SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
The combustion of compact samples was studied; the mechanism of autoignition is defined. Several studies are made of the combustibility of titanium using 50 samples. The data provide a clear idea of the combustibility of titanium powders.
The study of combustible particle clouds is of fundamental scientific interest as well as a practical concern. The principal scientific interests are the characteristic combustion properties, especially flame structure, propagation rates, stability limits, and the effects of stoichiometry, particle type, transport phenomena, and nonadiabatic processes on these properties. The feasibility tests for the particle cloud combustion experiment (PCCE) were performed in reduced gravity in the following stages: (1) fuel particles were mixed into cloud form inside a flammability tube; (2) when the concentration of particles in the cloud was sufficiently uniform, the particle motion was allowed to decay toward quiescence; (3) an igniter was energized which both opened one end of the tube and ignited the suspended particle cloud; and (4) the flame proceeded down the tube length, with its position and characteristic features being photographed by high-speed cameras. Gravitational settling and buoyancy effects were minimized because of the reduced gravity enviroment in the NASA Lewis drop towers and aircraft. Feasibility was shown as quasi-steady flame propagation which was observed for fuel-rich mixtures. Of greatest scientific interest is the finding that for near-stoichiometric mixtures, a new mode of flame propagation was observed, now called a chattering flame. These flames did not propagate steadily through the tube. Chattering modes of flame propagation are not expected to display extinction limits that are the same as those for acoustically undisturbed, uniform, quiescent clouds. A low concentration of fuel particles, uniformly distributed in a volume, may not be flammable but may be made flammable, as was observed, through induced segregation processes. A theory was developed which showed that chattering flame propagation was controlled by radiation from combustion products which heated the successive discrete laminae sufficiently to cause autoignition.
This paper presents a method for determining the surface temperature of liquid-oxygen turbopump bearings during the operation of the turbopump. The method relies on the fact that the surface temperature of a bearing can be correlated with the composition of oxides used to cover the bearings, using oxidation samples for calibration and AES for chemical analysis. Using this method, it was found that, for the bearings studied, the maximum temperature reached by stainless steel bearings was 600 C, which is well below the 1100-C autoignition temperature of the AISI stainless steel.
A small, uncooled plasma torch was developed and used in combination with an injector designed to study ignition and flameholding in hydrogen-fueled supersonic flows. The plasma torch was operated on mixtures of hydrogen and argon with total flows of 10 to 70 scfh. The fuel injector design consisted of five small upstream pilot fuel injectors, a rearward facing step for recirculation, and three main fuel injectors downstream of the step. The plasma torch was located in the recirculation region, and all injection was perpendicular to the Mach 2 stream. Both semi-freejet and ducted tests were conducted. The experimental results indicate that a low power plasma torch operating on a 1:1 volumetric mixture of hydrogen and argon and located in the recirculation zone fueled by the upstream pilot fuel injectors is a good igniter for flow conditions simulating a flight Mach number of 3.7. The total temperature required to autoignite the hydrogen fuel for this injector geometry was 2640 R. The injector configuration was shown to be a good flameholder over a wide range of total temperature. Spectroscopic measurements were used to verify the presence of air total temperatures below 1610 R.
Three models have been applied to very rapid compression of oxygen in a dead-ended tube. Pressures as high as 41 MPa (6000 psi) leading to peak temperatures of 1400 K are predicted. These temperatures are well in excess of the autoignition temperature (750 K) of teflon, a frequently used material for lining hoses employed in oxygen service. These findings are in accord with experiments that have resulted in ignition and combustion of the teflon, leading to the combustion of the stainless steel braiding and catastrophic failure. The system analyzed was representative of a capped off-high-pressure oxygen line, which could be part of a larger system. Pressurization of the larger system would lead to compression in the dead-end line, and possible ignition of the teflon liner. The model consists of a large plenum containing oxygen at the desired pressure (500 to 6000 psi). The plenum is connected via a fast acting valve to a stainless steel tube 2 cm inside diameter. Opening times are on the order of 15 ms. Downstream of the valve is an orifice sized to increase filling times to around 100 ms. The total length from the valve to the dead-end is 150 cm. The distance from the valve to the orifice is 95 cm. The models describe the fluid mechanics and thermodynamics of the flow, and do not include any combustion phenomena. A purely thermodynamic model assumes filling to be complete upstream of the orifice before any gas passes through the orifice. This simplification is reasonable based on experiment and computer modeling. Results show that peak temperatures as high as 4800 K can result from recompression of the gas after expanding through the orifice. An approximate transient model without an orifice was developed assuming an isentropic compression process. An analytical solution was obtained. Results indicated that fill times can be considerably shorter than valve opening times. The third model was a finite difference, 1-D transient compressible flow model. Results from the code show the recompression effect but predict much lower peak temperatures than the thermodynamic model.
Nitrogen oxide levels of low gas turbine engine emissions are correlated in this paper. The predictions of NO(x) emissions are based on a review of the literature of previous low NO(x) combustor programs and analytical chemical kinetic calculations. Concepts included in the literature review consisted of Lean-Premixed-Prevaporized (LPP), Rich Burn/Quick Quench/Lean/Burn (RQL), and Direct Injection. The NO(x) emissions were found to be an exponential function of adiabatic combustion temperature over a wide range of inlet temperatures, pressures and (lean) fuel-air ratios. It is stated that the low NO(X) potential of LPP is offset by the operational disadvantages of its narrow stability limits and its susceptibility to autoignition/ flashback. The RQL and the Direct Injection concepts have the advantage of wider stability limits comparable to conventional combustors. Results were obtained primarily with gaseous fuels and it is noted that the challenge will be to produce the same low levels of NO(x) with liquid fuels.
A scramjet combustor with four wall-ramp injectors containing Mach-1.7 fuel jets in the base of the ramps was investigated experimentally. During the test program, two swept ramp injector designs were evaluated. One swept-ramp model had 10-deg compression-ramps and the other had 10-deg expansion cavities between flush wall ramps. The scramjet combustor model was instrumented with pressure taps and heat-flux gages. The pressure measurements indicated that both injector configurations were effective in promoting mixing and combustion. Autoignition occurred for the compression-ramp injectors, and the fuel began to burn immediately downstream of the injectors. In tests of the expansion ramps, a pilot was required to ignite the fuel, and the fuel did not burn for a distance of at least two gaps downstream of the injectors. Once initiated, combustion was rapid in this configuration. Heat transfer measurements showed that the heat flux differed greatly both across the width of the combustor and along the length of the combustor.
This study demonstrates that the computational fluid dynamics (CFD) code GASP can be used to predict the features for flowfields representative of scramjet combustors. The validation program undertaken was composed of two parts: a low enthalpy mixing study and a simplified autoignition study. The low enthalpy mixing study was done using low angle helium injection into a Mach 6 airstream over a flat plate. Both matched and overpressurized injection cases were numerically modelled. The agreement with experimental data for the farfield bulk mixing in both cases was reasonable. The combustion studies modelled premixed hydrogen-air reaction with the results being evaluated qualitatively. GASP proved to be highly sensitive to the chemical species present for flow near the ignition temperature, but provided reasonable qualitative results for a subsonic flameholder model.
The purpose of this investigation was to provide an automatic injection valve of simple construction which would produce a finely atomized oil spray of broad cone angle and would fulfill the requirements of fuel injection in aircraft oil engines. The injection valve designed has only six parts - i. e., two concentric nozzle tubes flared at one end, two body parts, and two nuts. Analysis and engine tests indicate that the fuel spray from this type of injection valve has characteristics which reduce the time lag of autoignition and promote efficient combustion in high-speed oil engines.
Report presents the results of a study of combustion in a spark-ignition engine given in NACA Technical Reports 704 and 727. The present investigation was made with the NACA high-speed motion-picture camera, operating at 40,000 photographs a second, and with a cathode-ray oscillograph operating on a piezoelectric pick-up in the combustion chamber. Photographs are presented showing that the origin of knock is not necessarily in the end gas. The data obtained indicates that knock takes place only in a part of the cylinder charge which has been previously ignited either by autoignition or by the passage of the flame fronts but which has not burned to completion. Mottled regions in the high-speed Schlieren photographs are demonstrated to represent combustion regions.
The high-speed photographic investigation of the mechanics of spark-ignition engine knock recorded in three previous reports has been extended with use of the NACA high-speed camera and combustion apparatus with a piezoelectric pressure pickup in the combustion chamber. The motion pictures of knocking combustion were taken at the rate of 40,000 frames per second. Existence of the preknock vibrations in the engine cylinder suggested in Technical Report no.727 has been definitely proved and the vibrations have been analyzed both in the high-speed motion pictures and the pressure traces. Data are also included to show that the preknock vibrations do not progressively build up to cause knock. The effect of tetraethyl lead on the preknock vibrations has been studied and results of the tests are presented. Photographs are presented which in some cases clearly show evidence of autoignition in the end zone a considerable length of time before knock occurs.
A motion picture of the development of knock in a spark-ignition engine, is presented, which consists of 20 photographs taken at intervals of 5 microseconds, or at a rate of 200,000 photographs a second, with an equivalent wide-open exposure time of 6.4 microseconds for each photograph. A motion picture of a complete combustion process, including the development of knock, taken at the rate of 40,000 photographs a second is also presented to assist the reader in orienting the photographs of the knock development taken at 200,000 frames per second. The photographs taken at 200,000 frames per second are analyzed and the conclusion is made that the type of knock in the spark-ignition engine involving violent gas vibration originates as self-propagating disturbance starting at a point in the.burn1ig or autoigniting gases and spreading out from that point through the incompletely burned gases at a rate as high as 6800 feet per second, or about twice the speed of sound in the burned gases. Apparent formation of free carbon particles in both the burning and the burned gas is observed within 10 microseconds after passage of the knock disturbance through the gases.
An investigation was conducted to develop appropriate technologies for a low-NO(x), liquid-fueled combustor. The combustor incorporates an effervescent atomizer used to inject fuel into a premixing duct. Only a fraction of the combustion air is used in the premixing process to avoid autoignition and flashback problems. This fuel-rich mixture is introduced into the remaining combustion air by a rapid jet-shear-layer-mixing process involving radial fuel-air jets impinging on axial air jets in the primary combustion zone. Computational analysis was used to provide a better understanding of the fluid dynamics that occur in jet-shear-layer mixing and to facilitate a parametric analysis appropriate to the design of an optimum low-NO(x) combustor. A number of combustor configurations were studied to assess the key combustor technologies and to validate the modeling code. The results from the experimental testing and computational analysis indicate a low-NO(x) potential for the jet-shear-layer combustor. Key parameters found to affect NO(x) emissions are the primary combustion zone fuel-air ratio, the number of axial and radial jets, the aspect ratio and radial location of the axial air jets, and the radial jet inlet hole diameter. Each of these key parameters exhibits a low-NO(x) point from which an optimized combustor was developed. Using the parametric analysis, NO(x) emissions were reduced by a factor of 3 as compared with the emissions from conventional, liquid-fueled combustors operating at cruise conditions. Further development promises even lower NO(x) with high combustion efficiency.
A castable inhibitor is applied to the aft face of the Space Shuttle Redesigned Solid Rocket Motor (RSRM) forward segment propellant grain to control propellant surface burn area. During fabrication, the propellant surface is trimmed prior to the inhibitor application. This produces a potential for small propellant chips to remain undetected on the propellant surface and contaminate the inhibitor during application. The concern was that undetected propellant chips in the inhibitor might provide a fuse path for premature propellant ignition underneath the inhibitor. To evaluate the fuse path potential, testing was performed on inhibitor samples with embedded propellant. The internal motor environment was simulated with a calibrated CO2 laser beam directed onto a sample which was placed in a 4100 kPa (600 psi) nitrogen pressurized bomb (laser bomb). The testing showed definitive results pertaining to fuse path formation. Embedded propellant chips did not autoignite until the receding heat affected inhibitor surface reached, or passed, the propellant chip. Samples with embedded propellant chips in alignment did not propagate ignition from one chip to another with separation distances as small as 0.010 cm(0.004 inc) and some as little as 0.0051 cm (0.002 in). Propellant chips with volumes approximately less than 0.025 cu cm (0.0015 cu in) (which did not propagate ignition) did not increase the inhibitor material decomposition depth more than the resulting void cavity of the burned out propellant chip. In addition, the depth of this void cavity did not increase until it was overtaken by the surrounding material decomposition depth. This was due, in part, to the retention of the protective inhibitor char layer. Samples with embedded propellant strings, whose thicknesses were below 0.023 cm (0.009 in), did not propagate ignition. Propellant string thicknesses above 0.038 cm (0.015 in) did propagate ignition. Test sample char and heat affected layer measurements and observations compared well with those from the Space Shuttle Solid Rocket Motor (SRM) Technical Evaluation Motor no. 9(TEM-9).
The NASA White Sands Test Facility (WSTF) is developing cleaning and verification processes to replace currently used chlorofluorocarbon-113- (CFC-113-) based processes. The processes being evaluated include both aqueous- and solvent-based techniques. The presentation will include the findings of investigations of aqueous cleaning and verification processes that are based on a draft of a proposed NASA Kennedy Space Center (KSC) cleaning procedure. Verification testing with known contaminants, such as hydraulic fluid and commonly used oils, established correlations between nonvolatile residue and CFC-113. Recoveries ranged from 35 to 60 percent of theoretical. WSTF is also investigating enhancements to aqueous sampling for organics and particulates. Although aqueous alternatives have been identified for several processes, a need still exists for nonaqueous solvent cleaning, such as the cleaning and cleanliness verification of gauges used for oxygen service. The cleaning effectiveness of tetrachloroethylene (PCE), trichloroethylene (TCE), ethanol, hydrochlorofluorocarbon-225 (HCFC-225), tert-butylmethylether, and n-Hexane was evaluated using aerospace gauges and precision instruments and then compared to the cleaning effectiveness of CFC-113. Solvents considered for use in oxygen systems were also tested for oxygen compatibility using high-pressure oxygen autoignition and liquid oxygen mechanical impact testing.
A wave rotor may be used as a pressure-gain combustor effecting non-steady flow, and intermittent, confined combustion to enhance gas turbine engine performance. It will be more compact and probably lighter than an equivalent pressure-exchange wave rotor, yet will have similar thermodynamic and mechanical characteristics. Because the allowable turbine blade temperature limits overall fuel/air ratio to sub-flammable values, premixed stratification techniques are necessary to burn hydrocarbon fuels in small engines with compressor discharge temperature well below autoignition conditions. One-dimensional, unsteady numerical simulations of stratified-charge combustion are performed using an eddy-diffusivity turbulence model and a simple reaction model incorporating a flammability limit temperature. For good combustion efficiency, a stratification strategy is developed which concentrates fuel at the leading and trailing edges of the inlet port. Rotor and exhaust temperature profiles and performance predictions are presented at three representative operating conditions of the engine: full design load, 40% load, and idle. The results indicate that peak local gas temperatures will result in excessive temperatures within the rotor housing unless additional cooling methods are used. The rotor itself will have acceptable temperatures, but the pattern factor presented to the turbine may be of concern, depending on exhaust duct design and duct-rotor interaction.
Nonpremixed (diffusion) flames are attractive for practical applications because they avoid the stability, autoignition, flashback, etc. problems of premixed flames. Unfortunately, soot formation in practical hydrocarbon-fueled diffusion flames reduces their attractiveness due to widely-recognized public health and combustor durability problems of soot emissions. For example, more deaths are attributed to the emission of soot (15,000-60,000 deaths annually in the U.S. alone) than any other combustion-generated pollutant. In addition, continuum radiation from soot-containing flames is the principle heat load to combustor components and is mainly responsible for engine durability problems of aircraft and gas turbine engines. As a result, there is considerable interest in controlling both soot concentrations within flames and soot emissions from flames. Thus, the objective of the present investigation is to study ways to control soot formation in diffusion flames by manipulating the mixing process between the fuel and oxidant streams. In order to prevent the intrusion of gravity from masking flow properties that reduce soot formation in practical flames (where effects of gravity are small), methods developed during past work will be exploited to minimize effects of buoyant motion.
An experimental investigation is presented of a novel vitiated coflow spray flame burner. The vitiated coflow emulates the recirculation region of most combustors, such as gas turbines or furnaces; additionally, since the vitiated gases are coflowing, the burner allows exploration of the chemistry of recirculation without the corresponding fluid mechanics of recirculation. As such, this burner allows for chemical kinetic model development without obscurations caused by fluid mechanics. The burner consists of a central fuel jet (droplet or gaseous) surrounded by the oxygen rich combustion products of a lean premixed flame that is stabilized on a perforated, brass plate. The design presented allows for the reacting coflow to span a large range of temperatures and oxygen concentrations. Several experiments measuring the relationships between mixture stoichiometry and flame temperature are used to map out the operating ranges of the coflow burner. These include temperatures as low 300 C to stoichiometric and oxygen concentrations from 18 percent to zero. This is achieved by stabilizing hydrogen-air premixed flames on a perforated plate. Furthermore, all of the CO2 generated is from the jet combustion. Thus, a probe sample of NO(sub X) and CO2 yields uniquely an emission index, as is commonly done in gas turbine engine exhaust research. The ability to adjust the oxygen content of the coflow allows us to steadily increase the coflow temperature surrounding the jet. At some temperature, the jet ignites far downstream from the injector tube. Further increases in the coflow temperature results in autoignition occurring closer to the nozzle. Examples are given of methane jetting into a coflow that is lean, stoichiometric, and even rich. Furthermore, an air jet with a rich coflow produced a normal looking flame that is actually 'inverted' (air on the inside, surrounded by fuel). In the special case of spray injection, we demonstrate the efficacy of this novel burner with a methanol spray in a vitiated coflow. As a proof of concept, an ensemble light diffraction (ELD) optical instrument was used to conduct preliminary measurements of droplet size distribution and liquid volume fraction.