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Raman lidar measurements of water vapor and aerosol/clouds during the FIRE/SPECTRE field campaign

Water vapor is one of the most important constituents of the earth's atmosphere. It has a major impact on both atmospheric dynamics and radiative transfer. From a dynamic standpoint, the distribution of water vapor with height determines convective stability which is the major indicator of destructive storm development. Also, water vapor stored in the planetary boundary layer acts as the fuel to intensify severe weather. In regards to radiative transfer, water vapor is the most active IR molecule in the atmosphere. It is more effective in absorbing and emitting IR radiation than either carbon dioxide or methane, and thus plays an important role in global change. The main objective of FIRE (First ISSCCP (International Satellite Cloud Climatology Project) Regional Experiment) was to study the development and radiative characteristics of cirrus clouds. The SPECTRE (Spectral Radiation Experiment) project was designed to acquire the necessary atmospheric observations to compare radiative measurements with radiative transfer theory, with special emphasis on understanding the water vapor spectral continuum. The FIRE/SPECTRE field campaign was conducted during Nov. - Dec. 1991 in Coffeyville, Kansas. A complete understanding of water vapor, its distribution with height, and its temporal variation was important for both experiments.

Melfi, S. H.↗

Space-Time Variations in Water Vapor as Observed by the UARS Microwave Limb Sounder

Water vapor in the upper troposphere has a significant impact on the climate system. Difficulties in making accurate global measurements have led to uncertainty in understanding water vapor's coupling to the hydrologic cycle in the lower troposphere and its role in radiative energy balance. The Microwave Limb Sounder (MLS) on the Upper Atmosphere Research Satellite is able to retrieve water vapor concentration in the upper troposphere with good sensitivity and nearly global coverage. An analysis of these preliminary retrievals based on 3 years of observations shows the water vapor distribution to be similar to that measured by other techniques and to model results. The primary MLS water vapor measurements were made in the stratosphere, where this species acts as a conserved tracer under certain conditions. As is the case for the upper troposphere, most of the stratospheric discussion focuses on the time evolution of the zonal mean and zonally varying water vapor. Stratospheric results span a 19-month period and tropospheric results a 36-month period, both beginning in October of 1991. Comparisons with stratospheric model calculations show general agreement, with some differences in the amplitude and phase of long-term variations. At certain times and places, the evolution of water vapor distributions in the lower stratosphere suggests the presence of meridional transport.

Elson, Lee S.↗

Mobile lidar system for measurement of water vapor mixing ratio and ozone number density

The Water Vapor Lidar was modified and extended to make differential absorption measurements of ozone. Water vapor measurements make use of a weak molecular scattering process known as Raman scattering. It is characterized by a shift in wavelength of the scattered beam of light relative to the incident one. Some of the energy of the incident photon is converted to vibrational or rotational energy within the molecule leaving the scattered photon shifted to a slightly longer wavelength. When performing water vapor measurements, profiles are acquired of water vapor mixing ratio from near the ground to beyond 7 km every 2 minutes. By forming a color composite image of the individual profiles, the spatial and temporal evolution of water vapor is visible with vertical resolution of 75 to 150m and temporal resolution of 2 minutes. The ozone lidar is intended for use as a cross calibration facility for other stationary ozone lidar systems. The ozone measurement employs the technique known as differential absorption. The backscattered laser radiation from two different wavelengths is measured. Successful measurements of 308 nm returns were made from 80 km with an averaging period of 6 hours. Using these data and a standard atmosphere density curve, an ozone number density profile was made which agrees very well with the standard ozone curve between 20 and 40 km.

Whiteman, D.↗

A passive microwave technique for profiling of atmospheric water vapor

There is considerable interest in remote measurements of the vertical distribution of water vapor, particularly under cloud conditions. The net integrated amount of water vapor has been measured using the 22.235-GHz water vapor line (Staelin et al., 1975). Attempts to use this line for obtaining vertical distribution information have not been fruitful because of the weakness of absorption even at line center. The 183.310-GHz line is much stronger and thus provides a possibility of profiling water vapor. The paper presents a preliminary analysis of this possibility. A technique is described for retrieval of water vapor profiles from microwave radiometric measurements near the 183-GHz water vapor line, and weighting functions useful in the retrievals are developed. The results suggest that microwave radiometry near the 183-GHz water vapor line could yield interesting water vapor profiles, at least over oceans.

Schaerer, G.↗

Correlation among Cirrus Ice Content, Water Vapor and Temperature in the TTL as Observed by CALIPSO and Aura-MLS

Water vapor in the tropical tropopause layer (TTL) has a local radiative cooling effect. As a source for ice in cirrus clouds, however, it can also indirectly produce infrared heating. Using NASA A-Train satellite measurements of CALIPSO and Aura/MLS we calculated the correlation of water vapor, ice water content and temperature in the TTL. We find that temperature strongly controls water vapor (correlation r =0.94) and cirrus clouds at 100 hPa (r = −0.91). Moreover we observe that the cirrus seasonal cycle is highly (r =−0.9) anticorrelated with the water vapor variation in the TTL, showing higher cloud occurrence during December-January-February. We further investigate the anticorrelation on a regional scale and find that the strong anticorrelation occurs generally in the ITCZ (Intertropical Convergence Zone). The seasonal cycle of the cirrus ice water content is also highly anticorrelated to water vapor (r = −0.91) and our results support the hypothesis that the total water at 100 hPa is roughly constant. Temperature acts as a main regulator for balancing the partition between water vapor and cirrus clouds. Thus, to a large extent, the depleting water vapor in the TTL during DJF is a manifestation of cirrus formation.

Flury, T.↗

Alexandrite laser transmitter development for airborne water vapor DIAL measurements

In the DIAL technique, the water vapor concentration profile is determined by analyzing the lidar backscatter signals for laser wavelengths tuned 'on' and 'off' a water vapor absorption line. Desired characteristics of the on-line transmitted laser beam include: pulse energy greater than or equal to 100 mJ, high-resolution tuning capability (uncertainty less than 0.25 pm), good spectral stability (jitter less than 0.5 pm about the mean), and high spectral purity (greater than 99 percent). The off-line laser is generally detuned less than 100 pm away from the water vapor line. Its spectral requirements are much less stringent. In our past research, we developed and demonstrated the airborne DIAL technique for water vapor measurements in the 720-nm spectral region using a system based on an alexandrite laser as the transmitter for the on-line wavelength and a Nd:YAG laser-pumped dye laser for the off-line wavelength. This off-line laser has been replaced by a second alexandrite laser. Diode lasers are used to injection seed both lasers for frequency and linewidth control. This eliminates the need for the two intracavity etalons utilized in our previous alexandrite laser and thereby greatly reduces the risk of optical damage. Consequently, the transmitted pulse energy can be substantially increased, resulting in greater measurement range, higher data density, and increased measurement precision. In this paper, we describe the diode injection seed source, the two alexandrite lasers, and the device used to line lock the on-line seed source to the water vapor absorption feature.

Chyba, Thomas H.↗

Ground-based observations of Mars and Venus water vapor during 1972 and 1973

The Venus water vapor line at 8197.71 A has been monitored at several positions on the disk of Venus and at phase angles between 22 and 91 degrees. Comparisons are made between the water vapor abundances, the presence of UV features, and the CO2 abundances determined from near simultaneous observations of CO2 bands at the same positions on the disk of Venus. Two periods of the Martian year have been monitored. The first period was during and after the great 1971 dust storm (L8 = 280 to 20 degrees or summer in the southern hemisphere). The results obtained are compared to the Mariner 9 IRIS and Mars 3 observations made during the same period. During the second period (L8 = 124 to 266 degrees) observations were made to follow the seasonal latitudinal and diurnal changes in the water vapor abundance in the Martian atmosphere. Studies of the latitudinal and diurnal water vapor distributions indicate that the location of maximum and minimum abundances for this season are positively correlated with surface temperature variations.

Barker, E. S.↗

Water Vapor Tracers as Diagnostics of the Regional Hydrologic Cycle

Numerous studies suggest that local feedback of evaporation on precipitation, or recycling, is a significant source of water for precipitation. Quantitative results on the exact amount of recycling have been difficult to obtain in view of the inherent limitations of diagnostic recycling calculations. The current study describes a calculation of the amount of local and remote sources of water for precipitation, based on the implementation of passive constituent tracers of water vapor (termed water vapor tracers, WVT) in a general circulation model. In this case, the major limitation on the accuracy of the recycling estimates is the veracity of the numerically simulated hydrological cycle, though we note that this approach can also be implemented within the context of a data assimilation system. In this approach, each WVT is associated with an evaporative source region, and tracks the water until it precipitates from the atmosphere. By assuming that the regional water is well mixed with water from other sources, the physical processes that act on the WVT are determined in proportion to those that act on the model's prognostic water vapor. In this way, the local and remote sources of water for precipitation can be computed within the model simulation, and can be validated against the model's prognostic water vapor. Furthermore, estimates of precipitation recycling can be compared with bulk diagnostic approaches. As a demonstration of the method, the regional hydrologic cycles for North America and India are evaluated for six summers (June, July and August) of model simulation. More than 50% of the precipitation in the Midwestern United States came from continental regional tracers, and the local source was the largest of the regional tracers (14%). The Gulf of Mexico and Atlantic 2 regions contributed 18% of the water for Midwestern precipitation, but further analysis suggests that the greater region of the Tropical Atlantic Ocean may also contribute significantly. In general, most North American land regions showed a positive correlation between evaporation and recycling ratio (except the Southeast United States) and negative correlations of recycling ratio with precipitation and moisture transport (except the Southwestern United States). The Midwestern local source is positively correlated with local evaporation, but it is not correlated with water vapor transport. This is contrary to bulk diagnostic estimates of precipitation recycling. In India, the local source of precipitation is a small percentage of the precipitation owing to the dominance of the atmospheric transport of oceanic water. The southern Indian Ocean provides a key source of water for both the Indian continent and the Sahelian region.

Bosilovich, Michael G.↗

The observed day-to-day variability of Mars water vapor

The diurnal variability of atmospheric water vapor as derived from the Viking MAWD data is discussed. The detection of day to day variability of atmospheric water would be a significant finding since it would place constraints on the nature of surface reservoirs. Unfortunately, the diurnal variability seen by the MAWD experiment is well correlated with the occurrence of dust and/or ice hazes, making it difficult to separate real variations from observational effects. Analysis of the day to day variability of water vapor in the Martian atmosphere suggests that the observations are, at certain locations and seasons, significantly affected by the presence of water-ice hazes. Because such effects are generally limited to specific locations, such as Tharsis, Lunae Planum, and the polar cap edge during the spring, the seasonal and latitudinal trends in water vapor that have been previously reported are not significantly affected.

Jakosky, Bruce M.↗

MIR Measurements of Atmospheric Water Vapor Profiles

Three subjects related to atmospheric water vapor profiling using the 183.3 GHz absorption line are discussed in this paper. First, data acquired by an airborne millimeter-wave imaging radiometer (MIR) over ocean surface in the western Pacific are used to estimate three-dimensional (3-D) distribution of atmospheric water vapor. The instrument's radiometric measurements with mixed vertical and horizontal polarizations require modifications to the retrieval algorithm used in the past. It is demonstrated that, after the modifications, the new algorithm can provide adequate retrieval of water vapor profiles, even though the measured data are of mixed polarizations. Next, the retrieved profiles, in terms of water vapor mixing ratio rho (g/kg), are compared with those measured in near concurrence by dropsondes from a research aircraft in the western Pacific and by a ground-based Raman lidar at Wallops Island, Virginia. The ratio of the standard deviation to the mean rho is found to be 0.12 at 0.25 km altitude and gradually degraded to 0.67 at the highest altitude of the retrieval of 10.25 km. Finally, the effect of the "initial guess" relative humidity profile on the final retrieved product is analyzed with respect to the condition for the convergent retrieval. It is found that the effect is minimal if the initial profile is not unrealistically different from the true one. If the initial profile is very different from the true one, the final retrieved product could be subject to a substantial error. Tightening of the convergent condition in the retrieval helped reduce magnitude of the error, but not remove it totally. It is concluded that an initial profile based on climatology is likely to provide most reliable retrieval results.

Wang, J. R.↗

What Good is Raman Water Vapor Lidar?

Raman lidar has been used to quantify water vapor in the atmosphere for various scientific studies including mesoscale meteorology and satellite validation. Now the international networks of NDACC and GRUAN have interest in using Raman water vapor lidar for detecting trends in atmospheric water vapor concentrations. What are the data needs for addressing these very different measurement challenges. We will review briefly the scientific needs for water vapor accuracy for each of these three applications and attempt to translate that into performance specifications for Raman lidar in an effort to address the question in the title of "What good is Raman water vapor Iidar."

Whitman, David↗

Understanding the Water Cycle Above the North Polar Cap on Mars Using MRO CRISM Retrievals of Water Vapor

The north polar cap (NPC) on Mars is the major reservoir of atmospheric water (H2O) currently on Mars. The retrieval and monitoring of atmospheric water vapor abundance are crucial for tracking the cycle of water above the NPC. The Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) aboard the Mars Reconnaissance Orbiter (MRO) has provided a wealth of data that extend over 5 + Martian years, covering the time period between 2006 and 2016. CRISM is ideally suited for spring and summer observations of the north polar region (latitudes poleward of 60 °N). The retrievals of water vapor column abundances over this extended period of time were performed over both ice-free and water ice covered surfaces, extending the coverage of the water vapor maps to include the permanent cap, where a maximum value of 90 precipitable micrometers (pr–µm) is retrieved, as compared to 60 pr–µm over ice-free regions in the North Polar Region. Away from summertime maximum, modest interannual variability in the water vapor abundance is observed. Zonal averages over all the observed Martian years combined show a developing water front that shifts northward towards summer, before dissipating over the permanent cap during mid-summer. A prominent feature at latitudes around 75 °N shows large abundances of water vapor, indicating a water vapor annulus encircling the retreating edge of the seasonal polar cap during late spring. Meridional transport of water modeled here show that the annulus may be a result of the convergence of water vapor from both south and north along the retreating edge of the NPC.

Khayat, Alain S. J.↗

The Use of Water Vapor for Detecting Environments that Lead to Convectively Produced Heavy Precipitation and Flash Floods

This Tech Report summarizes years of study and experiences on using GOES Water vapor (6.7 micron and precipitable water) and Special Sensor Microwave Imager (SSM/1) from the Defense Meteorological Satellite Program (DMSP) derived Precipitable Water (PNAI) for detecting environments favorable for convectively produced flash floods. An emphasis is on the moisture. upper air flow, and equivalent potential temperature (Theta(sub e)) patterns that lead to devastating flood events. The 15 minute 6.7 micron water vapor imagery is essential for tracking middle to upper tropospheric disturbances that produce upward vertical motion and initiate flash flood producing systems. Water vapor imagery at 6.7 micron is also used to detect surges of upper level moisture (called tropical water vapor plumes) that have been associated with extremely heavy rainfall. Since the water vapor readily depicts lifting mechanisms and upper level moisture, water vapor imagery is often an excellent source of data for recognizing patterns of heavy precipitation and flash floods. In order to analyze the depth of the moisture, the PW aspects of the troposphere must be measured. The collocation (or nearby location) of high values ofP\V and instability are antecedent conditions prior to the flash flood or heavy rainfall events. Knowledge of PW magnitudes have been used as thresholds for impending flash flood events, PW trends are essential in flash flood prediction. Conceptual models and water vapor products are used to study some of the characteristics of convective systems that occurred over the United States of America (USA) during the summer of 1997 and the 1997-1998 El Nino. P\V plumes were associated with most of the \vest coast heavy precipitation events examined during the winter season of 1997 - 1998, In another study, conducted during the summer season of 1997. results showed that the collocation of water vapor (6.7 micron) and P\N' plumes possessed higher correlations with predicted rainfall amounts than when PW plumes occurred by themselves (i.e.. without the presence of 6.7 micron water vapor plumes). Satellite Analysis Branch (SAB) meteorologists use the 6.7 micron water and P\V products for their QPE's (interactive Flash Flood Analyzer (IFFA) and Auto-Estimator precipitation estimates), Outlooks, and heavy precipitation briefings with the Hydrometeorological Prediction Center/National Center for Environmental Prediction.

Scofield, Rod↗

Radiometric remote sensing of mesospheric and stratospheric water vapor

The remote sensing of stratospheric and mesospheric water vapor by microwave and millimeter radiometry is described. The received radiation is emitted by and interacts with all levels of the atmosphere. The pressure dependence of the linewidth for the absorption cross section of water vapor permits retrieval of vapor mixing ratios. The 183.31-GHz line of water vapor can also be used for remote sensing of the water vapor concentration in the upper atmosphere, but due to the much stronger absorption cross section for this line, ground-based observations are difficult. To date all measurements at 183 GHz have been made from platforms above the troposphere.

Croskey, Charles L.↗

A Regional-Scale Assessment of Satellite Derived Precipitable Water Vapor Across The Amazon Basin

Atmospheric water vapor is widely recognized as a key climate variable, linking an assortment of poorly understood and complex processes. It is a major element of the hydrological cycle and provides a mechanism for energy exchange among many of the Earth system components. Reducing uncertainty in our current knowledge of water vapor and its role in the climate system requires accurate measurement, improved modeling techniques, and long-term prediction. Satellites have the potential to satisfy these criteria, as well as provide high resolution measurements that are not available from conventional sources. The focus of this paper is to examine the temporal and mesoscale variations of satellite derived precipitable water vapor (PW) across the Amazon Basin. This region is pivotal in the functioning of the global climate system through its abundant release of latent heat associated with heavy precipitation events. In addition, anthropogenic deforestation and biomass burning activities in recent decades are altering the conditions of the atmosphere, especially in the planetary boundary layer. A physical split-window (PSW) algorithm estimates PW using images from the GOES satellites along with the NCEP/NCAR Reanalysis data that provides the first guess information. Retrievals are made at a three-hourly time step during daylight hours in the Amazon Basin and surrounding areas for the months of June and October in 1988 (dry year) and 1995 (wet year). Spatially continuous fields are generated 5 times daily at 12Z, 15Z, 18Z, 21Z, and 00Z. These fields are then averaged to create monthly and 3 hourly monthly grids. Overall, the PSW estimates PW reasonable well in the Amazon with MAE ranging from 3.0 - 9.0 mm and MAE/observed mean around 20% in comparison to radiosonde observations. The distribution of PW generally mimics that of precipitation. Maximum values (42 - 52 mm) are located in the Northwest whereas minimum values (18 - 27 mm) are found along Brazil's East coast. Aside from the East coast, PW has a stronger north-south gradient than that of rainfall. As for the temporal variation of PW, June (1988 and 1995) experiences a peak about 1400 local time, corresponding to a maximum in air temperature. In contrast, October (1988 and 1995) experiences a maximum early in the day, 1100 local time, with a gradual decrease toward nighttime.

DeLiberty, Tracy↗

Possible Near-IR Channels for Remote Sensing Precipitable Water Vapor from Geostationary Satellite Platforms

Remote sensing of tropospheric water vapor profiles from current geostationary weather satellites are made using a few broadband infrared (IR) channels in the 6 to 13- micrometers region. Uncertainties greater than 20 percent exist in derived water vapor values just above the surface from the IR emission measurements. In this paper, we propose three near-IR channels, one within the 0.94-micrometer water vapor band absorption region, and the other two in nearby atmospheric windows, for remote sensing of precipitable water vapor over land areas, excluding lakes and rivers, during daytime from future geostationary satellite platforms. The physical principles are as follows. The reflectance of most surface targets varies approximately linearly with wavelength near 1 micrometer. The solar radiation on the sun-surface-sensor ray path is attenuated by atmospheric water vapor...

Green, R. O.↗

Airborne water vapor DIAL system and measurements of water and aerosol profiles

The Lidar Applications Group at NASA Langley Research Center has developed a differential absorption lidar (DIAL) system for the remote measurement of atmospheric water vapor (H2O) and aerosols from an aircraft. The airborne H2O DIAL system is designed for extended flights to perform mesoscale investigations of H2O and aerosol distributions. This DIAL system utilizes a Nd:YAG-laser-pumped dye laser as the off-line transmitter and a narrowband, tunable Alexandrite laser as the on-line transmitter. The dye laser has an oscillator/amplifier configuration which incorporates a grating and prism in the oscillator cavity to narrow the output linewidth to approximately 15 pm. This linewidth can be maintained over the wavelength range of 725 to 730 nm, and it is sufficiently narrow to satisfy the off-line spectral requirements. In the Alexandrite laser, three intracavity tuning elements combine to produce an output linewidth of 1.1 pm. These spectral devices include a five-plate birefringent tuner, a 1-mm thick solid etalon and a 1-cm air-spaced etalon. A wavelength stability of +/- 0.35 pm is achieved by active feedback control of the two Fabry-Perot etalons using a frequency stabilized He-Ne laser as a wavelength reference. The three tuning elements can be synchronously scanned over a 150 pm range with microprocessor-based scanning electronics. Other aspects of the DIAL system are discussed.

Higdon, Noah S.↗

High Temperature Corrosion of Silicon Carbide and Silicon Nitride in Water Vapor

Silicon carbide (SiC) and silicon nitride (Si3N4) are proposed for applications in high temperature combustion environments containing water vapor. Both SiC and Si3N4 react with water vapor to form a silica (SiO2) scale. It is therefore important to understand the durability of SiC, Si3N4 and SiO2 in water vapor. Thermogravimetric analyses, furnace exposures and burner rig results were obtained for these materials in water vapor at temperatures between 1100 and 1450 C and water vapor partial pressures ranging from 0.1 to 3.1 atm. First, the oxidation of SiC and Si3N4 in water vapor is considered. The parabolic kinetic rate law, rate dependence on water vapor partial pressure, and oxidation mechanism are discussed. Second, the volatilization of silica to form Si(OH)4(g) is examined. Mass spectrometric results, the linear kinetic rate law and a volatilization model based on diffusion through a gas boundary layer are discussed. Finally, the combined oxidation and volatilization reactions, which occur when SiC or Si3N4 are exposed in a water vapor-containing environment, are presented. Both experimental evidence and a model for the paralinear kinetic rate law are shown for these simultaneous oxidation and volatilization reactions.

Opila, E. J.↗