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At least 91 records · Page 5

Bio-inspired Surface Structures to Mitigate Interfacial Particle Adhesion and Erosion - A Review

Lunar dust known as regolith is a huge challenge for lunar exploration missions. Formed over millennia by a complex process involving impacts of meteoroids and micrometeoroids on the lunar surface, lunar dust is porous, highly abrasive with sharp jagged edges, chemically reactive, electrostatically charged and sometimes magnetic. The chemical composition and thickness of the dust layer also varies in different regions of the lunar surface. From samples obtained by previous lunar missions, the average particle size is below 100 microns. This dust has the tendency to strongly adhere to any exposed surfaces, and often degrades the material functionality to eventually cause failure. Any material on the lunar surface is also subject to harsh temperature cycles ranging from -178 ̊C to + 123 ̊C and extreme ultraviolet radiation. While on the lunar surface, different classes of materials would be required for different applications. Advanced materials have been and will be used throughout the lunar lander, habitat, and mission equipment. Examples include: polymeric materials for astronaut protective clothing; metals and ceramics for the lunar lander legs and habitats, and excavating equipment; and semiconductors for solar panels and on-board electronics. In all these applications, the surfaces of the materials are expected or understood to be exposed to the extreme lunar environment condition that includes the regolith dust. During the Apollo missions, the dust clung to and abraded the astronaut’s suits, degraded seals, optics, clogged sensors and reduced performance of thermal radiators. The lunar dust adheres to the surface by various mechanisms, which include electrostatic and Coulombic interactions, Van-der-Waals forces, magnetic forces, mechanical interlocking, chemical bonding and donor-acceptor interactions. There are three primary strategies for developing technologies to minimize the lunar dust adhesion: active, passive and a combination of active and passive. In the active approach, an external energy is needed to prevent or remove particles from collecting on the surface. Mechanically powered brushes and electrodynamic dust screens are two examples. In the passive approach, no external power is needed, and the material surface properties are able to mitigate dust adhesion. A well-known example of this strategy is the low work function coatings for non-stick surfaces. In most cases a combination of active and passive methods might be needed to optimally manage the lunar regolith. The passive method is significantly more attractive as it does not require any external power or an additional control subsystem. These approaches optimize the mission payload and reduce risk. Surface modification to minimize the dust adhesion is thus very important to lunar missions. Here, naturally evolved surface structures might provide guidance for solutions. There are several factors that have to be considered for minimizing particle adhesion to a surface. These include the substrate material properties, surface topography, chemistry, and the characteristics of the adhering particles. When engineering a surface, the substrate material chosen would be dependent on the needs of the application. Tailoring the surface microstructure or chemistry opens up more possibilities for its optimal utilization

Lunar Dust↗

Polyimides containing pendent siloxane groups

The incorporation of siloxane units into the backbone of aromatic polyimides has been shown to impart certain advantages over the unmodified polyimides. These include enhanced solubility, lower moisture adsorption, lower dielectric constant, improved toughness and surface modification. Also, when exposed to an atomic oxygen environment these materials form an in-situ silicate (SiO2) surface coating which protects the underlying material from further erosion. These unique advantages make polyimide-siloxanes useful in a variety of electronic and aerospace applications. As part of an effort on high performance polymeric materials for potential aerospace applications, polyimides containing pendent siloxane groups are under study. These materials were prepared by reacting a functionalized siloxane compound with polyimides containing benzhydrol groups. Thin films of the polymers exhibited glass transition temperatures ranging from 167 to 235 C. Tensile strengths and moduli measured at 23 C ranged from 11 to 14 ksi and 250 to 450 ksi, respectively. The dielectric constant was lowered substantially from that of the unmodified polyimide.

Connell, John W.↗

Saturn's satellites - Near-infrared spectrophotometry (0.65-2.5 microns) of the leading and trailing sides and compositional implications

Water ice absorptions at 2.0, 1.5, and 1.25 microns are noted in near-IR spectra of Tethys, Dione, Rhea, Iapetus, and Hyperion, and the weak 1.04-micron ice absorption, which is detected for Rhea and Dione, is studied to establish band depth upper limits. The leading-trailing side 1.04-micron ice band depth differences on Saturn's satellites are similar to those for the Galilean satellites, indicating possible surface modification by magnetospheric charged particle bombardment. Limits are obtained for the amounts of particulates, trapped gases, and ammonium hydroxide on the surface. With the exception of the dark side of Iapetus, the surfaces of all of Saturn's satellites are nearly pure ice water.

Steele, A.↗

A One Billion Year Martian Climate Model: The Importance of Seasonally Resolved Polar Caps and the Role of Wind

Wind deflation and deposition are powerful agents of surface change in the present Mars climate regime. Recent studies indicate that, while the distribution of regions of potential deflation (or erosion) and deposition is remarkably insensitive to changes in orbital parameters (obliquity, timing of perihelion passage, etc.), rates of aeolian surface modification may be highly sensitive to these parameters even if the atmospheric mass remains constant. But previous work suggested the atmospheric mass is likely to be sensitive to obliquity, especially if a significant mass of carbon dioxide can be stored in the regolith or deposited in the form of massive polar caps. Deflation and erosion are highly sensitive to surface pressure, so feedback between orbit variations and surface pressure can greatly enhance the sensitivity of aeolian modification rates to orbital parameters. We used statistics derived from a 1 Gyr orbital integration of the spin axis of Mars, coupled with 3D general circulation models (GCMs) at a variety of orbital conditions and pressures, to explore this feedback. We also employed a seasonally resolved 1D energy balance model to illuminate the gross characteristics of the longterm atmospheric evolution, wind erosion and deposition over one billion years. We find that seasonal polar cycles have a critical influence on the ability for the regolith to release CO2 at high obliquities, and find that the atmospheric CO2 actually decreases at high obliquities due to the cooling effect of polar deposits at latitudes where seasonal caps form. At low obliquity, the formation of massive, permanent polar caps depends critically on the values of the frost albedo, A(sub frost), and frost emissivity, E(sub frost). Using our 1D model with values of A(sub frost) = 0.67 and E(sub frost) = 0.55, matched to the NASA Ames GCM results, we find that permanent caps only form at low obliquities (< 10 degrees). Thus, contrary to expectations, the Martian atmospheric pressure is remarkable static over time, and decreases both at high and low obliquity. Also, from our one billion year orbital model, we present new results on the fraction of time Mars is expected to experience periods of high and low obliquity. Finally, using GCM runs at a variety of pressures, we examine the likely role of wind erosion under an early more massive Martian atmosphere.

J C Armstrong↗

Developing Materials and Coating Technologies for Mitigation of Lunar Dust Adhesion and Abrasion

In order to support long duration missions on the Moon’s surface, materials resistant to the harsh lunar environment are critically needed. Lunar dust poses a major threat to the durability of components and vehicles due to its fine, jagged morphology and highly abrasive nature, enabling the particles to adhere and embed onto surfaces of components and devices and potentially leading to premature failure. There is significant effort within NASA to develop novel materials and coating technologies to mitigate lunar dust adhesion and abrasion. This effort has been exploring a variety of production routes and examining properties of candidate material systems, including ceramic, metallic and polymeric. Manufacturing methods investigated include ceramic powder processing, additive manufacturing and surface modification via laser ablation patterning of bulk materials and coatings. An overview of ongoing NASA materials and coating research and development efforts to enable lunar surface exploration will be presented.

Materials, Coatings, lunar dust mitigation↗

TWT efficiency enhancement with textured carbon surfaces on copper MDC electrodes

A method of improving the efficiency of multistage depressed collectors (MDC's) for traveling-wave tubes (TWT's) has been demonstrated at the NASA Lewis Research Center. A significant increase in MDC efficiency was brought about by the application of a thin layer of highly-textured carbon to the surfaces of oxygen-free, high-conductivity (OFHC) copper collector electrodes in an experimental TWT. The textured carbon layer was applied by means of a NASA developed sputtering procedure. In an experimental investigation recently completed, this electrode surface modification resulted in an increase in MDC efficiency by as much as 8.6 percentage points relative to that of the same MDC with untreated copper electrode surfaces. This increase in MDC efficiency was reflected by an increase in overall TWT efficiency by as much as 5.4 percentage points.

Curren, A. N.↗

Chemical modification of semiconductor surfaces

Results of research on the chemical modification of TiO2 powders in the gas phase and the examination of the modified powders by infrared absorption spectroscopy are comprehensively summarized. The range of information obtainable by IR spectroscopy of chemically modified semiconductors, and a definition of the optimum reaction conditions for synthesizing a monolayer of methylsilanes using vapor phase reaction conditions were considered.

Finklea, H. O.↗

Martian aeolian processes, sediments, and features

In this review of the aeolian regime on Mars, consideration is given to the sources and characteristics of the particles that are involved in aeolian processes and the winds that are required to set grains into motion. Dust storms are reviewed and previous observations and the mechanisms of dust-storm generation are assessed. Various aeolian features, including dunes and albedo features, as well as windblown mantle deposits are discussed. In planning for future missions to Mars, aeolian processes must be taken into account. Surface modifications by the wind and windblown deposits can influence remote-sensing observations, affect sampling strategies, and have detrimental effects on manned and unmanned spacecraft on the surface.

Greeley, Ronald↗

Probing Supraglacial Debris on Mars 2: Crater Morphology

Lobate debris aprons (LDA), lineated valley fill (LVF), and concentric crater fill (CCF) on Mars, interpreted to bedebris-covered glaciers, possess craters with a suite of distinct interior landforms (called "ring-mold craters")that have been attributed to the presence of glacial ice at depth or surface modification processes. We testedcurrent hypotheses for the formation of ring-mold craters by conducting a comprehensive analysis of the size andmorphology of 16,457 impact craters 125m in diameter formed within glacial deposits in DeuteronilusMensae. Two major groups, bowl-shaped craters and ring-mold craters, are found, with at least nine distinctcrater types. While there is statistical difference in median diameters between these crater types, this differenceis relatively small and is within the estimated uncertainty in diameter measurements and may be related to moreenhanced erosion of the rims of ring-mold craters. Clear degradation sequences are observed, supporting a rolefor post-impact modification in producing at least some of the diversity in crater landforms. The spatial densityof ring-mold craters is also directly correlated with the development of LDA, LVF, and CCF surface textures. Flowlineations cross-cut two ring-mold crater types but they maintain their circular planforms in some cases, suggestingthat the craters initially formed completely within mantling layers deposited after glacial flow hadceased. We also find analogous craters in non-glacial units; glacial ice is therefore not required to form theobserved morphologic diversity. Our observations are most consistent with formation of crater landforms byemplacement and modification of at least two depositional episodes of icy dust (i.e., "mantle"). This mantle wasinitially tens of meters in thickness to support crater formation, and has experienced much downwasting anderosion since emplacement. Derived crater retention ages of 460 Ma for LDA, LVF, and CCF features in the regiontherefore reflect deposition of mantle units and only give a very minimum age for the formation of LDA, LVF, andCCF

Geological↗

Hydrogen Plasma Reduction of Silicates for Lunar Oxygen Liberation

As crewed missions to the moon become closer, the focus on in-situ resource utilization efforts has increased. Since lunar soil has abundant oxygen on the surface of the moon, work has been done to process this resource in an efficient manner. Hydrogen reduction of lunar regolith has emerged as a method of liberating oxygen that can be used for fuel and water production. Traditional reduction techniques require high temperatures and increased complexity when dealing with high amounts of silicates. Plasma can reduce silicates efficiently and thus has become of high interest for use in the lunar highlands where silicates exist in high quantities. NASA’s Kennedy Space Center is exploring the use of low temperature plasmas for the reduction of silicates. This work shows that exposing silicates to a hydrogen plasma produces water. Residual gas analysis and optical emission spectroscopy were used to measure the relative quantities of water vapor production and OH (A-X) emission for hydrogen plasma interactions with lunar highland simulant and silica. X-ray photo-electron spectroscopy and scanning electron microscopy/energy-dispersive X-ray spectroscopy were also used to observe surface modifications to the silicates that reflect the key chemical reactions that occurred. From this data, plasma has emerged as a promising solution to produce oxygen on the lunar surface. *Work supported by NASA's Science Technology Mission Directorate Center Innovation Fund.

R. P. Gott↗

Plasma Reduction of Regolith for Oxygen Liberation

As crewed missions to the moon become closer, the focus on in-situ resource utilization efforts has increased. Since lunar soil has abundant oxygen on the surface of the moon, work has been done to process this resource in an efficient manner. Hydrogen reduction of lunar regolith has emerged as a method of liberating oxygen that can be used for fuel and water production. Traditional reduction techniques require high temperatures and increased complexity when dealing with high amounts of silicates. Plasma can reduce silicates efficiently and thus has become of high interest for use in the lunar highlands where silicates exist in high quantities. NASA’s Kennedy Space Center is exploring the use of low temperature plasmas for the reduction of silicates. This work shows that exposing silicates to a hydrogen plasma produces water. Residual gas analysis and optical emission spectroscopy were used to measure the relative quantities of water vapor production and OH (A-X) emission for hydrogen plasma interactions with lunar highland simulant and silica. X-ray photo-electron spectroscopy and scanning electron microscopy/energy-dispersive X-ray spectroscopy were also used to observe surface modifications to the silicates that reflect the key chemical reactions that occurred. From this data, plasma has emerged as a promising solution to produce oxygen on the lunar surface.

Ryan Gott↗

Physical Processing of Cometary Nuclei

Cometary nuclei preserve a cosmo-chemical record of conditions and processes in the primordial solar nebula, and possibly even the interstellar medium. However, that record is not perfectly preserved over the age of the solar system due to a variety of physical processes which act to modify cometary surfaces and interiors. Possible structural and/or internal processes include: collisional accretion, disruption, and reassembly during formation; internal heating by long and short-lived radionuclides; amorphous to crystalline phase transitions, and thermal stresses. Identified surface modification processes include: irradiation by galactic cosmic rays, solar protons, UV photons, and the Sun's T Tauri stage mass outflow; heating by passing stars and nearby supernovae; gardening by debris impacts; the accretion of interstellar dust and gas and accompanying erosion by hypervelocity dust impacts and sputtering; and solar heating with accompanying crust formation. These modification processes must be taken into account in both the planning and the interpretation of the results of a Comet Nucleus Sample Return Mission. Sampling of nuclei should be done at as great a depth below the surface crust as technically feasible, and at vents or fissures leading to exposed volatiles at depth. Samples of the expected cometary crust and near-surface layers also need to be returned for analysis to achieve a better understanding of the effects of these physical processes. We stress that comets are still likely less modified dm any other solar system bodies, but the degree of modification can vary greatly from one comet to the next.

Weissman, Paul R.↗

Atomic oxygen beam source for erosion simulation

A device for production of low-energy (5-10 eV) neutral atomic beams for surface modification studies, which recreates the flux of atomic oxygen in LEO, is described. The beam is produced by acceleration of plasma ions onto a negatively biased plate of high-Z metal; the ions are neutralized and reflected by the surface, retaining a large fraction of their incident kinetic energy, forming a beam of atoms. The device is based on a magnetically confined (3-4 kG) coaxial plasma source and the atom energy can be varied by adjusting the bias voltage. The source provides a neutral flux of roughly 5 x 10 to the 16th/sq cm/s at a distance of 10 cm and a fluence of roughly 10 to the 21st/sq cm in five hours. The source has been characterized with plasma diagnostics and by measuring the energy of an atomic argon beam using a mass spectrometer. Samples of carbon film, carbon-based paint, Kapton, Mylar, and Teflon exposed to atomic O beams show erosion quite similar to those observed in orbit on the Space Shuttle.

Cuthbertson, J. W.↗

Evidence for glaciation in Elysium

Evidence for the existence of permafrost and the surface modification due to frost effects and the presence of ice on Mars dates from early observations. Later analysis of the Viking Orbiter imagery produced evidence suggesting the former presence of ice sheets that could have played a part in shaping the surface of Mars. Similarities were pointed out between a number of streamlined Martian channel features and similar streamlined landforms created by Antarctic ice sheet movement. A study of Viking Orbiter imagery of Granicus Valles and the surrounding terrain in Elysium has produced further evidence of glaciation on Mars. Volcanism has played an important role in developing the landscapes of the Elysium region. A possible explanation is that subsidence occurred during formation of the Martian moberg ridges due to the melting of ground ice near the eruption area while at a distance most of the ground ice in the permafrost is still present and the original elevation was preserved. Meltwater during and following eruptions might be suddenly released during subglacial volcanism into Granicus Valles in one case and into Hrad Valles in the other. Fluvial erosion thus could have played a role in shaping both.

Anderson, Duwayne M.↗

Atomic oxygen beam source for erosion simulation

A device for the production of low energy (3 to 10 eV) neutral atomic beams for surface modification studies is described that reproduces the flux of atomic oxygen in low Earth orbit. The beam is produced by the acceleration of plasma ions onto a negatively biased plate of high-Z metal; the ions are neutralized and reflected by the surface, retaining some fraction of their incident kinetic energy, forming a beam of atoms. The plasma is generated by a coaxial RF exciter which produces a magnetically-confined (4 kG) plasma column. At the end of the column, ions fall through the sheath to the plate, whose bias relative to the plasma can be varied to adjust the beam energy. The source provides a neutral flux approximately equal to 5 x 10(exp 16)/sq cm at a distance of 9 cm and a fluence approximately equal to 10(exp 20)/sq cm in five hours. The composition and energy of inert gas beams was diagnosed using a mass spectometer/energy analyzer. The energy spectra of the beams demonstrate energies in the range 5 to 15 eV, and qualitatively show expected dependences upon incident and reflecting atom species and potential drop. Samples of carbon film, carbon-based paint, Kapton, mylar, and teflon exposed to atomic O beams show erosion quite similar to that observed in orbit on the space shuttle.

Cuthbertson, J. W.↗

Maps of Tethys' Thermophysical Properties

On 11th April 2015 Cassini's Composite Infrared Spectrometer (CIRS) made a series of observations of Tethys’ daytime anti-Saturn hemisphere over a nine-hour time period. During this time the sub-spacecraft position was remarkably stable (0.3° S to 3.9° S; 153.2° W to 221.8° W), and so these observations provide unprecedented coverage of diurnal temperature variations on Tethys’ anti-Saturn hemisphere. In 2012 a thermal anomaly was discovered at low latitudes on Tethys’ leading hemisphere; it appears cooler during the day and warmer at night than its surroundings (Howett et al., 2012) and is spatially correlated with a decrease in the IR3/UV3 visible color ratio (Schenk et al., 2011). The cause of this anomaly is believed to be surface alteration by high-energy electrons, which preferentially bombard low-latitudes of Tethys’ leading hemisphere (Schenk et al., 2011; Howett et al., 2012; Paranicas et al. 2014; Schaible et al., 2017). The thermal anomaly was quickly dubbed “Pac-Man” due to its resemblance to the 1980s video game icon. We use these daytime 2015 CIRS data, along with two sets of nighttime CIRS observations of Tethys (from 27 June 2007 and 17 August 2015) to make maps of bolometric Bond albedo and thermal inertia variations across the anti-Saturn hemisphere of Tethys (including the edge of its Pac-Man region). These maps confirm the presence of the Pac-Man thermal anomaly and show that while Tethys’ bolometric Bond albedo varies negligibly outside and inside the anomaly (0.69 plus or minus 0.02 inside, compared to 0.71 plus or minus 0.04 outside) the thermal inertia varies dramatically (29 plus or minus 10 J m−2 K−1 s−1/2 inside, compared to 9 plus or minus 4 J m−2 K−1 s−1/2 outside). These thermal inertias are in keeping with previously published values: 25 plus or minus 3 J m−2 K−1 s−1/2 inside, and 5 ± 1 J m−2 K−1 s−1/2 outside the anomaly (Howett et al., 2012). A detailed analysis shows that on smaller spatial-scales the bolometric Bond albedo does vary: increasing to a peak value at 180° W. For longitudes between approximately 100° W and approximately 160° W the thermal inertia increases from northern to southern latitudes, while the reverse is true for bolometric Bond albedo. The thermal inertia on Tethys generally increases towards the center of its leading hemisphere but also displays other notable small-scale variations. These thermal inertia and bolometric Bond albedo variations are perhaps due to differences in competing surface modification by E ring grains and high-energy electrons which both bombard Tethys’ leading hemisphere (but in different ways). A comparison between the observed temperatures and our best thermal model fits shows notable discrepancies in the morning warming curve, which may provide evidence of regional variations in surface roughness effects, perhaps again due to variations in surface alteration mechanisms.

Howett, C. J. A.↗