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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Metabolic Synergy between Human Symbionts Bacteroides and Methanobrevibacter

Trophic interactions between microbes are postulated to determine whether a host microbiome is healthy or causes predisposition to disease. Two abundant taxa, the Gram-negative heterotrophic bacterium Bacteroides thetaiotaomicron and the methanogenic archaeon Methanobrevibacter smithii, are proposed to have a synergistic metabolic relationship. Both organisms play vital roles in human gut health; B. thetaiotaomicron assists the host by fermenting dietary polysaccharides, whereas M. smithii consumes end-stage fermentation products and is hypothesized to relieve feedback inhibition of upstream microbes such as B. thetaiotaomicron. To study their metabolic interactions, we defined and optimized a coculture system and used software testing techniques to analyze growth under a range of conditions representing the nutrient environment of the host. Here we verify that B. thetaiotaomicron fermentation products are sufficient for M. smithii growth and that accumulation of fermentation products alters secretion of metabolites by B. thetaiotaomicron to benefit M. smithii. Studies suggest that B. thetaiotaomicron metabolic efficiency is greater in the absence of fermentation products or in the presence of M. smithii. Under certain conditions, B. thetaiotaomicron and M. smithii form interspecies granules consistent with behavior observed for syntrophic partnerships between microbes in soil or sediment enrichments and anaerobic digesters. Furthermore, when vitamin B 12 , hematin, and hydrogen gas are abundant, coculture growth is greater than the sum of growth observed for monocultures, suggesting that both organisms benefit from a synergistic mutual metabolic relationship.

59 BASIC BIOLOGICAL SCIENCES↗

A CANDELS-3d-HST Synergy: Resolved Star Formation Patterns at 0.7 less than z less than 1.5

We analyze the resolved stellar populations of 473 massive star-forming galaxies at 0.7 < z < 1.5, with multiwavelength broadband imaging from CANDELS andHalpha surface brightness profiles at the same kiloparsec resolution from 3D-HST. Together, this unique data set sheds light on how the assembled stellar mass is distributed within galaxies, and where new stars are being formed. We find the Halpha morphologies to resemble more closely those observed in the ACS I band than in the WFC3 H band, especially for the larger systems. We next derive a novel prescription for Halpha dust corrections, which accounts for extra extinction toward H II regions. The prescription leads to consistent star formation rate (SFR) estimates and reproduces the observed relation between the Halpha/UV luminosity ratio and visual extinction, on both a pixel-by-pixel and a galaxy-integrated level. We find the surface density of star formation to correlate with the surface density of assembled stellar mass for spatially resolved regions within galaxies, akin to the so-called "main sequence of star formation" established on a galaxy-integrated level. Deviations from this relation toward lower equivalent widths are found in the inner regions of galaxies. Clumps and spiral features, on the other hand, are associated with enhanced H alpha equivalent widths, bluer colors, and higher specific SFRs compared to the underlying disk. Their Halpha/UV luminosity ratio is lower than that of the underlying disk, suggesting that the ACS clump selection preferentially picks up those regions of elevated star formation activity that are the least obscured by dust. Our analysis emphasizes that monochromatic studies of galaxy structure can be severely limited by mass-to-light ratio variations due to dust and spatially inhomogeneous star formation histories.

SYNERGY↗

Wide-Field InfraRed Survey Telescope (WFIRST) Mission and Synergies with LISA and LIGO-Virgo

The Wide-Field InfraRed Survey Telescope (WFIRST) is a NASA space mission in study for launch in 2024. It has a 2.4 m telescope, wide-field IR instrument operating in the 0.7 - 2.0 micron range and an exoplanet imaging coronagraph instrument operating in the 400 - 1000 nm range. The observatory will perform galaxy surveys over thousands of square degrees to J=27 AB for dark energy weak lensing and baryon acoustic oscillation measurements and will monitor a few square degrees for dark energy SN Ia studies. It will perform microlensing observations of the galactic bulge for an exoplanet census and direct imaging observations of nearby exoplanets with a pathfinder coronagraph. The mission will have a robust and wellfunded guest observer program for 25% of the observing time. WFIRST will be a powerful tool for time domain astronomy and for coordinated observations with gravitational wave experiments. Gravitational wave events produced by mergers of nearby binary neutron stars (LIGO-Virgo) or extragalactic supermassive black hole binaries (LISA) will produce electromagnetic radiation that WFIRST can observe.

Wide-Field InfraRed Survey Telescope (WFIRST) Miss↗

NASA's Orgins Space Telescope Mission and Its Synergies with SOFIA

The Origins Space Telescope (OST) is the mission concept for the Far Infrared Surveyor, a study in development by NASA in preparation for the 2020 Astronomy and Astrophysics Decadal Survey. The science program that has been selected to drive the OST performance requirements is broad, covering four main themes: Charting the Rise of Metals, Dust, and the First Galaxies; Unveiling the Growth of Black Holes and Galaxies Over Cosmic Time; Tracing the Signatures of Life and the Ingredients of Habitable Worlds; and Characterizing Small Bodies in the Solar System. The OST telescope itself will have a primary mirror diameter of 8-15 m (depending on the launch vehicle that is selected), will be diffraction-limited at 40m, and will be actively cooled to approximately 5K. Five science instruments have been base-lined for the observatory: a heterodyne instrument covering 150-500 m with a spectral resolving power of R1e7; a low-spectral resolution (R500) spectrometer covering 35-500 m; a high-spectral resolution (R1e5) spectrometer covering 50-500 m; a far-infrared imager (R15) covering 35-500m; and a mid-infrared imagerspectrometer (R15-500) covering 6-40m. In addition to having a vastly higher sensitivity than the corresponding SOFIA instrumentation that will allow more detailed follow-up of SOFIAs discoveries, the OST mission will be configured to provide efficient large-area mapping, which will further complement SOFIAs science capabilities by providing new targets for study by SOFIA. Furthermore, new SOFIA instruments can provide an excellent testbed for the advanced far-infrared detector technologies what will be required to achieve the anticipated OST performance.

Mission↗

Synergy of Observations and Dynamo Models to Understand and Predict Solar Activity Cycles

The long-standing problem of understanding the evolution of the global magnetic fields that drive solar activity through different temporal scales is becoming more tractable because, in addition to 400 years of sunspot records, we now have almost 4 solar cycles of magnetic field observations. These observations allow us to discern physical connections between dynamo model variables and observations using data assimilation analysis. In particular, the Ensemble Kalman Filter approach takes into account uncertainties in both observations and modeling and allows us to make reliable forecasts of solar cycle activity cycles by using a relatively simple non-linear dynamical model of the solar dynamo. To expand this approach for more complex 2D and 3D dynamo modeling, it is necessary to decompose the observed synoptic magnetograms into poloidal and toroidal field components. In this presentation I will present initial results on magnetogram decomposition and assimilation of magnetogram data into dynamo modeling.

Synergy↗

Synergy of Ion Doping and Spiral Array Architecture on Ti 2 Nb 10 O 29 : A New Way to Achieve High-Power Electrodes

Ameliorating electronic/ionic transport and structural stability of electrode materials is important to the development of power-intensive lithium ion batteries. Despite its great potential as a high-power anode, titanium niobium oxide (Ti 2 Nb 10 O 29 , TNO) still underperforms due to its unsatisfactory electronic/ionic conductivity. In this work, a powerful synergistic strategy by combining ion doping and spiral array architecture to boost high-rate performance of TNO is reported. Cr 3+ doped TNO nanoparticles (Cr-TNO) of 5-10 nm intimately grow on a conductive vertical graphene@TiC-C (VGTC) skeleton, forming novel Cr-TNO@VGTC spiral arrays. The unique spiral growth of TNO is achieved due to the confinement effect of VGTC skeleton. Meanwhile, a more open TNO crystal structure with faster ion transfer paths and enhanced structural stability is realized by Cr 3+ doping, demonstrated via density functional theory calculation and in situ synchrotron X-ray diffraction technique. Benefiting from the superior conductive network, enhanced intrinsic electronic/ionic conductivity of Cr-TNO and reinforced structural stability, the Cr-TNO@VTC arrays show prominent high-power performance with a large capacity of 220 mAh g -1 at 40 C (power density of ≈11 kW kg -1 ) and superior durability (91% retention after 500 cycles). This work provides a new path for the construction of widespread high-power electrodes for fast energy storage.

36 MATERIALS SCIENCE↗

Pushing Lithium–Sulfur Batteries towards Practical Working Conditions through a Cathode–Electrolyte Synergy

Abstract The commercialization of lithium–sulfur (Li−S) batteries is still hindered by the unsatisfactory cell performance under practical working conditions, which is mainly caused by the sluggish cathode redox kinetics, severe polysulfide shuttling, and poor Li stripping/plating reversibility. Herein, we report an effective strategy by combining Se‐doped S hosted in an ordered macroporous framework with a highly fluorinated ether (HFE)‐based electrolyte to simultaneously address the aforementioned issues in both cathode and anode. A reversible and stable high areal capacity of >5.4 mAh cm −2 with high Coulombic efficiency >99.2 % can be achieved under high areal Se/S loading (5.8 mg cm −2 ), while the underlying mechanism was further revealed through synchrotron X‐ray probes and Time‐of‐Flight Secondary Ion Mass Spectrometry (ToF‐SIMS). The practical application potential was further evaluated at low (0 °C) and high (55 °C) temperatures under high areal Se/S loading (>5.0 mg cm −2 ) and thin Li metal (40 μm).

Zhao, Chen↗

Synergy of Oxygen Vacancies and Base Sites for Transfer Hydrogenation of Nitroarenes on Ceria Nanorods

Abstract CeO 2 nanorod based catalysts for the base‐free synthesis of azoxy‐aromatics via transfer hydrogenation of nitroarenes with ethanol as hydrogen donor have been synthesized and investigated. The oxygen vacancies (O v ) and base sites are critical for their excellent catalytic properties. The O v , i.e., undercoordinated Ce cations, serve as the sites to activate ethanol and nitroarenes by lowering the energy barrier to transfer hydrogen from α−C sp3 −H in ethanol to the nitro group coupling it to the redox reactions between Ce 3+ and Ce 4+ . At the same time, the base sites catalyze the condensation step to selectively produce azoxy‐aromatics. The catalytic route opens a much improved way to use non‐noble metal oxides without additives for the selective functional group reduction and coupling reactions.

Yuan, Ziliang↗

Pushing Lithium–Sulfur Batteries towards Practical Working Conditions through a Cathode–Electrolyte Synergy

The commercialization of lithium-sulfur (Li-S) batteries is still hindered by the unsatisfactory cell performance under practical working conditions, which is mainly caused by the sluggish cathode redox kinetics, severe polysulfide shuttling, and poor Li striping/platting reversibility. We reported an effective strategy by combining Se-doped S hosted in an ordered macroporous framework with highly fluorinated ether (HFE)-based electrolyte to simultaneously address the aforementioned issues in both cathode and anode. A reversible and stable high areal capacity of > 5.4 mAh cm -2 with high coulombic efficiency > 99.2% can be achieved under high areal Se/S loading (5.8 mg cm -2 ), while the underlying mechanism was further revealed through synchrotron X-ray probes and Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS). The practical application potential was further evaluated at low (0 °C) and high (55 °C) temperatures under high areal Se/S loading (> 5.0 mg cm -2 ) and thin Li metal (40 µm).

25 ENERGY STORAGE↗

Synergy of Oxygen Vacancies and Base Sites for Transfer Hydrogenation of Nitroarenes on Ceria Nanorods

CeO 2 nanorod based catalysts for the base-free synthesis of azoxy-aromatics via transfer hydrogenation of nitroarenes with ethanol as hydrogen donor have been synthesized and investigated. The oxygen vacancies (O v ) and base sites are critical for their excellent catalytic properties. The O v , i.e., undercoordinated Ce cations, serve as the sites to activate ethanol and nitroarenes by lowering the energy barrier to transfer hydrogen from α–C sp3 –H in ethanol to the nitro group coupling it to the redox reactions between Ce 3+ and Ce 4+ . At the same time, the base sites catalyze the condensation step to selectively produce azoxy-aromatics. Finally, the catalytic route opens a much improved way to use non-noble metal oxides without additives for the selective functional group reduction and coupling reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Exploring Fission–Fusion Synergies to Accelerate Compatibility Understanding

To address the significant commercial interest in fusion energy, it will be necessary to accelerate the compatibility research associated with liquid breeders including Li, eutectic Pb–Li and LiF-BeF 2 (FLiBe) molten salt. Particularly for FLiBe, compatibility understanding is limited especially for fusion relevant materials such as reduced activation ferritic-martensitic steels, SiC and V alloys. The historical knowledge associated with molten salt reactors (MSRs) and recent work to commercialize MSRs can benefit fusion research. Recent experimental and modeling work has improved understanding and this knowledge can be applied to fusion relevant materials. For liquid metals (LMs), the comparisons to Li and Pb–Li are less direct but nevertheless can help guide the pathway toward commercialization. For Pb–Li, Al-rich coatings have been shown to inhibit dissolution and potentially increase operating temperatures. For commercialization, the experience with sensors and on-line cleanup can help guide future developments. Thus, it is worth considering the potential for fission-related research with LMs and molten salts to help accelerate fusion research.

36 MATERIALS SCIENCE↗

Multi-objective sizing and dispatch for building thermal and battery storage towards economic and environmental synergy

The role of building thermal and battery storage is pivotal in advancing smart cities and achieving sustainability goals through effective energy management. Despite their significance, there are several limitations in the sizing approach and value stream analysis with various objectives for their widespread adoption in buildings. This work proposes a flexible and scalable multi-objective optimization framework for optimal sizing and dispatch of building thermal and battery storage, addressing conflicting objectives simultaneously using mixed-integer linear programming. The weighted-sum method is adapted, combining multiple objectives into a single function. The two-stage procedure iterates over different weights, generating optimal solutions and forming the Pareto front. Case studies are performed to assess the energy, economic, and environmental benefits of building energy storage systems for a large office building in three climate locations. The results demonstrate that the proposed framework efficiently determines optimal sizing and dispatch strategies, addressing the balance between economic viability and emission reduction. The dynamic relationship between time-of-use energy charges and emission factors leads to significantly different strategies based on whether economic or environmental concerns are prioritized. This research enhances our understanding of the benefits of TES and BES systems in buildings, providing valuable guidance to stakeholders.

25 ENERGY STORAGE↗

Iterative redox activation promotes interfacial synergy in an Ag/Cu x O catalyst for oxygen reduction

In this study, an iterative electrochemical activation process is demonstrated to maximize the interface between Ag and Cu x O. Morphological reconstruction and phase transformation of Cu x O occurs through the iterative electrochemical redox reaction, as indicated by energy-dispersive spectroscopy and X-ray photoelectron spectroscopy. The activated Ag/Cu x O/C catalysts exhibits enhanced oxygen reduction reaction performance, with an onset potential of 0.86 V vs. the reversible hydrogen electrode, a Tafel slope of 46mV dec -1 , and a high stability as compared to Ag/C. A mechanistic study using density functional theory shows that the weakened binding energy of the OH intermediate, originating from the charge transfer from Ag to Cu x O, improves the ORR activity at the interface sites of the Ag/Cu x O electrocatalysts. Ag/Cu x O shows a higher limiting potential of 0.14V for interface sites than isolated Ag nanoparticles. The interfacial charge transfer between Ag and CuO is verified experimentally.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Entropy-defect synergy for dual luminescence mechanism in spinel: Time-resolved anti-counterfeiting and fingerprint visualization

Multimodal luminescent materials, while promising for anti-counterfeiting, often lack dynamic time-dependent responses and controllable spatial distribution, limiting their encryption capabilities in the spatiotemporal dimension. Here, this work presents a coordinated control strategy based on entropy and defect engineering, and uses a backpropagation (BP) neural network for material screening to successfully prepare spinel Mg 0.8 (Fe 0.04 Co 0.04 Ni 0.04 Cu 0.04 Zn 0.04 )Cr 2 O 4 (MgA 5 CO) phosphors with time-dependent dynamic luminescence behavior. This phosphor simultaneously activated the d-d transition luminescence (∼618 nm) derived from Co 2+ /Cr 3+ and the defect luminescence (∼398 nm) related to zinc vacancies (V Zn ) in a single-phase solid solution. The phosphor exhibits a time-dependent color evolution from pink to purple under fixed-wavelength excitation, due to the different excited-state dynamics and decay lifetimes associated with the d-d transition and defect luminescence. Structural characterization and spectral analysis confirmed the existence of V Zn and its significant role in defect luminescence process. The fluorescent and dynamic luminescent properties of entropy-based spinel oxide enable its use in advanced anti-counterfeiting applications like fingerprint recognition and color-changing dedicated anti-counterfeiting mark, showing promise in high-end and time-dynamic anti-counterfeiting fields. This research not only developed a new type of fluorescent dynamic anti-counterfeiting material, but also provided a new idea for constructing advanced optical functional materials with multiple luminescence mechanisms.

Defect project↗

Synergy between cosmological and laboratory searches in neutrino physics

The intersection of the cosmic and neutrino frontiers is a rich field where much discovery space still remains. Neutrinos play a pivotal role in the hot big bang cosmology, influencing the dynamics of the universe over numerous decades in cosmological history. Recent studies have made tremendous progress in understanding some properties of cosmological neutrinos, primarily their energy density. Upcoming cosmological probes will measure the energy density of relativistic particles with higher precision, but could also start probing other properties of the neutrino spectra. When convolved with results from terrestrial experiments, cosmology can become even more acute at probing new physics related to neutrinos or even Beyond the Standard Model (BSM). Any discordance between laboratory and cosmological data sets may reveal new BSM physics and/or suggest alternative models of cosmology. Here we give examples of the intersection between terrestrial and cosmological probes in the neutrino sector, and briefly discuss the possibilities of what different laboratory experiments may see in conjunction with cosmological observatories.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗