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Theoretical and experimental studies of the atmospheric sodium layer

Atmospheric atomic sodium was studied with a laser radar system. Photocount data were processed using a digital filter to obtain continuous estimates of the sodium concentration versus altitude. Wave-like structures in the sodium layer were observed, and there was evidence for the presence of a standing wave in the layer. The bottomside of the layer was observed to undulate with a period of about 2 1/2 hours, and the layer was observed to broaden through the night. A meteor ablation-cluster ion theory of sodium was developed. The theory shows good agreement with existing atmospheric observations as well as laboratory measurements of rate constants.

Richter, E. S.↗

Io's sodium cloud - Explanation of the east-west asymmetries

An explanation of the east-west asymmetries of Io's sodium clouds is suggested based upon the force experienced by sodium atoms as they resonantly scatter sunlight and upon the ability of this force to alter the cloud atom orbits, as determined by the gravitational fields of Io and Jupiter. Orbit calculations illustrating the time-dependent changes in the sodium atom trajectories produced by the solar radiation force as a function of Io's orbital location are presented in support of this explanation. This theory agrees with the idea that sodium atoms are emitted from the satellite nonisotropically and at a constant rate. These conclusions may be important in studying the global effects of active volcanoes and the intense satellite plasma torus discovered for Io from Voyager I spacecraft measurements.

Smyth, W. H.↗

Density response of the mesospheric sodium layer to gravity wave perturbations

Lidar observations of the mesospheric sodium layer often reveal wavelike features moving through the layer. It is often assumed that these features are a layer density response to gravity waves. Chiu and Ching (1978) described the approximate form of the linear response of atmospheric layers to gravity waves. In this paper, their results are used to predict the response of the sodium layer to gravity waves. These simulations are compared with experimental observations and a good correlation is found between the two. Because of the thickness of the sodium layer and the density gradients found in it, a linear model of the layer response is not always adequate to describe gravity wave-sodium layer interactions. Inclusion of nonlinearities in the layer response is briefly discussed. Experimental data is seen to contain features consistent with the predicted nonlinearities.

Shelton, J. D.↗

Laser fluorescence studies of the chemical interactions of sodium species with sulfur bearing fuels

By using a large matrix of fuel rich and fuel lean H2/O2/N2 and fuel rich C2H2/O2/N2 flames, the behavior of sodium and its interactions with sulfur at high temperatures was extensively characterized. OH concentrations were measured for each flame using the previously validated laser induced fluorescence technique. Sodium atomic concentrations were obtained by the saturated laser fluorescence method. Measurements were made in the absence and presence of up to 2% sulfur. In oxygen rich systems sodium is depleted by NaO2 and NaOH formation. The relative amounts of each are controlled by the degree of nonequilibration of the flame radicals and by the temperature. The bond strength of NaO2 was established. For the first time, a complete understanding of the complex behavior of sodium in fuel lean H2/O2 flames has emerged and computer modeling has permitted various rate constants of Na, NaO2 and NaOH reactions to be approximately fixed.

Steinberg, M.↗

A modeling analysis program for the JPL Table Mountain Io sodium cloud data

The necessary personnel software base was established to accomplish the data processing requirements for this project. Conversion of software required in reformatting the raw Io sodium cloud data was completed and data processing activities were initiated. Slit spectra data acquired by the JPL Table Mountain Io sodium cloud observing program were reviewed and their scientific value assessed. The lifetime description for sodium atoms in the Io sodium cloud model was improved by incorporating the most recently available temperatures and densities for ions and electrons in the plasma torus.

Smyth, W. H.↗

Discovery of sodium in the atmosphere of Mercury

The spectrum of Mercury at the Fraunhofer sodium D lines shows strong emission features that are attributed to resonant scattering of sunlight from sodium vapor in the atmosphere of the planet. The total column abundance of sodium was estimated to be 8.1 x 10 to the 11th atoms per square centimeter which corresponds to a surface density at the subsolar point of about 150,000 atoms per cubic centimeter. The most abundant atmospheric species found by the Mariner 10 mission to Mercury was helium, with a surface density of 4500 atoms per cubic centimeter. It now appears that sodium vapor is a major constituent of Mercury's atmosphere.

Potter, A.↗

Measuring Sodium Chloride Contents of Aerosols

Amount of sodium chloride in individual aerosol particles measured in real time by analyzer that includes mass spectrometer. Analyzer used to determine mass distributions of active agents in therapeutic or diagnostic aerosols derived from saline solutions and in analyzing ocean spray. Aerosol particles composed of sodium chloride introduced into oven, where individually vaporized on hot wall. Vapor molecules thermally dissociated, and some of resulting sodium atoms ionized on wall. Ions leave oven in burst and analyzed by spectrometer, which is set to monitor sodium-ion intensity.

Sinha, M. P.↗

Wave motions in the upper atmospheric sodium layer observed with a lidar technique

Since the middle of 1980, the vertical profile of the atmospheric sodium layer was observed with a tunable laser radar at Mt. Zao Observatory in northern Japan. The principal characteristics of the lidar system are summarized. The output wavelength is continuously monitored by using a sodium resonance cell, a spectrometer, and a Fabry-Perot interferometer provided with the reference spectrum of the sodium lamp. Owing to the strict temperature control of the filters, the tuning is sufficiently stable throughout the night. The calibration of the absolute sodium density was carried out by adopting the method established by previous works.

Kamiyama, H.↗

Lidar observations of the nighttime sodium layer at 33 deg N

Measurements of the nighttime atmospheric sodium layer have been performed since 1977, using a dye lidar at Fukuoka (33.4 deg N, 130.2 deg E.). The Kyushu lidar uses a flashlamp pumped dye laser tuned to the sodium D sub 2 line (589.0 nm) as a transmitter. The dye laser used in the Kyushu lidar system has been described elsewhere. Sporadic enhancements of the total column abundance of the layer during the Perseids meteor shower were observed on the nights of August 12 and 13, 1978, 1979, 1981, and 1983. Degrading weather conditions prevented observation on the nights during 1980 and 1983. A contour plot of the sodium layer for the period of 8 hours from 21:00 to 5:00 JST on the night of August 12 to 13 1983, is shown. The predominant feature visible is the increase in the height of peak density from 21:00 to 2:00 JST, and the slight decrease in the height of peak density from 2:00 to 5:00 JST. The average abundance had a maximum of about 7 x 10 to the 13th power/sq m on August 13. A plot is presented of the nightly average abundance for available data. The sodium layer abundance increased on the night of August 12 to 13, 1983, during the peak of the Perseids meteor shower, and the following night, August 13 to 14, almost went back to the monthly mean.

Uchiumi, M.↗

Daytime lidar measurements of tidal winds in the mesospheric sodium layer at Urbana, Illinois

For more than 15 years lidar systems have been used to study the chemistry and dynamics of the mesospheric sodium layer. Because the layer is an excellent tracer of atmospheric wave motions, sodium lidar has proven to be particularly useful for studying the influence of gravity waves and tides on mesospheric dynamics. These waves, which originate in the troposphere and stratosphere, propagate through the mesosphere and dissipate their energy near the mesopause making important contributions to the momentum and turbulence budget in this region of the atmosphere. Recently, the sodium lidar was modified for daytime operation so that wave phenomena and chemical effects could be monitored throughout the complete diurnal cycle. The results of continuous 24 hour lidar observations of the sodium layer structure are presented alond with measurement of the semidiurnal tidal winds.

Kwon, K. H.↗

A modeling analysis program for the JPL table mountain Io sodium cloud data

Research in the third and final year of this project is divided into three main areas: (1) completion of data processing and calibration for 34 of the 1981 Region B/C images, selected from the massive JPL sodium cloud data set; (2) identification and examination of the basic features and observed changes in the morphological characteristics of the sodium cloud images; and (3) successful physical interpretation of these basic features and observed changes using the highly developed numerical sodium cloud model at AER. The modeling analysis has led to a number of definite conclusions regarding the local structure of Io's atmosphere, the gas escape mechanism at Io, and the presence of an east-west electric field and a System III longitudinal asymmetry in the plasma torus. Large scale stability, as well as some smaller scale time variability for both the sodium cloud and the structure of the plasma torus over a several year time period are also discussed.

Smyth, William H.↗

A general model for Io's neutral gas clouds. II - Application to the sodium cloud

A previously developed neutral cloud model is applied to the neutral sodium cloud produced by Io. Past models for the cloud are reviewed and the motivation for developing better models is discussed. The interactions of sodium in the plasma torus are discussed. It is shown how the new model can be used to provide a consistent physical explanation for the basic physical characteristics of the spatially extended Io sodium cloud and for the east-west intensity asymmetry observed very near Io. This leads to definite conclusions regarding the flux distribution and density of sodium in Io's exosphere, the level of the collisional exobase in the atmosphere, the nature of the interaction of the corotating plasma torus and the satellite atmosphere/corona, and the presence of an east-west electric field in the planetary system.

Smyth, W. H.↗

Discovery of sodium and potassium vapor in the atmosphere of the moon

A ground-based telescopic study of the lunar surface with high resolution spectroscopy has led to the discovery of sodium and potassium vapor 'atmospheres'. The scale height for the sodium atmosphere is 120 + or - 42 km, and for potassium 90 + or - 20 km; these values imply that the effective temperature of the two elements closely approximates that of the lunar surface. The sodium density at the south polar region is similar to that at the subsolar point, indicating widespread distribution of the vapor. The ratio of sodium to potassium densities, at 6 (+ or - 3):1, is close to the lunar surface ratio and suggests that the atmosphere originated in the vaporization of surface minerals.

Potter, A. E.↗

Observations of sodium in the tenuous lunar atmosphere

Spectra showing the sodium D lines above the moon's bright limb (subsolar point) were obtained at first and last quarters, May 27 and June 7, 1988. The number density at the surface is 57 + or - 20 atoms/cu cm and the scale height is 79 + or - 8 km, compatible with the temperature of the surface. Comparison with the Mercurian density of 26,000 atoms/cu cm reveals an enigma. Despite the apparent general similarity of the surfaces, the sodium densities are in a ratio of about 400. The difference may be attributed to differences in source or loss mechanisms or to some fundamental compositional difference between the two planets. The possibility that the source is rapid diffusion of sodium through Mercury's crust and regolith is discussed, as well as recent observational evidence that Mercury's regolith is of intermediate rock type and may be more sodium-rich than the moon's.

Tyler, Ann L.↗

Copper Chloride Cathode For Liquid-Sodium Cell

Rechargeable liquid-sodium cell with copper chloride cathode offers substantial increase in energy density over cells made with other cathode materials. Unit has theoretical maximum energy density of 1135 W.h/kg. Generates electricity by electrochemical reaction of molten sodium and solid copper chloride immersed in molten electrolyte, sodium tetrachloroaluminate at temperature of equal to or greater than 200 degrees C. Wall of alumina tube separates molten electrolyte from molten sodium anode. Copper chloride cathode embedded in pores of sintered nickel cylinder or directly sintered.

Bugga, Ratnakumar V.↗

Molecular origin of Io's fast sodium

Neutral sodium emissions encircling Jupiter exhibit an intricate and variable structure that is well matched by a simple loss process from Io's atmosphere. These observations imply that fast neutral sodium is created locally in the Io plasma torus, both near Io and as much as 8 hours downstream. Sodium-bearing molecules may be present in Io's upper atmosphere, where thay are ionized by the plasma torus and swept downstream. The molecular ions dissociate and dissociatively recombine on a short time scale, releasing neutral fragments into escape trajectories from Jupiter. This theory explains a diverse set of sodium observations, and it implies that molecular reactions (particularly electron impact ionization and dissociation) are important at the top of Io's atmosphere.

Schneider, Nicholas M.↗

Sodium and potassium in the lunar atmosphere

The discovery that sodium and potassium vapor can be observed in the lunar atmosphere using ground-based telescopes has opened up a field of investigation that was closed after the last Apollo mission to the Moon. Sodium has been detected at altitudes up to 1500 km above the surface. This implies a high effective temperature for sodium, of the order of 1000 K. However, there is some evidence for two populations of sodium and potassium, one at temperatures corresponding to the surface, and another corresponding to high temperatures. The sources for the lunar atmosphere are not understood. Meteoric bombardment of the surface, solar wind sputtering of the surface, and photo-sputtering of the surface have all been suggested as possible sources for the lunar atmosphere. One of the objectives of the current research is to test different hypotheses by measurements of the atmosphere under different conditions of solar illumination and shielding from the solar wind by the Earth.

Potter, A. E.↗

Development of Mesospheric Sodium Laser Beacon for Atmospheric Adaptive Optics

A solid-state source of long pulse length, sodium-resonance radiation was developed for the purpose of generating an artificial star in the earth's mesospheric sodium layer. This radiation is generated by sum-frequency mixing the output of a 1.064 micron Nd:YAG laser with the output of a 1.319-micron Nd:YAG laser. By operating these lasers at wavelengths very close to the peak of their tuning curves, it is possible to match the wavelength of the sum-frequency radiation to that of the sodium D2 adsorption wavelength. Two pulsed laser systems were constructed, one producing as much as 0.6 J of sodium resonance radiation at a 10-Hz repetition rate and another producing as much as 24 mJ at a 840-Hz repetition rate. In both laser systems, the 1.06-micron and 1.32-micron Nd:YAG lasers are configured as mode-locked master oscillators followed by power amplifiers. Other aspects of this project are presented.

Jeys, T. H.↗