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NASA NTRS2015

Connections Between the TTL and Sea Surface Temperatures: Interannual Variability and Trends

Comprehensive chemistry climate models and satellite data are used to investigate the forcing of variability in the tropical lower stratosphere and upper troposphere. As this region is the origination region for air parcels which enter the stratosphere, it is important to understand variability in this region on timescales ranging from the seasonal to decadal. The warming trend in the tropical upper troposphere over the past 30 years is strongest near the Indo Pacific warm pool, while the warming trend in the western and central Pacific is much weaker. In the lower stratosphere, these trends are reversed: the historical cooling trend is strongest over the Indo Pacific warm pool and is weakest in the western and central Pacific. These zonal variations are stronger than the zonal mean response in boreal winter. Targeted experiments with a chemistry climate model are used to demonstrate that sea surface temperature trends are driving the zonal asymmetry in upper tropospheric and lower stratospheric tropical temperature trends. The anomalous circulation set up by the changing SSTs has led to zonal structure in the ozone and water vapor trends near the tropopause, and subsequently to less water vapor entering the stratosphere. Projected future sea surface temperatures appear to drive a temperature and water vapor response whose zonal structure is similar to the historical response. In the lower stratosphere, the changes in water vapor and temperature due to projected future sea surface temperatures is of similar strength to, though slightly weaker than, that due directly to projected future CO2, ozone, and methane. Finally, targeted experiments with a chemistry climate model are used to demonstrate that seasonality and the location of the peak warming of sea surface temperatures dictate the response of stratospheric water vapor to El Nino. In spring, El Nino events in which sea surface temperature anomalies peak in the eastern Pacific lead to a warming at the tropopause above the warm pool region, and subsequently to more stratospheric water vapor (consistent with previous work). However, in fall and in early winter, and also during El Nino events in which the sea surface temperature anomaly is found mainly in the central Pacific, the response is qualitatively different: temperature changes in the warm pool region are nonuniform and less water vapor enters the stratosphere. The difference in water vapor in the lower stratosphere between the two variants of El Nino approaches 0.3 ppmv, while the difference between the winter and spring responses exceeds 0.5 ppmv.

Tropical Tropopause Layer↗

NASA NTRS2012

The Connection between Model Performance on the CCMVal Transport Diagnostics and Simulated Sensitivity of Ozone to Chlorine Change

The chemistry climate models that contributed simulations for past and future ozone evolution to the 2010 Scientific Assessment of Ozone Depletion were subject to extensive evaluation by the SPARC (Stratospheric Processes and their Role in Climate) CCMVal (Chemistry-Climate Model Validation) activity. The sensitivity of ozone to changes in composition and climate varies among the models, but the relationship between these variations and the model evaluations of CCMVal is not obvious. We have learned that the transport evaluation can be used to interpret the comparisons between observed and simulated columns of chlorine reservoirs, hydrochloric acid (HCl) and chlorine nitrate (ClONO2); these comparisons were part of the CCMVal evaluation of chemistry. The simulations with best performance on the transport diagnostics most faithfully reproduce the evolution and seasonal variation of the chlorine reservoirs as observed at NDACC (Network for Detection of Atmospheric Composition Change) stations (NyAlesund 78.9N, Kiruna 67.8N, Harestua 60.2N, Jungfraujoch 46.6N, Toronto 43.6N, Kitt Peak 31.9N, Izana 28.3N, Mauna Loa 19.5N, Lauder 45S and Arrival Heights 77.8S). In the simulations, the HCl in the lower stratosphere depends on total inorganic chlorine (Cly) and partitioning between HCl and ClON02. Total inorganic chlorine depends on the fractional release of chlorine from source gases, and ratio of ClON02 to HCl is inversely dependent on methane and varies quadratically with ozone. Simulated HCl from various models may agree with observations even though Cly is in error, partitioning is in error, or both. Simulated ozone sensitivity to chlorine is shown to be greater for models that produce larger values of chlorine nitrate for background chlorine levels, and vice versa. Comparisons with the NDACC data show why the models with 'best' transport have similar sensitivity to chlorine change. The realistic evolution of the simulated HCl and ClONO2 columns suggests realistic levels of Cly in the lower atmosphere. In addition, the wide range values for the sensitivity of ozone to chlorine obtained from the CCMVal simulations is explained by the wide range in lower atmospheric columns of ClONO2 and the concomitant wide range of levels for chlorine monoxide.

Douglass, Anne↗

DOE OSTI2023

An inconsistency in aviation emissions between CMIP5 and CMIP6 and the implications for short-lived species and their radiative forcing

We report on an inconsistency in the latitudinal distribution of aviation emissions between the data products of phases 5 and 6 of the Coupled Model Intercomparison Project (CMIP). Emissions in the CMIP6 data occur at higher latitudes than in the CMIP5 data for all scenarios, years, and emitted species. A comparative simulation with the chemistry–climate model ECHAM/MESSy Atmospheric Chemistry (EMAC) reveals that the difference in nitrogen oxide emission distribution leads to reduced overall ozone changes due to aviation in the CMIP6 scenarios because in those scenarios the distribution of emissions is partly shifted towards the chemically less active higher latitudes. The radiative forcing associated with aviation ozone is 7.6 % higher, and the decrease in methane lifetime is 5.7 % larger for the year 2015 when using the CMIP5 latitudinal distribution of emissions compared to when using the CMIP6 distribution. We do not find a statistically significant difference in the radiative forcing associated with aviation aerosol emissions. In total, future studies investigating the effects of aviation emissions on ozone and climate should consider the inconsistency reported here.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2015

Impact of Stratospheric Ozone Zonal Asymmetries on the Tropospheric Circulation

The depletion and recovery of Antarctic ozone plays a major role in changes of Southern Hemisphere (SH) tropospheric climate. Recent studies indicate that the lack of polar ozone asymmetries in chemistry climate models (CCM) leads to a weaker and warmer Antarctic vortex, and smaller trends in the tropospheric mid-latitude jet and the surface pressure. However, the tropospheric response to ozone asymmetries is not well understood. In this study we report on a series of integrations of the Goddard Earth Observing System Chemistry Climate Model (GEOS CCM) to further examine the effect of zonal asymmetries on the state of the stratosphere and troposphere. Integrations with the full, interactive stratospheric chemistry are compared against identical simulations using the same CCM except that (1) the monthly mean zonal mean stratospheric ozone from first simulation is prescribed and (2) ozone is relaxed to the monthly mean zonal mean ozone on a three day time scale. To analyze the tropospheric response to ozone asymmetries, we examine trends and quantify the differences in temperatures, zonal wind and surface pressure among the integrations.

Chemistry-Climate Modeling↗

NASA NTRS2018

Effects of Greenhouse Gas Increase and Stratospheric Ozone Depletion on Stratospheric Mean Age of Air in 1960-2010

The relative impacts of greenhouse gas (GHG) increase and stratospheric ozone depletion on stratospheric mean age of air in the 1960-2010 period are quantified using the Goddard Earth Observing System Chemistry-Climate Model. The experiment compares controlled simulations using a coupled atmosphere-ocean version of the Goddard Earth Observing System Chemistry-Climate Model, in which either GHGs or ozone depleting substances, or both factors evolve over time. The model results show that GHGs and ozone-depleting substances have about equal contributions to the simulated mean age decrease, but GHG increases account for about two thirds of the enhanced strength of the lower stratospheric residual circulation. It is also found that both the acceleration of the diabatic circulation and the decrease of the mean age difference between downwelling and upwelling regions are mainly caused by GHG forcing. The results show that ozone depletion causes an increase in the mean age of air in the Antarctic summer lower stratosphere through two processes: (1) a seasonal delay in the Antarctic polar vortex breakup that inhibits young midlatitude air from mixing with the older air inside the vortex, and (2) enhanced Antarctic downwelling that brings older air from middle and upper stratosphere into the lower stratosphere.

stratospheric ozone depletion↗

NASA NTRS2020

Lower-Stratospheric Tracer Trends and Variability from Reanalyses

Previous studies have robustly identified a decrease since 1998 in lower stratospheric ozone in the Northern Hemisphere (NH). While this ozone decrease is qualitatively explained as resulting from changes in the large-scale circulation, there is not yet a quantitative mechanistic explanation of these changes. Here we explore the drivers of recent ozone changes using two different configurations of the Goddard Earth Observing System (GEOS) general circulation model. The first configuration of GEOS includes a full chemistry module and is constrained with meteorological fields from the MERRA-2 reanalysis. This configuration (M2GMI) is used to analyze an idealized tracer that covaries closely with ozone on interannual and decadal timescales, revealing that recent ozone decreases in the NH subtropics are associated with a poleward expansion of upwelling in the NH LS, with reduced (enhanced) downwelling over northern subtropics (midlatitudes). The second configuration of GEOS is a free-running version of the GEOS Chemistry-Climate Model (CCM) that is used to perform a ten-member ensemble of free-running simulations. Comparisons of the two configurations reveal that, while the free-running model can produce negative ozone changes in the NH LS, the magnitude of these changes is significantly weaker, relative to both M2GMI and MERRA-2; moreover, these weaker ozone decreases are consistent with weaker simulated changes in the residual circulation. Finally, we examine the GEOS model results in the broader context of the hindcast simulations performed as part of Phase 1 of the Chemistry Climate Modeling Initiative. We show that the majority of the free-running simulations considered here also exhibit weaker long-term residual circulation changes, compared to reanalyses.

Wargan, Kris↗

NASA NTRS2020

Mechanisms Linked to Recent Ozone Decreases in the Northern Hemisphere Lower Stratosphere

Previous studies have robustly identified a decrease since 1998 in lower stratospheric (LS) ozone in the Northern Hemisphere (NH). While this ozone decrease is qualitatively explained as resulting from changes in the large‐scale circulation, there is not yet a quantitative mechanistic explanation of these changes. Here we explore the drivers of recent ozone changes using two different configurations of the Goddard Earth Observing System (GEOS) general circulation model. The first configuration of GEOS includes a full chemistry module and is constrained with meteorological fields from the Modern‐Era Retrospective analysis for Research and Applications, Version 2 (MERRA‐2). This configuration (M2GMI) is used to analyze an idealized tracer that covaries closely with ozone on interannual and decadal timescales, revealing that recent ozone decreases in the NH subtropics are associated with a poleward expansion of upwelling in the NH LS, with reduced (enhanced) downwelling over northern subtropics (midlatitudes). The second configuration of GEOS is a free‐running version of the GEOS Chemistry‐Climate Model (CCM) that is used to perform a ten‐member ensemble of free‐running simulations. Comparisons of the two configurations reveal that, while the free‐running model can produce negative ozone changes in the NH LS, the magnitude of these changes is significantly weaker, relative to both M2GMI and MERRA‐2; moreover, these weaker ozone decreases are consistent with weaker simulated changes in the residual circulation. Finally, we examine the GEOS model results in the broader context of the hindcast simulations performed as part of Phase 1 of the Chemistry Climate Modeling Initiative. We show that the majority of the free‐running simulations considered here also exhibit weaker long‐term residual circulation changes, compared to reanalyses.

Ozone↗

NASA NTRS2013

Temperature Trends in the Tropical Upper Troposphere and Lower Stratosphere: Connections with Sea Surface Temperatures and Implications for Water Vapor and Ozone

Satellite observations and chemistry-climate model experiments are used to understand the zonal structure of tropical lower stratospheric temperature, water vapor, and ozone trends. The warming in the tropical upper troposphere over the past 30 years is strongest near the Indo-Pacific warm pool, while the warming trend in the western and central Pacific is much weaker. In the lower stratosphere, these trends are reversed: the historical cooling trend is strongest over the Indo-Pacific warm pool and is weakest in the western and central Pacific. These zonal variations are stronger than the zonal-mean response in boreal winter. Targeted experiments with a chemistry-climate model are used to demonstrate that sea surface temperature (hereafter SST) trends are driving the zonal asymmetry in upper tropospheric and lower stratospheric tropical temperature trends. Warming SSTs in the Indian Ocean and in the warm pool region have led to enhanced moist heating in the upper troposphere, and in turn to a Gill-like response that extends into the lower stratosphere. The anomalous circulation has led to zonal structure in the ozone and water vapor trends near the tropopause, and subsequently to less water vapor entering the stratosphere. The radiative impact of these changes in trace gases is smaller than the direct impact of the moist heating. Projected future SSTs appear to drive a temperature and water vapor response whose zonal structure is similar to the historical response. In the lower stratosphere, the changes in water vapor and temperature due to projected future SSTs are of similar strength to, though slightly weaker than, that due directly to projected future CO2, ozone, and methane.

water vapor↗

NASA NTRSDate not supplied

Projecting the Lasting Fate of the Hunga Tonga-Hunga Ha’apai Eruption on the Stratosphere through Connecting Measurements to Models

On 15th Jan. 2022 the submarine volcano Hunga Tonga-Hunga Ha’apai (HTHH) injected approximately 0.5 Tg of sulfur dioxide into the stratosphere, but more significantly added 150-170 Tg of water vapor to the stratospheric background (over a 10% perturbation) in a matter of several hours. The sulfur dioxide rapidly converted to sulfate aerosol and along with water vapor, was transported around the Southern Hemisphere sub-tropics into midlatitudes with some transport into the Northern Hemisphere. With a much longer lifetime than sulfate aerosol, measurable water vapor mass anomalies have persisted with only small losses over the past almost 2 years and are likely to continue above background for the remainder of the decade. Satellite measurements from limb and nadir viewing observing instruments provide the information needed to reasonably initialize the HTHH eruption in the Goddard Earth Observing System (GEOS) model using the “replay” framework coupled to the Global Modeling Initiative (GMI) stratosphere-troposphere chemical mechanism for the recent past and continue the simulations into the future with the free running chemistry climate model (CCM). Using a number of model ensemble members together with the satellite observations, we quantify how the HTHH eruption is perturbing stratospheric composition and climate and projecting the influences to come as the enhanced water vapor continues in the stratosphere with only very slow removal mechanisms. HTHH eruption provides a useful test of chemistry climate models and an opportunity for observation-based process understanding, which we will highlight.

Hunga Tonga-Hunga Ha’apai↗

NASA NTRSDate not supplied

Observing and Projecting the Lasting Fate of the Hunga Eruption on Atmospheric Water Vapor and Hydroxyl Radical

On 15th Jan. 2022 the submarine Hunga volcano erupted injecting approximately 0.5 Tg of sulfur dioxide into the stratosphere, but more significantly added 150-170 Tg of water vapor to the stratospheric background (over a 10% perturbation) in a matter of several hours. The sulfur dioxide rapidly converted to sulfate aerosol and along with water vapor, was transported around the Southern Hemisphere sub-tropics into midlatitudes and beyond with some transport into the Northern Hemisphere. With a much longer lifetime than sulfate aerosol, measurable water vapor mass anomalies have persisted with only small losses over more than 2 years since the eruption and are likely to continue above background for the remainder of the decade. Satellite measurements from limb and nadir viewing observing instruments provide the information needed to reasonably initialize the Hunga eruption in the Goddard Earth Observing System (GEOS) model using the “replay” framework coupled to the Global Modeling Initiative (GMI) stratosphere-troposphere chemical mechanism for the recent past and have continued the simulations into the future with the free running chemistry climate model (CCM). Using a number of model ensemble members together with the satellite observations, we quantify how the Hunga eruption is perturbing atmospheric composition and climate and projecting the influences to come as the enhanced water vapor continues in the stratosphere with only very slow removal mechanisms. Modeling suggests that the water rich eruption enhanced stratospheric hydroxyl radiacal (OH) and is supported by the speed of the observed conversion of SO2 into sulfate aerosol. These simulations also suggest a significant reduction in tropospheric OH over the mid-high latitude Southern Hemisphere, which has implications for numerous species that are impacted by this radical. The Hunga eruption provides a useful test of chemistry climate models and an opportunity for observation-based process understanding and in making new connections.

Hunga volcano↗

NASA NTRS2020

GISS Model E2.2: A Climate Model Optimized for the Middle Atmosphere. Part 2: Validation of Large-Scale Transport and Evaluation of Climate Response

Here we examine the large‐scale transport characteristics of the new ``Middle Atmosphere" NASA Goddard Institute for Space Studies climate model (E2.2). First we evaluate the stratospheric transport circulation in historical atmosphere‐only simulations integrated with interactive trace gas and aerosol chemistry. Compared to lower vertical resolution model versions, E2.2 exhibits improved tropical ascent and older stratospheric mean ages that are more consistent with observed values. In the troposphere, poleward transport to the Arctic and interhemispheric mean ages in E2.2 are comparable to models participating in the Chemistry Climate Modeling Initiative. In addition to validating E2.2 we also assess its ``transport sensitivity" using the coupled atmosphere‐ocean abrupt 4xCO2 and transient 1%CO2 simulations submitted to the Coupled Model Intercomparison Project, Phase 6, along with a 2xCO2 simulation used to evaluate the linearity of the transport circulation's response to increased CO2. We show that decreases (increases) in a stratospheric mean age (idealized surface loss) tracer scale linearly with increased lower stratospheric upwelling, which also increases linearly with warming tropical sea surface temperatures (SSTs). Abrupt 2xCO2 and 4xCO2 experiments constrained with (fixed) pre‐industrial SSTs are also used to quantify the relative importance of rapid adjustments versus SST feedbacks to the transport circulation responses in the model. Finally, sensitivity experiments are presented to illustrate the impact of changes in the convective parameterization on stratospheric transport.

GISS Model E2.2↗

NASA NTRS2016

Analysis of Ozone in Cloudy Versus Clear Sky Conditions

Convection impacts ozone concentrations by transporting ozone vertically and by lofting ozone precursors from the surface, while the clouds and lighting associated with convection affect ozone chemistry. Observations of the above-cloud ozone column (Ziemke et al., 2009) derived from the OMI instrument show geographic variability, and comparison of the above-cloud ozone with all-sky tropospheric ozone columns from OMI indicates important regional differences. We use two global models of atmospheric chemistry, the GMI chemical transport model (CTM) and the GEOS-5 chemistry climate model, to diagnose the contributions of transport and chemistry to observed differences in ozone between areas with and without deep convection, as well as differences in clean versus polluted convective regions. We also investigate how the above-cloud tropospheric ozone from OMI can provide constraints on the relationship between ozone and convection in a free-running climate simulation as well as a CTM.

Cloud↗

NASA NTRS1997

Coupling Processes Between Atmospheric Chemistry and Climate

This is the first semi-annual report for NAS5-97039 summarizing work performed for January 1997 through June 1997. Work in this project is related to NAS1-20666, also funded by NASA ACMAP. The work funded in this project also benefits from work at AER associated with the AER three-dimensional isentropic transport model funded by NASA AEAP and the AER two-dimensional climate-chemistry model (co-funded by Department of Energy). The overall objective of this project is to improve the understanding of coupling processes between atmospheric chemistry and climate. Model predictions of the future distributions of trace gases in the atmosphere constitute an important component of the input necessary for quantitative assessments of global change. We will concentrate on the changes in ozone and stratospheric sulfate aerosol, with emphasis on how ozone in the lower stratosphere would respond to natural or anthropogenic changes. The key modeling tools for this work are the AER two-dimensional chemistry-transport model, the AER two-dimensional stratospheric sulfate model, and the AER three-wave interactive model with full chemistry.

Ko, M. K. W.↗

DOE OSTI2021

Development and Evaluation of Chemistry‐Aerosol‐Climate Model CAM5‐Chem‐MAM7‐MOSAIC: Global Atmospheric Distribution and Radiative Effects of Nitrate Aerosol

Abstract An advanced aerosol treatment, with a focus on semivolatile nitrate formation, is introduced into the Community Atmosphere Model version 5 with interactive chemistry (CAM5‐chem) by coupling the Model for Simulating Aerosol Interactions and Chemistry (MOSAIC) with the 7‐mode Modal Aerosol Module (MAM7). An important feature of MOSAIC is dynamic partitioning of all condensable gases to the different fine and coarse mode aerosols, as governed by mode‐resolved thermodynamics and heterogeneous chemical reactions. Applied in the free‐running mode from 1995 to 2005 with prescribed historical climatological conditions, the model simulates global distributions of sulfate, nitrate, and ammonium in good agreement with observations and previous studies. Inclusion of nitrate resulted in ∼10% higher global average accumulation mode number concentrations, indicating enhanced growth of Aitken mode aerosols from nitrate formation. While the simulated accumulation mode nitrate burdens are high over the anthropogenic source regions, the sea‐salt and dust modes respectively constitute about 74% and 17% of the annual global average nitrate burden. Regional clear‐sky shortwave radiative cooling of up to −5 W m −2 due to nitrate is seen, with a much smaller global average cooling of −0.05 W m −2 . Significant enhancements in regional cloud condensation nuclei (at 0.1% supersaturation) and cloud droplet number concentrations are also attributed to nitrate, causing an additional global average shortwave cooling of −0.8 W m −2 . Taking into consideration of changes in both longwave and shortwave radiation under all‐sky conditions, the net change in the top of the atmosphere radiative fluxes induced by including nitrate aerosol is −0.7 W m −2 .

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2016

The Effect of Future Ambient Air Pollution on Human Premature Mortality to 2100 Using Output from the ACCMIP Model Ensemble

Ambient air pollution from ground-level ozone and fine particulate matter (PM(sub 2.5)) is associated with premature mortality. Future concentrations of these air pollutants will be driven by natural and anthropogenic emissions and by climate change. Using anthropogenic and biomass burning emissions projected in the four Representative Concentration Pathway scenarios (RCPs), the ACCMIP ensemble of chemistry climate models simulated future concentrations of ozone and PM(sub 2.5) at selected decades between 2000 and 2100. We use output from the ACCMIP ensemble, together with projections of future population and baseline mortality rates, to quantify the human premature mortality impacts of future ambient air pollution. Future air-pollution-related premature mortality in 2030, 2050 and 2100 is estimated for each scenario and for each model using a health impact function based on changes in concentrations of ozone and PM(sub 2.5) relative to 2000 and projected future population and baseline mortality rates. Additionally, the global mortality burden of ozone and PM(sub 2.5) in 2000 and each future period is estimated relative to 1850 concentrations, using present-day and future population and baseline mortality rates. The change in future ozone concentrations relative to 2000 is associated with excess global premature mortality in some scenarios/periods, particularly in RCP8.5 in 2100 (316 thousand deaths per year), likely driven by the large increase in methane emissions and by the net effect of climate change projected in this scenario, but it leads to considerable avoided premature mortality for the three other RCPs. However, the global mortality burden of ozone markedly increases from 382000 (121000 to 728000) deaths per year in 2000 to between 1.09 and 2.36 million deaths per year in 2100, across RCPs, mostly due to the effect of increases in population and baseline mortality rates. PM(sub 2.5) concentrations decrease relative to 2000 in all scenarios, due to projected reductions in emissions, and are associated with avoided premature mortality, particularly in 2100: between 2.39 and 1.31 million deaths per year for the four RCPs. The global mortality burden of PM(sub 2.5) is estimated to decrease from 1.70 (1.30 to 2.10) million deaths per year in 2000 to between 0.95 and 1.55 million deaths per year in 2100 for the four RCPs due to the combined effect of decreases in PM(sub 2.5) concentrations and changes in population and baseline mortality rates. Trends in future air-pollution-related mortality vary regionally across scenarios, reflecting assumptions for economic growth and air pollution control specific to each RCP and region. Mortality estimates differ among chemistry climate models due to differences in simulated pollutant concentrations, which is the greatest contributor to overall mortality uncertainty for most cases assessed here, supporting the use of model ensembles to characterize uncertainty. Increases in exposed population and baseline mortality rates of respiratory diseases magnify the impact on premature mortality of changes in future air pollutant concentrations and explain why the future global mortality burden of air pollution can exceed the current burden, even where air pollutant concentrations decrease.

Silva, Raquel A.↗

NASA NTRS2013

Stratospheric Ozone Response in Experiments G3 and G4 of the Geoengineering Model Intercomparison Project (GeoMIP)

Geoengineering with stratospheric sulfate aerosols has been proposed as a means of temporarily cooling the planet, alleviating some of the side effects of anthropogenic CO2 emissions. However, one of the known side effects of stratospheric injections of sulfate aerosols is a decrease in stratospheric ozone. Here we show results from two general circulation models and two coupled chemistry climate models that have simulated stratospheric sulfate aerosol geoengineering as part of the Geoengineering Model Intercomparison Project (GeoMIP). Changes in photolysis rates and upwelling of ozone-poor air in the tropics reduce stratospheric ozone, suppression of the NOx cycle increases stratospheric ozone, and an increase in available surfaces for heterogeneous chemistry modulates reductions in ozone. On average, the models show a factor 20-40 increase of the sulfate aerosol surface area density (SAD) at 50 hPa in the tropics with respect to unperturbed background conditions and a factor 3-10 increase at mid-high latitudes. The net effect for a tropical injection rate of 5 Tg SO2 per year is a decrease in globally averaged ozone by 1.1-2.1 DU in the years 2040-2050 for three models which include heterogeneous chemistry on the sulfate aerosol surfaces. GISS-E2-R, a fully coupled general circulation model, performed simulations with no heterogeneous chemistry and a smaller aerosol size; it showed a decrease in ozone by 9.7 DU. After the year 2050, suppression of the NOx cycle becomes more important than destruction of ozone by ClOx, causing an increase in total stratospheric ozone. Contribution of ozone changes in this experiment to radiative forcing is 0.23 W m-2 in GISS-E2-R and less than 0.1 W m-2 in the other three models. Polar ozone depletion, due to enhanced formation of both sulfate aerosol SAD and polar stratospheric clouds, results in an average 5 percent increase in calculated surface UV-B.

aerosol↗

NASA NTRS2026

Updated global and regional trends of stratospheric ozone profiles

We present updated evaluation of stratospheric ozone profile trends in the 60° S–60°N latitude range using long-term ground-based and satellite climate data records, as well as simulations by chemistry-climate models. The trends are evaluated using the LOTUS (Long-term Ozone Trends and Uncertainties in the Stratosphere) regression model. Analyses of satellite data confirm the statistically significant positive ozone trends in the period 2000–2024 in the upper stratosphere of ~1–3% per decade, with larger trends at mid-latitudes compared to the tropics. The trends are slightly positive or close to zero in the middle stratosphere, and mostly negative, -1 to -2% per decade, in the lower stratosphere, but they are not statistically significant. The morphology and magnitude of ozone trends are similar to previous analyses (2000–2020 trends). Ozone trends in 2000–2024 predicted by chemistry-climate model simulations are in good agreement with combined satellite trends. In the upper stratosphere, models predict a slightly stronger ozone recovery than observations. In the lower stratosphere, both models and satellite observations report negative trends in the tropics, while modelled ozone trends are slightly positive at mid-latitudes. Ozone profile trends over several stations estimated from ground-based records capture the same overall vertical pattern of ozone trends as merged gridded satellite datasets. Analyses of regional ozone profile trends in 2003–2024 using merged satellite datasets confirmed the previous observations of a longitudinal structure in ozone trends in the NH mid-latitude stratosphere, with positive trends over Scandinavia and negative trends over Siberia. However, the magnitude of this dipole-like structure is reduced compared to previous analyses.

trends↗

NASA NTRS2010

Trend Analysis and Detection of Changes in the Stratospheric Circulation

Increases in the circulation of the stratosphere appear to be a robust result of climate change in chemistry-climate models over decadal time scales. To date observations have yet to show a significant change in this circulation. It is important for the design of future observational missions to identify suitable atmospheric constituents and to determine the accuracy and length of record needed to identify a significant trend that can be attributed to circulation change. First, we determine what atmospheric variables can be used as proxies for stratospheric circulation changes. A few examples are changes in tropical lower stratospheric ozone, phase lag of the water vapor tape recorder, CO2, and SF6. Then, using both the Goddard Earth Observing System Chemistry-Climate Model (GEOS CCM) and observations from satellites and balloon soundings, we calculate the number of years needed to detect a significant trend, taking into account observational uncertainty. Model simulations will be evaluated to see how well they represent observed variability. In addition, the impacts of autocorrelation among the output or data and gaps in the observational record will be discussed.

Oman, Luke↗