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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Monte Carlo prediction of radiative heat transfer in inhomogeneous, anisotropic, nongray media

A Monte Carlo solution technique has been formulated to predict the radiative heat transfer in three-dimensional, inhomogeneous participating media which exhibit spectrally dependent emission and absorption and anisotropic scattering. Details of the technique and selected numerical sensitivities are discussed. The technique was applied to a problem involving a medium composed of a gas mixture of carbon dioxide and nitrogen and suspended carbon particles. A homogeneous medium was modeled to examine the effect of total pressure and carbon-particle concentration on radiative heat transfer. Variation in total pressure, over the range studied, had minimal effect on the amount of heat radiated to the enclosure walls and on the radiative-flux distribution within the medium. Increases in the carbon particle concentration produced significantly higher heat fluxes at the boundaries and altered the radiative flux distribution. The technique was then applied to an inhomogeneous medium to examine effects of specific temperature and carbon particle concentration distributions on radiative heat transfer. For the inhomogeneous conditions examined, the largest radiative flux divergence occurs near the center of the medium and the regions near some enclosure walls act as energy sinks.

HEAT FLUXES↗

Effects of Turbulence and Temperature Fluctuations on Knock Development in an Ethanol/Air Mixture

The effects of turbulence on knock development and intensity for a thermally inhomogeneous stoichiometric ethanol/air mixture at a representative end-gas autoignition condition in internal combustion engines are investigated using direct numerical simulations with a skeletal reaction mechanism. Two- and three-dimensional simulations are performed by varying the most energetic length scale of temperature, \(l_T\) , and its relative ratio with the most energetic length scale of turbulence, \(l_T/l_e\) , together with two different levels of the turbulent velocity fluctuation, \(u'\) . It is found that \(l_T\) / \(l_e\) and the ratio of ignition delay time to eddy-turnover time, \(\tau _{ig}/\tau _t\) , are the key parameters that control the detonation development. An increase in either \(l_T\) or \(l_e\) enhances the detonation propensity by allowing a longer run-up distance for the detonation development. The characteristic length scale of the temperature field, \(l_T\) , is significantly modified by high turbulence intensity achieved by a large \(l_e\) and \(u'\) . The intense turbulence mixing effectively distributes the initial temperature field to broader scales to support the developing detonation waves, thereby increasing the likelihood of the detonation formation. On the contrary, high turbulence intensity with a short mixing time scale, achieved by a small \(l_e\) and a large \(u'\) , reduces the super-knock intensity attributed to the finer broken-up structures of detonation waves. Either \(\tau _{ig}/\tau _t\) less than unity or \(l_e = l_T\) even with a large \(u'\) is found to have no significant effect on super-knock mitigation. Finally, high turbulent intensity may induce high-pressure spikes comparable to the von Neumann spike. Overall, increased temperature and pressure by combustion heating, noticeably after the peak of heat release rate, significantly enhance the collision and interaction of multiple emerging autoignition fronts near the ending combustion process, resulting in localized high-pressure spikes.

42 ENGINEERING↗

Tabulated equations of state from models informed by chiral effective field theory

Abstract We construct four equation of state (EoS) tables, tabulated over a range of temperatures, densities, and charge fractions, relevant for neutron star applications such as simulations of neutron star mergers. The EoS are computed from a relativistic mean-field theory constrained by the pure neutron matter EoS from chiral effective field theory, inferred properties of isospin-symmetric nuclear matter, and astrophysical observations of neutron star structure. To model nuclear matter at low densities, we attach an EoS that models inhomogeneous nuclear matter at arbitrary temperatures and charge fractions. The four EoS tables we develop are available from the CompOSE EoS repository https://compose.obspm.fr/eos/297 and gitlab.com/ahaber/qmc-rmf-tables .

79 ASTRONOMY AND ASTROPHYSICS↗

The moon as a proposed radiometric standard for microwave and infrared observations of extended sources.

Measured values of the average midnight and morning terminator infrared brightness temperatures of the central portion of the lunar disk can quite accurately determine the mean surface temperature despite likely horizontal and vertical inhomogeneities of the thermal properties of the lunar soil. These data together with laboratory measurements on lunar soil and in situ temperature measurements in and on the lunar surface lead to a mean surface temperature of 220.5 K plus or minus 2.5 per cent and a mean temperature 35 K hotter at a depth of 1 m. The monthly average brightness temperature is then estimated as a function of wavelength between 10 microns and 100 cm taking into account likely temperature dependencies of the thermal conductivity and loss tangent, and the variation of emissivity with wavelength.

Linsky, J. L.↗

A computer-controlled apparatus for Seebeck inhomogeneity testing of sheathed thermocouples

Mineral-insulated metal-sheathed (MIMS) thermocouple assemblies are used throughout industry and research facilities as a method of temperature measurement where requirements for either harsh environmental conditions exist, or where rigidity of the measurement probe is required. Seebeck inhomogeneity is the abnormal variation of the Seebeck coefficient from point to point in a material. It is not disclosed in conventional calibration. A standardized method of measuring thermoelectric inhomogeneity along the thermocouple probe length is not available. Therefore, calibration for sheathed probes normally does not include testing of probe inhomogeneity. The measurement accuracy would be severely impacted if significant inhomogeneity and a temperature gradient were present in the same region of the probe. A computer-controlled system for determining inhomogeneities was designed, fabricated, and tested. This system provides an accurate method for the identification of the location of inhomogeneity along the length of a sheathed thermocouple and for the quantification of the inhomogeneity. This paper will discuss the apparatus and procedure used to perform these tests and will present data showing tests performed on sheathed thermocouple probes.

Burkett, Cecil G., Jr.↗

Sectoral and growth rate control on elemental uptake by individual calcite crystals

Heterogeneous distribution of trace elements (impurities) within individual calcite crystals is a phenomenon commonly observed in natural and laboratory systems. Changes in thermodynamic intensive parameters (mostly chemical potential and temperature) cannot always explain the inhomogeneous impurity patterns in calcite crystals and it has been suggested that growth rate and crystallographic orientation may exert strong effects on elemental incorporation into calcite. In addition, there are a number of experimental studies on micro-scale element (E) distribution between non-equivalent pairs of calcite vicinal faces (known as sectoral zoning); however, the variability of partition coefficients (e.g., K E = (E/Ca) calcite /(E/Ca) fluid ) within individual crystals remains undetermined. In this study, we have extended the work on elemental distribution between crystal sectors to evaluation of partition coefficients of trace and minor elements (Li, B, Mg, and Sr) in calcite crystal faces (10–14) and (01-12), whose growth rates were assessed. Growth entrapment model (GEM) and lattice strain theory were applied to explain K E heterogeneity by varying near-surface diffusivity of Mg and Sr and by varying surface enrichment factor for Li, B, Mg, and Sr. Decoupling of sectoral and growth rate effects reveals that sectoral zoning plays a key role in elemental distribution. More specifically, K Li and K B vary by more than one order of magnitude and K Mg varies by a factor of two within individual crystal faces. Strontium sectoral distribution is different from those of Li, B, and Mg and K Sr varies by up to a factor of two. Finally, these behaviors likely reflect different mechanisms of incorporation of Li, B, Mg, and Sr into calcite.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Primordial non-Gaussianity from the effects of the Standard Model Higgs during reheating after inflation

We propose a new way of studying the Higgs potential at extremely high energies. The Standard Model (SM) Higgs boson, as a light spectator field during inflation in the early Universe, can acquire large field values from its quantum fluctuations which vary among different causal (Hubble) patches. Such a space dependence of the Higgs after the end of inflation leads to space-dependent SM particle masses and hence variable efficiency of reheating, when the inflaton decays to Higgsed SM particles. Inhomogeneous reheating results in (observable) temperature anisotropies. Further, the resulting temperature anisotropy spectrum acquires a significant non-Gaussian component, which is constrained by Planck observations of the Cosmic Microwave Background (CMB) and potentially detectable in next-generation experiments. Constraints on this non-Gaussian signal largely exclude the possibility of the observed temperature anisotropies arising primarily from Higgs effects. Hence, in principle, observational searches for non-Gaussianity in the CMB can be used to constrain the dynamics of the Higgs boson at very high (inflationary) energies.

79 ASTRONOMY AND ASTROPHYSICS↗

Influence of inhomogeneous stochasticity on the falsifiability of mean-field theories and examples from accretion disc modelling

ABSTRACT Despite spatial and temporal fluctuations in turbulent astrophysical systems, mean-field theories can be used to describe their secular evolution. However, observations taken over time scales much shorter than dynamical time scales capture a system in a single state of its turbulence ensemble. Comparing with mean-field theory can falsify the latter only if the theory is additionally supplied with a quantified precision. The central limit theorem provides appropriate estimates to the precision only when fluctuations contribute linearly to an observable and with constant coherent scales. Here, we introduce an error propagation formula that relaxes both limitations, allowing for non-linear functional forms of observables and inhomogeneous coherent scales and amplitudes of fluctuations. The method is exemplified in the context of accretion disc theories, where inhomogeneous fluctuations in the surface temperature are propagated to the disc emission spectrum – the latter being a non-linear and non-local function of the former. The derived precision depends non-monotonically on emission frequency. Using the same method, we investigate how binned spectral fluctuations in telescope data change with the spectral resolving power. We discuss the broader implications for falsifiability of a mean-field theory.

79 ASTRONOMY AND ASTROPHYSICS↗

Effective temperatures of A and F stars

Effective temperatures of late A and early F stars are determined from the observed fluxes in the visual at 1900 A and 1420 A. The observed ratios are compared with those calculated by Kurucz (1979). A correction of the theoretical fluxes at 1900 A brings the effective temperatures obtained from different ratios into reasonable agreement. The effective temperatures determined in this way for late A stars agree well with those obtained from the optical region. For F stars, however, the effective temperatures obtained from the UV are found to be higher than those obtained from the optical region if radiative equilibrium models are used for the comparison. It is thought that this discrepancy may derive from the effects of temperature, pressure, and absorption coefficient inhomogeneities caused by convection.

Boehm-Vitense, E.↗

A Monte Carlo-finite element model for strain energy controlled microstructural evolution - 'Rafting' in superalloys

This paper presents a specialized microstructural lattice model, MCFET (Monte Carlo finite element technique), which simulates microstructural evolution in materials in which strain energy has an important role in determining morphology. The model is capable of accounting for externally applied stress, surface tension, misfit, elastic inhomogeneity, elastic anisotropy, and arbitrary temperatures. The MCFET analysis was found to compare well with the results of analytical calculations of the equilibrium morphologies of isolated particles in an infinite matrix.

Gayda, J.↗

On the hydrodynamic interaction of shock waves with interstellar clouds. 1: Nonradiative shocks in small clouds

The interstellar medium (ISM) is inhomogeneous, with clouds of various temperatures and densities embedded in a tenuous intercloud medium. Shocks propagating through the ISM can ablate or destroy the clouds, at the same time significantly altering the properties of the intercloud medium. This paper presents a comprehensive numerical study of the simplest case of the interaction between a shock wave and a spherical cloud, in which the shock far from the cloud is steady and planar, and in which radiative losses, thermal conduction, magnetic fields, and gravitational forces are all neglected. As a result, the problem is completely specified by two numbers: the Mach number of the shock, M, and the ratio of the density of the cloud to that of the intercloud medium, Chi. For strong shocks we show that the dependence on M scales out, so the primary independent parameter is Chi. Variations from this simple case are also considered: the potential effect of radiative losses is assessed by calculations in which the ratio of specific heats in the cloud is 1.1 instead of 5/3; the effect of the initial shape of the cloud is studied by using a cylindrical cloud instead of a spherical one; and the role of the initial shock is determined by considering the case of a cloud embedded in a wind. Local adaptive mesh refinement techniques with a second-order, two-fluid, two-dimensional Godunov hydrodynamic scheme are used to address these problems, allowing heretofore unobtainable numerical resolution. Convergence studies to be described in a subsequent paper demonstrate that about 100 zones per cloud radius are needed for accurate results; previous calculations have generally used about a third of this number. The results of the calculations are analyzed in terms of global quantities which provide an overall description of te shocked cloud: the size and shape of the cloud, the mean density, the mean pressure, the mean velocity, the velocity dispersion, and the total circulation.

Klein, Richard I.↗

Observations of Aerosol, Cloud, Turbulence, and Radiation Properties at the Top of the Marine Boundary Layer over the Eastern North Atlantic Ocean: The ACORES Campaign

We report on the Azores Stratocumulus Measurements of Radiation, Turbulence and Aerosols (ACORES) campaign, which took place around Graciosa and Pico Islands/Azores in July 2017. The main objective was to investigate the vertical distribution of aerosol particles, stratocumulus microphysical and radiative properties, and turbulence parameters in the eastern North Atlantic. The vertical exchange of mass, momentum, and energy between the free troposphere (FT) and the cloudy marine boundary layer (MBL) was explored over a range of scales from submeters to kilometers. To cover these spatial scales with appropriate measurements, helicopter-borne observations with unprecedented high resolution were realized using the Airborne Cloud Turbulence Observation System (ACTOS) and Spectral Modular Airborne Radiation Measurement System–Helicopter-Borne Observations (SMART-HELIOS) instrumental payloads. Here, the helicopter-borne observations were combined with ground-based aerosol measurements collected at two continuously running field stations on Pico Mountain (2,225 m above sea level, in the FT), and at the Atmospheric Radiation Measurement (ARM) station on Graciosa (at sea level). First findings from the ACORES observations we are discussing in the paper are as follows: (i) we have observed a high variability of the turbulent cloud-top structure on horizontal scales below 100 m with local temperature gradients of up to 4 K over less than 1 m vertical distance, (ii) we have collected strictly collocated radiation measurements supporting the relevance of small-scale processes by revealing significant inhomogeneities in cloud-top brightness temperature to scales well below 100 m, and (iii) we have concluded that aerosol properties are completely different in the MBL and FT with often-complex stratification and frequently observed burst-like new particle formation.

54 ENVIRONMENTAL SCIENCES↗

The imprint of proper motion of nonlinear structures on the cosmic microwave background

We investigate the imprint of nonlinear matter condensations on the cosmic microwave background (CMB) in an Omega = 1, cold dark matter (CDM) model universe. Temperature anisotropies are obtained by numerically evolving matter inhomogeneities and CMB photons from the beginning of decoupling until the present epoch. The underlying density field produced by the inhomogeneities is followed from the linear, through the weakly clustered, into the fully nonlinear regime. We concentrate on CMB temperature distortions arising from variations in the gravitational potentials of nonlinear structures. We find two sources of temperature fluctuations produced by time-varying potentials: (1) anisotropies due to intrinsic changes in the gravitational potentials of the inhomogeneities and (2) anisotropies generated by the peculiar, bulk motion of the structures across the microwave sky. Both effects generate CMB anisotropies in the range of 10(exp -7) approximately less than or equal to (Delta T/T) approximately less than or equal to 10(exp -6) on scales of approximately 1 deg. For isolated structures, anisotropies due to proper motion exhibit a dipole-like signature in the CMB sky that in principle could yield information on the transverse velocity of the structures.

Tuluie, Robin↗

Calculation of infrared spectral transmittances of inhomogeneous gases

Calculation of spectral transmittance for a particular inhomogeneous gas path is made by combining known data on gases at constant temperature, pressure, and concentration. The spectral transmittances of the inhomogeneous plume gases is needed to calculate the heat radiated from the exhaust plume to the rocket base of a multiple engine rocket.

Huffaker, R. M.↗

Ultrawide bandgap vertical β-(Al x Ga1 −x )2O3 Schottky barrier diodes on free-standing β-Ga2O3 substrates

Ultrawide bandgap β-(AlxGa1−x)2O3 vertical Schottky barrier diodes on (010) β-Ga2O3 substrates are demonstrated. The β-(AlxGa1−x)2O3 epilayer has an Al composition of 21% and a nominal Si doping of 2 × 1017 cm−3 grown by molecular beam epitaxy. Pt/Ti/Au has been employed as the top Schottky contact, whereas Ti/Au has been utilized as the bottom Ohmic contact. The fabricated devices show excellent rectification with a high on/off ratio of ∼109, a turn-on voltage of 1.5 V, and an on-resistance of 3.4 mΩ cm2. Temperature-dependent forward current-voltage characteristics show effective Schottky barrier height varied from 0.91 to 1.18 eV while the ideality factor from 1.8 to 1.1 with increasing temperatures, which is ascribed to the inhomogeneity of the metal/semiconductor interface. The Schottky barrier height was considered a Gaussian distribution of potential, where the extracted mean barrier height and a standard deviation at zero bias were 1.81 and 0.18 eV, respectively. A comprehensive analysis of the device leakage was performed to identify possible leakage mechanisms by studying temperature-dependent reverse current-voltage characteristics. At reverse bias, due to the large Schottky barrier height, the contributions from thermionic emission and thermionic field emission are negligible. By fitting reverse leakage currents at different temperatures, it was identified that Poole–Frenkel emission and trap-assisted tunneling are the main leakage mechanisms at high- and low-temperature regimes, respectively. Electrons can tunnel through the Schottky barrier assisted by traps at low temperatures, while they can escape these traps at high temperatures and be transported under high electric fields. This work can serve as an important reference for the future development of ultrawide bandgap β-(AlxGa1−x)2O3 power electronics, RF electronics, and ultraviolet photonics.

Materials Science↗

Constitutive Behavior and Hot Workability of a Hot Isostatic Pressed Ti-22Al-25Nb Alloy during Hot Compression

A Ti-22Al-25Nb alloy was fabricated from prealloyed powders by hot isostatic pressing for 2 h at a temperature of 1050 °C and pressure of 100 MPa. The hot deformation behavior of the Ti-22Al-25Nb alloy was characterized by isothermal compression testing at deformation temperatures between 900 and 1060 °C and strain rates between 0.001 and 1 s{sup −1}. Based on the true stress–strain curves, a constitutive equation was constructed to describe the flow stress as a function of the strain rate and deformation temperature. Three-dimensional (3D) processing maps were developed based on dynamic material model theory using the stress flow data to identify the instability and optimization regions of the hot processing parameters. The results show that the flow stress decreases with increasing deformation temperature and decreasing strain rate, and the softening mechanisms are different under different deformation conditions. The apparent activation energies in the (α{sub 2} + β/B2 + O) and (α{sub 2} + B2) phase regions are calculated to be 865.177 and 590.661 kJ/mol, respectively, which suggests that the hot isostatic pressed (HIPed) Ti-22Al-25Nb alloy requires a high hot deformation activation energy. Combined with microstructural observations, the optimal processing domains are determined to be a temperature range of 1030-1060 °C and strain rate range of 0.01-0.1 s{sup −1} in the α{sub 2} + B2 phase region. Moreover, the results indicate that adiabatic shear bands and severe inhomogeneous deformation cause flow instability at lower temperatures (900-1005 °C) and higher strain rates (> 0.1 s{sup −1}).

36 MATERIALS SCIENCE↗

Critical Fluctuations in Beam-Plasma Systems and Solar Type III Radio Bursts

It is shown that the Langmuir waves are excited similar to critical fluctuations during phase transitions when the negative absorption due to electron beam traveling radially outward in the solar atmosphere is balanced by the positive absorption due to collisions in the corona and due to scattering on electron density inhomogeneities in the interplanetary medium. The effective temperature of the Langmuir fluctuations range from 1011 to 1013 K, explaining the majority of the type III bursts. The Rayleigh scattering and direct coupling due to density gradient as well as due to density inhomogeneities are discussed in the context of fundamental radiation and the combination scattering for second harmonic. The number density of electrons in type III beams is estimated and compared with observations. It is also shown that the stabilization of type III beams is achieved automatically since the instability does not develop in the case of critical fluctuations.

Fluctuations↗

Stabilizing homogeneous CaMn6Sn6via oscillatory crystal growth: structural complexity in a kagome metal

CaMn6Sn6 is a member of the large family of Mn-based kagome metals derived by filling voids of the prototypical CoSn structure. We observed Ca-deficiency and structural complexity, with approximately 10% deficiency of calcium relative to the ideal 166 stoichiometry. These features are common in related Ca-based materials. We find that growth conditions stabilize different phases with varying Curie temperatures. Diffraction and magnetization measurements reveal that conventional growth profiles yield inhomogeneity both within and between crystals in a given batch, whereas an oscillatory temperature profile promotes homogeneous crystals that adopt a superstructure beyond the parent hexagonal structure type. We present the physical properties of crystals grown using the oscillatory approach. The crystals are highly conductive, with a c-axis residual resistivity ratio ρ(300 K)/ρ(2 K) exceeding 100 and a positive, linear magnetoresistance at base temperature. Magnetically, the crystals are quite similar to MgMn6Sn6, with easy-plane ferromagnetic behavior and a Curie temperature of TC ≈ 237 K. These results highlight the critical role of growth conditions in stabilizing homogeneous crystals of complex phases such as Ca0.9Mn6Sn6. The oscillatory growth approach provides an effective route for accessing the intrinsic properties of this complex material and may be broadly useful for the growth of related kagome systems.

May, Andrew [ORNL] (ORCID:0000000307778539)↗