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Lunar surface mobility systems comparison and evolution - resource planning for mobility systems derived from lunar module, command module, and multimission module
Manganese(I) carbonyl complexes are promising electrocatalysts for CO2 reduction, yet their application in homogeneous aqueous media remains limited by poor solubility and selectivity. Here, we report water-soluble Mn(I) and Re(I) complexes fac-[M(bpy2+)(CO)3X]2+ (X = I or Cl), featuring bipyridine ligands functionalized with -Ph-CH2-(NMe3)+ cationic ammonium groups that integrate water solubility with secondary-sphere stabilization. In bicarbonate buffer at pH 6.8, the Mn catalyst is completely selective for CO production at a low overpotential (η = 0.3 V), operating by a protonation-first mechanism with observed rates of ~10 s−1. Pulse radiolysis reveals that the one-electron reduced Mn species undergoes dimerization in the absence of CO2 but uniquely reacts competitively with CO2 through an initial pre-equilibrium followed by fast formation of a dinuclear CO2-bridged species (ΔGo = −12.4 kcal mol−1). At a higher 0.6 V over-potential, a faster reduction-first pathway (~100 s−1) is available upon reduction of the metallo-carboxylic acid intermediate, Mn-CO2H2+; however, this regime is functionally limited by the formation of a resistive, noncatalytic film on the electrode surface. Comparison to the analo-gous water-soluble Re catalyst (kobs = 440 s−1, η = 0.6 V) highlights the distinct mechanistic ad-vantages of earth-abundant Mn in low-potential catalysis. These results demonstrate how cati-onic second-sphere design enables selective, homogeneous CO2 reduction in water while reveal-ing competing radical and electrode-mediated processes that govern catalytic performance.
Buoyancy forcing in the subpolar North Atlantic Ocean (SPNA) is an important driver of the Atlantic Meridional Overturning Circulation (AMOC). To advance understanding of the mechanisms connecting the two processes and their relative importance in sub-basins within the SPNA, we apply the Water Mass Transformation Framework to a matched-pair of forced, ocean-sea ice simulations configured at eddying and non-eddying resolution. Within the first decade of simulation, the non-eddying simulation produces a weak AMOC, ~11 Sv at 26.5 ° N, while the AMOC in the eddying simulation is more realistic and is thus analyzed for comparison. Surface water mass transformation and boundary transport are calculated in both density and temperature–salinity coordinates in three separate deep water formation regions, the Iceland Basin, the Irminger Sea and Labrador Sea, during the first decade of both simulations. We identify strong surface freshening in the Irminger and Labrador seas in the non-eddying simulation during the AMOC decline. This freshening significantly reduces the density of the surface outcrops where surface water mass formation occurs, essentially removing this contribution to deep water formation. Concurrently, boundary transports in these two regions are warmer and saltier in the non-eddying simulation compared to the eddying simulation where the density of surface water mass formation is stable. The warming and salinification of boundary transports in the non-eddying simulation is interpreted as an obstacle to deep water formation. Labrador Sea surface water mass transformation is important, despite its small contribution to buoyancy overturning.
Images acquired by the Double Asteroid Redirection Test (DART) before its impact into Dimorphos—the moon of the Didymos binary asteroid system—unexpectedly reveal a set of discontinuous rays spanning the imaged surface. These albedo features are visible only after correcting for lighting differences, which normalize the effects of the pervasive boulders that cover the surface. Comparison to physical experiments and numerical simulations shows that these bright, fan-shaped albedo features are consistent with the aftermath of a low-velocity impact into a field of boulders and provide our first direct evidence for the transfer of material in a binary asteroid system due to the shedding material from radiative torques. Parts of these and possible additional albedo markings from the reentry of boulders after the DART impact may be visible to the Hera mission when it explores the post-DART Didymos system.
Conventionally sol-gel spray-on transducers require a high-temperature (> 700 ◦C) sintering process; however, this process can affect the microstructure of the substrate material. For mechanical elbows and valves utilized for fluid transport in the energy sector, the components are designed to have a specific microstructure, and deviations from these specifications can create weak points in the system. For this reason it is important to investigate how the temperature of the deposition process affects the substrate. This paper investigates the effect of high-temperature and low-temperature (< 150 ◦C) processing conditions on the surface composition of the substrate. Furthermore, the resultant transducers from high- and low-temperature fabrication processes are compared to determine if a low-temperature processing method is feasible. For these studies a sol-gel spray-on process is employed to deposit piezoelectric ceramics onto a stainless-steel 316L substrate. Energy-dispersive X-ray spectroscopy is utilized to determine the composition of the substrate surface before and after transducer deposition. Results indicate that the high-temperature processing conditions may alter the surface composition of the metal due to a diffusion of the metal into the ceramic, which results in a metal surface that is bonded to the ceramic. Furthermore, it is shown that low-temperature processing of spray-on transducers is a viable method for transducer fabrication where the resultant transducers meet the industry minimum requirement of 30 dB signalto-noise ratio. In parallel simulation calculations, finite-element method (FEM) studies were performed to model the adhesive strength of the low-temperature processed transducer to the substrate surface. Comparisons between the simulations and experiments suggest that the bond strength is much greater than the commercial gel bonds and closer to hardened epoxy glue bonds. These results indicate that spray-on transducers fabricated under lowtemperature processing conditions are a viable solution for leave-in-place monitoring of structures.
Using the specular point theory of scatter from a very rough surface, the average backscatter cross section per unit area per radar cell width is derived for a cell located at a given height above the mean sea surface. This result is then applied to predict the average radar cross section observed by a short-pulse altimeter as a function of time for two modes of operation: pulse-limited and beam-limited configurations. For a pulse-limited satellite altimeter, a family of curves is calculated showing the distortion of the leading edge of the receiver output signal as a function of sea state (i.e., wind speed). A signal processing scheme is discussed that permits an accurate determination of the mean surface position--even in high seas--and, as a by-product, the estimation of the significant seawave height (or wind speed above the surface). Comparison of these analytical results with experimental data for both pulse-limited and beam-limited operation lends credence to the model. Such a model should aid in the design of short-pulse altimeters for accurate determination of the geoid over the oceans, as well as for the use of such altimeters for orbital sea-state monitoring.
It is reported that the Apollo 16 command module astronomical photography was performed with the specific objective of capitalizing on the uniqueness of the double umbra as a vantage point to collect astronomical data that are obtainable only near our Moon. For this reason, these data will be compared directly to analogous photography performed from Earth orbit during Project Mercury and the Gemini Program as well as to the Apollo-duplicated photography taken from sites on the Earth surface. Comparison with Earth-based photography should yield direct information on the Earth airglow layer and on atmospheric scattering and extinction.
An analytic approximation to the Green's function for the displacements due to a strike slip point source in an elastic layer over a viscoelastic half-space is developed. This approximate Green's function is useful because it can be analytically integrated over the fault surface. Comparison with a numerical integration of the exact solution integral indicates that the approximation is quite good. The approximate Green's function is integrated analytically to obtain the displacements due to a finite rectangular strike slip fault in an elastic layer over a viscoelastic half-space. Ground displacements and angle changes from a model survey net are computed to illustrate the viscoelastic relaxation which follows a fracture in the elastic region.
A new method for mapping the Sun's magnetic field B from the photosphere through the corona and interplanetary space is presented. The method entails the derivation of B from a scalar potential within a current-free annular volume bounded inside by photosphere and outside by a prescribed nonspherical source surface to which B is made (as nearly as possible) perpendicular. As usual we obtain the potential for the part of B that arises from currents inside the Sun by fitting an expansion to the observed line-of-sight component of B at the photosphere. A second least-squares fit is introduced to obtain the part of B that arises from currents outside the source surface. Comparisons are made between this model and observed coronal and interplanetary structures. There is evidence that observation data underestimate the strength of photospheric polar magnetic fields.
An experimental investigation of V/STOL thrust augmenter wings in flight at slow forward speeds is reported. Two rectangular planforms of differing relative chord lengths were tested. The augmenters were positioned in the aft portion of the wing to produce increases in circulation lift. Two blown flap configurations were tested for comparison. Surface pressures as well as total forces and moments were obtained on the semispan models at two flap deflections and a range of momentum coefficients. Tabulations of surveys at the pressure augmenter exit, downwash surveys downstream of the wing, and force and moment data are included.
An experimental investigation has been conducted to determine wing-alone supersonic aerodynamic characteristics at high angles of attack. The family of wings tested varied in aspect ratio from 0.5 to 4.0 and taper ratio from 0.0 to 1.0. The wings were tested at angles of attack ranging from 0 to 60 deg and Mach numbers from 1.6 to 4.6. The aerodynamic characteristics were obtained by integrating local pressures measured over the wing surface. Comparison of these data with the limited available data from the literature indicate the present data are free of sting interference effects through the test range of angle of attack. Presented and discussed are results showing the effects of model geometry, Mach number and angle of attack on aerodynamic characteristics consisting of normal force, pitching moment, bending moment, longitudinal center-of-pressure locations, and lateral center-of-pressure locations.
A method was developed for calculating the internal temperature distribution in an aircraft tire while free rolling under load. The method uses an approximate stress analysis of each point in the tire as it rolls through the contact patch, and from this stress change the mechanical work done on each volume element may be obtained and converted into a heat release rate through a knowledge of material characteristics. The tire cross-section is then considered as a body with internal heat generation, and the diffusion equation is solved numerically with appropriate boundary conditions of the wheel and runway surface. Comparison with data obtained with buried thermocouples in tires shows good agreement.
A method was developed for calculating the internal temperature distribution in an aircraft tire while free rolling under load. The method uses an approximate stress analysis of each point in the tire as it rolls through the contact patch, and from this stress change the mechanical work done on each volume element may be obtained and converted into a heat release rate through a knowledge of material characteristics. The tire cross-section is then considered as a body with internal heat generation, and the diffusion equation is solved numerically with appropriate boundary conditions of the wheel and runway surface. Comparison with data obtained with buried thermocouples in tires shows good agreement.
A method was developed for calculating the internal temperature distribution in an aircraft tire while free rolling under load. The method uses an approximate stress analysis of each point in the tire as it rolls through the contact patch, and from this stress change the mechanical work done on each volume element may be obtained and converted into a heat release rate through a knowledge of material characteristics. The tire cross-section is then considered as a body with internal heat generation, and the diffusion equation is solved numerically with appropriate boundary conditions of the wheel and runway surface. Comparison with data obtained with buried thermocouples in tires shows good agreement.
A simple theoretical model is proposed to describe the flow of a turbulent wall jet along a curved surface into a quiescent atmosphere. An integral method is used to solve the momentum equation and identifies three contributions to the spreading rate of the wall jet: (1) turbulent diffusion in the wall jet; (2) wall curvature; and (3) rate of change of wall curvature. Closed from approximate solutions are found for the case of a plane wall, a circular cylinder, and a logarithmic spiral surface. Comparison with experimental data for these three cases is made showing good agreement.
Techniques have been developed for the sub-pixel location of control points in satellite images returned by the Voyager spacecraft. The procedure uses digital imaging data in the neighborhood of the point to form a multipicture model of a piece of the surface. Comparison of this model with the digital image in each picture determines the control point locations to about a tenth of a pixel. At this level of precision, previously insignificant effects must be considered, including chromatic aberration, high level imaging distortions, and systematic errors due to navigation uncertainties. Use of these methods in the study of Jupiter's satellite Io has proven very fruitful.
Earth-based telescopic measurements of the Reiner Gamma Formation in the 3-micron region were made to search for evidence of water at this proposed site of cometary interaction with the lunar surface. Comparison of the spectra of Reiner Gamma and laboratory measurements of a variety of minerals with adsorbed water or structural OH(-) show that there is no evidence for water at the locations measured. While these measurements rule out the presence of abundant bound H2O at these locations, they do not exclude the presence of OH(-) bearing minerals that have absorptions not detectable through the wet terrestrial atmosphere. The possible effects of high lunar temperatures on the reflectance spectra were examined, and it was concluded that these effects would not obscure a bound water absorption if it were present. Upper limits on the amount of water that could be present at the locations observed and remain undetected are 2.25 average wt pct for a mixture consisting of discrete patches of water-bearing and water-free minerals and 0.01 wt pct for an intimate mixture of these two materials.
A microwave scattering model was developed for layered vegetation based on an iterative solution of the radiative transfer equation up to the second order to account for multiple scattering within the canopy and between the ground and the canopy. The model is designed to operate over a wide frequency range for both deciduous and coniferous forest and to account for the branch size distribution, leaf orientation distribution, and branch orientation distribution for each size. The canopy is modeled as a two-layered medium above a rough interface. The upper layer is the crown containing leaves, stems, and branches. The lower layer is the trunk region modeled as randomly positioned cylinders with a preferred orientation distribution above an irregular soil surface. Comparisons of this model with measurements from deciduous and coniferous forests show good agreements at several frequencies for both like and cross polarizations. Major features of the model needed to realize the agreement include allowance for: (1) branch size distribution, (2) second-order effects, and (3) tree component models valid over a wide range of frequencies.