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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
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The Experiment for Cryogenic Large-aperture Intensity Mapping (EXCLAIM)

Submillimeter and far-IR spectroscopy provides insight into galaxy evolution through measurement of atomic and molecular line emission. The EXperiment for Cryogenic Large-Aperture Intensity Mapping (EXCLAIM) is a cryogenic balloon-borne instrument designed to carry out intensity mapping to measure the cumulative redshifted line emission from carbon monoxide and singly-ionized carbon to probe star formation in windows from the present to z=3.5. During this time, the rate of star formation dropped dramatically, while dark matter continued to cluster. Intensity mapping permits a blind and complete survey of emitting gas through statistics of cumulative brightness fluctuations. EXCLAIM achieves high sensitivity using a cryogenic telescope coupled to six integrated spectrometers with spectral resolving power R=512 and employing microwave kinetic inductance detectors. Here we summarize the status of the mission.

Maryam Rahmani↗
NASA NTRS1969

Planetary ultraviolet spectroscopy.

Spaceborne planetary UV spectroscopic search for atoms and molecules basic to life, specifically molecular N and water vapor photodissociation products

Barth, C. A.↗
DOE OSTI2021

Spectroscopy of Rydberg states in erbium using electromagnetically induced transparency

We present a study of the Rydberg spectrum in 166 Er for series connected to the 4 f 12 ( 3 H 6 )6s, J c = 13/2 and J c = 11/2 ionic core states using an all-optical detection based on electromagnetically induced transparency in an effusive atomic beam. Identifying approximately 550 individual states, we find good agreement with a multi-channel quantum defect theory (MQDT) which allows assignment of most states to ns or nd Rydberg series. We provide an improved accuracy for the lowest two ionization thresholds to E IP, J c =13/2 = 49260:750(1) cm -1 and E IP, J c =11/2 = 49701:184(1) cm -1 as well as the corresponding quantum defects for all observed series. We identify Rydberg states in five different isotopes, and states between the two lowest ionization thresholds. Our results open the way for future applications of Rydberg states for quantum simulation using erbium and exploiting its special open-shell structure.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2021

The design of a photoionization front experiment using the Z-Machine as a driving source and estimated measurements

Radiation-driven heat fronts are present in the early universe during reionization, the circumstellar medium of supernovae, and in high-energy-density physics experiments. Dedicated experiments to observe and diagnose the behavior of these types of heat fronts can improve our understanding of these phenomena. A simulation study of photoionization fronts using the HELIOS-CR radiation hydrodynamics code provides an experimental design for the Z-Machine at Sandia National Laboratory using a measurement-calibrated input radiation flux to drive the photoionization front. The simulations use detailed atomic physics and non-diffusive radiation transport in 1D to determine an optimal gas pressure of 0.75 atm for an experiment in N gas as well as the effects of increasing the thickness of the window that seals the gas cell. Post-processing of these simulations demonstrates that ratios of atomic rate coefficients place the heat front in a physics regime where photoionization dominates the energy deposition. Here, to see the sensitivity of the simulations to changes in the model and spatial grid, this analysis performed resolution, atomic model detail, and radiation transport angular grid studies showing less than 10% deviation from the nominal model for increased complexity, when possible. An effort to emulate 3D geometric effects on the radiation flux using an artificial attenuation scheme has shown that, even for conservative estimates of the flux, simulations still produce a photoionization front. Estimations of a streaked, visible spectroscopy measurement using SPECT3D showed that line emission measurements are present early in time and that later in time thermal emission should become dominant.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Two-Center Interference in the Photoionization Delays of Kr 2

Herein we present the experimental observation of two-center interference in the ionization time delays of Kr 2 . Using attosecond electron-ion-coincidence spectroscopy, we simultaneously measure the photoionization delays of krypton monomer and dimer. The relative time delay is found to oscillate as a function of the electron kinetic energy, an effect that is traced back to constructive and destructive interference of the photoelectron wave packets that are emitted or scattered from the two atomic centers. Our interpretation of the experimental results is supported by solving the time-independent Schrödinger equation of a 1D double-well potential, as well as coupled-channel multiconfigurational quantum-scattering calculations of Kr 2 . This work opens the door to the study of a broad class of quantum-interference effects in photoionization delays and demonstrates the potential of attosecond coincidence spectroscopy for studying weakly bound systems.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2020

Lifetime-Limited Interrogation of Two Independent 27 Al + Clocks Using Correlation Spectroscopy

Laser decoherence limits the stability of optical clocks by broadening the observable resonance linewidths and adding noise during the dead time between clock probes. Correlation spectroscopy avoids these limitations by measuring correlated atomic transitions between two ensembles, which provides a frequency difference measurement independent of laser noise. Here, we apply this technique to perform stability measurements between two independent clocks based on the 1 S 0 ↔ 3 P 0 transition in 27 Al + . By stabilizing the dominant sources of differential phase noise between the two clocks, we observe coherence between them during synchronous Ramsey interrogations as long as 8 s at a frequency of 1.12 × 10 15 Hz. Here, the observed contrast in the correlation spectroscopy signal is consistent with the 20.6 s 3 P 0 state lifetime and represents a measurement instability of (1.8 ± 0.5) × 10 –16 /√τ/s for averaging periods longer than the probe duration when dead time is negligible.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2025

Probing New Bosons and Nuclear Structure with Ytterbium Isotope Shifts

In this Letter, we present mass-ratio measurements on highly charged Yb 42+ ions with a precision of 4 ×10 -12 and isotope-shift measurements on Yb + on the 2 S 1/2 → 2 D 5/2 and 2 S 1/2 → 2 F 7/2 transitions with a precision of 4 ×10 -9 for the isotopes 168,170,172,174,176 Yb. We present a new method that allows us to extract higher-order changes in the nuclear charge distribution along the Yb isotope chain, benchmarking ab initio nuclear structure calculations. Additionally, we perform a King plot analysis to set bounds on a fifth force in the keV/c 2 to MeV/c 2 range coupling to electrons and neutrons.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2021

Outbursting Young Stellar Object PGIR 20dci in the Perseus Arm

We report the discovery of a likely outbursting Class I young stellar object, associated with the star-forming region NGC 281-W (distance ~2.8 kpc). The source is currently seen only at infrared wavelengths, appearing in both the Palomar Gattini InfraRed (1.2 μm) and the Near-Earth Object Wide-field Infrared Survey Explorer (3.4 and 4.6 μm) photometric time-domain surveys. Recent near-infrared imaging reveals a new, extended scattered light nebula. Recent near-infrared spectroscopy confirms the similarity of PGIR 20dci to FU Ori–type sources, based on strong molecular absorption in CO, H{sub 2}O, and OH; weak absorption in several atomic lines; and a warm wind/outflow as indicated by a P Cygni profile in the He i λ10830 line. This is a rare case of an FU Ori star with a well-measured long-term photometric rise before a sharper outburst, and the second instance of an FU Ori star with a documented two-step brightening in the mid-infrared.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2021

Electrocatalytic Isoxazoline–Nanocarbon Metal Complexes

In this work, we report the synthesis of new carbon-nanomaterial-based metal chelates that enable effective electronic coupling to electrocatalytic transition metals. In particular, multiwalled carbon nanotubes (MWCNTs) and few-layered graphene (FLG) were covalently functionalized by a microwave-assisted cyclo-addition with nitrile oxides to form metal-binding isoxazoline functional groups with high densities. The covalent attachment was evidenced by Raman spectroscopy, and the chemical identity of the surface functional groups was confirmed by X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). The functional carbon nanomaterials effectively chelate precious metals Ir(III), Pt(II), and Ru(III), as well as earth-abundant metals such as Ni(II), to afford materials with metal contents as high as 3.0 atom %. The molecularly dispersed nature of the catalysts was confirmed by X-ray absorption spectroscopy (XAS) and energy-dispersive X-ray spectroscopy (STEM-EDS) elemental mapping. The interplay between the chelate structure on the graphene surface and its metal binding ability has also been investigated by a combination of experimental and computational studies. The defined ligands on the graphene surfaces enable the formation of structurally precise heterogeneous molecular catalysts. The direct attachment of the isoxazoline functional group on the graphene surfaces provides strong electronic coupling between the chelated metal species and the conductive carbon nanomaterial support. We demonstrate that the metal-chelated carbon nanomaterials are effective heterogeneous catalysts in the oxygen evolution reaction with low overpotentials and tunable catalytic activity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Co-Assembly of Carbon Nanotube Porins into Biomimetic Peptoid Membranes

Robust and cost-effective membrane-based separations are essential to solving many global crises, such as the lack of clean water. Even though the current polymer-based membranes are widely used for separations, their performance and precision can be enhanced by using a biomimetic membrane architecture that consists of highly permeable and selective channels embedded in a universal membrane matrix. Researchers have shown that artificial water and ion channels, such as carbon nanotube porins (CNTPs), embedded in lipid membranes can deliver strong separation performance. However, their applications are limited by the relative fragility and low stability of the lipid matrix. In this work, we demonstrate that CNTPs can co-assemble into two-dimension (2D) peptoid membrane nanosheets, opening up a way to produce highly programmable synthetic membranes with superior crystallinity and robustness. A combination of molecular dynamics (MD) simulations, Raman spectroscopy, X-ray diffraction (XRD), and atomic force microscopy (AFM) measurements to verify the co-assembly of CNTP and peptoids are used and show that it does not disrupt peptoid monomer packing within the membrane. In conclusion, these results provide a new option for designing affordable artificial membranes and highly robust nanoporous solids.

36 MATERIALS SCIENCE↗
NASA NTRS1974

Research Investigation Directed Toward Extending the Useful Range of the Electromagnetic Spectrum

The report discusses completed and proposed research in atomic and molecular physics conducted at the Columbia Radiation Laboratory from July 1972 to June 1973. Central topics described include the atomic spectra and electronic structure of alkali metals and helium, molecular microwave spectroscopy, the resonance physics of photon echoes in some solid state systems (including Raman echoes, superradiance, and two photon absorption), and liquid helium superfluidity.

Hartmann, S. R.↗
NASA NTRS1977

Ultraviolet absorption: Experiment MA-059

A technique devised to permit the measurement of atmospheric species concentrations is described. This technique involves the application of atomic absorption spectroscopy and the quantitative observation of resonance fluorescence in which atomic or molecular species scatter resonance radiation from a light source into a detector. A beam of atomic oxygen and atomic nitrogen resonance radiation, strong unabsorbable oxygen and nitrogen radiation, and visual radiation was sent from Apollo to Soyuz. The density of atomic oxygen and atomic nitrogen between the two spacecraft was measured by observing the amount of resonance radiation absorbed when the line joining Apollo and Soyuz was perpendicular to their velocity with respect to the ambient atmosphere. Results of postflight analysis of the resonance fluorescence data are discussed.

Donahue, T. M.↗
NASA NTRS2012

Studies of Supernovae, SNR, and Dust with the James Webb Space Telescope

The james Webb Space Telescope (JWST) will provide breakthrough capabilities for the study of supernovae and supernova remnants, as well as many other science objectives. JWST is a large aperture, cryogenic, infrared-optimized general purpose space observatory under construction by NASA, ESA, and CSA for launch in 2018. The JWST instrumentation will provide imaging, coronagraphy, and spectroscopy between 6000A to 29 microns. This spectral region contains many atomic, molecular, and particulate diagnostics that are especially relevant for the study of dust formation. The spectroscopic capabilities include velocity resolution down to approx. 100 km/sec, a near-IR multi-object spectrograph with a approx. 3x3 arcmin field of view array of approx. 250,000 addressable shutters, and near-IR and mid-IR approx. 3x3 arcsec integral field units. The JWST telescope will have a 6.5m-diameter segmented primary mirror and will be diffraction-limited at 2 microns (PSF FWHM - 0.07 arcsec). The imaging and spectroscopic sensitivities will be about 100x lower than previous capabilities in the near- and mid-IR. The JWST observatory will be placed in a L2 orbit by an Ariane 5 launch vehicle provided by ESA. The JWST telescope and instruments will be passively cooled to approx. 40K by a sunshield that will be unfolded after launch. The sunshield geometry limits the JWST pointing on the sky to be between 85 deg and 135 deg from the Sun. The observatory is designed for a 5-year prime science mission, with consumables for 10 years of science operations, and a Target of Opportunity response time of 48 hours.

Sonneborn, George↗
NASA NTRS2012

Operations Concept for Moving Target Observations with the James Webb Space Telescope

The James Webb Space Telescope (JWST) will provide breakthrough capabilities for the study of Solar System objects. JWST is a large aperture, cryogenic, infrared-optimized, general purpose space observatory under construction by NASA, ESA, and CSA for launch in 2018. The JWST instrumentation will provide imaging. coronagraphy, and spectroscopy between 6000A to 29 microns. This spectral region contains many atomic, molecular, and particulate diagnostics that are especially relevant for the study of gaseous, rocky and icy bodies in the Solar System. This talk describes the concept for observations of moving targets, including the system design for acquiring and tracking guide stars to hold the science target fIxed in the instrument field of view.

Sonneborne, George↗
DOE OSTI2020

Cyclopropenylidenes as Strong Carbene Anchoring Groups on Au Surfaces

The creation of stable molecular monolayers on metallic surfaces is a fundamental challenge of surface chemistry. N-Heterocyclic carbenes (NHCs) were recently shown to form self-assembled monolayers that are significantly more stable than the traditional thiols on Au system. In this study, we theoretically and experimentally demonstrate that the smallest cyclic carbene, cyclopropenylidene, binds even more strongly than NHCs to Au surfaces without altering the surface structure. We deposit bis(diisopropylamino)cyclopropenylidene (BAC) on Au(111) using the molecular adduct BAC–CO 2 as a precursor and determine the structure, geometry, and behavior of the surface-bound molecules through high-resolution X-ray photoelectron spectroscopy, atomic force microscopy, and scanning tunneling microscopy. Our experiments are supported by density functional theory calculations of the molecular binding energy of BAC on Au(111) and its electronic structure. Our work is the first demonstration of surface modification with a stable carbene other than NHC; more broadly, it drives further exploration of various carbenes on metal surfaces.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2020

Isomer-specific spectroscopy of aromatics and their resonance-stabilized radical intermediates

There are many circumstances in which complex gas-phase reaction mixtures must be interrogated and understood, including combustion, plasmas, atmospheres, and molecular clouds. Spectroscopic tools are essential to selective detection and characterization of the widening array of precursors and the reactive intermediates they generate. This research program has focused on the development and implementation of sensitive spectroscopic detection schemes that are isomer-specific and even conformation-specific. In particular, we used an array of laser-based and broadband microwave methods to carry out isomer-specific and conformation-specific spectroscopy on large flexible molecules and reactive intermediates formed by photolysis, pyrolysis, combustion, or electron-driven chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗