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NASA Earth Resources Survey Symposium. Volume 1-A: Agriculture, environment

A number of papers dealing with the practical application of imagery obtained from remote sensors on LANDSAT satellites, the Skylab Earth resources experiment package, and aircraft to problems in agriculture and the environment were presented. Some of the more important topics that were covered included: range management and resources, environmental monitoring and management, crop growth and inventory, land management, multispectral band scanners, forest management, mapping, marshlands, strip mining, water quality and pollution, ecology.

Source record↗

Gulf of Mexico Air Quality: CALIPSO Support for Gulf of Mexico Air Quality Relating to the Deepwater Horizon Oil Spill

On April 20, 2010, an oil platform belonging to BP exploded and leaked a huge volume of oil into the Gulf of Mexico. In an effort to control the spread of the oil, BP applied dispersants such as Corexit and conducted in-situ burnings of the oil. This catastrophe created a complex chain of events that affected not only the fragile water and land ecosystems, but the humans who breathe the air every day. Thousands of people were exposed to fumes associated with oil vapors from the spill, burning of the oil, and the toxic mixture of dispersants. While aiding in clean-up efforts, local fishermen were directly exposure to fumes when working on the Gulf. A notable amount of Gulf Coast residents were also exposed to the oil fumes as seasonal southeasterly winds blew vapors toward land. The Volatile Organic Compounds (VOC) found in oil vapors include: benzene, toluene, ethyl benzene, xylene, naphthalene, hydrogen sulfide and particulate matter (PM). Increases in water temperature and sunlight due to the summer season allow for these VOCs and PM to evaporate into the air more rapidly. Aside from the VOCs found in oil vapors, the dispersant being used to break up the oil is highly toxic and is thought to be even more toxic than the oil itself (EPA website, 2010). To protect human health, the environment, and to make informed policy decisions relevant to the spill, the EPA Region 6 has continuously monitored the affected areas carefully for levels of pollutants in the outdoor air that are associated with petroleum products and the burning of oil along the coast. In an effort to prevent, prepare for, and respond to future oil spills that occur in and around inland waters of the United States, the EPA has been working with local, state, and federal response partners. Air quality measurements were collected by the EPA at five active monitoring systems stationed along the coast.

Nguyen, Myngoc T.↗

A machine learning approach to water quality forecasts and sensor network expansion: Case study in the Wabash River Basin, United States

Abstract Midwestern cities require forecasts of surface nitrate loads to bring additional treatment processes online or activate alternative water supplies. Concurrently, networks of nitrate monitoring stations are being deployed in river basins, co‐locating water quality observations with established stream gauges. However, tools to evaluate the future value of expanded networks to improve water quality forecasts remains challenging. Here, we construct a synthetic data set of stream discharge and nitrate for the Wabash River Basin—one of the United States’ most nutrient polluted basins—using the established Agro‐IBIS and THMB models. Synthetic data enables rapid, unbiased and low‐cost assessment of potential sensor placements to support management objectives, such as near‐term forecasting. Using the synthetic data, we established baseline 1‐day forecasts for surface water nitrate at 12 cities in the basin using support vector machine regression (SVMR; RMSE 0.48–3.3 ppm). Next, we used the SVMRs to evaluate the improvement in forecast performance associated with deployment of additional nitrate sensors. We identified the optimal sensor placement to improve forecasts at each city, and the relative value of sensors at each candidate location. Finally, we assessed the co‐benefit realized by other cities when a sensor is deployed to optimize a forecast at one city, finding significant positive externalities in all cases. Ultimately, our study explores the potential for machine learning to make near‐term predictions and critically evaluate the improvement realized by expanding a monitoring network. While we use nitrate pollution in the Wabash River Basin as a case study, this approach could be readily applied to any problem where the future value of sensors and network design are being evaluated.

54 ENVIRONMENTAL SCIENCES↗

Solutions Network Formulation Report. Visible/Infrared Imager/Radiometer Suite and Landsat Data Continuity Mission Simulated Data Products for the Great Lakes Basin Ecological Team

The proposed solution would simulate VIIRS and LDCM sensor data for use in the USGS/USFWS GLBET DST. The VIIRS sensor possesses a spectral range that provides water-penetrating bands that could be used to assess water clarity on a regional spatial scale. The LDCM sensor possesses suitable spectral bands in a range of wavelengths that could be used to map water quality at finer spatial scales relative to VIIRS. Water quality, alongshore sediment transport and pollutant discharge tracking into the Great Lakes system are targeted as the primary products to be developed. A principal benefit of water quality monitoring via satellite imagery is its economy compared to field-data collection methods. Additionally, higher resolution satellite imagery provides a baseline dataset(s) against which later imagery can be overlaid in GIS-based DST programs. Further, information derived from higher resolution satellite imagery can be used to address public concerns and to confirm environmental compliance. The candidate solution supports the Public Health, Coastal Management, and Water Management National Applications.

Estep, Leland↗

OCTS and SeaWiFS Bio-Optical Algorithm and Product Validation and Intercomparison in US Coastal Waters

The successful launch of the National Space Development Agency of Japan (NASDA) Ocean Color and Temperature Sensor (OCTS) in August 1996, and the launch of Orbital Science Corporation's (OSC) Sea-viewing Wide-Field-of-view Sensor (SeaWiFS) in August 1997 signaled the beginning of a new era for ocean color research and application. These data may be used to remotely evaluate 1) water quality, 2) transport of sediments and adhered pollutants, 3) primary production, upon which commercial shellfish and finfish populations depend for food, and 4) harmful algal blooms which pose a threat to public health and economies of affected areas. Several US government agencies have recently expressed interest in monitoring U.S. coastal waters using optical remote sensing. This renewed interest is broadly driven by 1) resource management concerns over the impact of coastward shifts in population and land use on the ecosystems of estuaries, wetlands, nearshore benthic environments and fisheries, 2) recognition of the need to understand short time scale global change due to urbanization of sensitive land-margin ecosystems, and 3) national security issues. Satellite ocean color sensors have the potential to furnish data at the appropriate time and space scales to evaluate and resolve these concerns and problems. In this draft technical memorandum, we outline our progress during the first year of our SIMBIOS project to evaluate ocean color bio-optical algorithms and products generated using OCTS and SeaWiFS data in coastal US waters.

Brown, Christopher W.↗

The Ozone Water-Land Environmental Transition Study: An Innovative Strategy for Understanding Chesapeake Bay Pollution Events

Coastal regions have historically represented a significant challenge for air quality investigations because of water-land boundary transition characteristics and a paucity of measurements available over water. Prior studies have identified the formation of high levels of ozone over water bodies, such as the Chesapeake Bay, that can potentially recirculate back over land to significantly impact populated areas. Earth-observing satellites and forecast models face challenges in capturing the coastal transition zone where small-scale meteorological dynamics are complex and large changes in pollutants can occur on very short spatial and temporal scales. An observation strategy is presented to synchronously measure pollutants “over land” and “over water” to provide a more complete picture of chemical gradients across coastal boundaries for both the needs of state and local environmental management and new remote sensing platforms. Intensive vertical profile information from ozone lidar systems and ozonesondes, obtained at two main sites, one over land and the other over water, are complemented by remote sensing and in situ observations of air quality from ground-based, airborne (both personned and unpersonned), and shipborne platforms. These observations, coupled with reliable chemical transport simulations, such as the National Oceanic and Atmospheric Administration (NOAA) National Air Quality Forecast Capability (NAQFC), are expected to lead to a more fully characterized and complete land–water interaction observing system that can be used to assess future geostationary air quality instruments, such as the National Aeronautics and Space Administration (NASA) Tropospheric Emissions: Monitoring of Pollution (TEMPO), and current low-Earth-orbiting satellites, such as the European Space Agency’s Sentinel-5 Precursor (S5-P) with its Tropospheric Monitoring Instrument (TROPOMI).

Forecast Models↗

WET Water Resources: A Google Earth Engine Python API Tool to Automate Wetland Extent Mapping Using Radar Satellite Sensors for Wetland Management and Monitoring

Wetland ecosystems are annually or seasonally wet transition zones between land and water. They provide a range of ecosystem services such as water filtration, flood mitigation, and carbon sequestration, as well as hosting biodiversity hotspots. Although they fulfill fundamental physical and natural processes, wetland extent and health are threatened by anthropogenic influences related to urbanization, population increase, pollution, and climate change. Recognizing the need to quantitatively monitor changes in these recently threatened ecosystems in a timely and cost-effective way, we developed a Google Earth Engine (GEE) Python API tool for automated wetland extent mapping using optical and radar satellite sensors that can be applied globally. The tool will significantly improve wetland change analysis and monitoring as the optical and SAR data proves high resolution (5-10 m) imagery, and SAR data is unaffected by cloud cover and light availability (day vs. night), which are common limitations for other remotely sensed sensors. The tool utilizes Copernicus Sentinel-1 C-band and NISAR L-band synthetic aperture radar (SAR) imagery. During image preprocessing, we applied a MODIS snow mask product to mask global snow coverage, which would affect land classification sensitivity. Calibration and validation were conducted through a historical change and sensitivity analysis of the Sudd watershed located in central Sudan. The tool was the first of its kind, as it enables NISAR data processing through an open-source GEE repository, further expanding and improving the utility of NASA Earth observations and contributing to NASA Open Science initiatives. We anticipate the tool will be used by researchers and practitioners interested in wetland monitoring and management..

Lori Berberian↗

WET Water Resources: A Google Earth Engine Python API Tool to Automate Wetland Extent Mapping Using Radar Satellite Sensors for Wetland Management and Monitoring

Wetland ecosystems are annually or seasonally wet transition zones between land and water. They provide a range of ecosystem services such as water filtration, flood mitigation, and carbon sequestration, as well as hosting biodiversity hotspots. Although they fulfill fundamental physical and natural processes, wetland extent and health are threatened by anthropogenic influences related to urbanization, population increase, pollution, and climate change. Recognizing the need to quantitatively monitor changes in these recently threatened ecosystems in a timely and cost-effective way, we developed a Google Earth Engine (GEE) Python API tool for automated wetland extent mapping using optical and radar satellite sensors that can be applied globally. The tool will significantly improve wetland change analysis and monitoring as SAR data provides high resolution (5-10 m) imagery, unaffected by cloud cover and light availability (day vs. night), common limitations for other remotely sensed sensors. The tool utilizes Copernicus Sentinel-1 C-band and NISAR L-band (once operational and available on the GEE repository) synthetic aperture radar (SAR) imagery. During image preprocessing, we applied a Terra Moderate Resolution Imaging Spectroradiometer (MODIS) snow product to determine regional snow coverage, which affects land classification sensitivity. Calibration and validation were conducted through a historical change and sensitivity analysis of the Sudd wetland located in central Sudan. The tool was the first of its kind, as it enables NISAR data processing through an open-source GEE repository, further expanding and improving the utility of NASA Earth observations and contributing to NASA Open Science initiatives. We anticipate the tool will be used by researchers and practitioners interested in wetland monitoring and management.

Inundation↗

Environmental impact statement for National Aeronautics and Space Administration Lewis Research Center, Cleveland, Ohio

The probable environmental impact and adverse effects of the Lewis Research Center are assessed. The Cleveland and Plum Brook facilities are briefly described. It is felt that the absence of harmful environmental impact from the Cleveland site is apparent, and the monitoring at the Plum Brook reactor facility shows the effectiveness of effluent controls. The probable adverse effects are considered for air, water, and noise pollution, and radioactive and hazardous waste storage and disposal; it is concluded that all emissions are maintained below Federal, and local standards. There are no appropriate alternatives to the operation of the Center, and no improvement in environmental quality would result from relocation. The relationship between local short-term productivity is briefly discussed. No adverse comment has been received from public agencies or private organizations or individuals.

Source record↗

INL Environmental Monitoring Plan (DOE/ID-11088 Rev. 5)

This plan provides a high-level summary of environmental monitoring performed by various organizations within and around the Idaho National Laboratory (INL) Site as required by U.S. Department of Energy (DOE) Order 435.1, Radioactive Waste Management, and DOE Order 458.1, Radiation Protection of the Public and the Environment, Guide DOE/EH-0173T, Environmental Regulatory Guide for Radiological Effluent Monitoring and Environmental Surveillance, and in accordance with 40 Code of Federal Regulations (CFR) 61, National Emission Standards for Hazardous Air Pollutants. The purpose of these orders is to 1) implement sound stewardship practices that protect the air, water, land, and other natural and cultural resources that may be impacted by DOE operations, and 2) to establish standards and requirements for the operations of DOE and DOE contractors with respect to protection of the environment and members of the public against undue risk from radiation. This plan describes the organizations responsible for conducting environmental monitoring across the INL Site, the rationale for monitoring, the types of media being monitored, where the monitoring is conducted, and where monitoring results can be obtained. Detailed monitoring procedures, program plans, or other governing documents used by contractors or agencies to implement requirements are referenced in this plan. This plan covers all planned monitoring and environmental surveillance. Non-routine activities such as special research studies and characterization of individual sites for environmental restoration are outside the scope of this plan.

54 ENVIRONMENTAL SCIENCES↗

Managing Toxicological Risks: The Legacy of Shuttle Operations

Space toxicology greatly matured as a result of research and operations associated with the Shuttle. Materials offgassing had been a manageable concern since the Apollo days, but we learned to pay careful attention to compounds that could escape containment, to combustion events, to toxic propellants, to overuse of utility compounds, and to microbial and human metabolites. We also learned that flying real-time hardware to monitor air pollutants was a pathway with unanticipated speed bumps. Each new orbiter was tested for any excess offgassing products that could pollute the air during flight. In the late 1990s toxicologists and safety experts developed a 5-level toxicity rating system to guide containment of toxic compounds. This system is now in use aboard the International Space Station (ISS). Several combustion events during Shuttle Mir and also during Shuttle free-flight impelled toxicologists to identify hardware capable of monitoring toxic products; however, rapid adaptation of the hardware for the unique conditions of spaceflight caused unexpected missteps. Current and planned combustion analyzers would be useful to commercial partners that wish to manage the risk of health effects from thermal events. Propellants received special attention during the Shuttle program because of the possibility of bringing them into the habitable volume on extravehicular activity suits. Monitors for the airlocks were developed to mitigate this risk. Utility materials, such as lubricants, posed limited toxicological problems because water was not recovered. One clearly documented case of microbial metabolites polluting the Shuttle atmosphere was noted, and this has implications for commercial flights and control of microbes. Finally, carbon dioxide, the major human metabolite, episodically presented air quality problems aboard Shuttle, especially when nominal air flows were obstructed. Commercial vehicles must maintain robust air circulation given the anticipated high density of human occupants.

James, John T.↗

Reversible parts-per-trillion-level detection of perfluorooctane sulfonic acid in tap water using field-effect transistor sensors

Widespread, persistent and toxic per- and polyfluoroalkyl substances (PFAS) pose a major threat to water systems and human health. Current detection methods are relatively expensive, slow and complex, underscoring the need for more accessible alternatives to meet increasingly stringent PFAS regulations. Here, in this study, we present an ultrasensitive sensing platform for perfluorooctane sulfonic acid detection in tap water with a reporting limit ( ~ 250 parts per quadrillion) lower than the US Environmental Protection Agency’s regulatory standard (4 parts per trillion), using a remote gate field-effect transistor featuring β-cyclodextrin (β-CD)-modified reduced graphene oxide as the sensing membrane. The sensor exhibits excellent selectivity against common inorganic ions, natural organic matter and select organic pollutants in tap water. The reversible and rapid response ( < 2 min) indicates the potential of remote gate field-effect transistor for continuous in-line monitoring. Mechanistic studies using quartz crystal microbalance and molecular dynamics simulations reveal key roles of analyte adsorption and charge properties in sensing performance and offer insights for designing more selective PFAS capture probes.

Wang, Yuqin [University of Chicago, IL (United Sta↗

Lawrence Livermore National Laboratory Annual Environmental Report 2019

The purposes of the Lawrence Livermore National Laboratory (LLNL) Environmental Report 2019 are to record LLNL's compliance with environmental standards and requirements, describe LLNL’s environmental protection and remediation programs, and present the results of environmental monitoring at the two LLNL sites—the Livermore Site and Site 300. The report is prepared for the U.S. Department of Energy (DOE) by LLNL’s Environmental Functional Area. Submittal of the report satisfies requirements under DOE Order 231.1B, “Environment, Safety and Health Reporting,” and DOE Order 458.1, “Radiation Protection of the Public and Environment.” The report begins with an executive summary, which provides the purpose of the report and an overview of LLNL’s compliance and monitoring results. The first three chapters provide background information: Chapter 1 is an overview of the location, meteorology, and hydrogeology of the two LLNL sites; Chapter 2 is a summary of LLNL’s compliance with environmental regulations; and Chapter 3 is a description of LLNL’s environmental programs with an emphasis on the Environmental Management System including pollution prevention. The majority of the report covers LLNL’s environmental monitoring programs and monitoring data for 2019: effluent and ambient air monitoring and dose assessment (Chapter 4); waters, including wastewater, storm water runoff, surface water, rain, and groundwater (Chapter 5); and terrestrial, including soil, sediment, vegetation, foodstuff, ambient radiation, and special status wildlife and plants (Chapter 6). The remaining two chapters discuss LLNL’s groundwater remediation program (Chapter 7), and quality assurance for the environmental monitoring programs (Chapter 8). Complete monitoring data, which are summarized in the body of the report, are provided in Appendix A.

54 ENVIRONMENTAL SCIENCES↗

Lawrence Livermore National Laboratory Environmental Report 2021

The purposes of the Lawrence Livermore National Laboratory Environmental Report 2021 are to record Lawrence Livermore National Laboratory’s (LLNL’s) compliance with environmental standards and requirements, describe LLNL’s environmental protection and remediation programs, and present the results of environmental monitoring at the two LLNL sites—the Livermore Site and Site 300. The report is prepared for the U.S. Department of Energy (DOE) by LLNL’s Environmental Functional Area. Submittal of the report satisfies requirements under DOE Order 231.1B, “Environment, Safety and Health Reporting,” and DOE Order 458.1, “Radiation Protection of the Public and Environment.” The report is distributed electronically and is available at https://saer.llnl.gov/, the website for the LLNL annual environmental report. Previous LLNL annual environmental reports beginning with 1994 are also on the website. Some references in the electronic report text are underlined, which indicates that they are clickable links. Clicking on one of these links will open the related document, data workbook, or website. Sampling location maps throughout this report were created using ArcGIS® software by Esri. The report begins with an executive summary, which provides the purpose of the report and an overview of LLNL’s compliance and monitoring results. The first three chapters provide background information: Chapter 1 is an overview of the location, meteorology, and hydrogeology of the two LLNL sites; Chapter 2 is a summary of LLNL’s compliance with environmental regulations; and Chapter 3 is a description of LLNL’s environmental programs with an emphasis on the Environmental Management System including pollution prevention. The majority of the report covers LLNL’s environmental monitoring programs and monitoring data for 2021: effluent and ambient air monitoring and dose assessment (Chapter 4); waters, including wastewater, storm water runoff, surface water, rain, and groundwater (Chapter 5); and terrestrial, including soil, sediment, vegetation, foodstuff, ambient radiation, and special status wildlife and plants (Chapter 6). The remaining two chapters discuss LLNL’s groundwater remediation program (Chapter 7), and quality assurance for the environmental monitoring programs (Chapter 8). Complete monitoring data, which are summarized in the body of the report, are provided in Appendix A. The report uses Système International units, consistent with the federal Metric Conversion Act of 1975 and Executive Order 12770, “Metric Usage in Federal Government Programs” (1991). For ease of comparison to environmental reports issued prior to 1991, dose values and many radiological measurements are given in both metric and U.S. customary units. A conversion table is provided in the glossary. The report is the responsibility of LLNL’s Environmental Functional Area. Monitoring data were obtained through the combined efforts of the Environmental Functional Area; Environmental Restoration Department; Physical and Life Sciences Environmental Monitoring Radiological Laboratory; and the Radiation Protection Functional Area.

54 ENVIRONMENTAL SCIENCES↗

Effect of oxidation on the release of multiple metals from industrially polluted sediments and synchrotron-based evidence of Cu–S dynamic association

Disposal operations for industrially polluted sediments are usually accompanied by disturbance and resuspension, which can induce metal remobilization and secondary pollution. Evaluating the risk of metal release under various redox conditions is fundamental for predicting contaminant mobilization and guiding remediation measures. An abandoned oxidation pond, Yanjia Lake, China, was selected as a typical industrially polluted site. Re-suspension experiments were carried out by mixing polluted sediments with lake water under oxic or anoxic conditions, then investigating the effect of oxidation conditions on the release of multiple metals. Metal concentrations and aqueous chemistry in the overlying water were monitored. Synchrotron-based methods, including X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS), were used to characterize oxidation states and coordination conditions of metals in sediments. The release of metals, including Cr, Co, Ni, Cu, Zn, Se, Mo, Sn, Cd, and Pb, was enhanced under oxic vs. anoxic conditions. The XANES analysis revealed that elevated Cr and Zn concentrations under oxic conditions likely resulted from the oxidation of Cr(III) and oxidizing dissolution of ZnS, respectively. K-edge Cu XANES, S XANES, and Cu EXAFS analyses reconstructed the Cu–S association, indicating that S-related oxidation promoted Cu release and Cu–O partly replaced Cu–S in the sediment after a 7-day oxic treatment. The release of most metals was promoted under oxic conditions, resulting from the oxidation of sulfides and metals as indicated by aqueous and synchrotron-based evidence. The risk of secondary pollution is greatly enhanced under oxic conditions, which suggests that measures should be taken to minimize the redox disturbance during sediment remediation. This information can guide the management of sediments in Yanjia Lake and other contaminated sites with similar properties.

54 ENVIRONMENTAL SCIENCES↗

Environment surveys

Environment applications are concerned with the quality, protection, and improvement of water, land, and air resources and, in particular, with the pollution of these resources caused by man and his works, as well as changes to the resources due to natural phenomena (for example, drought and floods). The broad NASA objectives related to the environment are directed toward the development and demonstration of the capability to monitor remotely and assess environmental conditions related to water quality, land and vegetation quality, wildlife resources, and general environment. The contributions of ERTS-1 to these subdiscipline areas are broadly summarized.

Greenwood, L. R.↗

High‐Resolution Mapping of Nitrogen Dioxide With TROPOMI: First Results and Validation Over the Canadian Oil Sands

TROPOspheric Monitoring Instrument (TROPOMI), on-board the Sentinel-5 Precursersatellite, is a nadir-viewing spectrometer measuring reflected sunlight in the ultraviolet, visible,near-infrared, and shortwave infrared. From these spectra several important air quality and climate-relatedatmospheric constituents are retrieved, including nitrogen dioxide (NO2) at unprecedented spatialresolution from a satellite platform. We present the first retrievals of TROPOMI NO2over the Canadian OilSands, contrasting them with observations from the Ozone Monitoring Instrument satellite instrument,and demonstrate TROPOMI's ability to resolve individual plumes and highlight its potential for derivingemissions from individual mining facilities. Further, the first TROPOMI NO2validation is presented,consisting of aircraft and surface in situ NO2observations, and ground-based remote-sensingmeasurements between March and May 2018. Our comparisons show that the TROPOMI NO2verticalcolumn densities are highly correlated with the aircraft and surface in situ NO2observations, and theground-based remote-sensing measurements with a low bias (15–30 %); this bias can be reduced byimproved air mass factors. Plain Language Summary: Nitrogen dioxide (NO2) is a pollutant that is linked to respiratoryhealth issues and has negative environmental impacts such as soil and water acidification. Near thesurface the most significant sources of NO2are fossil fuel combustion and biomass burning. With a recentlylaunched satellite instrument (TROPOspheric Monitoring Instrument [TROPOMI]), NO2can be measuredwith an unprecedented combination of accuracy, spatial coverage, and resolution. This work presents thefirst TROPOMI NO2measurements near the Canadian Oil Sands and shows that these measurements havean outstanding ability to detect NO2on a very high horizontal resolution that is unprecedented for satelliteNO2observations. Further, these satellite measurements are in excellent agreement with aircraft andground-based measurements.

TROPOspheric Monitoring Instrument (TROPOMI)↗

Tropospheric Emissions: Monitoring of Pollution (TEMPO)

TEMPO (Tropospheric Emissions: Monitoring of Pollution) was selected in 2012 by NASA as the first Earth Venture Instrument, for launch between 2018 and 2021. It will measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO observes from Mexico City, Cuba, and the Bahamas to the Canadian oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution (approximately 2.1 kilometers N/S by 4.4 kilometers E/W at 36.5 degrees N, 100 degrees W). TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry, as well as contributing to carbon cycle knowledge. Measurements are made hourly from geostationary (GEO) orbit, to capture the high variability present in the diurnal cycle of emissions and chemistry that are unobservable from current low-Earth orbit (LEO) satellites that measure once per day. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a commercial GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve ozone (O3), nitrogen dioxide (NO2), sulfur dioxide (SO2), formaldehyde (H2CO), glyoxal (C2H2O2), bromine monoxide (BrO), IO (iodine monoxide),water vapor, aerosols, cloud parameters, ultraviolet radiation, and foliage properties. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, substantially reducing uncertainty in air quality predictions. TEMPO quantifies and tracks the evolution of aerosol loading. It provides these near-real-time air quality products that will be made publicly available. TEMPO will launch at a prime time to be the North American component of the global geostationary constellation of pollution monitoring together with the European Sentinel-4 (S4) and Korean Geostationary Environment Monitoring Spectrometer (GEMS) instruments.

tropospheric measurement suite↗