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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Delamination Depth Imaging for Quasi-Static and Fatigue Load Testing Using Passive Thermography

Passive thermography is used to monitor small increases in temperature resulting from delamination damage formation in composite hat-stiffened panels during both quasi-static and fatigue loading. It has been observed that rapid damage formation produces heating. This is composed of two heat generation components. The first component is an instantaneous response due to an irreversible thermoelastic strain release. The second component is mechanical heating, at the interface of failure, due to fracture damage. This produces a transient rise in temperature as the heat diffuses to the surface. The first component defines the thermal start time for the transient response. A one-dimensional thermal model is fitted to the data pixel by pixel, to produce imagery of the damage depth. The results are compared to ultrasonic and X-ray CT data.

Passive thermography↗
NASA NTRS1983

Transport and the seasonal variation of ozone

The transport mechanisms responsible for the seasonal behavior of total ozone are deduced from the comparison of model results to stratospheric data. The seasonal transport is dominated by a combination of the diabatic circulation and transient planetary wave activity acting on a diffusively and photochemically determined background state. The seasonal variation is not correctly modeled as a diffusive process. The buildup of total ozone at high latitudes during winter is dependent upon transient planetary wave activity of sufficient strength to cause the breakdown of the polar vortex. While midwinter warmings are responsible for enhanced ozone transport to high latitudes, the final warming marking the transition from zonal mean westerlies to zonal mean easterlies is the most important event leading to the spring maximum. The final warming is not followed by reacceleration of the mean flow; so that the ozone transport associated with this event is more pronounced than that associated with midwinter warmings.

Rood, R. B.↗
NASA NTRS1991

Analysis of redox additive-based overcharge protection for rechargeable lithium batteries

The overcharge condition in secondary lithium batteries employing redox additives for overcharge protection, has been theoretically analyzed in terms of a finite linear diffusion model. The analysis leads to expressions relating the steady-state overcharge current density and cell voltage to the concentration, diffusion coefficient, standard reduction potential of the redox couple, and interelectrode distance. The model permits the estimation of the maximum permissible overcharge rate for any chosen set of system conditions. Digital simulation of the overcharge experiment leads to numerical representation of the potential transients, and estimate of the influence of diffusion coefficient and interelectrode distance on the transient attainment of the steady state during overcharge. The model has been experimentally verified using 1,1-prime-dimethyl ferrocene as a redox additive. The analysis of the experimental results in terms of the theory allows the calculation of the diffusion coefficient and the formal potential of the redox couple. The model and the theoretical results may be exploited in the design and optimization of overcharge protection by the redox additive approach.

Narayanan, S. R.↗
NASA NTRS1991

Velocity and pressure characteristics of a model SSME high pressure fuel turbopump

Under the present effort an experiment rig has been constructed, an instrumentation package developed and a series of mean and rms velocity and pressure measurements made in a turbopump which modelled the first stage of the Space Shuttle Main Engine (SSME) High Pressure Fuel Turbopump. The rig was designed so as to allow initial experiments with a single configuration consisting of a bell-mouth inlet, a flight impeller, a vaneless diffuser and a volute. Allowance was made for components such as inlet guide vanes, exit guide vanes, downstream pumps, etc. to be added in future experiments. This flexibility will provide a clear baseline set of experiments and allow evaluation in later experiments of the effect of adding specific components upon the pump performance properties. The rotational speed of the impeller was varied between 4260 and 7680 rpm which covered the range of scaled SSME rotation speeds when due allowance is made for the differing stagnation temperature, model to full scale. The results at the inlet obtained with rotational speeds of 4260, 6084 and 7680 rpm showed that the axial velocity at the bell-mouth inlet remained roughly constant at 2.2 of the bulk velocity at the exit of the turbopump near the center of the inlet, but it decreased rapidly with increasing radius at all three speeds. Reverse flow occurred at a radius greater than 0.9 R for all three speeds and the maximum negative velocity reduced from 1.3 of the bulk velocity at the exit of the turbopump at 4260 rpm to 0.35 at 7680 rpm, suggesting that operating at a speed closer to the design condition of 8700 rpm improved the inlet characteristics. The reverse flow caused positive prerotation at the impeller inlet which was negligibly small near the center but reached 0.7 of the impeller speed at the outer annulus. The results in the diffuser and the volute obtained at 7680 rpm show that the hub and shroud walls of the diffuser were characterized by regions of transient reverse flow with negative revolution-averaged velocity of 8 percent of the maximum forward revolution-averaged velocity at the center of the diffuser passage near the shroud wall.

Tse, D. G-N.↗
DOE OSTI2025

Challenge Problem 1: Preliminary Results of the Direct Numerical Simulation of Transient Flows

This report presents the first direct numerical simulations (DNS) of transient mixed convection in an idealized downcomer-like channel (Challenge Problem 1, Phase II). Using the GPU-accelerated NekRS solver, we modeled a sudden decay in driving pressure, mimicking loss-of-flow events, and tracked the resulting evolution of Reynolds number, boundary-layer structure, turbulence statistics, and heat-transfer metrics. Key findings include the systematic thickening and eventual asymmetry of velocity and thermal boundary layers under buoyant deceleration; minimal “memory” lag in Reynolds shear stress and TKE profiles when sampled at matching Re, yet clear shifts of peak locations toward the cooled wall; overshoots in transient eddy-viscosity and eddy-diffusivity (and corresponding sub-unity turbulent Prandtl numbers) on the cooled side; and a pronounced transient Nusselt-number enhancement driven by wall-temperature inertia and residual eddy mixing. These effects combined to offer a temporary cooling margin above steady-state predictions during reactor LOF transients. Future work will extend this work to a more complex “Case II” geometry (90° turn + lower plenum) and generate multi-Re/Pr datasets for data-driven turbulence closures.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS1991

Modelling of the dynamics of HgCdTe growth by the vertical Bridgman method

The analysis of Kim and Brown (1989), which described the pseudo-steady state of the HgCdTe melt/crystal system grown by the vertical Bridgman method, is extended to the study of the transients during the crystal growth and, in particular, at the beginning of the growth. The time-dependent numerical simulations developed show the development of a diffusion layer in the melt and the direct relationship between this layer and the intensity and the pattern of convection in the melt. It is shown that the spread of the solute layer occurs on a diffusive time scale, with the initial transient to the steady-state growth rate lasting several hours for the slow growth rates that are typical of the HgCdTe growth. The simulations demonstrate all the features observed experimentally by Szofran et al. (1984).

Kim, Do H.↗
DOE OSTI2026

Transition from Vehicular to Structural Ionic Transport in Electrified Alkali Aqueous Solutions

A molecular understanding of the solvation and dynamics of ions under static electric fields is crucial for modelling a wide range of natural and technological processes. Yet, traditional simulation methods suffer from a trade-off that has to be made between accuracy and statistical convergence. To bridge this gap, herein we extend our recently introduced Perturbed Neural Network Potential Molecular Dynamics (PNNP MD) approach to investigate the solvation structures and ionic transport mechanisms of electrified alkali cationic solutions. We obtain ionic conductivities for Li+, Na+ and Cs+ from the field dependence of the ionic current density in good agreement with experiment. Surprisingly, the migration mechanism is found to be strikingly different for the three ions despite their similar ionic conductivities. While Li+ conducts predominantly through vehicular migration of a stable 4-fold coordinated ion at all field strengths, Cs+ conducts strictly through a structural diffusion mechanism, where 9-12 transient first shell water coordination bonds are broken and renewed. Notably, aqueous Na+ emerges as a “Goldilocks” ion: its ion-water interactions are strong enough to maintain distinct 5-6 fold coordination shells at zero field (unlike Cs+) yet labile enough to be strongly perturbed by electric fields (unlike Li+). As a consequence, we observe an electric field-induced transition from vehicular to structural ionic transport for Na+ that is accompanied by a marked increase in the ionic current density. Our results imply that the conductance mechanism of ions with moderate ion-solvent interactions can be effectively tuned by external electric fields.

Joll, Kit↗
DOE OSTI2023

Reversible transformations between the non-porous phases of a flexible coordination network enabled by transient porosity

Abstract Flexible metal–organic materials that exhibit stimulus-responsive switching between closed (non-porous) and open (porous) structures induced by gas molecules are of potential utility in gas storage and separation. Such behaviour is currently limited to a few dozen physisorbents that typically switch through a breathing mechanism requiring structural contortions. Here we show a clathrate (non-porous) coordination network that undergoes gas-induced switching between multiple non-porous phases through transient porosity, which involves the diffusion of guests between discrete voids through intra-network distortions. This material is synthesized as a clathrate phase with solvent-filled cavities; evacuation affords a single-crystal to single-crystal transformation to a phase with smaller cavities. At 298 K, carbon dioxide, acetylene, ethylene and ethane induce reversible switching between guest-free and gas-loaded clathrate phases. For carbon dioxide and acetylene at cryogenic temperatures, phases showing progressively higher loadings were observed and characterized using in situ X-ray diffraction, and the mechanism of diffusion was computationally elucidated.

Chemistry↗
NASA NTRS1984

The solution of non-linear hyperbolic equation systems by the finite element method

A finite-element method for the solution of nonlinear hyperbolic systems of equations, such as those encountered in non-self-adjoint problems of transient phenomena in convection-diffusion or in the mixed representation of wave problems, is developed and demonstrated. The problem is rewritten in moving coordinates and reinterpolated to the original mesh by a Taylor expansion prior to a standard Galerkin spatial discretization, and it is shown that this procedure is equivalent to the time-discretization approach of Donea (1984). Numerical results for sample problems are presented graphically, including such shallow-water problems as the breaking of a dam, the shoaling of a wave, and the outflow of a river; compressible flows such as the isothermal flow in a nozzle and the Riemann shock-tube problem; and the two-dimensional scalar-advection, nonlinear-shallow-water, and Euler equations.

Loehner, R.↗
DOE OSTI2022

Kinetic Model for Moisture-Controlled CO 2 Sorption

The understanding of the sorption/desorption kinetics is essential for practical applications of moisture-controlled CO 2 sorption. We introduce an analytic model of the kinetics of moisture-controlled CO 2 sorption and its interpretation in two limiting cases. In one case, chemical reaction kinetics on pore surfaces dominates, in the other case, diffusive transport through the sorbent defines the kinetics. Here, we show that reaction kinetics, which is dominant in the first case, can be expressed as a linear combination of 1st and 2nd order kinetics in agreement with the static isotherm equation derived and validated in a previous paper. The interior transport kinetics can be described by non-linear diffusion equations. By combining all carbon species into a single equation, we can eliminate — in certain limits — the source terms associated with chemical reactions. In this case, the governing equation is ∂θ/∂t = –∇ · (–D eff ∇ θ ). For a sorbent in a form of a flat sheet or a membrane, one can maintain the same functional form of a diffusion equation by introducing a generalized effective diffusivity D M that combines contributions from both surface chemical reaction kinetics and interior diffusive transport kinetics. Experimental data of transient CO 2 flux in a preconditioned commercial anion exchange membrane fit well to the 1st order model as long as very dry states are avoided, validating the theory. The observed DM for a preconditioned commercial anion exchange membrane ranges from 6.6× 10 -14 to 7.1× 10 -14 m 2 s -1 at 35°C. These small values compared to typical ionic diffusivities imply a very slow kinetics, which will be the largest issue that needs to be addressed for practical application. The collected transient CO 2 flux data are used to predict the magnitude of a continuous CO 2 pumping flux in an active membrane that transports CO 2 against a CO 2 concentration gradient. The pumped CO 2 flux is supported by water flux due to a water concentration gradient.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Low Thermal Conductivity and Diffusivity at High Temperatures Using Stable High–Entropy Spinel Oxide Nanoparticles

The realization of low thermal conductivity at high temperatures (0.11 W m –1 K –1 800 °C) in ambient air in a porous solid thermal insulation material, using stable packed nanoparticles of high-entropy spinel oxide with 8 cations (HESO-8 NPs) with a relatively high packing density of ≈50%, is reported. The high-density HESO-8 NP pellets possess around 1000-fold lower thermal diffusivity than that of air, resulting in much slower heat propagation when subjected to a transient heat flux. The low thermal conductivity and diffusivity are realized by suppressing all three modes of heat transfer, namely solid conduction, gas conduction, and thermal radiation, via stable nanoconstriction and infrared-absorbing nature of the HESO-8 NPs, which are enabled by remarkable microstructural stability against coarsening at high temperatures due to the high entropy. Furthermore, this work can elucidate the design of the next-generation high-temperature thermal insulation materials using high-entropy ceramic nanostructures.

thermal insulation↗
DOE OSTI2023

Operando Interaction and Transformation of Metastable Defects in Layered Oxides for Na‐Ion Batteries

Non-equilibrium defects often dictate the macroscopic properties of materials. They largely define the reversibility and kinetics of processes in intercalation hosts in rechargeable batteries. Recently, imaging methods have demonstrated that transient dislocations briefly appear in intercalation hosts during ion diffusion. Despite new discoveries, the understanding of impact, formation and self-healing mechanisms of transient defects, including and beyond dislocations, is lacking. Here, operando X-ray Bragg Coherent Diffractive Imaging (BCDI) and diffraction peak analysis capture the stages of formation of a unique metastable domain boundary, defect self-healing, and resolve the local impact of defects on ionic diffusion in Na x Ni 1-y MnyO 2 intercalation hosts in a charging sodium-ion battery. Results, applicable to a wide range of layered intercalation materials due to the shared nature of framework layers, elucidate new dynamics of transient defects and their connection to macroscopic properties, and suggest how to control the nanostructure dynamics.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Comparing Constant and Transient Membrane Transport Parameters for Use in Wave Desalination Models

Directly pressurizing seawater for desalination with reverse osmosis membranes via wave motion is a promising and sustainable method for producing freshwater in coastal regions. However, such a system could result in significant pressure fluctuations and a departure from conventional steady-state desalination operations. This study sought to assess if membrane transport parameters (apparent water and salt permeability) should be modeled as transient or constant in solution–diffusion-based modeling efforts of dynamically operated desalination systems, such as those coupled to wave power. Two approaches were used to model membrane transport parameters: one considered each parameter to be a function of the net driving pressure of the system, and the other assumed they were constant across all conditions. A pilot-scale system was used to conduct steady-state and controlled ramping experiments. Data from steady-state experiments were used to calculate transient and constant transport parameters. Parameter combinations were used in a simulation model to predict water flux and effective permeate salinity, and simulation outcomes were compared against experimental ramping results. The transient relationships for both water and salt permeability produced the most accurate results for water flux and comparable results for effective permeate salinity. Development of such relationships would be unique to a specific system but could be valuable in modeling wave-driven desalination systems across the wide range of operating conditions they experience.

13 HYDRO ENERGY↗
NASA NTRS1981

Space processing of electronic materials

The relative values of thermal conductivity of solid and liquid HgCdTe are critically important in the design configuration of the furnaces used for Bridgman crystal growth. The thermal diffusivity of the material is closely linked to the conductivity by the defining relation D = k/rho c, where D is the diffusivity, K is the thermal conductivity, rho is the density, and c is the specific heat. The use of transient and periodic heating approaches to measure the diffusivity are explored. A system for securing and extracting heat from silica or glass tubes under high C vacuum conditions is described.

Workman, G. L.↗
DOE OSTI2021

Automated Parameterized CFD Simulations of Phase-Change Material Embedded Heat Exchangers

Thermal storage can be implemented using Phase-Change Materials (PCM), which absorb significant latent heat with a relatively small temperature change. PCM phase-change processes are transient and are driven by thermal diffusion and natural convection – the latter, especially for melting process. Modeling and simulation of PCM heat exchangers is typically computationally intensive due to the relative complex time-dependent underlying physics. This paper presents a study investigating a single straight tube with circular transverse fins in the vertical orientation, using PCM’s with 37oC nominal melting temperature, leveraging automated parametric CFD simulations. The computational domain is reduced to 2D axisymmetric for a segment of the HX comprising a region in between two fins with constant wall temperature as boundary condition. This approach allows for faster evaluations of the transient thermal characteristics for a given design space of interest. Correlations and reduced order models (ROM’s) are developed. Results indicate that the ROM’s reproduce the CFD simulations with high accuracy for designs from the training data set, however, designs from cross-validation and test sets do not always have good agreement. The limited number of designs in the training set is a possible cause for the lack of robustness of the ROM’s and thus additional training designs will be added in future work. The ROM’s solve the simulations on average 500,000 times faster than CFD.

25 ENERGY STORAGE↗
DOE OSTI2026

High energy neutrinos from pulsar-powered optical transients: LFBOTs as potential origin of the KM3NeT event KM3-230213A

Recently, the KM3NeT Collaboration reported the detection of an ultra-high energy ($\sim 220$ PeV) neutrino event, KM3-230213A. In this work, we perform a detailed investigation into whether this event could originate from the diffuse neutrino flux produced by a class of pulsar-powered optical transients. In particular, we consider populations of ordinary supernovae (SNe), super-luminous supernovae (SLSNe), and luminous fast blue optical transients (LFBOTs) with a newly formed magnetar as the central engine. We discuss both the thermal electromagnetic and non-thermal neutrino emission from such sources. We scan the parameter space of the dipolar magnetic field strength and the initial spin period to determine characteristic optical emission properties and lightcurve timescales of these transients. Additionally, our scan identifies which classes of these transients can reproduce the required diffuse flux level and neutrino energies. Combining our results, we conclude that a diffuse neutrino flux from a population of LFBOTs can explain the KM3NeT event. Therefore, pulsar-powered optical transients may serve as promising sources for the current and upcoming high-energy and ultra-high energy neutrino telescopes.

Mukhopadhyay, Mainak [Fermilab; Chicago U., KICP] ↗
DOE OSTI2024

Climate forcing controls on carbon terrestrial fluxes during shale weathering

Climate influences near-surface biogeochemical processes and thereby determines the partitioning of carbon dioxide (CO 2 ) in shale, and yet the controls on carbon (C) weathering fluxes remain poorly constrained. Using a dataset that characterizes biogeochemical responses to climate forcing in shale regolith, we implement a numerical model that describes the effects of water infiltration events, gas exchange, and temperature fluctuations on soil respiration and mineral weathering at a seasonal timescale. Our modeling approach allows us to quantitatively disentangle the controls of transient climate forcing and biogeochemical mechanisms on C partitioning. We find that ~3% of soil CO 2 (1.02 mol C/m 2 /y) is exported to the subsurface during large infiltration events. Here, net atmospheric CO 2 drawdown primarily occurs during spring snowmelt, governs the aqueous C exports (61%), and exceeds the CO 2 flux generated by pyrite and petrogenic organic matter oxidation (~0.2 mol C/m 2 /y). We show that shale CO 2 consumption results from the temporal coupling between soil microbial respiration and carbonate weathering. This coupling is driven by the impacts of hydrologic fluctuations on fresh organic matter availability and CO 2 transport to the weathering front. Diffusion-limited transport of gases under transient hydrological conditions exerts an important control on CO 2 (g) egress patterns and thus must be considered when inferring soil CO 2 drawdown from the gas phase composition. Our findings emphasize the importance of seasonal climate forcing in shaping the net contribution of shale weathering to terrestrial C fluxes and suggest that warmer conditions could reduce the potential for shale weathering to act as a CO 2 sink.

58 GEOSCIENCES↗
NASA NTRSDate not supplied

Characterization of Composite Damage Using Passive Thermography

Passive thermography is used to monitor small increases in temperature on a composite structure during loading. A rise in temperature can be attributed to damage formation due to matrix cracking and fiber breaks. An infrared camera allows for imaging the damage location, size, and shape. Recently, a technique has been developed to estimate the depth of the damage in a composite hat-stiffened panel during quasi-static loading. This technique is based on two heat generation components. The first component is an instantaneous thermoelastic response due to a strain release. The second component is mechanical heating, at the interface of failure, due to fracture damage. This second component produces a transient rise in temperature that is a function of the damage depth and thermal diffusivity. The first component defines the thermal start time for the transient response. A one-dimensional thermal model is used to determine the damage depth for a known thermal diffusivity. The results are compared to ultrasonic and X-ray CT data and show good agreement for damage depth.

Thermal nondestructive evaluation↗