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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Creep and Environmental Durability of EBC/CMCs Under Imposed Thermal Gradient Conditions

Interest in SiC fiber-reinforced SiC ceramic matrix composite (CMC) environmental barrier coating (EBC) systems for use in high temperature structural applications has prompted the need for characterization of material strength and creep performance under complex aerospace turbine engine environments. Stress-rupture tests have been performed on SiC/SiC composites systems, with varying fiber types and coating schemes to demonstrate material behavior under isothermal conditions. Further testing was conducted under exposure to thermal stress gradients to determine the effect on creep resistance and material durability. In order to understand the associated damage mechanisms, emphasis is placed on experimental techniques as well as implementation of non-destructive evaluation; including electrical resistivity monitoring. The influence of environmental and loading conditions on life-limiting material properties is shown.

Appleby, Matthew↗

The effect of stress on the migration of He gas bubbles under a thermal gradient in Fe by phase-field modeling

Here a phase-field model is parameterized to study the effect of elastic stresses on the migration of He gas bubbles in Fe under a temperature gradient. Stresses caused by the gas bubble pressure and residual stress in the Fe matrix are considered. The dependence of He bubble migration velocity on the magnitude of the residual stress, average temperature, temperature gradient, and bubble size is measured. In agreement with a theoretical model based on surface diffusion, simulation results demonstrate that He bubbles move towards the high temperature region with velocities in Fe that are orders of magnitude faster than previously reported in UO 2 . It is found that local stresses in the matrix caused by the He bubble have negligible effect on the bubble migration process; however, residual stresses in the Fe matrix, potentially caused by processing or irradiation, can modestly modify bubble kinetics through pressure dependence of the He diffusion coefficients. Compressive residual stress decreases diffusion coefficients for bulk and surface diffusion mechanisms, thus reducing the migration velocity of the gas bubble. In contrast, tensile residual stress increases the diffusion coefficients, resulting in an increase in the gas bubble migration velocity. This pressure dependence is also consistent with a theoretical model. This phase field model lays the foundation for analysis of bubble coalescence-induced fracture in He bubble-containing steels.

36 MATERIALS SCIENCE↗

Carbon-Sequestration Straw Cellulose-Aerogel Gradient Thermal Insulation Material

Green superinsulation materials are essential for net-zero sustainable building envelopes. Realizing such potential is indispensable for simultaneously achieving carbon-sequestration and superinsulation performance. Here, we report the synthesis of a water glass-based silica aerogel exhibiting a thermal conductivity of 17.2 mW/m·K and a high porosity of 92%. Here, we used carbon-sequestration wheat straw fiber to create a gradient cellulose-aerogel composite to improve mechanical stability. The as-prepared gradient composite exhibits a thermal conductivity of 27.1 mW/m·K and a flexural modulus of 824 MPa, while exhibiting superhydrophobicity (water contact angle of 135.4°) for the development of green building insulation materials.

36 MATERIALS SCIENCE↗

Microgravity Experiments and Numerical Modeling of Rotating Buoyant Convection in a Spherical Shell with Latitudinal Thermal Gradients

The results of numerical model calculations are compared with space laboratory experiments for rotating, thermally driven flow in a hemispherical shell, and various flow regimes are described. A spherically symmetric body force, analogous to gravity, is imposed in the radial direction through the use of a dielectric fluid and an electrostatic potential difference across the gap. The spherical boundaries are maintained at constant temperature profiles (with the pole and the inner sphere being the warmer surfaces), and the equatorial wall is an insulator. Typical parameter combinations result in highly nonlinear, but laminar, flow. For weak enough buoyant forcing, the flow is axisymmetric. It consists of a single meridional cell, rising in warm latitudes (in this case, near the pole) and sinking in cool latitudes, with prograde flow in the equatorial region and near the inner hemisphere for other latitudes, and retrograde motion elsewhere. For fast rotation, the first transition due to the instability of this simple flow is also axisymmetric, consisting of rings of convection in the polar region, which propagate poleward. The first nonaxisymmetric convection occurs at Rayleigh numbers which increase with rotation rate. The form of the convection near the transition also depends upon the rate of rotation. Selected flow patterns near the transition as well as those beyond it are studied numerically. For those cases where there exist laboratory experiments with which to compare, the numerical and experimental results agree very well.

Leslie, Fred W.↗

Two-Zone Bridgman Furnace With Sharp Thermal Gradient

Two-zone vertical directional-solidification furnace designed and built to grow crystals from stoichiometric and nonstoichiometric melts and from solutions. Includes conventional wire heater in lower zone, tubular silicon carbide heating element in upper zone, and thermal baffle between zones. Temperature gradients up to 125 degrees centigrade per centimeter achieved in the crystal-growth region. Sharper gradient enables both faster growth and better separation between solid and liquid. Furnace used in laboratory or industrial setting for growth of crystals from congruently melting materials as well as for growth of compounds formed by peritectic reactions.

Borshchevsky, Alex↗

Thermal analysis of a functionally graded material subject to a thermal gradient using the boundary element method

The boundary element method is utilized in this study to conduct thermal analysis of functionally graded composites, materials in which the internal microstructure or properties are explicitly tailored in order to obtain an optimal response, on the micromechanical (constituent) scale. A unique feature of the boundary element formulations used here is the use of circular shape functions to convert the two-dimensional integrations of the composite fibers to one dimensional integrations. Using the computer code BEST-CMS, the through the thickness temperature profiles are computed for a representative material with varying numbers of fibers and fiber spacing in the thickness direction. The computed temperature profiles are compared to those obtained using an alternate analytical theory which explicitly couples the heterogeneous microstructure to the global analysis. The boundary element results compared favorably to the analytical calculations, with discrepancies that are explainable based on the boundary element formulation. The results serve both to demonstrate the ability of the boundary element method to analyze these types of materials, and to verify the accuracy of the analytical theory.

Goldberg, Robert K.↗

Bearing Wear in Large Thermal Gradients

Report presents results of study of bearing distress resulting from malfunction of spring-preloading arrangements. Study examined effect of thermal growth on wear depth of bearing. Report considers bearing-failure modes, relationships between growth and wear, maximum stresses as function of load, and effect of thermal growth on spring-load deflections.

Kannel, J. W.↗

Micrometeorite dynamic pyrometamorphism: Observation of a thermal gradient in iron-nickel sulfide

Dynamic pyrometamorphism describes the mineralogical changes in a micrometeorite that occur in response to flash-heating during atmospheric entry. Mineral reactions during this event will be endothermic and act as local sinks for thermal energy which delays a uniform temperature distribution in decelerating micrometeorites. The most common pyrometamorphic reaction is formation of magnetite nanocrystal decorations on Mg,Fe-silicate grains and magnetite or (partial) maghemite rims. Constituent silicates also respond to this thermal event and show formation of olivine-maghemite symplectites and growth of garnet and partial laihunitisation. In continued effort to constrain dynamic pyrometamorphism of unmelted interplanetary dust particles (IDP's), I determined the mineralogical composition, and Fe,Ni-sulfide chemistry, in the sulfide-rich particles L2005C39, L2005E40, and L2006A28 using a JEOL 2000FX analytical electron microscope equipped with a TN5500 energy dispersive spectrometer for in situ microanalysis. Sulfide compositions in these three IDP's are distinctly different from those in silicate-rich particle L2005T13 which might suggest a delicate balance of the fO2/fS2 ratios during dynamic pyrometamorphism.

Rietmeijer, Frans J. M.↗

On the control of structures by applied thermal gradients

Some preliminary results of research on control of flexible structures performed at the Jet Propulsion Laboratory are presented. It was shown that the thermoelectric device is a feasible actuator and may effectively be used to control structures, provided the structure has a relatively low thermal inertia. The control law only depends on the open-loop system natural frequency.

Edberg, Don↗

Thermal Gradient Effects on Local Hotspot Ignition in 1,3,5,7‐Tetranitro‐1,3,5,7‐tetrazocane (HMX)

Understanding hotspot ignition, growth, and criticality, as well as the timescales of each, is crucial for parameterizing mesoscale and continuum‐level models that rely on a statistical understanding of hotspots. However, these models often consider hotspots to have uniform temperatures or for hotspots of a given temperature and size to always behave the same. Therefore, using molecular dynamics simulations, we assess the influence of thermal distribution effects on hotspot local ignition and time to ignition in 1,3,5,7‐tetranitro‐1,3,5,7‐tetrazocane (HMX) nanoscale hotspots. Finally, by assessing hotspots with a gradient driven from an initial two‐temperature core–shell setup, we show that small increases in the core temperature under a constant average temperature can lead to order‐of‐magnitude effects on reaction and local ignition timescales.

36 MATERIALS SCIENCE↗

Skyrmion lattice manipulation with electric currents and thermal gradients in MnSi

The skyrmion lattice (SkL) in MnSi was studied using small-angle neutron scattering and under the influence of a radial electric current in a Corbino geometry. In response to the applied current, the SkL undergoes an angular reorientation with respect to the MnSi crystal lattice. The reorientation is nonmonotonic with increasing current, with the SkL rotating first in one direction and then the other. The SkL reorientation was studied at different sample locations and found to depend on the local current density as inferred from a finite-element analysis. Here, the nonmonotonic response indicates the presence of two competing effects on the SkL, most likely due to the presence of both radial electric and thermal currents. Such a scenario is supported by micromagnetic simulations, which show how these effects can act constructively or destructively to drive the SkL rotation, depending on the direction of the electric current. In addition, the simulations also suggest how the direction of the skyrmion flow may affect the SkL orientation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Surface Chemistry and Particle Morphology Changes in Pine Biomass under Indirect Thermal Gradients: Implications for Feed Screw Design

The conversion of biomass feedstocks into fuels and chemicals using fast pyrolysis is a promising approach to renewable energy. Feed screws that convey biomass to pyrolysis reactors, however, often encounter plugging. Indirect heating of the feed screw occurs due to contact with the pyrolysis chamber, resulting in a heating gradient ranging from ambient temperature (22 °C) to reactor temperature (500 °C). Given that major cell wall macromolecules, such as lignin, cellulose, and hemicellulose, begin to produce bio-oils and volatile resin acid compounds within this temperature gradient, we hypothesized that indirect heating during feed screw conveyance is sufficient to cause premature degradation of biomass. We characterized this degradation by observing increases in surface roughness, changes in overall particle morphology, and the production and deposition of bio-oils on biomass particle surfaces. Correlative analysis between optical in situ hot-stage microscopy, confocal Raman spectroscopy, and SEM analysis revealed that heating at temperatures as low as 375 °C caused significant increases in surface roughness, with large fissures forming between and within cell walls. Additionally, droplets of bio-oil were observed on particles, especially in the bark and cambium samples. This work suggests that these phenomena contribute to particle agglomeration, leading to feed screw plugging, and that engineering a solution to cool the feed screw could prevent particle agglomeration and reduce plugging incidents, thereby increasing biomass processing efficiency.

09 BIOMASS FUELS↗