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At least 91 records · Page 5

Evaluation of Bosch-Based Systems Using Non-Traditional Catalysts at Reduced Temperatures

Oxygen and water resupply make open loop atmosphere revitalization (AR) systems unfavorable for long-term missions beyond low Earth orbit. Crucial to closing the AR loop are carbon dioxide reduction systems with low mass and volume, minimal power requirements, and minimal consumables. For this purpose, NASA is exploring using Bosch-based systems. The Bosch process is favorable over state-of-the-art Sabatier-based processes due to complete loop closure. However, traditional operation of the Bosch required high reaction temperatures, high recycle rates, and significant consumables in the form of catalyst resupply due to carbon fouling. A number of configurations have been proposed for next-generation Bosch systems. First, alternative catalysts (catalysts other than steel wool) can be used in a traditional single-stage Bosch reactor to improve reaction kinetics and increase carbon packing density. Second, the Bosch reactor may be split into separate stages wherein the first reactor stage is dedicated to carbon monoxide and water formation via the reverse water-gas shift reaction and the second reactor stage is dedicated to carbon formation. A series system will enable maximum efficiency of both steps of the Bosch reaction, resulting in optimized operation and maximum carbon formation rate. This paper details the results of testing of both single-stage and two-stage Bosch systems with alternative catalysts at reduced temperatures. These results are compared to a traditional Bosch system operated with a steel wool catalyst.

Abney, Morgan B.

Design and development of the combustor inlet diffuser for the NASA/GE energy efficient engine

Results of an experimental investigation of the aerodynamic performance of a split duct annular combustor inlet diffuser system are presented. Several diffuser configurations were investigated in 3X-scale water table tests and the preferred design was evaluated in full-scale annular airflow model tests. Pressure recovery and flow losses were determined as a function of prediffuser inlet velocity profile, flow extraction at the prediffuser exit, and distribution of flow in the combustor. Inlet velocity profile and turbulence levels were found to have a pronounced effect on system performance. Flow extraction at the prediffuser exit was found to have little influence on system performance. Generally, the annular split duct diffuser system was found to satisfy the performance objectives for the engine.

Sabla, P. E.

Optimum retrieval of precipitable water fields from VAS and surface data

The use of VAS radiances and conventional surface data to determine the optimum resolution and accuracy of low-level precipitable water fields retrieved from geosynchronous satellite observations is examined. VAS retrievals of precipitated water (PW) are compared with various channel selections in the regression algorithm and with the split window algorithm. The split window algorithm and the linear regression algorithm are described. Consideration is given to the sounding-field-of-view (SFOV) resolution; the data reveal that the optimum resolution for the split window algorithm is at 15-60 km resolution, and 30-60 km SFOV resolution is optimal for the regression method. Statistics and images from PW retrieval experiments conducted on July 13, 1981 are presented and utilized to determine optimum channel selection. A fast contouring method for VAS sounding images is proposed.

Chesters, Dennis

Computation and use of the reflectivity at 3.75 micrometers from AVHRR thermal channels

Global study of land surface properties uses AVHRR channels 1 and 2, but channel 3 may be of interest, although its use requires preprocessing. It consists of both a reflective part and an emissive part, the former can be derived from T3, T4 and T5. Since the water vapor affects channel 3, its content is retrieved from the channel 4 and 5 using the split window technique. A formula of reflective part retrieval at 3.75 micrometers is tested in the case of sunglint observations where the emissivities of channels 4 and 5 can be set to the unity. The formula is adapted and validated to land surface using the FIFE-87 data set. Preliminary applications of the reflectance at 3.75 micrometers to the studies of surface properties retrieval, aerosol retrieval over land, and desertic aerosol retrieval, are addressed.

Roger, J. C.

Submillimeter heterodyne spectroscopy and remote sensing of the upper atmosphere

Submillimeter-wavelength heterodyne spectroscopy by microwave limb sounding (MLS) from orbiting satellite is a measurement technique for studying Earth's stratosphere, mesosphere and lowerr thermosphere on a global scale. Development and deployment of such tools are timely, as stratospheric ozone shileds life from solar ultraviolet radiation but is depleted by pollution from industrial activities. MLS experiments on NASA's Upper Atmosphere Research Satellite (UARS) and Earth Observing System (EOS) are now being developed and implementend for global monitoring. Atmospheric thermal-emission spectra at millimeter and submillimeter wave-lengths are measured as the instrument field of view (FOV) is scanned through the limb from above. Atmospheric profiles of molecular abundances, temperature, pressure, wind and magnetic field can be determined from the measured emission spectra. Intensity of the emission can provide abundance and temperature. Measured linewidths, and emission from temperature-insensitive O2 lines, can provide pressure. Differentitaion of measured pressure with repsect ot measured height differential (obtaiend from the instrument FOV scan encoder) can also provide temperature through atmospheric hydrostatic equilibrium (which relates temperature to pressure and height differential). Doppler shifts of spectral lines can provide wind, and Zeeman splitting of the magnetic-dipole lines of O2 can provide magnetic field.

Waters, J. W.

Physical and chemical weathering

Physical and chemical weathering processes that might be important on Mars are reviewed, and the limited observations, including relevant Viking results and laboratory simulations, are summarized. Physical weathering may have included rock splitting through growth of ice, salt or secondary silicate crystals in voids. Chemical weathering probably involved reactions of minerals with water, oxygen, and carbon dioxide, although predicted products vary sensitively with the abundance and physical form postulated for the water. On the basis of kinetics data for hydration of rock glass on earth, the fate of weathering-rind formation on glass-bearing Martian volcanic rocks is tentatively estimated to have been on the order of 0.1 to 4.5 cm/Gyr; lower rates would be expected for crystalline rocks.

Gooding, James L.

Scramjet Performance Assessment Using Water Absorption Diagnostics (U)

Simultaneous multiple path measurements of temperature and H2O concentration will be presented for the AIMHYE test entries in the NASA Ames 16-Inch Shock Tunnel. Monitoring the progress of high temperature chemical reactions that define scramjet combustor efficiencies is a task uniquely suited to nonintrusive optical diagnostics. One application strategy to overcome the many challenges and limitations of nonintrusive measurements is to use laser absorption spectroscopy coupled with optical fibers. Absorption spectroscopic techniques with rapidly tunable lasers are capable of making simultaneous measurements of mole fraction, temperature, pressure, and velocity. The scramjet water absorption diagnostic was used to measure combustor efficiency and was compared to thrust measurements using a nozzle force balance and integrated nozzle pressures to develop a direct technique for evaluating integrated scramjet performance. Tests were initially performed with a diode laser tuning over a water absorption feature at 1391.7 nm. A second diode laser later became available at a wavelength near 1343.3 nm covering an additional water absorption feature and was incorporated in the system for a two-wavelength technique. Both temperature and mole fraction can be inferred from the lineshape analysis using this approach. Additional high temperature spectroscopy research was conducted to reduce uncertainties in the scramjet application. The lasers are optical fiber coupled to ports at the combustor exit and in the nozzle region. The output from the two diode lasers were combined in a single fiber, and the resultant two-wavelength beam was subsequently split into four legs. Each leg was directed through 60 meters of optical fiber to four combustor exit locations for measurement of beam intensity after absorption by the water within the flow. Absorption results will be compared to 1D combustor analysis using RJPA and nozzle CFD computations as well as to data from a nozzle metric balance measuring thrust and integrated pressure measurements along the length of the nozzle. Assessment of its value as a combustor performance evaluation tool will be conducted.

Cavolowsky, John A.

Investigation of isovaline enantiomeric excesses in CM meteorites using liquid chromatography time of flight mass spectrometry

The enantiomeric abundances of the alpha-dialkyl amino acid isovaline were measured in the CM2 meteorites Murchison and LEW 90500 using a new liquid chromatography-time of flight-mass spectrometry (LC-ToF-MS) technique coupled with OPA/NAC derivatization and UV fluorescence detection. Previous analyses of Murchison have shown that L-enantiomeric excesses of isovaline range from 0 to 15.2% with significant variation between meteorite fragments [1]. For this study, hot water extracts of interior fragments (> 2 cm from fusion crust) of the Murchison (USNM 6650.2, mass 6 g) and LEW 90500 (split 69, parent 1, mass 5 g) carbonaceous meteorites were analyzed. Enantiomeric excesses were measured using the single ion LC-ToF-MS trace for the OPA/NAC derivative of isovaline at d z 393.15 (Fig. 1). L-isovaline excesses in these meteorite samples ranged from 18.9 to 20.5% for Murchison and -0.5 to 3.0% for LEW 90500. The measured values for Murchison are the largest enantiomeric excesses for isovaline reported to date. The enantiomeric excesses of L-isovaline cannot be the result of interference from other C5 amino acid isomers present in the meteorites or terrestrial contamination from the landing site environments. The L-isovaline excesses in Murchison are inconsistent with the synthesis of all of the isovaline by the Strecker-cyanohydrin pathway on the CM meteorite parent body. The mechanism(s) for the formation of the enantiomeric asymmetry in isovaline in Murchison are currently unknown and it is not clear how the asymmetry of alpha-dialkyl amino acids could be transferred to the a-hydrogen protein amino acids common in all life on Earth today.

Glavin, Daniel P.

Diagnosing convective instability using VAS data

The utility of combining visible and various infrared images from the VAS to produce a forecasting tool, that can be available on a near real time basis, to predict severe weather development is shown. Areas where dry air in the midtroposphere overlays substantial moisture at low levels are used to diagnose mesoscale regions that have the potential for being convectively unstable before the onset of severe convection. Specifically, 6.7 micron water vapor imagery, used for isolating regions of substantial midlevel dryness, are combined with images of low level clouds or with split-window low level moisture images to delineate regions that have the potential for convective instability. In areas where scattered low level clouds are present, computer generated, color image combinations are used to isolate those warm, low level clouds that are in potential convectively unstable environments from clouds that exist under a deeply moist atmosphere. In clear regions, the split window technique is used for delineating areas of substantial boundary layer moisture. These images are again computer overlayed by the midlevel dryness to produce a color coded image of potential convective instability.

Petersen, R. A.

NASA Tech Briefs, February 2005

Topics discussed include: Instrumentation for Sensitive Gas Measurements; Apparatus for Testing Flat Specimens of Thermal Insulation; Quadrupole Ion Mass Spectrometer for Masses of 2 to 50 Da; Miniature Laser Doppler Velocimeter for Measuring Wall Shear; Coherent Laser Instrument Would Measure Range and Velocity; Printed Microinductors for Flexible Substrates; Digital Receiver for Microwave Radiometry; Printed Antennas Made Reconfigurable by Use of MEMS Switches; Traffic-Light-Preemption Vehicle-Transponder Software Module; Intersection-Controller Software Module; Central-Monitor Software Module; Estimating Effects of Multipath Propagation on GPS Signals; Parallel Adaptive Mesh Refinement Library; Predicting Noise From Aircraft Turbine-Engine Combustors; Generating Animated Displays of Spacecraft Orbits; Diagnosis and Prognosis of Weapon Systems; Training Software in Artificial-Intelligence Computing Techniques; APGEN Version 5.0; Single-Command Approach and Instrument Placement by a Robot on a Target; Three-Dimensional Audio Client Library; Isogrid Membranes for Precise, Singly Curved Reflectors; Nickel-Tin Electrode Materials for Nonaqueous Li-Ion Cells; Photocatalytic Coats in Glass Drinking-Water Bottles; Fast Laser Shutters With Low Vibratory Disturbances; Series-Connected Buck Boost Regulators; Space Physics Data Facility Web Services; Split-Resonator, Integrated-Post Vibratory Microgyroscope; Blended Buffet-Load-Alleviation System for Fighter Airplane; Gifford-McMahon/Joule-Thomson Refrigerator Cools to 2.5 K; High-Temperature, High-Load-Capacity Radial Magnetic Bearing; Fabrication of Spherical Reflectors in Outer Space; Automated Rapid Prototyping of 3D Ceramic Parts; Tissue Engineering Using Transfected Growth-Factor Genes; Automation of Vapor-Diffusion Growth of Protein Crystals; Atom Skimmers and Atom Lasers Utilizing Them; Gears Based on Carbon Nanotubes; Patched Off-Axis Bending/Twisting Actuators for Thin Mirrors; and Improving Control in a Joule-Thomson Refrigerator.

Source record

Discovery of coesite and shocked quartz associated with the upper Eocene cpx spherule layer

At least two major impact ejecta layers have been discovered in upper Eocene strata. The upper layer is the North American microtektite layer. lt consists tektite fragments, microtektites, and shocked mineral grains (e.g., quartz and feldspar with multiple sets of PDFs, coesite and reidite (a high-pressure polymorph of zircon)). The slightly older layer contains clinopyroxene-bearing (cpx) spherules and microtektites associated with an Ir anomaly. The North American tektite layer may be derived from the Chesapeake Bay impact structure, and the cpx spherule layer may from the Popigai impact crater. A cpx spherule layer associated with a positive Ir anomaly was recently found at ODP Site 709, western Indian Ocean. A large sample (Hole 709C, core 31, section 4, 145-150 cm), originally used for a study of interstitial water by shipboard scientists, was acquired for the purpose of recovering a large number of spherules for various petrographic and geochemical studies. A split of the sample (50.35 g) was disaggregated and wet-sieved. More than 17,000 cpx spherules and several hundred microtektites (larger than 125 microns) were recovered from the sample. Rare white opaque grains were observed in the 125-250 micron size fraction after removal of the carbonate component using dilute HCI. Seven of the white opaque grains were X-rayed using a Gandolfi camera and six were found to be coesite (probably mixed with lechatelierite). Eighty translucent colorless grains from the 63-125 micron size fraction were studied with a petrographic microscope. Four of the grains exhibit one to two sets of planar deformation features (PDFs). The only other possible known occurrence of shocked minerals associated with the cpx spherule layer is at Massignano, Italy, where pancake-shaped clay spherules (thought to be diagenetically altered cpx spherules are associated with a positive Ir anomaly and Ni- rich spinel crystals. Shocked quartz grains with multiple sets of PDFs also occur at this site. Until now, unmelted impact ejecta have not been found associated with the cpx spherules at any of the other 20 sites around the world and this is the first time that coesite has been found associated with the cpx spherule layer. The discovery of coesite and shocked quartz associated with the cpx spherules at Site 709 in Indian Ocean is further evidence for the impact origin of the cpx spherule layer. We hope that future discovery of other unmelted minerals from this sample may provide materials to establish constraints on the provenance of this late Eocene ejecta.

Liu, S.

Characterization of Potential Springs in the Lower Colorado Desert of Southern California using Satellite Radar and Landsat Time Series Analysis

Renewable energy development in southern California is receiving increasing attention due to potential impacts on wildlife habitats and water sources. This study was designed to quantify and map, for the first time, sub-surface water sources from springs in the Lower Colorado Desert area of southern California using satellite radar data and 30 years of Landsat satellite image data. Synthetic Aperture Radar (SAR) data was used to identify sub-surface water sources not already documented as springs or seeps in the National Hydrography Database. Landsat imagery starting in 1985 was used to characterize vegetation growth patterns at these suspected spring locations detected from SAR analysis. Results showed a total of 104 potential spring locations across the Lower Colorado Desert study area, 19 of which were detected within Solar Energy Zone (SEZ) development boundaries, roughly evenly split between Riverside East and Imperial East, and 13 of which (both inside and outside SEZs) showed relatively high green vegetation index values over the period of 1985 to 2015 that would depend on non-precipitation water sources associated with active springs.

DRECP

Nutrient management effects on sweetpotato genotypes under controlled environment

Sweetpotato is one of several crops recommended by National Aeronautics and Space Administration (NASA) for bioregenerative life support studies. One of the objectives of the Tuskegee University NASA Center is to optimize growth conditions for adaptability of sweetpotatoes for closed bioregenerative systems. The role of nutrient solution management as it impacts yield has been one of the major thrusts in these studies. Nutrient solution management protocol currently used consists of a modified half Hoagland solution that is changed at 14-day intervals. Reservoirs are refilled with deionized water if the volume of the nutrient solution was reduced to 8 liters or less before the time of solution change. There is the need to recycle and replenish nutrient solution during crop growth, rather than discard at 14 day intervals as previously done, in order to reduce waste. Experiments were conducted in an environmental growth room to examine the effects of container size on the growth of several sweetpotato genotypes grown under a nutrient replenishment protocol. Plants were grown from vine cuttings of 15cm length and were planted in 0.15 x 0.15 x 1.2m growth channels using a closed nutrient film technique system. Nutrient was supplied in a modified half strength Hoagland's solution with a 1:2.4 N:K ratio. Nutrient replenishment protocol consisted of daily water replenishment to a constant volume of 30.4 liters in the small containers and 273.6 liters in the large container. Nutrients were replenished as needed when the EC of the nutrient solution fell below 1200 mhos/cm. The experimental design used was a split-plot with the main plot being container size and genotypes as the subplot. Nine sweetpotato genotypes were evaluated. Results showed no effect of nutrient solution container size on storage root yield, foliage fresh and dry mass, leaf area or vine length. However, plants grown using the large nutrient solution container accumulated more storage root dry mass than those with the small containers. Although plants grown with the smaller containers showed greater water uptake, plant nutrient uptake was lower than with the larger container. All genotypes evaluated showed variation in their responses to all parameters measured.

Solanaceae/genetics/growth & development

Advanced Raman water vapor lidar

Water vapor and aerosols are important atmospheric constituents. Knowledge of the structure of water vapor is important in understanding convective development, atmospheric stability, the interaction of the atmosphere with the surface, and energy feedback mechanisms and how they relate to global warming calculations. The Raman Lidar group at the NASA Goddard Space Flight Center (GSFC) developed an advanced Raman Lidar for use in measuring water vapor and aerosols in the earth's atmosphere. Drawing on the experience gained through the development and use of our previous Nd:YAG based system, we have developed a completely new lidar system which uses a XeF excimer laser and a large scanning mirror. The additional power of the excimer and the considerably improved optical throughput of the system have resulted in approximately a factor of 25 improvement in system performance for nighttime measurements. Every component of the current system has new design concepts incorporated. The lidar system consists of two mobile trailers; the first (13m x 2.4m) houses the lidar instrument, the other (9.75m x 2.4m) is for system control, realtime data display, and analysis. The laser transmitter is a Lambda Physik LPX 240 iCC operating at 400 Hz with a XeF gas mixture (351 nm). The telescope is a .75m horizontally mounted Dall-Kirkham system which is bore sited with a .8m x 1.1m elliptical flat which has a full 180 degree scan capability - horizon to horizon within a plane perpendicular to the long axis of the trailer. The telescope and scan mirror assembly are mounted on a 3.65m x .9m optical table which deploys out the rear of the trailer through the use of a motor driven slide rail system. The Raman returns from water vapor (403 nm), nitrogen (383 nm) and oxygen (372 nm) are measured in addition to the direct Rayleigh/Mie backscatter (351). The signal from each of these is split at about a 5/95 ratio between two photomultiplier detectors. The 5 percent detector is used for measurements below about 4.0 km, while the 95 percent detector provides the information above this level.

Whiteman, David N.

NSSFC: VAS assessment activities

Vertical atmospheric sounder data were evaluated. Basic work thus far has been directed toward evaluating, over the in near real time to determine the instrument's ability to detect regions with potential for severe storm development. A real time hourly water vapor loop 16 hours daily provides data to monitor position and trends of mid and upper level meteorological features. Because water vapor is more uniform than clouds, the water vapor images improve the ability to monitor certain atmospheric features such as jets, shortwaves, vorticity centers, and subsidence zones. Additional products to be evaluated include a version of the split window developed by NASA and cloud drift winds generated from three hourly sequenced CO2 VAS channels. A technique also under evaluation at NSSFC provides hail size potential based on VAS sounding data. Part of a planned upgrade to CSIS linking the 9600 baud phone line to one of the CSIS CPUs to allow access to VAS data via CSIS.

Anthony, R. W.

A Vertically Lagrangian Finite-Volume Dynamical Core for Global Models

A finite-volume dynamical core with a terrain-following Lagrangian control-volume discretization is described. The vertically Lagrangian discretization reduces the dimensionality of the physical problem from three to two with the resulting dynamical system closely resembling that of the shallow water dynamical system. The 2D horizontal-to-Lagrangian-surface transport and dynamical processes are then discretized using the genuinely conservative flux-form semi-Lagrangian algorithm. Time marching is split- explicit, with large-time-step for scalar transport, and small fractional time step for the Lagrangian dynamics, which permits the accurate propagation of fast waves. A mass, momentum, and total energy conserving algorithm is developed for mapping the state variables periodically from the floating Lagrangian control-volume to an Eulerian terrain-following coordinate for dealing with physical parameterizations and to prevent severe distortion of the Lagrangian surfaces. Deterministic baroclinic wave growth tests and long-term integrations using the Held-Suarez forcing are presented. Impact of the monotonicity constraint is discussed.

Lin, Shian-Jiann

The Compressive Behavior of Isocyanate-crosslinked Silica Aerogel at High Strain Rates

Aerogels are low-density, highly nano-porous materials. Their engineering applications are limited due to their brittleness and hydrophilicity. Recently, a strong lightweight crosslinked silica aerogel has been developed by encapsulating the skeletal framework of amine-modified silica aerogels with polyureas derived by isocyanate. The mesoporous structure of the underlying silica framework is preserved through conformal polymer coating, and the thermal conductivity remains low. Characterization has been conducted on the thermal, physical properties and the mechanical properties under quasi-static loading conditions. In this paper, we present results on the dynamic compressive behavior of the crosslinked silica aerogel (CSA) using a split Hopkinson pressure bar (SHPB). A new tubing pulse shaper was employed to help reach the dynamic stress equilibrium and constant strain rate. The stress-strain relationship was determined at high strain rates within 114-4386/s. The effects of strain rate, density, specimen thickness and water absorption on the dynamic behavior of the CSA were investigated through a series of dynamic experiments. The Young's moduli (or 0.2% offset compressive yield strengths) at a strain rate approx.350/s were determined as 10.96/2.08, 159.5/6.75, 192.2/7.68, 304.6/11.46, 407.0/20.91 and 640.5/30.47 MPa for CSA with densities 0.205, 0.454, 0.492, 0.551,0.628 and 0.731 g/cu cm, respectively. The deformation and failure behaviors of a native silica aerogel with density (0.472 g/cu cm ), approximately the same as a typical CSA sample were observed with a high speed digital camera. Digital image correlation technique was used to determine the surface strains through a series of images acquired using high speed photography. The relative uniform axial deformation indicated that localized compaction did not occur at a compressive strain level of approx.17%, suggesting most likely failure mechanism at high strain rate to be different from that under quasi-static loading condition. The Poisson s ratio was determined to be 0.162 in nonlinear regime under high strain rates. CSA samples failed generally by splitting, but were much more ductile than native silica aerogels.

Luo, H.

Ice Cloud Properties in Ice-Over-Water Cloud Systems Using TRMM VIRS and TMI Data

A multi-layered cloud retrieval system (MCRS) is updated and used to estimate ice water path in maritime ice-over-water clouds using Visible and Infrared Scanner (VIRS) and TRMM Microwave Imager (TMI) measurements from the Tropical Rainfall Measuring Mission spacecraft between January and August 1998. Lookup tables of top-of-atmosphere 0.65- m reflectance are developed for ice-over-water cloud systems using radiative transfer calculations with various combinations of ice-over-water cloud layers. The liquid and ice water paths, LWP and IWP, respectively, are determined with the MCRS using these lookup tables with a combination of microwave (MW), visible (VIS), and infrared (IR) data. LWP, determined directly from the TMI MW data, is used to define the lower-level cloud properties to select the proper lookup table. The properties of the upper-level ice clouds, such as optical depth and effective size, are then derived using the Visible Infrared Solar-infrared Split-window Technique (VISST), which matches the VIRS IR, 3.9- m, and VIS data to the multilayer-cloud lookup table reflectances and a set of emittance parameterizations. Initial comparisons with surface-based radar retrievals suggest that this enhanced MCRS can significantly improve the accuracy and decrease the IWP in overlapped clouds by 42% and 13% compared to using the single-layer VISST and an earlier simplified MW-VIS-IR (MVI) differencing method, respectively, for ice-over-water cloud systems. The tropical distribution of ice-over-water clouds is the same as derived earlier from combined TMI and VIRS data, but the new values of IWP and optical depth are slightly larger than the older MVI values, and exceed those of single-layered layered clouds by 7% and 11%, respectively. The mean IWP from the MCRS is 8-14% greater than that retrieved from radar retrievals of overlapped clouds over two surface sites and the standard deviations of the differences are similar to those for single-layered clouds. Examples of a method for applying the MCRS over land without microwave data yield similar differences with the surface retrievals. By combining the MCRS with other techniques that focus primarily on optically thin cirrus over low water clouds, it will be possible to more fully assess the IWP in all conditions over ocean except for precipitating systems.

Minnis, Patrick