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At least 91 records · Page 5

Ambient temperature fatigue tests of elements of an actively cooled honeycomb sandwich structural panel

Elements of an actively cooled structural panel for a hypersonic aircraft have been investigated for fatigue characteristics. The study involved a bonded honeycomb sandwich panel with d-shaped coolant tubes. The curved portion of these tubes was embedded in the honeycomb, and the flat portion was bonded or soldered to the inner surface of the outer skin. The elements examined were two plain skin specimens (aluminum alloy); two specimens with skins attached to manifolds and tubes (one specimen was bonded, the other soldered); and a specimen representative of a corner section of the complete cooled sandwich. Sinusoidal loads were applied to all specimens. The honeycomb sandwich specimen was loaded in both tension and compression; the other specimens were loaded in tension only. The cooling tubes were pressurized with oil throughout the fatigue tests. The most significant results of these tests follow: All specimens exceeded their design life of 20,000 cycles without damage. Crack growth rates obtained in the plain skin specimens were used to determine the crack growth characteristics of aluminum alloy. Cracks in skins either bonded or soldered to cooling tubes propagated past the tubes without penetration. The coolant tubes served as crack arresters and temporarily stopped crack growth when a crack reached a tube-skin interface. The honeycomb core demonstrated that it could contain leakage from a tube.

Sharpe, E. L.↗

Application of ion chromatography to the study of hydrolysis of some halogenated hydrocarbons at ambient temperatures

The application of ion chromatography to the study of very slow rates of hydrolysis of some halogenated hydrocarbons was investigated. The halide concentrations in the aqueous phase of mixtures of a carbonate buffer (pH = 10.3) and either chloroform (CHC13) or fluorotrichloromethane (CFC13) after aging for various lengths of time at room temperature, were determined by ion chromatography. Hydrolysis of CHC13 caused the C1(-) concentration to increase by about 1500 ppb per day. On the other hand neither the F(-) or C1(-) concentration in the CFC13 mixture increased by as much as 1 ppb per day. The magnitude of errors in the determination of halides prevented any firm conclusions regarding hydrolysis in this mixture. However, these results were used to show how ion chromatography could expedite identification of the hydrolyzing substance as well as investigations of hydrolysis mechanisms.

Otterson, D. A.↗

Rechargeable ambient temperature lithium cells

The cycling performance of a secondary lithium cell with a 2-methyl THF lithium hectofluorarsenate electrolyte is discussed. Stripping efficiency, dendritization, passivation on standing, and discharge efficiency are considered.

Holleck, G. L.↗

Factors affecting cycle life in ambient temperature of secondary lithium batteries

Three major factors are discussed: electrode integrity, electrolyte stability, and dendrite formation. It is concluded that elastomers can function as improved binders for rechargeable cathodes. The cathodes can retain integrity under long cycle life with no visual deteriorations. It is found that microelectrodes can be made from powdery cathode materials for voltammetry studies.

Somoano, R.↗

Laboratory discharge studies of a 6 V alkaline lantern-type battery Eveready Energizer no. 528, under various ambient temperatures (-15 deg C and + 22 deg C) and loads (30 omega and 60 omega)

The voltages of two Eveready No. 528 batteries, one the test battery, the other the control battery, were simultaneously recorded as they were discharged across 30 omega loads using a dual chart recorder. The test battery was initially put in a freezer at -15 + or - 3 C. After its voltage had fallen to .6 V, it was brought back out into the room at 22 + or - 3 C. A second run was made with 60 omega loads. Assuming a 3.0 V cut-off, the total energy output of the test battery at -15 C was 26 WHr 30 omega and 35 WHr 60 omega, and the corresponding numbers for the control battery at 22 C were 91 WHr and 100 WHr. When the test battery was subsequently allowed to warm up, the voltage rose above 4 V and the total energy output rose to 80 WHr 30 omega and 82 WHR 60 omega.

Ahrens, S. T.↗

Microwave Surface Resistivity of Several Materials at Ambient Temperature

Microwave surface resistivity of a number of metal and other sample materials was measured at X-band, approximately 8400 MHz. The method of measurement uses a TE sub 011 mode circular waveguide cavity resonator wherein the sample is used as one end of the cavity. This method has been used previously in JPL work with good results. Microwave reflection loss and noise arising from the dissipative loss are given, for materials having negligible transmission leakage.

H. F. Reilly↗

High-Performance Ambient-Temperature Heat Pipe

Heat pipe with two channels designed for regulation of temperature in enclosed spaces. Made of aluminum, heat-transfer material is ammonia. Contains two channels: one for vapor phase and one for liquid phase of ammonia. Porous wick of sintered aluminum powder lines vapor channel and fills slot between two channels. Design confers several advantages.

Keddy, Michael D.↗

Advances in ambient temperature secondary lithium cells

The goal is to develop secondary lithium cells with a 100 Wh/kg specific energy capable of 1000 cycles at 50 percent DOD. The approach towards meeting this goal initially focused on several basic issues related to the cell chemistry, selection of cathode materials and electrolytes and component development. The performance potential of Li-TiS2, Li-MoS3, Li-V6O13 and Li-NbSe3 electrochemical systems was examined. Among these four, the Li-TiS2 system was found to be the most promising system in terms of achievable specific energy and cycle life. Major advancements to date in the development of Li-TiS2 cells are in the areas of cathode processing technology, mixed solvent electrolytes, and cell assembly. A summary is given of these advances.

Subbarao, S.↗

Capacity decline of ambient temperature secondary Li-TiS2 cells

The main objective of the study described was to identify the causes responsible for the capacity losses observed during cycling of secondary Li-TiS2 cells. Experimental Li-TiS2 cells were fabricated and tested for their cycle life performance. The open circuit voltage of the cells was monitored during the rest period between the charging and discharging. The polarization at the Li and TiS2 electrodes was also monitored during cycling. Cycled cells were disassembled and the cathodes were analyzed by various analytical techniques. The results of the study indicate that the observed capacity loss is almost entirely due to the increased polarization of the TiS2 electrode with cycling. The electrolyte was found to degrade during cycling and the degradation products were found to deposit at the TiS2 electrode, which probably lead to the higher polarization.

Subbarao, S.↗

Symposium on High Power, Ambient Temperature Lithium Batteries, 180th Meeting of the Electrochemical Society, Phoenix, AZ, Oct. 13-17, 1991, Proceedings

Papers presented in these proceedings are on the state of the art in high-power lithium batteries, a design analysis of high-power Li-TiS2 battery, the performance and safety features of spiral wound lithium/thionyl chloride cells, the feasibility of a superhigh energy density battery of the Li/BrF3 electrochemical system, and an enhanced redox process of disulfide compounds and their application in high energy storage. Attention is also given to the structure and charge-discharge characteristics of mesophase-pitch based carbons, a study of carbons and graphites as anodes for lithium rechargeable cells, Li metal-free rechargeable Li(1+x)Mn2O4/carbon cells, and rechargeable lithium batteries using V6O13/V5O5 as the positive electrode material. Other papers discuss the electrochemical stability of organic electrolytes in contact with solid inorganic cathode materials, the electrochemical behavior of methyl formate solutions, and the interface between a solid polymer electrolyte and lithium anode.

Clark, W. D. K.↗

Electronic Ambient-Temperature Recorder

Electronic temperature-recording unit stores data in internal memory for later readout. Records temperatures from minus 40 degrees to plus 60 degrees C at intervals ranging from 1.875 to 15 minutes. With all four data channels operating at 1.875-minute intervals, recorder stores at least 10 days' data. For only one channel at 15-minute intervals, capacity extends to up to 342 days' data. Developed for recording temperatures of instruments and life-science experiments on satellites, space shuttle, and high-altitude aircraft. Adaptable to such terrestrial uses as recording temperatures of perishable goods during transportation and of other systems or processes over long times. Can be placed directly in environment to monitor.

Russell, Larry↗

Slow Crack Growth Behavior and Life/Reliability Analysis of 96 wt % Alumina at Ambient Temperature With Various Specimen/Loading Configurations

Extensive constant stress-rate testing for 96 wt % alumina was conducted in room-temperature distilled water using four different specimen/loading configurations: rectangular beam test specimens under four-point uniaxial flexure, square plate test specimens in ring-on-ring biaxial flexure, square plate test specimens in ball-on-ring biaxial flexure, and dog-boned tensile test specimens in pure tension. The slow crack growth (SCG) parameter n was almost independent of specimen/loading configurations, in either four-point uniaxial flexure, ring-on-ring biaxial flexure, ball-on-ring biaxial flexure, or pure tension, ranging from n = 35 to 47 with an average value of n = 41.1 +/- 4.5. The prediction of fatigue strength/reliability based on the four-point uniaxial flexure data by using the CARES/Life design code as well as a simple PIA model was in good agreement with both the ring-on-ring biaxial and the ball-on-ring biaxial flexure data. A poor prediction using the PIA model was observed for the dog-boned tensile test specimens, presumably due to different flaw population involved in the tensile test specimens.

Choi, Sung R.↗

High-T(sub c) Superconductor-Normal-Superconductor Junctions with Polyimide-Passivated Ambient Temperature Edge Formation

The ability to controllably fabricate High-Temperature Superconductor (HTS) S-Normal-S (SNS) Josephson Juntions (JJ's) enhances the possibilities fro many applications, including digital circuits, SQUID's, and mixers. A wide variety of approaches to fabricating SNS-like junctions has been tried and analyzed in terms of proximity effect behavior.

HTS SNS Josephson Junction JJ polyimide films poly↗

Development of Ambient Temperature Lithium-Ion Cells

Four types of materials have been evaluated as anodes for Li-ion cell fabrication. Among the materials evaluated, graphite and magnasium silicide were identified to be suitable candidate anode materials.

Li alloys Lithium-Ion↗