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At least 91 records · Page 5

Energy transfer of O(D-1) atoms in collision with O(P-3) atoms

Calculations are carried out of the elastic scattering and excitation exchange cross-sections in collisions of O(D-1) and O(P-3) atoms, which determine the degree of thermalization of the O(D-1) atoms produced by dissociative recombination in the thermosphere. The effective elastic scattering and excitation exchange cross-sections are calculated to be 1.55 x 10 to the -15th and 6.25 x 10 to the -16th sq cm, respectively, at a relative collision energy of 1.0 eV. The mutual diffusion coefficient between O(D-1) and O(P-3) atoms is also presented.

Yee, Jeng-Hwa↗

Hot Hydrogen Testing of Uranium Nitride Cermet for Nuclear Thermal Propulsion

This study investigated the thermochemical stability and performance characteristics of uranium mononitride tungsten molybdenum cermet (UN-Mo30W) as a potential fuel material for Nuclear Thermal Propulsion (NTP) engines. Twelve monolithic cylinders were subjected to conditions simulating an active NTP engine. The tests demonstrated thermal variability within the test article and highlighted the dissociation of UN into U and N2 at elevated temperatures, affecting the microstructure and causing bonding between cermet wafers and cooling tubes. Findings indicate that while UN-Mo30W cermet exhibits some desirable properties for NTP applications, its suitability is limited by high-temperature thermochemical instability.

nuclear fuels↗

Non-thermal distribution of O(1D) atoms in the night-time thermosphere

The 6300 A O(1D-3P) emission has been used for many years to remotely monitor the thermospheric temperature from the Doppler width of its line profile. The O(1D) atoms in the nighttime thermosphere are initially produced by the dissociative recombination of O2(+) ions with kinetic energy much greater than the thermal energy of the ambient neutrals. The validity of the technique to monitor neutral ambient temperature by measuring O(1D) 6300 A emission depends on the degree of thermalization of the O(1D) atoms. The object of this study is to calculate the velocity distribution of the O(1D) atoms and to examine the effect of nonthermal distribution on the nighttime thermospheric neutral temperature determined.

Yee, Jeng-Hwa↗

Theoretical and Experimental Investigation of Heat Conduction in Air, Including Effects of Oxygen Dissociation

Solutions are presented for the conduction of beat through a semi-infinite gas medium having a uniform initial temperature and a constant boundary temperature. The coefficients of thermal conductivity and diffusivity are treated as variables, and the solutions are extended to the case of air at temperatures where oxygen dissociation occurs. These solutions are used together with shock-tube measurements to evaluate the integral of thermal conductivity for air as a function of temperature.

Hansen, C. Frederick↗

A blast of gas in the latest Paleocene: simulating first-order effects of massive dissociation of oceanic methane hydrate

Carbonate and organic matter deposited during the latest Paleocene thermal maximum is characterized by a remarkable -2.5% excursion in delta 13C that occurred over approximately 10(4) yr and returned to near initial values in an exponential pattern over approximately 2 x 10(5) yr. It has been hypothesized that this excursion signifies transfer of 1.4 to 2.8 x 10(18) g of CH4 from oceanic hydrates to the combined ocean-atmosphere inorganic carbon reservoir. A scenario with 1.12 x 10(18) g of CH4 is numerically simulated here within the framework of the present-day global carbon cycle to test the plausibility of the hypothesis. We find that (1) the delta 13C of the deep ocean, shallow ocean, and atmosphere decreases by -2.3% over 10(4) yr and returns to initial values in an exponential pattern over approximately 2 x 10(5) yr; (2) the depth of the lysocline shoals by up to 400 m over 10(4) yr, and this rise is most pronounced in one ocean region; and (3) global surface temperature increases by approximately 2 degrees C over 10(4) yr and returns to initial values over approximately 2 x 10(6) yr. The first effect is quantitatively consistent with the geologic record; the latter two effects are qualitatively consistent with observations. Thus, significant CH4 release from oceanic hydrates is a plausible explanation for observed carbon cycle perturbations during the thermal maximum. This conclusion is of broad interest because the flux of CH4 invoked during the maximum is of similar magnitude to that released to the atmosphere from present-day anthropogenic CH4 sources.

Non-NASA Center↗

The composition of heavy molecular ions inside the ionopause of Comet Halley

The RPA2-PICCA instrument aboard the Giotto spacecraft obtained 10-210 amu mass spectral of cold thermal molecular ions in the coma of Comet Halley. The dissociation products of the long chain formaldehyde polymer polyoxymethylene (POM) have recently been proposed as the dominant complex molecules in the coma of Comet Halley; however, POM alone cannot account for all of the features of the high resolution spectrum. An important component of the dust at Comet Halley is particles highly enriched in carbon, hydrogen, oxygen, and nitrogen relative to the composition of carbonaceous chondrites. Since this dust could be a source for the heavy molecules observed by PICCA, a search was conducted for other chemical species by determining all the molecules with mass between 20 and 120 amu which can be made from the relatively abundant C, H, O, and N, without regard to chemical structure.

Mitchell, David L.↗

Applications of Low Density Flow Techniques and Catalytic Recombination at the Johnson Space Center

The talk presents a brief background on defInitions of catalysis and effects associated with chemically nonequilibrium and low-density flows of aerospace interest. Applications of catalytic recombination on surfaces in dissociated flow are given, including aero heating on reentry spacecraft thermal protection surfaces and reflection of plume flow on pressure distributions associated with the space station. Examples include aero heating predictions for the X-38 test vehicle, the inlet of a proposed gas-sampling probe used in high enthalpy test facilities, and a parabolic body at angle of attack. The effect of accommodation coefficients on thruster induced pressure distributions is also included. Examples of tools used include simple aero heating formulas based on boundary layer solutions, an engineering approximation that uses axisymmetric viscous shock layer flow to simulate full three dimensional flow, full computational fluid dynamics, and direct simulation Monte-Carlo calculations. Methods of determining catalytic recombination rates in arc jet flow are discus ed. An area of catalysis not fully understood is the formation of single-wall carbon nanotubes (SWNT) with gas phase or nano-size metal particles. The Johnson Space Center is making SWNTs using both a laser ablation technique and an electric arc vaporization technique.

Scott, Carl D.↗

Nitrogen escape from Mars

The mass spectrometer on the Viking spacecraft measured anomalous N-15:N-14 ratio of about 1.62 times the terrestrial value. This enhancement presumably results from differential escape of N-15. The escape of N is non-thermal and potential escape mechanisms include photodissociation, photoionization, and electron impact dissociative ionization of N2, and ion-molecule reactions and dissociative recombination of N2(+). The authors propose some calculations to explain the N ratio, but even with all escape mechanisms considered, the ratios don't balance. This leads to the assumption that some other escape mechanisms must exist that are unexplained.

Fox, J. L.↗

Hypersonic Flight and the Re-Entry Problem: The Twenty-First Wright Brothers Lecture

Up to this point the discussion of the problems of rocket vehicles has been confined to the effects of phenomena which have in the past been important ones for lower speed aircraft and will continue to be important for aircraft of all speeds. Now with considerable extension of both speed and altitude, other phenomena also become important. The nature of some problems will be altered, as a result, and new problems, of course, will be encountered. First, it is well to note that our interest in bluff bodies for ballistic vehicles in particular, and in rounded-nosed bodies generally, has changed our emphasis in aerodynamics. The detached bow waves which occur with such bodies at high supersonic speeds complicate the calculations of the flow-field characteristics. In the present period, much attention is being given to such studies. In addition, at the very high altitudes attained by most of the rocket-craft, the mean free path of air molecules can be of the same order, or long, compared to the dimensions of the vehicles. Thus, slip-flow and free-molecule-flow studies are of interest, particularly for satellite vehicles." The aerodynatnicist must deal with air having unfamiliar states and properties. Second, at hypersonic speeds where, for example, air is greatly decelerated, it may undergo considerable change in composition, the degree of change depending upon many factors. Dissociation of oxygen and nitrogen molecules can occur and, in addition, thermal ionization of many of the constituents. It is naturally to be expected that the convective heat transfer will, as a result, be altered from what it was for the "perfect" gas, and this has been the subject of much recent research effort. Moreover, the decelerated gas becomes capable of radiating energy and the radiative heat transfer must generally be considered for hypersonic vehicles, particularly for long-range ballistic rockets. It is not only the aerodynamic heating problems that are affected. The fact that at very high air temperature the gas becomes electrically conductive introduces new problems in radio wave transmission and reception. In addition, a conducting gas flow can, of course, be influenced by a magnetic field. The study of such flows, which has been termed "magneto gas dynamics," is still in too primitive a state to indicate how important a role it can play, but many interesting possibilities suggest themselves. Third, our experience with airplanes powered by air-breathing engines has naturally been restricted to the stratosphere, or lower. Our ignorance increases with altitude. For rockets, literally, "the sky's the limit," and it is not surprising that a great emphasis has now been placed on obtaining a more thorough understanding of the whole atmosphere. These studies are not aimed at an understanding of the chemical and physical characteristics alone, but also of the occurrence of high-energy particles, from meteors to cosmic rays, and the nature of the problems they will promote.

Wright Brother↗

Proposed geomagnetic control of semiannual waves in the mesospheric zonal wind

The polar semiannual oscillation in zonal wind explains midwinter weakening of the polar vortex and the relatively short stratospheric and mesospheric summer easterlies. The phase of the wind oscillation is equinoctial, as is the phase of the semiannual component in magnetic storm activity. For a given altitude, the contours of amplitude of the semiannual wind oscillation have less variability in geomagnetic than in geographic coordinates. It is suggested that the polar wind oscillations are caused by the semiannual maxima in magnetic storm activity, which lead to electron dissociation of O2 into O, in turn increasing ozone more rapidly than the dissociation of N2 destroys ozone, and inducing a semiannual variation in the thermal and wind fields. This implies that geomagnetic processes may cause or affect the development of sudden warmings. As the tropical semiannual wind oscillation is symmetric about the geomagnetic equator, the same processes may also influence the location of the tropical wind wave.

Belmont, A. D.↗

Semiclassical Calculation of Reaction Rate Constants for Homolytical Dissociations

There is growing interest in extending organometallic chemical vapor deposition (OMCVD) to III-V materials that exhibit large thermal decomposition at their optimum growth temperature, such as indium nitride. The group III nitrides are candidate materials for light-emitting diodes and semiconductor lasers operating into the blue and ultraviolet regions. To overcome decomposition of the deposited compound, the reaction must be conducted at high pressures, which causes problems of uniformity. Microgravity may provide the venue for maintaining conditions of laminar flow under high pressure. Since the selection of optimized parameters becomes crucial when performing experiments in microgravity, efforts are presently geared to the development of computational OMCVD models that will couple the reactor fluid dynamics with its chemical kinetics. In the present study, we developed a method to calculate reaction rate constants for the homolytic dissociation of III-V compounds for modeling OMCVD. The method is validated by comparing calculations with experimental reaction rate constants.

Beatriz H. Cardelino↗

Phosphonium chloride for thermal storage

Development of systems for storage of thermal energy is discussed. Application of phosphonium chloride for heat storage through reversible dissociation is described. Chemical, physical, and thermodynamic properties of phosphonium chloride are analyzed and dangers in using phosphonium chloride are explained.

Sutton, J. G.↗

Proposed geomagnetic control of semiannual waves in the mesospheric zonal wind

The polar semiannual oscillation in zonal wind can explain midwinter weakening of the polar vortex and the relatively short stratospheric and mesospheric summar easterlies. The phase of the wind oscillation is equinoctial, as is the phase of the semiannual component in magnetic storm activity. For a given altitude, the contours of amplitude of the semiannual wind oscillation have less variability in geomagnetic than in geographic coordinates. It is suggested that polar wind oscillations are caused by the semiannual maxima in magnetic storm activity which lead to electron dissociation of O2 into O, in turn increasing ozone more rapidly than the dissociation of N2 destroys ozone, and thereby inducing a semiannual variation in the thermal and wind fields. This implies that geomagnetic processes may cause or affect the development of sudden warmings. As the tropical semiannual wind oscillation is symmetric about the geomagnetic equator, the same processes may also influence the location of the tropical wind wave.

Belmont, A. D.↗

Theoretical and experimental investigation of the destruction of graphites in a flow of dissociated air

A method is presented for calculating the heating and erosion of blunt bodies made of graphite in a high-enthalpy flow of dissociated air, assuming chemical equilibrium on the surface and taking account of the thermal effects of combustion and sublimation of graphite. The analysis involves the use of a finite difference scheme to solve an equation of unsteady heat conduction. Attention is given to the equilibrium vaporization of C, C2 and C3 molecules. The calculations agree well with experimental data for a wide range of temperatures and stagnation pressures.

Bovina, T. A.↗

Mass and energy balance of the cold Io torus

A new model of the cold Io torus is described. Ions and energy are injected into the system by independent processes so that the mass balance is isolated from the energy balance. The primary source of energy is local ionization and acceleration of hot pickup ions resulting from charge exchange between thermal ions and an extended cloud of Iogenic sulfur and oxygen atoms. The primary energy loss mechanism of the plasma is collisionally excited line emission at optical wavelengths. The primary ion source is radial diffusion inward from the hot torus on a time scale of 140-710 days. The primary ion loss mechanism is a novel two-step enhanced recombination mechanism involving charge exchange between thermal ions and an extended cloud of neutral SO2 molecules, followed by rapid dissociative recombination of the resultant molecular ion. The model provides a self-consistent solution which reconciles a number of diverse observations with known physical processes.

Moreno, M. A.↗

Analysis of IUE observations of hydrogen in comets

The large body of hydrogen Lyman-alpha observations of cometary comae obtained with the International Ultraviolet Explorer satellite has gone generally unanalyzed because of two main modeling complications. First, the inner comae of many bright (gas productive) comets are often optically thick to solar Lyman-alpha radiation. Second, even in the case of a small comet (low gas production) the large IUE aperture is quite small as compared with the immense size of the hydrogen coma, so an accurate model which properly accounts for the spatial distribution of the coma is required to invert the inferred brightnesses to column densities and finally to H atom production rates. Our Monte Carlo particle trajectory model (MPTM), which for the first time provides the realistic full phase space distribution of H atoms throughout the coma was used as the basis for the analysis of IUE observations of the inner coma. The MCPTM includes the effects of the vectorial ejection of the H atoms upon dissociation of their parent species (H2O and OH) and of their partial collisional thermalization. Both of these effects are crucial to characterize the velocity distribution of the H atoms. A new spherical radiative transfer calculation based on our MCPTM was developed to analyze IUE observations of optically thick H comae. The models were applied to observations of comets P/Giacobini-Zinner and P/Halley.

Combi, Michael R.↗

Analysis of IUE Observations of Hydrogen in Comets

The 15-years worth of hydrogen Lyman-alpha observations of cometary comae obtained with the International Ultraviolet Explorer (IUE) satellite had gone generally unanalyzed because of two main modeling complications. First, the inner comae of many bright (gas productive) comets are often optically thick to solar Lyman-alpha radiation. Second, even in the case of a small comet (low gas production) the large IUE aperture is quite small as compared with the immense size of the hydrogen coma, so an accurate model which properly accounts for the spatial distribution of the coma is required to invert the infrared brightnesses to column densities and finally to H atom production rates. Our Monte Carlo particle trajectory model (MCPTM), which for the first time provides the realistic full phase space distribution of H atoms throughout the coma has been used as the basis for the analysis of IUE observations of the inner coma. The MCPTM includes the effects of the vectorial ejection of the H atoms upon dissociation of their parent species (H2O and OH) and of their partial collisional thermalization. Both of these effects are crucial to characterize the velocity distribution of the H atoms. This combination of the MCPTM and spherical radiative transfer code had already been shown to be successful in understanding the moderately optically thick coma of comet P/Giacobini-Zinner and the coma of comet Halley that varied from being slightly to very optically thick. Both of these comets were observed during solar minimum conditions. Solar activity affects both the photochemistry of water and the solar Lyman-alpha radiation flux. The overall plan of this program here was to concentrate on comets observed by IUE at other time during the solar cycle, most importantly during the two solar maxima of 1980 and 1990. Described herein are the work performed and the results obtained.

Combi, Michael R.↗