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Black Carbon (Soot) Aerosol in the Lower Stratosphere and Upper Troposphere

We have used two approaches to measure BCA in the stratosphere. The first method consists of collecting aerosols by impaction on quartz rods, upon which are mounted strips of polystyrene filter material. Each 25 mm by 0.5 mm filter strip is alternately masked and exposed in 5 mm long sections. After sampling, the optical density of the exposed sections is measured and compared with the optical density of the masked (unexposed) sections. The filter strip is a Lambertian collector, the scattering property of which is not affected by the deposition of liquid sulfuric acid droplets which dominate the stratospheric aerosol. Hence, all attenuation greater in the exposed than in the non-exposed sections is due to absorption by BCA or rare opaque materials such as meteoritic iron. In a second approach we expose carbon-coated gold or palladium wires to air outside the aircraft boundary layer [Farlow et al., 1979; Pueschel et al., 1989]. With a field emission scanning electron microscope we are able to characterize BCA particles in addition to the dominant sulfuric acid droplets. Typically, soot is comprised of 20 nm diameter spheres linked together as branching chains or loosely packed aggregates (Figure 1a). The microscope has a lateral image resolution of 1.5 nm and can clearly resolve individual spheres making up BCA aggregates. Their morphology is uniquely different from that of the liquid sulfuric acid-water aerosol (Figure 1b). We approximate the size of each BCA particle by that of a sphere of equivalent volume and fit a lognormal size distribution to both the BCA and H2SO4/H2O aerosols. Both sampler types have been mounted on NASA's ER-2 high-altitude research aircraft (altitude ceiling of 70,000 feet), and on NASA's DC-8 (40,000 feet ceiling) aircraft to sample aerosols from a significant portion of the atmosphere.

Pueschel, R. F.↗

Using Importance Sampling Monte Carlo to Analyze Aircraft Takeoff and Landing

Aircraft have achieved high levels of reliability, so the probability of undesirable dynamics is very low. The low probability of a bad takeoff or landing challenges nondeterministic methods to quantify the uncertainty of these improbable events. In the present work, a Monte Carlo method is defined to more effectively quantify these unlikely events that is suitable for uncertainty analysis of a mature design with many uncertainty parameters. The proposed Monte Carlo method has been applied to the takeoff and landing of the X-59 Quiet SuperSonic Technology (QueSST). Takeoff and landing simulation profiles were defined using a combination of industry standards and piloted simulation experience. The proposed method is shown to be able to quantify events with significantly fewer samples than would be required with conventional Monte Carlo. These results improve understanding of the sensitivity of the takeoff and landing dynamics to inform further studies and test planning.

Jeffrey Ouellette↗

Using Importance Sampling Monte Carlo to Analyze Aircraft Takeoff and Landing

Aircraft have achieved high levels of reliability, so the probability of undesirable dynamics is very low. The low probability of a bad takeoff or landing challenges nondeterministic methods to quantify the uncertainty of these improbable events. In the present work, a Monte Carlo method is defined to more effectively quantify these unlikely events that is suitable for uncertainty analysis of a mature design with many uncertainty parameters. The proposed Monte Carlo method has been applied to the takeoff and landing of the X-59 Quiet SuperSonic Technology (QueSST). Takeoff and landing simulation profiles were defined using a combination of industry standards and piloted simulation experience. The proposed method is shown to be able to quantify events with significantly fewer samples than would be required with conventional Monte Carlo. These results improve understanding of the sensitivity of the takeoff and landing dynamics to inform further studies and test planning.

Jeffrey Ouellette↗

Spectro-Microscopy Studies of Atmospheric Particles

Our project investigated composition and physical properties of individual atmospheric particles collected in field campaigns organized by the DOE Atmospheric Systems Research and Atmospheric Radiation Measurement (ASR/ARM) programs, such as the Green Ocean Amazon (GoAmazon, 2014/5), the Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems (HI-SCALE, 2016/7), the Aerosol and Cloud Experiment in the Eastern North Atlantic (ACE-ENA, 2017/8), the Aerosol–Ice Formation Closure Pilot Study (AEROICESTUDY, 2019) and in additional small-scale supporting field experiments focused on the investigation of the light-absorbing (aka brown carbon) atmospheric particles. In these studies, we investigated the contribution of natural and anthropogenic sources to populations of atmospheric particles during representative atmospheric conditions; characterized particle composition and evaluated their hygroscopic properties and propensity to act as cloud condensation nuclei (CCN) and ice nuclei (IN); correlated typical particle-type and mixing state characteristics with real-time measurements in the areas of studies. We used multi-modal spectro-microscopy techniques to examine elemental and molecular composition, mixing state, size, and higher order morphology for individual particles. Specifically, we used computer-controlled scanning electron microscopy and X-ray microanalysis for quantitative analysis of particle elemental composition, and we used transmission electron microscopy to provide additional information on the distribution of different components within individual particles (particle heterogeneity). We used synchrotron-based scanning transmission X-ray microscopy for quantitative description of the mixing state and molecular bonding of carbon in particles. The particle composition, mixing state, and morphology from analyzed periods was then combined with the real-time ARM measurements of aerosol size distribution, CCN concentration, hygroscopicity, and aerosol bulk composition. Combined together, results of our studies allowed us to assess the major particle sources (biogenic vs. anthropogenic, primary vs secondary) and gain insight into the atmospheric processing of aerosol particles resulting from condensation, coagulation, oxidative aging, and cloud processing. In collaboration with other scientists involved in field campaigns, we carried out statistical analysis of particle properties and their source-specific contributions to regional aerosol loading under representative air mass, meteorological, and cloud conditions.

scanning transmission X-ray microscopy↗

Satellite data for surface-mine inventory

To determine the feasibility of satellite data for surface-mine inventory, particularly as it applies to coal, a case study was conducted in Maryland. A band-ratio method was developed to measure disturbed surface areas, and it proved to be extendible both temporally and geographically. This method was used to measure area changes in the region over three time periods from September 1972 through July 1974 and to map the entire two-county area for 1973. For mines ranging between 31 and 244 acres (12 to 98 hectares) the measurement accuracy of total affected acreage was determined to be 92%. Mines of 120 acres (50 hectares) and larger were measured with greater accuracy, some within one percent of the actual area. The ability to identify, classify, and measure strip-mine surfaces in a two-county area (1,541 square kilometers - 595 square miles) of western Maryland was demonstrated through the use of computer processing. On the basis of these results the use of LANDSAT satellite data and multilevel sampling of aircraft and field verification inspections, multispectral analysis of digital data is shown to be an effective, rapid, and accurate means of monitoring the surface mining cycle.

Anderson, A. T.↗

Landsat imagery for surface-mine inventory

The feasibility of using Landsat imagery for routine monitoring of surface mining and reclamation was tested in a two-county (1541 sq km) area of western Maryland. Two digital analysis methods were studied. The first, a four-band analysis distinguishing various strip mine associated classes and conditions, proved useful, but has limited extendibility over a seasonal or annual period. In the second approach, a band-ratio method was developed for measuring disturbed surface areas, and it proved to be both temporally and geographically extendible. For mines ranging between 31 and 244 acres, the measurement accuracy of total affected acreage was 92%. The use of Landsat satellite data together with multilevel sampling of aircraft and field verification inspections has shown that multispectral analysis of digital data is an effective means of monitoring the progress of surface mining operations.

Anderson, A. T.↗

Lightweight, low compression aircraft diesel engine

The feasibility of converting a spark ignition aircraft engine to the diesel cycle was investigated. Procedures necessary for converting a single cylinder GTS10-520 are described as well as a single cylinder diesel engine test program. The modification of the engine for the hot port cooling concept is discussed. A digital computer graphics simulation of a twin engine aircraft incorporating the diesel engine and Hot Fort concept is presented showing some potential gains in aircraft performance. Sample results of the computer program used in the simulation are included.

Gaynor, T. L.↗

Use of LANDSAT data to assess waterfowl habitat quality

The author has identified the following significant results. The capability of mapping ponds over a very large area was demonstrated, with multidate, multiframe LANDSAT imagery. A small double sample of aircraft data made it possible to adjust a LANDSAT large area census. Terrain classification was improved by using multitemporal LANDSAT data. Waterfowl production was estimated, using remotely determined pond data, in conjunction with FWS estimates of breeding population. Relative waterfowl habitat quality was characterized on a section by section basis.

Colwell, J. E.↗

Trajectories of the Mount St. Helens eruption plume

The plume of the major eruption of Mount St. Helens on May 18, 1980 penetrated 10 to 11 km into the stratosphere, attaining heights of 22 to 23 km. Wind shears rapidly converted the plume from an expanding vertical cone to a thin, slightly inclined lamina. The lamina was extruded zonally in the stratosphere as the lower part moved eastward at jet stream velocities, while the upper part slowly moved westward in the region of nonsteady transition from the westerlies to the summer stratospheric easterlies. Trajectories computed to position the NASA U-2 aircraft for sampling in the plume are described. Plume volume after 8 hours of strong volcanic emission is estimated at 2,000,000 cu km. Only about 1% of this volume is attributed to the volcano; the rest was entrained from the environment.

Danielsen, E. F.↗

Identification of acetylene /C2H2/ in infrared atmospheric absorption spectra

Infrared atmospheric absorption spectra at 0.02/cm resolution were obtained during a balloon flight on March 23, 1981 from the Holloman AFB, New Mexico. The absorption features, attributed to C2H2, were used to derive a preliminary mixing ratio of about 25 pptv near 9 km, accurate to + or - 40%. This mixing ratio falls into the range of values calculated for the upper troposphere C2H2 in a photochemical/transport model. However, previous measurements from aircraft grab sampling (Cronn and Robinson, 1979) show four to twelve times this C2H2 concentration 1.5 km below the tropopause.

Goldman, A.↗

Experimental study using Nearfield Acoustical Holography of sound transmission fuselage sidewall structures

This project involves the development of the Nearfield Acoustic Holography (NAH) technique (in particular its extension from single frequency to wideband noise measurement) and its application in a detailed study of the noise radiation characteristics of several samples of aircraft sidewall panels. With the extensive amount of information provided by the NAH technique, the properties of the sound field radiated by the panels may be correlated with their structure, mounting, and excitation (single frequency or wideband, spatially correlated or uncorrelated, structure-borne). The work accomplished at the beginning of this grant period included: (1) Calibration of the 256 microphone array and test of its accuracy. (2) extension of the facility to permit measurements on wideband noise sources. The extensions incuded the addition of high-speed data acquisition hardware and an array processor, and the development of new software. (3) Installation of motion picture graphics for correlating panel motion with structure, mounting, radiation, etc. (4) Development of new holographic data processing techniques.

Maynard, J. D.↗

Size-specific composition of aerosols in the El Chichon volcanic cloud

A NASA U-2 research aircraft flew sampling missions in April, May, July, November, and December 1982 aimed at obtaining in situ data in the stratospheric cloud produced from the March-April 1982 El Chichon eruptions. Post flight analyses provided information on the aerosol composition and morphology. The particles ranged in size from smaller than 0.05 m to larger than 20 m diameter and were quite complex in composition. In the April, May, and July samples the aerosol mass was dominated by magmatic and lithic particles larger than about 3 m. The submicron particles consisted largely of sulfuric acid. Halite particles, believed to be related to a salt dome beneath El Chichon, were collected in the stratosphere in April and May. On the July 23 flight, copper-zinc oxide particles were collected. In July, November, and December, in addition to the volcanic ash and acid particles, carbon-rich particles smaller than about 0.1 m aerodynamic diameter were abundant.

Woods, D. C.↗

On the transfer of stratospheric ozone into the troposphere near the North Pole

A series of nearly daily ozone vertical profiles obtained at station T-3 on Fletcher's Ice Island (about 85 deg N, about 90 deg W) during the period January-March 1971 shows several significant ozone intrusions into the troposphere. These intrusions are not only associated with enhanced ozone amounts in the stratosphere but also require tropopause folding events to transport ozone into the troposphere. These folds in the arctic tropopause appear to be capable of contributing significantly to the ozone budget of the arctic troposphere during the late winter and spring seasons. The importance of tropopause folding for bringing ozone into the troposphere seen in the daily ozone profiles confirms the results found in the Arctic Gas and Aerosol Sampling Program aircraft flights.

Oltmans, Samuel J.↗

Preliminary airborne measurements for the SR-71 sonic boom propagation experiment

SR-71 sonic boom signatures were measured to validate sonic boom propagation prediction codes. An SR-71 aircraft generated sonic booms from Mach 1.25 to Mach 1.6, at altitudes of 31,000 to 48,000 ft, and at various gross weights. An F-16XL aircraft measured the SR-71 near-field shock waves from close to the aircraft to more than 8,000 ft below, gathering 105 signatures. A YO-3A aircraft measured the SR-71 sonic booms from 21,000 to 38,000 feet below, recording 17 passes. The sonic booms at ground level and atmospheric data were recorded for each flight. Data analysis is underway. Preliminary results show that shock wave patterns and coalescence vary with SR-71 gross weight, Mach number, and altitude. For example, noncoalesced shock wave signatures were measured by the YO-3A at 21,000 ft below the SR-71 aircraft while at a low gross weight, Mach 1.25, and 31,000-ft altitude. This paper describes the design and execution of the flight research experiment. Instrumentation and flight maneuvers of the SR-71, F-16XL, and YO-3A aircraft and sample sonic boom signatures are included.

Haering, Edward A., Jr.↗

Desert Dust Layers Over Polluted Marine Boundary Layers: ACE-2 Measurements and ACE-Asia Plans

Aerosols in ACE-Asia are expected to have some commonalties with those in ACE-2, along with important differences. Among the commonalities are occurrences of desert dust layers over polluted marine boundary layers. Differences include the nature of the dust (yellowish in the East Asia desert outflow, vs. reddish-brown in the Sahara Outflow measured in ACE-2) and the composition of boundary-layer aerosols (e.g., more absorbing, soot and organic aerosol in-the Asian plume, caused by coal and biomass burning, with limited controls). In this paper we present ACE-2 measurements and analyses as a guide to our plans for ACE-2 Asia. The measurements include: (1) Vertical profiles of aerosol optical depth and extinction (380-1558 nm), and of water vapor column and concentration, from the surface through the elevated desert dust, measured by the 14-channel Ames Airborne Tracking Sunphotometer (AATS-14); (2) Comparisons of airborne and shipborne sunphotometer optical depths to satellite-retrieved values, with and without desert dust; (3) Comparisons between airborne Sunphotometer optical depth and extinction spectra and those derived from coincident airborne in situ measurements of aerosol size distribution, scattering and absorption; (4) Comparisons between size distributions measured in situ and retrieved from sunphotometer optical depth spectra; (5) Comparisons between aerosol single scattering albedo values obtained by several techniques, using various combinations of measurements of backscatter, extinction, size distribution, scattering, absorption, and radiative flux. We show how analyses of these data can be used to address questions important to ACE-Asia, such as: (1) How do dust and other absorbing aerosols affect the accuracy of satellite optical depth retrievals? How important are asphericity effects? (2) How important are supermicron dust and seasalt aerosols to overall aerosol optical depth and radiative forcing? How well are these aerosols sampled by aircraft inlets and instruments? (3) How consistent are suborbital in situ and remote measurements of aerosols, among themselves and with satellite retrievals? What are the main reasons for observed inconsistencies?

Russell, Philip B.↗

Combining New Satellite Tools and Models to Examine Role of Mesoscale Interactions in Formation and Intensification of Tropical Cyclones

The objective of this research is to start filling the mesoscale gap to improve understanding and probability forecasts of formation and intensity variations of tropical cyclones. Sampling by aircraft equipped to measure mesoscale processes is expensive, thus confined in place and time. Hence we turn to satellite products. This paper reports preliminary results of a tropical cyclone genesis and early intensification study. We explore the role of mesoscale processes using a combination of products from TRMM, QuikSCAT, AMSU, also SSM/I, geosynchronous and model output. Major emphasis is on the role of merging mesoscale vortices. These initially form in midlevel stratiform cloud. When they form in regions of lowered Rossby radius of deformation (strong background vorticity) the mesoscale vortices can last long enough to interact and merge, with the weaker vortex losing vorticity to the stronger, which can then extend down to the surface. In an earlier cyclongenesis case (Oliver 1993) off Australia, intense deep convection occurred when the stronger vortex reached the surface; this vortex became the storm center while the weaker vortex was sheared out as the major rainband. In our study of Atlantic tropical cyclones originating from African waves, we use QuikSCAT to examine surface winds in the African monsoon trough and in the vortices which move westward off the coast, which may or may not undergo genesis (defined by NHC as reaching TD, or tropical depression, with a west wind to the south of the surface low). We use AMSU mainly to examine development of warm cores. TRMM passive microwave TMI is used with SSM/I to look at the rain structure, which often indicates eye formation, and to look at the ice scattering signatures of deep convection. The TRMM precipitation radar, PR, when available, gives precipitation cross sections. So far we have detailed studies of two African-origin cyclones, one which became severe hurricane Floyd 1999, and the other reached TD2 in June 2000 and then died out. The atmosphere off West African is dry and stable. It becomes less so between June and September, as the SST and convection heat up. QuikSCAT shows the African monsoon trough and shear zone extend westward over the ocean to nearly 30 degrees West. The evidence is strong that the two cyclones had in common multiple midlevel mergers, which extended to the surface keeping the surface vortex strong. These continued until both systems were designated TD's by NHC. In the June 2000 case, the main reason for failure was the lower SST and dry, stable atmosphere. This is shown by the comparison of the equivalent potential temperature maps and profiles with those from pre-Floyd. In the vortex which became Floyd, QuikSCAT shows continuous importation of high theta e (warm, moist) air from the south. From September 2-8, this air flowed around the vortex center, building up a high theta-e pool to the north. Then late on September 9, a 100-km wide jet of high theta-e air penetrated the vortex core, a major convective burst' was observed, and an intensifying, more elevated warm core was seen on AMSU. Rapid pressure fall and wind intensification were underway by 0000 UTC on September 10. Floyd became a Hurricane at 1200 UTC on Sept 10, 1999, with successive convective bursts running the hurricane thermodynamic engine by intensifying the warm core. TD2 was a strong African vortex, sustained by moderate convection (up to about 12.5 km) offshore of Africa. It peaked on June 23, showing an apparent "eye" on passive microwave composites. However, it could not assemble the ingredients for a convective burst. Thus it failed to get the thermodynamic hurricane engine going before it moved too far west of the region of lowered Rossby radius. By June 26, cloud systems were dying out. On June 25, a surface vortex was no longer seen on QuikSCAT, although one continued above the surface on model profiles until June 27. One of our main findings so far is showing the role of the mesoscale vortex interactions in sustaining some African vortices far out in to the mid Atlantic, where under adequate thermal/moisture conditions the hurricane heat engine can sometimes be started. We are working on similar studies of Cindy and Irene 1999. Cindy illustrates a case of wind shear working against an early-stage hurricane heat engine, while Irene formed from a Caribbean wave. An enormous value of combinations of satellite tools is that tropical cyclones can be studied in all parts of the global oceans where they occur. Detailed studies like ours are labor intensive but many statistical studies can be based on physical postulates developed. There are other new tools such as MODIS on TERRA of the Earth Observing System (EOS) which can be used to study the microphysics of tropical cyclones world wide, in particular to investigate the presence of mixed phase and the impact of atmospheric aerosols on the hydrometeor structure and rainfall from tropical cyclones.

Simpson, Joanne↗

The Relationship of Subvisible Cirrus Clouds Observed During NASA's Tropical Ozone

Thin, subvisible cirrus (SVC) clouds at the tropical tropopause have been observed by a number of methods in a variety of observational programs, including in situ sampling and aircraft and space-based lidar. Modeling studies suggest that these clouds play an important role in dehydrating tropospheric air as it enters the stratosphere. This is because particles large enough to have significant fall speeds can form under the conditions of slow cooling that are implied by the large horizontal extent of the SVC sheets. The IRA radiation that these clouds absorb, and the upward vertical motion this implies, also make them candidates for a tropical troposphere-to-stratosphere mass transfer mechanism. These sheets were observed on five flights during the Tropical Ozone Transport Experiment (TOTE) by the NASA Langley DIAL lidar aboard NASA's DC-8 research aircraft, operating during December 1995 and February 1996 south of Hawaii (12 S to 21 N). This experiment provided a unique look at these clouds since temperature profiles were available for all the SVC observations. Thus, the observed distributions of SVC's can be compared with the position of the tropopause to establish whether the SVC's are tropospheric or stratospheric. It also allows comparison of TOTE observations with in situ experiments, where water and cloud particle data is available as a function of temperature and potential temperature.

Pfister, L.↗

Observations of Subvisible Cirrus Clouds and Gravity Waves at the Tropical Tropopause

Thin, subvisible cirrus (SVC) clouds at the tropical tropopause have been observed by a number of methods in a variety of observational programs, including in situ sampling and aircraft and space-based lidar. Modeling studies suggest that these clouds play an important role in dehydrating tropospheric air as it enters the stratosphere. This is because particles large enough to have significant fall speeds can form under the conditions of slow cooling that are implied by the large horizontal extent of the SVC sheets. The IR radiation that these clouds absorb, and the upward vertical motion this implies, also makes them candidates for a tropical troposphere-to-stratosphere mass transfer mechanism. They may also play a role in the earth's radiation budget. These sheets were observed on five flights during the Tropical Ozone Transport Experiment (TOTE) by the NASA Langley DIAL lidar aboard NASA's DC-8 research aircraft operating during December 1995 and February 1996 south of Hawaii. The relationship of the SVC's observed during TOTE to convection was not a simple one. One class of SVC's are within 1000 km of the persistent strong convection near 15S (the SPCZ). Trajectory analyses indicated that the SVC air masses have in fact passed through the SPCZ within a few days of observation. These clouds are very close to the tropopause, with maximum potential temperatures not much higher than 370K, consistent with in situ water and total water measurements near the tropopause made during the Stratosphere Troposphere Exchange Project in January 1987 at Darwin, Australia. A second class of SVC's are not immediately downstream of convection. These clouds tend to be higher, reaching potential temperatures of 390K or more. Trajectory analyses indicate that the air in these SVC's originates either in the equatorial western Pacific or along the subtropical jet. In any case, the warm temperatures the SVC air masses encounter just prior to the observation time along the back trajectory imply that the clouds cannot be residual particles from cirrus blowoff, but must form locally as the air move upward and equatorward south of Hawaii. Since all the parcels have encountered colder temperatures than those at the time of observation early in their history, subsynoptic scale temperatures colder than the analysis temperatures appear to be required to explain the formation of ice particles. In fact, the sloping shapes of the SVC's do suggest that they are gravity or inertia-gravity waves. In situ meteorological measurements made by the ER-2 within a day of the DC-8 remote lidar observations show a gravity wave structure near the equator with an estimated period of about 30 hours. This is sufficiently long to allow large particles to form and fall out (thus allowing dehydration). Other ER-2 flights south of Hawaii at other times of year show gravity and inertia-gravity waves with a poleward wavenumber component and significant (5 degrees peak to peak) temperature perturbation.

Pfister, Leonhard↗