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At least 91 records · Page 5

Vaporization of the group IVB metal carbides

High temperature vaporization of titanium, zirconium, hafnium and thorium carbides by Knudsen effusion mass spectrometry, measuring ion intensities, formation enthalpies and dissociation energies

Kohl, F. J.↗

Fourier spectroscopy with a one-million-point transformation

A new type of interferometer for use in Fourier spectroscopy has been devised at the Aime Cotton Laboratory of the National Center for Scientific Research (CNRS), Orsay, France. With this interferometer and newly developed computational techniques, interferograms comprising as many as one million samples can now be transformed. The techniques are described, and examples of spectra of thorium and holmium, derived from one million-point interferograms, are presented.

Connes, J.↗

Alpha-particle spectrometer experiment

Mapping the radon emanation of the moon was studied to find potential areas of high activity by detection of radon isotopes and their daughter products. It was felt that based on observation of regions overflown by Apollo spacecraft and within the field of view of the alpha-particle spectrometer, a radon map could be constructed, identifying and locating lunar areas of outgassing. The basic theory of radon migration from natural concentrations of uranium and thorium is discussed in terms of radon decay and the production of alpha particles. The preliminary analysis of the results indicates no significant alpha emission.

Gorenstein, P.↗

Primordial radioelements and cosmogenic radionuclides in lunar samples from Apollo 15.

Two basalts, two breccias, and two soils from Apollo 15 were analyzed by nondestructive gamma-ray spectrometry. The concentrations of potassium, thorium, and uranium in the basalts were similar to those in the Apollo 12 basalts, but the potassium:uranium ratios were somewhat higher. Primordial radioelements were enriched in the soils and breccia, consistent with a two-component mixture of mare basalt and up to 20 percent foreign component (KREEP). The abundance patterns for cosmogenic radionuclides implied surface sampling for all specimens. The galactic cosmic-ray production rate of vanadium-48 was determined as 57 (plus or minus 11) disintegrations per minute per kilogram of iron. Cobalt-56 concentrations were used to estimate the intensity of the solar flare of January 25, 1971.

O'Kelley, G. D.↗

U-Th-Pb analyses of soil from the Sea of Fertility.

Analyses have been made of lead, uranium, and thorium in two soil samples from the Luna 16 mission. Lead was found to be distinctly radiogenic, but significantly less radiogenic than other lunar soils. The Th/U ratio was found to be 3.8, and the uranium concentration was the lowest so far found for lunar soils.

Tera, F.↗

Superconductivity in d- and f- band metals; Proceedings of the Conference, University of Rochester, Rochester, N.Y., October 29, 30, 1971.

High critical field measurements are discussed together with the lattice dynamics of transition metals, energy bands for transition metals and compounds, the importance of transverse acoustic phonons in A-15 superconductors, and aspects of electron-phonon coupling in transition metals. Other subjects considered include the superconductivity of Nb3Ga, the transition temperature of transition-metal superconductors, the relation of normal and superconducting properties to the electronic density of states, and questions of the superconductivity of various ternary thorium compounds. Individual items are abstracted in this issue.

Douglass, D. H.↗

Thermal property measurements on lunar material returned by Apollo 11 and 12 missions.

Measurement of thermal diffusivity on Apollo 11 type A and type C samples in the temperature range between 150 and 440 K under atmospheric pressure. Thermal diffusivity of type C material is lower and less temperature-dependent than type A material. Both types of samples exhibit lower thermal diffusivities than nonporous terrestrial basalt. The rate of heat generation of Apollo 11 and 12 samples was calculated from the concentrations of radioactive elements: potassium, thorium, and uranium. Apollo 11 crystalline rocks show an average rate of heat generation which is not significantly different from terrestrial basalt. The Th/U ratio does not differ greatly from chondritic and terrestrial averages.

Horai, K.-I.↗

Lunar thermal history revisited.

New information is used to demonstrate that better models for the thermal history of the moon are required. As a first step, account is taken of (1) a nonuniform initial composition in terms of fraction of low melting to high melting phase present, and for variation in the uranium, potassium, and thorium contents as a function of depth, (2) partitioning of the radioactive elements between the melt and the solid phases, and (3) a cutoff value of melt which must be exceeded before magma can move to the surface. The results of several attempts to determine whether reasonable conditions, composition, and thermal properties can be expected to give rise to two separate periods of volcanism are discussed. Two models with somewhat different distributions of radioactive heat sources and different conductivities are examined.

Mcconnell, R. K., Jr.↗

Gas analysis of Apollo 12, 14, and 15 samples by laser-probe mass spectrometry

Solar wind gases, cosmogenic gases from high energy spallation reactions from soxmic rays, and radiogenic gases from decay of radioactive potassium and from uranium and thorium isotopes were analyzed in lunar materials. Details are presented on two aspects of the studies: (1) The spatial distribution of Ar-40/Ar-38 ages in lunar breccia 14301 was determined. The ages of clasts within this breccia are 3.68 + or - 0.09 and 2.9 + or - 0.3 x 10 to the 9th power years. Parentless radiogenic Ar-40 exists within the fine-grained matrix. (2) The distribution of helium, neon, and argon isotopes within Apollo 15 samples results primarily from fractionated solar wind gases, accompanied by small quantities of cosmogenic gases. Comparison of this Apollo 15 data with Kapoeta and Fayetteville meteorite and Apollo 12 and 14 data indicates that solar wind implantation followed by fractionation of the gases was primarily responsible for incorporation of original gas phase within solid bodies of the solar system.

Imegrue, G. H.↗

Nuclear Analysis

Exploratory calculations were performed for several gas core breeder reactor configurations. The computational method involved the use of the MACH-1 one dimensional diffusion theory code and the THERMOS integral transport theory code for thermal cross sections. Computations were performed to analyze thermal breeder concepts and nonbreeder concepts. Analysis of breeders was restricted to the (U-233)-Th breeding cycle, and computations were performed to examine a range of parameters. These parameters include U-233 to hydrogen atom ratio in the gaseous cavity, carbon to thorium atom ratio in the breeding blanket, cavity size, and blanket size.

Clement, J. D.↗

Apollo orbital geochemistry: Gamma rays

Lunar gamma ray spectra obtained during Apollo-15 and -16 flights show a natural radioactivity due to potassium, thorium, and uranium as well as a cosmic ray induced activity in the lunar surface due to high neutron interactions produced by (p,n) reaction in the lunar surface. The radioactivity is at a low in the highlands on the backside of the moon; most of the radioactivity is confined to the Oceanus Procellarum/Mare Imbrium region and to the Van de Graff area on the lunar backside.

Trombka, J. I.↗

U-Th-Pb and Rb-Sr measurements on some Apollo 14 lunar samples.

The concentrations of selected elements and elemental ratios in some Apollo 14 samples are presented in a table. Another table shows the isotopic composition of lead and strontium in some Apollo 14 samples. Graphs are provided with lead isotope ratio plots and a strontium evolution diagram. Rb-Sr ages are discussed together with isochron age methods of U-Th-Pb, a primary Pb-Pb isochron, a secondary Pb-Pb isochron, U-Pb concordia age relations, and U-Th-Pb concordia relations. Breccias and some soil samples as well as a basalt sample give evidence of significant enrichment of lead relative to uranium and thorium billions of years ago at the Fra Mauro site.

Tatsumoto, M.↗

Helium-uranium dating of corals.

Fanale and Schaeffer (1965) determined He/U ages of corals and other aragonitic fossils, and found that the results generally agreed with independent age estimates. As a more extensive and rigorous test of the reliability of He/U ages of fossil corals, I have determined He/U ages of forty-five independently dated Cenozoic corals. Uranium and thorium isotope compositions and Rn-222 retentivities were also determined as consistency checks. The results indicate that reliable ages are obtained when certain consistency tests are met and specified corrections are made.

Bender, M. L.↗