebased technologies successfully used in MAXIE were mixed-mode ASIC microcircuits, a zero torque scanning system with associated viscoelastic damping, a paraffin stow release mechanism, a parallel integrating PHA processor, a low noise Si(Li) sensor telescope, and an advanced thermal cooling system. MAXIE's on orbit operation, control of penetrating particle backgrounds, and scientific data indicated good overall performance.
Imhof, W. L.↗
Exploring the Promise of Multifunctional “Zintl-Phase-Forming” Electrolytes for Si-Based Full Cells
Li-M-Si ternary Zintl phases have gained attention recently due to their high structural stability, which can improve the cycling stability compared to a bulk Si electrode. Adding multivalent cation salts (such as Mg 2+ and Ca 2+ ) in the electrolyte was proven to be a simple way to form Li-M-Si ternary phases in situ in Si-based Li-ion cells. To explore the promise of Zintl-phaseforming electrolytes, we systematically investigated their application in pouch cells via electrochemical and multiscale postmortem analysis. The introduction of multivalent cations, such as Mg 2+ , during charging can form Li x M y Si ternary phases. They can stabilize Si anions and reduce side reactions with electrolyte, improving the bulk stability. More importantly, Mg 2+ and Ca 2+ incorporate into interfacial side reactions and generate inorganic-rich solid- electrolyte interphase, thus enhancing the interfacial stability. Therefore, the full cells with Zintl-phase-forming electrolytes achieve higher capacity retentions at the C/3 rate after 100 cycles, compared to a baseline electrolyte. Additionally, strategies for mitigating the electrode-level fractures of Si were evaluated to make the best use of Zintl-phase-forming electrolytes. In conclusion, this work highlights the significance of synergistic impact of multifunctional additives to stabilize both bulk and interface chemistry in high-energy Si anode materials for Li-ion batteries.
25 ENERGY STORAGE↗
Quantifying lithium loss in amorphous silicon thin-film anodes via titration-gas chromatography
Silicon with a high theoretical capacity (3,579 mAh/g) is a promising anode candidate for lithium-ion batteries. However, commercialization is still impeded by low Coulombic efficiency, caused by solid electrolyte interphase (SEI) formation and trapped lithium (Li)-silicon (Si) alloy during repeated volume change. Quantifying capacity losses from each factor is crucial to formulate rational design strategies for further improvement. In this work, titration-gas chromatography and cryogenic transmission electron microscopy are applied to characterize the evolution of trapped Li-Si alloy and SEI growth in a silicon thin-film anode. It is found that continuous growth of the SEI is the dominant factor for lithium inventory loss during cycling, with only a marginal increase in trapped Li-Si alloy. This study offers a quantitative approach to differentiate Li in the SEI from trapped Li in Li-Si alloy through a silicon thin-film anode, providing unique insights into identifying critical bottlenecks for developing Si anodes.
25 ENERGY STORAGE↗