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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Nickel-hydrogen battery state of charge during low rate trickle charging

The NASA AXAF-I program requires high battery state of charge at launch. Traditional approaches to providing high state of charge, during prelaunch operations, require significant battery cooling. The use of active cooling, in the AXAF-I prelaunch environment, was considered and proved to be difficult to implement and very expensive. Accordingly alternate approaches were considered. An approach utilizing adiabatic charging and low rate trickle charge, was investigated and proved successful.

Lurie, C.↗

Electronic Characterization of Defects in Narrow Gap Semiconductors-Comparison of Electronic Energy Levels and Formation Energies in Mercury Cadmium Telluride, Mercury Zinc Telluride, and Mercury Zinc Selenide

We have used a Green's function technique to calculate the energy levels and formation energy of deep defects in the narrow gap semiconductors mercury cadmium telluride (MCT), mercury zinc telluride (MZT) and mercury zinc selenide (MZS). The formation energy is calculated from the difference between the total energy with an impurity cluster and the total energy for the perfect crystal. Substitutional (including antisite), interstitial (self and foreign), and vacancy deep defects are considered. Relaxation effects are calculated (with molecular dynamics). By use of a pseudopotential, we generalize the ideal vacancy model so as to be able to consider relaxation for vacancies. Different charge states are considered and the charged state energy shift (as computed by a modified Haldane-Anderson model) can be twice that due to relaxation. Different charged states for vacancies were not calculated to have much effect on the formation energy. For all cases we find deep defects in the energy gap only for cation site s-like orbitals or anion site p-like orbitals, and for the substitutional case only the latter are appreciably effected by relaxation. For most cases for MCT, MZT, MZS, we consider x (the concentration of Cd or Zn) in the range appropriate for a band gap of 0.1 eV. For defect energy levels, the absolute accuracy of our results is limited, but the precision is good, and hence chemical trends are accurately predicted. For the same reason, defect formation energies are more accurately predicted than energy level position. We attempt, in Appendix B, to calculate vacancy formation energies using relatively simple chemical bonding ideas due to Harrison. However, these results are only marginally accurate for estimating vacancy binding energies. Appendix C lists all written reports and publications produced for the grant. We include abstracts and a complete paper that summarizes our work which is not yet available.

Patterson, James D.↗

Air Force Ni-H2 cell test program: State of Charge test

Nickel-Hydrogen cells are being cycled under a LEO (low earth orbit) test regime to examine the benefits of operating the cells at lower States of Charge (SOC) than typically used. A group of four cells are cycled using a voltage limiting charge regime that limits the State of Charge that the cells are allowed to reach. The test cells are then compared to identical cells being cycled at or near 100% State of Charge using a constant current charge regime.

Moore, Bruce↗

Iron Charge Distribution as an Identifier of Interplanetary Coronal Mass Ejections

We present solar wind Fe charge state data measured on the Advanced Composition Explorer (ACE) from early 1998 to the middle of 2000. Average Fe charge states in the solar wind are typically around 9 to 11. However, deviations from these average charge states occur, including intervals with a large fraction of Fe(sup greater or = 16+) which are consistently associated with interplanetary coronal mass ejections (ICMEs). By studying the Fe charge state distribution we are able to extract coronal electron temperatures often exceeding 2 x 10(exp 6) kelvins. We also discuss the temporal trends of these events, indicating the more frequent appearance of periods with high Fe charge states as solar activity increases.

Lepri, S. T.↗

Nickel-Hydrogen Battery Fault Clearing at Low State of Charge

Fault clearing currents were achieved and maintained at discharge rates from C/2 to C/3 at high and low states of charge. The fault clearing plateau voltage is strong function of: discharge current, and voltage-prior-to-the-fault-clearing-event and a weak function of state of charge. Voltage performance, for the range of conditions reported, is summarized.

Lurie, C.↗

A Battery Charger and State of Charge Indicator

A battery charger which has a full wave rectifier in series with a transformer isolated 20 kHz dc-dc converter with high frequency switches, which are programmed to actively shape the input dc line current to be a mirror image of the ac line voltage is discussed. The power circuit operates at 2 kW peak and 1 kW average power. The BC/SCI has two major subsystems: (1) the battery charger power electronics with its controls; and (2) a microcomputer subsystem which is used to acquire battery terminal data and exercise the state of charge software programs. The state of charge definition employed is the energy remaining in the battery when extracted at a 10 kW rate divided by the energy capacity of a fully charged new battery. The battery charger circuit is an isolated boost converter operating at an internal frequency of 20 kHz. The switches selected for the battery charger are the single most important item in determining its efficiency. The combination of voltage and current requirements dictate the use of high power NPN Darlington switching transistors. The power circuit topology is a three switch design which utilizes a power FET on the center tap of the isolation transformer and the power Darlingtons on each of the two ends. An analog control system is employed to accomplish active input current waveshaping as well as the necessary regulation.

Latos, T. S.↗

Transport, charge exchange and loss of energetic heavy ions in the earth's radiation belts - Applicability and limitations of theory

Computer simulations of processes which control the relative abundances of ions in the trapping regions of geospace are compared with observations from discriminating ion detectors. Energy losses due to Coulomb collisions between ions and exospheric neutrals are considered, along with charge exchange losses and internal charge exchanges. The time evolution of energetic ion fluxes of equatorially mirroring ions under radial diffusion is modelled to include geomagnetic and geoelectric fluctutations. Limits to the validity of diffusion transport theory are discussed, and the simulation is noted to contain provisions for six ionic charge states and the source effect on the radiation belt oxygen ion distributions. Comparisons are made with ion flux data gathered on Explorer 45 and ISEE-1 spacecraft and results indicate that internal charge exchanges cause the radiation belt ion charge state to be independent of source charge rate characteristics, and relative charge state distribution is independent of the radially diffusive transport rate below the charge state redistribution zone.

Spjeldvik, W. N.↗

"Fuel Gage" for Electric Vehicles

Gas-emmission and time-integrated-current measurements indicate battery charge state. Tests indicate possibility of monitoring state of charge of lead/acid batteries at any stage in charging cycle by measuring charging current and either gas evolution or electrode potential. Data then processed by microcomputer. Uses include cell voltage, cell pressure, cell temperature and rate of gas recombination on catalyst.

Rowlette, J. J.↗

Changes in impedance of Ni electrodes upon standing and cycling

Impedances of Ni electrodes vary with many factors including voltage, cycling, and manufacturer. However, results from Ni/H2 cells being tested for Space Station Freedom show that consistent results are obtained within a group of cells from the same manufacturer if the cells are cycled and stored in the same manner. Impedance changes with storage and cycling are being investigated. Impedances are low in the fully charged state but rise abruptly by several orders of magnitude at a voltage corresponding to a very low state-of-charge. After standing for several months, this increase occurred at a higher voltage, consistent with an increase in structural order during storage which hinders diffusion of protons and reduces high rate capacity. Early measurements on the effects of cycling on Ni/H2 cells being tested for Space Station Freedom show differences between cells from different manufacturers.

Reid, Margaret A.↗

Spatial Relationship of Signatures of Interplanetary Coronal Mass Ejections

Interplanetary coronal mass ejections (ICMEs) are characterized by a number of signatures. In particular, we examine the relationship between Fe charge states and other signatures during ICMEs in solar cycle 23. Though enhanced Fe charge states characterize many ICMEs, average charge states vary from event to event, are more likely to be enhanced in faster or flare-related ICMEs, and do not appear to depend on whether the ICME is a magnetic cloud.

Richardson, I. G.↗

Parametric Study of State-of-Charge for an Electric Aircraft in Urban Air Mobility

The envisioned concept of urban air mobility is anticipated to support passenger transportation, cargo delivery, and emergency services in major metropolitan areas with increasing autonomy levels in the future. Distributed electric propulsion powered electric vertical takeoff and landing aircraft are expected to enable urban air mobility. However, the low specific energy of onboard lithium-ion polymer batteries and wind conditions impose constraints on flight endurance. Therefore, to enable autonomous urban air mobility operations using electric aircraft, one of the critical steps from a safety and efficiency perspective is to understand how various operational and environmental conditions impact the state-of-charge of the onboard lithium-ion polymer batteries. This research performs a parametric study of the state-of-charge for a NASA-proposed conceptual multirotor aircraft flight in the urban environment. The parameters considered for the parametric analysis are cruise airspeed, cruise altitude, climb and descent profiles, wind conditions (wind magnitude, wind direction relative to the route, and wind magnitude uncertainty), and required time of arrival.

Urban Air Mobility↗

Parametric Study of State of Charge for an Electric Aircraft in Urban Air Mobility

The envisioned concept of urban air mobility is anticipated to support passenger transportation, cargo delivery, and emergency services in major metropolitan areas with increasing autonomy levels in the future. Distributed electric propulsion powered electric vertical takeoff and landing aircraft are expected to enable urban air mobility. However, the low specific energy of onboard lithium-ion polymer batteries and wind conditions impose constraints on flight endurance. Therefore, to enable autonomous urban air mobility operations using electric aircraft, one of the critical steps from a safety and efficiency perspective is to understand how various operational and environmental conditions impact the state-of-charge of the onboard lithium-ion polymer batteries. This research performs a parametric study of the state-of-charge for a NASA-proposed conceptual multirotor aircraft flight in the urban environment. The parameters considered for the parametric analysis are cruise airspeed, cruise altitude, climb and descent profiles, wind conditions (wind magnitude, wind direction relative to the route, and wind magnitude uncertainty), and required time of arrival.

Urban Air Mobility↗

Thermal State-of-Charge in Solar Heat Receivers

A theoretical framework is developed to determine the so-called thermal state-of-charge (SOC) in solar heat receivers employing encapsulated phase change materials (PCMS) that undergo cyclic melting and freezing. The present problem is relevant to space solar dynamic power systems that would typically operate in low-Earth-orbit (LEO). The solar heat receiver is integrated into a closed-cycle Brayton engine that produces electric power during sunlight and eclipse periods of the orbit cycle. The concepts of available power and virtual source temperature, both on a finite-time basis, are used as the basis for determining the SOC. Analytic expressions for the available power crossing the aperture plane of the receiver, available power stored in the receiver, and available power delivered to the working fluid are derived, all of which are related to the SOC through measurable parameters. Lower and upper bounds on the SOC are proposed in order to delineate absolute limiting cases for a range of input parameters (orbital, geometric, etc.). SOC characterization is also performed in the subcooled, two-phase, and superheat regimes. Finally, a previously-developed physical and numerical model of the solar heat receiver component of NASA Lewis Research Center's Ground Test Demonstration (GTD) system is used in order to predict the SOC as a function of measurable parameters.

Hall, Carsie A., Jr.↗

Thermal State-of-Charge in Solar Heat Receivers

A theoretical framework is developed to determine the so-called thermal state-of-charge (SOC) in solar heat receivers employing encapsulated phase change materials (PCMS) that undergo cyclic melting and freezing. The present problem is relevant to space solar dynamic power systems that would typically operate in low-Earth-orbit (LEO). The solar heat receiver is integrated into a closed-cycle Brayton engine that produces electric power during sunlight and eclipse periods of the orbit cycle. The concepts of available power and virtual source temperature, both on a finite-time basis, are used as the basis for determining the SOC. Analytic expressions for the available power crossing the aperture plane of the receiver, available power stored in the receiver, and available power delivered to the working fluid are derived, all of which are related to the SOC through measurable parameters. Lower and upper bounds on the SOC are proposed in order to delineate absolute limiting cases for a range of input parameters (orbital, geometric, etc.). SOC characterization is also performed in the subcooled, two-phase, and superheat regimes. Finally, a previously-developed physical and numerical model of the solar heat receiver component of NASA Lewis Research Center's Ground Test Demonstration (GTD) system is used in order to predict the SOC as a function of measurable parameters.

Hall, Carsie, A., III↗