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NASA NTRS1992

Gastrointestinal citrate absorption in nephrolithiasis

Gastrointestinal absorption of citrate was measured in stone patients with idiopathic hypocitraturia to determine if citrate malabsorption could account for low urinary citrate. Citrate absorption was measured directly from recovery of orally administered potassium citrate (40 mEq.) in the intestinal lavage fluid, using an intestinal washout technique. In 7 stone patients citrate absorption, serum citrate levels, peak citrate concentration in serum and area under the curve were not significantly different from those of 7 normal subjects. Citrate absorption was rapid and efficient in both groups, with 96 to 98% absorbed within 3 hours. The absorption of citrate was less efficient from a tablet preparation of potassium citrate than from a liquid preparation, probably due to a delayed release of citrate from wax matrix. However, citrate absorption from solid potassium citrate was still high at 91%, compared to 98% for a liquid preparation. Thus, hypocitraturia is unlikely to be due to an impaired gastrointestinal absorption of citrate in stone patients without overt bowel disease.

Non-NASA Center↗

NASA NTRS1973

Fine structure in the optical-absorption edge of silicon.

Investigation of the dependence of the photocurrent generated in silicon p-n junctions on the energy of the incident photons to obtain details concerning the fine structure in the indirect optical-absorption edge of silicon. It is found that at room temperature there are three prominent thresholds in the absorption tail. The first, which is not too well defined, occurs at 0.91 eV, the second at 0.99 eV, and the third at 1.026 eV. The dependence of the absorption coefficient on the photon energy following the latter two thresholds is found to differ from that found by Mcfarlane et al. (1958). The threshold energies and temperature dependence of the absorption coefficient suggest that two- and three-phonon processes give rise to the absorption tail. In the transverse-optical phonon-absorption region more structure is found in the absorption coefficient than is accounted for by the theory.

Anagnostopoulos, C.↗

NASA NTRS1978

The line-locking hypothesis, absorption by intervening galaxies, and the z = 1.95 peak in redshifts

The controversy over whether the absorption spectrum in QSOs is intrinsic or extrinsic is approached with attention to the peak of redshifts at z = 1.95. Also considered are the line-locking and the intervening galaxy hypotheses. The line locking hypothesis is based on observations that certain ratios found in absorption line QSOs are preferred, and leads inevitably to the conclusion that the absorption line systems are intrinsic. The intervening galaxy hypothesis is based on absorption redshifts resulting from given absorption cross-sections of galactic clusters and the intergalactic medium, and would lead to the theoretical conclusion that most QSOs show strong absorption, a conclusion which is not supported by empirical data. The 1.95 peak, on the other hand, is most probably an intrinsic property of QSOs. The peak is enhanced by redshift, and it is noted that both an emission and an absorption redshift peak are seen at 1.95.

Burbidge, G.↗

NASA NTRS1980

Absorption-line spectra of quasi-stellar objects - Physical properties of absorbing gas

The optical absorption lines of quasars are examined, and implications of the lines for the physical properties of the absorbing gas are discussed. Consideration is given to the characteristics of broad absorption lines observed in such quasars as PHL 5200 and Q 1246-057 and of the more prevalent extremely narrow lines, with discussion of the presumed physical conditions in the absorbing gas and the distribution of absorption-line redshifts with respect to emission-line redshifts. It is pointed out that absorption features become more prevalent in quasar spectra with emission redshifts greater than 2.3, and results of studies of column densities and abundances and of the presence of absorption in radio compact quasars are indicated. Research programs currently under way are then described, including a search for the distribution of absorption lines in a fixed wavelength range less than the Lyman alpha emission wavelength, study of low absorption-redshift systems, a study of individual objects such as the quasar pair 1548+114a and b, and various theoretical investigations.

Burbidge, E. M.↗

NASA NTRS1985

Ultraviolet interstellar absorption toward stars in the Small Magellanic Cloud. IV - Highly ionized gas associated with the Small Magellanic Cloud

High-dispersion International Ultraviolet Explorer satellite spectra of seven stars in the Small Magellanic Cloud (SMC) are examined to study the properties of interstellar C IV and Si IV absorption in the SMC. Absorption by C IV or Si IV or both is found near 160 km/s for all the stars. The velocity and the relative C IV and Si IV strengths suggest UV-photoionized nebular gas as the origin of this absorption. In addition, the stars show absorption by C IV and, sometimes, Si IV in the velocity range 100-130 km/s. This velocity is 30-60 km/s more negative than that expected for normal nebular gas, and the relative C IV and Si IV strengths indicate an ionization source other than stellar UV photoionization by normal Population I stars. Possible global origins are considered for this absorption, including a hot phase of the SMC interstellar medium and a circum-SMC distribution of highly ionized gas. The only detection of interstellar N V toward a SMC star is for HD 5980. The line is broad, possibly complex, and spans the velocity range of the nebular absorption and the 100-130 km/s absorption.

Fitzpatrick, E. L.↗

NASA NTRS1990

Deconvolution of mineral absorption bands - An improved approach

Although visible and near IR reflectance spectra contain absorption bands that are characteristic of the composition and structure of the absorbing species, deconvolving a complex spectrum is nontrivial. An improved approach to spectral deconvolution is presented that accurately represents absorption bands as discrete mathematical distributions and resolves composite absorption features into individual absorption bands. The frequently used Gaussian model of absorption bands is shown to be inappropriate for the Fe(2+) electronic transition absorptions in pyroxene spectra. A modified Gaussian model is derived using a power law relationship of energy to average bond length. The modified Gaussian model is shown to provide an objective and consistent tool for deconvolving individual absorption bands in the more complex orthopyroxene, clinopyroxene, pyroxene mixtures, and olivine spectra.

Sunshine, Jessica M.↗

NASA NTRS1990

Radio line and continuum observations of quasar-galaxy pairs and the origin of low reshift quasar absorption line systems

There are a number of known quasars for which our line of sight to the high redshift quasar passes within a few Holmberg radii of a low redshift galaxy. In a few of these cases, spectra of the quasar reveal absorption by gas associated with the low redshift galaxy. A number of these pairs imply absorption by gas which lies well outside the optical disk of the associated galaxy, leading to models of galaxies with 'halos' or 'disks' of gas extending to large radii. The authors present observations of 4 such pairs. In three of the four cases, they find that the associated galaxy is highly disturbed, typically due to a gravitational interaction with a companion galaxy, while in the fourth case the absorption can be explained by clouds in the optical disk of the associated galaxy. They are led to an alternative hypothesis concerning the origin of the low redshift absorption line systems: the absorption is by gas clouds which have been gravitationally stripped from the associated galaxy. These galaxies are rapidly evolving, and should not be used as examples of absorption by clouds in halos of field spirals. The authors conclude by considering the role extended gas in interacting systems plays in the origin of higher redshift quasar absorption line systems.

Carilli, C. L.↗

NASA NTRS1992

Detection of Ca II absorption in the QSO 0958 + 559 due to a Heiles shell in NGC 3079

Optical observations of the QSO 0958 + 559 and the nearby, edge-on spiral galaxy NGC 3079 are presented. Spectra of the QSO show Ca II absorption lines due to extended gas in NGC 3079; the Na absorption lines due to NGC 3079 are not detected. An unrelated higher redshift absorption system at 1.1327 is also present in the QSO spectrum. The QSO sightline shines directly through a Heiles shell. The coincidence in position coupled with the agreement between the Ca II absorption and shell emission velocities demonstrates that the QSO absorption system is due to gas in this shell. This system is discussed in comparison with the six other low-redshift QSO-galaxy pair absorption systems, and the influence of Heiles shells on the interpretation of higher redshift QSO absorption systems is addressed.

Womble, Donna S.↗

NASA NTRS1993

Theoretical calculations on the electron absorption spectra of selected Polycyclic Aromatic Hydrocarbons (PAH) and derivatives

As a theoretical component of the joint effort with the laboratory of Dr. Lou Allamandola to search for potential candidates for interstellar organic carbon compound that are responsible for the visible diffuse interstellar absorption bands (DIB's), quantum mechanical calculations were performed on the electron absorption spectra of selected polycyclic aromatic hydrocarbons (PAH) and derivatives. In the completed project, 15 different species of naphthalene, its hydrogen abstraction and addition derivatives, and corresponding cations and anions were studied. Using semiempirical quantum mechanical method INDO/S, the ground electronic state of each species was evaluated with restricted Hartree-Fock scheme and limited configuration interaction. The lowest energy spin state for each species was used for electron absorption calculations. Results indicate that these calculations are accurate enough to reproduce the spectra of naphthalene cation and anion observed in neon matrix. The spectral pattern of the hydrogen abstraction and addition derivatives predicted based on these results indicate that the electron configuration of the pi orbitals of these species is the dominant determinant. A combined list of 19 absorptions calculated from 4500 A to 10,400 A were compiled and suggested as potential candidates that are relevant for the DIB's absorptions. Continued studies on pyrene and derivatives revealed the ground state symmetries and multiplicities of its neutral, anionic, and cationic species. Spectral calculations show that the cation (B(sub 3g)-2) and the anion (A(sub u)-2) are more likely to have low energy absorptions in the regions between 10 kK and 20 kK, similar to naphthalene. These absorptions, together with those to be determined from the hydrogen abstraction and addition derivatives of pyrene, can be used to provide additional candidates and suggest experimental work in the search for interstellar compounds that are responsible for DIB's.

Du, Ping↗

NASA NTRS1993

Clear evidence for the presence of O VI absorption in QSO metal systems

We have detected O VI 1031.93 A, 1037.62 A doublet absorption in a composite QSO spectrum formed from a large number of intervening C IV absorption systems. The detections constitute the first firm evidence for the presence of O VI in intervening QSO metal absorption systems. The equivalent width of the detected O VI absorption implies an O VI column density N(O VI) not less than 2.8 x 10 exp 14/sq cm. This value, together with the nondetection of the N V 1238.82 A, 1242.80 A doublet absorption, suggests that N(O VI)/N(N V) not less than 4.4. For collisionally ionized gas with a solar O to N abundance ratio in thermal equilibrium the above ratio requires a temperature T not less than 2.5 x 10 exp 5 K. It is found that C IV systems which show low-ionization species and those which do not both have associated O VI absorption, suggesting that O VI is probably present in all C IV systems. We also find that C IV systems which show low-ionization species on average have stronger high-ionization absorption lines than those which do not. A simple interpretation was given to explain this trend.

Lu, Limin↗

NASA NTRS1993

Damped Lyman-alpha absorption by disk galaxies with large redshifts. IV - More intermediate-resolution spectroscopy

Intermediate-resolution spectra of six QSOs exhibiting seven Ly-alpha absorption troughs that are candidates for damped Ly-alpha absorption lines are presented. The metal content of the confirmed damped systems is investigated by examining the metal-line velocity profiles, and by performing curve-of-growth analyses for four of the six confirmed damped systems. The low-ionization lines associated with the z(metals) = 2.0399 damped system toward Q0458-020 have velocity widths up to 10 times wider than the width of the 21-cm absorption feature found at the same redshift. Since the 21-cm absorption arises in a low velocity dispersion layer of H I that extends more than 8/h kpc transverse to the line of sight, the H I absorption cannot arise from the same clouds responsible for the bulk of the metal-line absorption. This is strong evidence for a two-component model consisting of high column density 'quiescent' gas which gives rise to damped Ly-alpha and 21-cm absorption, and low column density 'turbulent' gas which dominates equivalent widths of saturated metal lines.

Wolfe, Arthur M.↗

NASA NTRS1994

A model predicting the evolution of ice particle size spectra and radiative properties of cirrus clouds. Part 2: Dependence of absorption and extinction on ice crystal morphology

This study builds upon the microphysical modeling described in Part 1 by deriving formulations for the extinction and absorption coefficients in terms of the size distribution parameters predicted from the micro-physical model. The optical depth and single scatter albedo of a cirrus cloud can then be determined, which, along with the asymmetry parameter, are the input parameters needed by cloud radiation models. Through the use of anomalous diffraction theory, analytical expressions were developed describing the absorption and extinction coefficients and the single scatter albedo as functions of size distribution parameters, ice crystal shapes (or habits), wavelength, and refractive index. The extinction coefficient was formulated in terms of the projected area of the size distribution, while the absorption coefficient was formulated in terms of both the projected area and mass of the size distribution. These properties were formulated as explicit functions of ice crystal geometry and were not based on an 'effective radius.' Based on simulations of the second cirrus case study described in Part 1, absorption coefficients predicted in the near infrared for hexagonal columns and rosettes were up to 47% and 71% lower, respectively, than absorption coefficients predicted by using equivalent area spheres. This resulted in single scatter albedos in the near-infrared that were considerably greater than those predicted by the equivalent area sphere method. Reflectances in this region should therefore be underestimated using the equivalent area sphere approach. Cloud optical depth was found to depend on ice crystal habit. When the simulated cirrus cloud contained only bullet rosettes, the optical depth was 142% greater than when the cloud contained only hexagonal columns. This increase produced a doubling in cloud albedo. In the near-infrared (IR), the single scatter albedo also exhibited a significant dependence on ice crystal habit. More research is needed on the geometrical properties of ice crystals before the influence of ice crystal shape on cirrus radiative properties can be adequately understood. This study provides a way of coupling the radiative properties of absorption, extinction, and single scatter albedo to the microphysical properties of cirrus clouds. The dependence of extinction and absorption on ice crystal shape was not just due to geometrical differences between crystal types, but was also due to the effect these differences had on the evolution of ice particle size spectra. The ice particle growth model in Part 1 and the radiative properties treated here are based on analytical formulations, and thus represent a computationally efficient means of modeling the microphysical and radiative properties of cirrus clouds.

Mitchell, David L.↗

NASA NTRS1994

Al III, Si IV, and C IV absorption toward zeta Ophiuchi: Evidence for photionized and collisionally ionized gas

We present Goddard High-Resolution Spectrograph observations at 3.5 km/s resolution and signal-to-noise ratios of 30 to 60 for the Al III, Si IV, and N V absorption lines in the far-ultraviolet spectrum of the O9.5 V star zeat Ophiuchi. The measurement reveal three types of highly ionized gas along the 140 pc line of sight. (1) Narrow components of Al III (b = 4.3 km/s, the mean value of (v(helio)) = -7.8 km/s; b = 3.2 km/s, the mean value of (v(sub helio)) = -14.4 km/s) and Si IV (b = 5.3 km/s, the mean value of (v(sub helio)) = -15.0 km/s) trace photionized gas in the expanding H II region surrounding zeta Oph. The observed magnitude and direction of the velocity offset between the Al III and Si IV profiles can be explained by models of H II regions that incorporate expansion. Narrow C IV absorption associated with the H II region is not detected. Predictions of the expected amounts of Si IV and C IV overestimate the column densities of these ions by factors of 30 and more than 10, respectively. The discrepancy may be due to the effects of elemental depletions in the gas and/or to the interaction of the stellar wind with surrounding matter. (2) Broad (b = 15 to 18 km/s) and weak Si IV and C IV absorption components are detected near the mean value of (v(sub helio)) = -26 km/s. The high-ionization species associated with these absorption components are probably produced by electron collisional ionization in a heated gas. This absorption may be physically related to the zeta Oph bow shock ot to a cloud complex situated within the local interstellar medium at d less than 60 pc. The C IV to Si IV column density ratio in this gas is 8, a factor of 6 less than conductive interface models predict, but this discrepancy may be removed by considering the effects of self-photoionization within the cooling gas in the model calculations. (3) A broad (b = 13 km/s) and weak C IV absorption feature detected at the mean value of (v(sub helio)) = -61 km/s is not seen in other species. We tentatively ascribe this absorption to gas in a postshock ragion of an optically thin shock in the zeta Oph stellar wind.

Sembach, Kenneth R.↗

NASA NTRS1994

The Hubble Space Telescope quasar absorption line key project. 6: Properties of the metal-rich systems

We present an analysis of the properties of a sample of 18 metal-rich, low-redshift z(sub abs) much less than z(sub em) absorbers seen in low- and medium-resolution spectra obtained for the Quasar Absorption Line Key Project with the Hubble Space Telescope Faint Object Spectrograph (HST/FOS). For most of the C IV and Lyman-limit systems, observations in the optical wavelength range of the expected associated Mg II absorption are available. As at high redshift (z approximately 2), there are two subclasses of absorbers which are characterized by the presence or absence of MG II absorption. However, some low-redshift Mg II and Fe absorptions originate from regions optically thin to UV ionizing photons and thus, at low redshift, the low-ionization systems do not always trace high opacities, as is the case at high redshift. This implies that the mean ionization state of metal-rich, optically thin absorbing clouds falls with decreasing redshift, which is consistent with the hypothesis that the gas is photoionized by the metagalactic UV background radiation field. Two main constraints are derived from the analysis of the Lyman-limit sample, assuming photoionization models are valid. First, a low opacity to ionizing photons (tau(sub LL) approximately less than 1), as observed for several Mg II-Fe II systems at z approximately 0.5, sets limits on the ionization level of hydrogen, thus on the total hydrogen column density and the heavy element abundances, (Z/H) approximately -0.5 to -0.3. Second, the dimensions of individual Mg II clouds are smaller than at high redshift by a factor 3-10. At z approximately greater than 0.6, the O VI absorption doublet is detected in four of the five z(sub abs) much less than z(sub em) systems for which the O VI wavelength range has been observed, whereas the associated N V doublet is detected in only two cases. This suggests that the presence of a high-ionization O VI phase is a general property of z approximately 0.6-1 absorption systems, as is also probably the case at high redshift. These O VI absorbers can be ionized by the UV metagalactic field if their density is low, nH approximately less than 3 x 10(exp -4)/cc. The O VI phase would then be a homogeneous region of large extent, r approximately greater than 50 kpc. A detailed photoionization model of the z(sub abs) = 0.791 absorber toward PKS 2145+06 confirms the properties derived from the Mg II, C IV, O VI, and Lyman-limit samples. The galaxy causing this extensive metal-line absorption system has been identified, and its possible contribution to the UV ionizing flux does not substantially modify the value of the derived parameters. The heavy element abundances are about half the solar values. The O VI region has a density about 20 times lower than the Mg II clouds and a size of approximately 70 kpc. Alternatively, the high-ionization phase could be collisionally ionized and trace gas associated with a possible group of galaxies at the absorber redshift.

Bergeron, Jacqueline↗

NASA NTRS1995

The ultraviolet spectrum of the gravitational lens candidate UM 425 = QSO 1120+019: Evidence for broad absorption line (BAL) structure

The UV line profile structure of high-ionization resonance lines found with the International Ultraviolet Explorer (IUE) in the brightest of four multiply imaged sources (images-A) in the candidate gravitational lens UM 425 = QSO 1120+019 indicates broad absorption line (BAL) structure. The deep-broad trough associated with the O IV line extends to velocities approiximately -12,000 km/s, and contains disrete features that suggest multicomponent velocity structure. This structure may include contributions from C IV absorption from the early-type galaxy that is believed to lens UM 425. A strong absorption feature in the blue wing of the Lyman-alpha lambda 1216 emission line may be a Lyman alpha absorption system at a Z(sub Ly alpha) = 1.437 +/- 0.003, or it may be formed by the superposition of the broad N V lambda lambda 1238, 1242 absorption trough on the extended blue emission wing of the QSO Lyman-alpha line. We obtained a redshift of Z(sub QSO) = 1.471 +/- 0.003 from Lyman-alpha lambda 1215, consistent with the redshift found by Meylan and Djorgovski in the optical. The Lyman-alpha line appears unusally weak due to the presence of N V lambda 1240 BAL absorption. A Lyman-limit absorption system at lambda 912 was not observed in the QSO rest frame. The detection of BAL structure in the other weaker ground-state resonance lines of N II (l) and S IV (l) was not found, suggesting these lines are formed in a region that is distinct from the BAL component. Detection of BAL structure in the other fainter images in this system with Hubble Space Telescope (HST) instrumentation, similar to structure observed here in image A, could provide evidence that UM 425 is a gravitational lens.

Michelitsianos, A. G.↗

NASA NTRS1997

Roto-Translational Collision-Induced Absorption of CO2 for the Atmosphere of Venus at Frequencies from 0 to 250 cm(exp -1), at Temperatures from 200 to 800 K

The collision-induced absorption (CIA)of gaseous CO2 is the primary source of far-infrared opacity of the atmosphere of Venus. At the temperatures and densities of the venusian atmosphere, the absorption is due mainly to binary collisions of CO2 molecules. Using a realistic anisotropic intermolecular potential and assuming the absorbing dipole to be due to the electrostatic induction and a quantum overlap, a series of molecular dynamics simulations were performed for the temperature range 200 to 800 K, and the roto-translational (RT) collision-induced absorption spectra at frequencies from 0 to 250 cm(exp -1) were derived. The absorption coefficient in the submillimeter region, used in constituency retrieval studies, decreases more than 10 times in the temperature range 200 to 800 K. On the other hand, the absorption coefficient at 800 K and at the frequency range above 150 cm(exp -1) was found to be almost 10 times higher than at 200 K. Earlier works relied on experimental RT CIA data at a fixed temperature of 300 K. The new, temperature-dependent absorption bands may, when included in the analysis of the atmospheric radiative transfer of the planet, help explain the observed high far-infrared opacity of the lower layers of the atmosphere. To make the results of the simulations readily available for atmospheric abundance and radiative transfer analysis, an analytic model of the roto-translational collision-induced absorption spectral profile, applicable from 200 to 800 K, is being proposed here. The FORTRAN computer code of this newly developed model is available from the authors on request.

Gruszka, Marcin↗

NASA NTRS1995

Scramjet Performance Assessment Using Water Absorption Diagnostics (U)

Simultaneous multiple path measurements of temperature and H2O concentration will be presented for the AIMHYE test entries in the NASA Ames 16-Inch Shock Tunnel. Monitoring the progress of high temperature chemical reactions that define scramjet combustor efficiencies is a task uniquely suited to nonintrusive optical diagnostics. One application strategy to overcome the many challenges and limitations of nonintrusive measurements is to use laser absorption spectroscopy coupled with optical fibers. Absorption spectroscopic techniques with rapidly tunable lasers are capable of making simultaneous measurements of mole fraction, temperature, pressure, and velocity. The scramjet water absorption diagnostic was used to measure combustor efficiency and was compared to thrust measurements using a nozzle force balance and integrated nozzle pressures to develop a direct technique for evaluating integrated scramjet performance. Tests were initially performed with a diode laser tuning over a water absorption feature at 1391.7 nm. A second diode laser later became available at a wavelength near 1343.3 nm covering an additional water absorption feature and was incorporated in the system for a two-wavelength technique. Both temperature and mole fraction can be inferred from the lineshape analysis using this approach. Additional high temperature spectroscopy research was conducted to reduce uncertainties in the scramjet application. The lasers are optical fiber coupled to ports at the combustor exit and in the nozzle region. The output from the two diode lasers were combined in a single fiber, and the resultant two-wavelength beam was subsequently split into four legs. Each leg was directed through 60 meters of optical fiber to four combustor exit locations for measurement of beam intensity after absorption by the water within the flow. Absorption results will be compared to 1D combustor analysis using RJPA and nozzle CFD computations as well as to data from a nozzle metric balance measuring thrust and integrated pressure measurements along the length of the nozzle. Assessment of its value as a combustor performance evaluation tool will be conducted.

Cavolowsky, John A.↗

NASA NTRS2004

Quasar Absorption Studies

The aim of the proposal is to investigate the absorption properties of a sample of inter-mediate redshift quasars. The main goals of the project are: Measure the redshift and the column density of the X-ray absorbers; test the correlation between absorption and redshift suggested by ROSAT and ASCA data; constrain the absorber ionization status and metallicity; constrain the absorber dust content and composition through the comparison between the amount of X-ray absorption and optical dust extinction. Unanticipated low energy cut-offs where discovered in ROSAT spectra of quasars and confirmed by ASCA, BeppoSAX and Chandra. In most cases it was not possible to constrain adequately the redshift of the absorber from the X-ray data alone. Two possibilities remain open: a) absorption at the quasar redshift; and b) intervening absorption. The evidences in favour of intrinsic absorption are all indirect. Sensitive XMM observations can discriminate between these different scenarios. If the absorption is at the quasar redshift we can study whether the quasar environment evolves with the Cosmic time.

Mushotzky, Richard↗