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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Use of intrinsic hysteresis for the active control of internal transport barriers in magnetically confined fusion plasmas

In magnetically confined fusion devices, control of internal transport barriers (ITBs) is important both to enhance and suppress the turbulent transport to improve confinement control. Barrier control should allow for the improvement of confinement to aid in achieving the needed fusion criteria while also permitting the degradation of confinement to control profiles and clean the device by moving out the impurities accumulated near the core. In this work, we present a novel control scenario that takes advantage of the hysteresis intrinsic to transport barriers to easily cycle through enhanced and degraded confinement regimes. The control scenario is illustrated using a five-field simplified transport model for an ITB using typical parameters of a neutral beam injection-heated DIII-D tokamak discharge. Pellets and ion cyclotron resonance frequency power are used as control knobs for this active control scenario. These knobs adequately modify at will the local gradients and, therefore, the growth rates and shearing rates, allowing for easy and efficient control of the barrier by taking advantage of the barrier hysteresis. The result is a control cycle that could be operated with a relatively small amount of power in high performance regimes which, nowadays, typically require large power to control. It may also have advantages to avoid, or at least ameliorate, the appearance of magnetohydrodynamic instabilities in the barrier region.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Thermal confinement and transport in spherical tokamaks: a review

Here, we review the thermal plasma confinement and transport properties observed and predicted in low aspect ratio tokamaks, or spherical tokamaks (STs), which can depart significantly from those observed at higher aspect ratio. In particular, thermal energy confinement scalings show a strong, near linear dependence of energy confinement time on toroidal magnetic field, while the dependence on plasma current is more modest, the opposite of what is seen at higher aspect ratio. STs have revealed a very strong improvement in normalized confinement with decreasing collisionality, much stronger than at higher aspect ratio, which bodes well for an ST-based fusion pilot plant should this trend continue at an even lower collisionality than has already been accessed. These differences arise because of fundamental differences in transport in STs due to the more extreme toroidicity (i.e. reduced region of bad curvature), and to the relatively larger $E_r \times B$ shearing rates, both of which can suppress electrostatic drift wave instabilities at both ion and electron gyroradius scales. In addition, electromagnetic effects are much stronger in STs because they operate at high β T . Gyrokinetic (GK) studies, coupled with low- and high-k turbulence measurements, have shed light on the underlying physics controlling transport. At lower β T , both ion- and electron-scale electrostatic drift turbulence may be responsible for transport. At higher β T , microtearing, kinetic ballooning, and hybrid trapped electron/kinetic ballooning modes increasingly play a role, and they have a much stronger impact in the core of ST plasmas than at higher aspect ratio. Flow shear affects the balance between ion- and electron-scale modes. Non-linear GK simulations find regimes where the electron heat flux decreases with decreasing collisionality, consistent with the experimental global normalized confinement scaling. The ST is unique in that the relatively low toroidal magnetic field allows for localized measurements of electron-scale turbulence, and this coupled with turbulence measurements at ion-scales has facilitated detailed comparisons with GK simulations. These data have provided compelling evidence for the presence of ion temperature gradient and electron temperature gradient turbulence in some plasmas, and direct experimental support for the impact of experimental actuators like rotation shear, density gradient and magnetic shear on turbulence and transport.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Stability analysis of WEST L-mode discharges with improved confinement from boron powder injection

WEST L-mode plasmas with dominant electron heating and no core torque source have observed improvements in confinement during boron (B) powder injection. These results are reminiscent of previous powder injection experiments on other devices and gaseous impurity seeding experiments on WEST. During powder injection, the stored energy increased up to 25% due to enhanced ion and electron heat and particle confinement. The improvements in confinement were not indicative of an L-H transition. To identify the dominant mechanisms and the causality chain behind these improvements in confinement, we employ interpretative modeling using METIS, predictive integrated modeling using a high-fidelity plasma simulator (HFPS), and stand-alone gyrokinetic simulations using quasi-linear gyrokinetic code. Interpretative modeling with METIS allowed for the estimation of missing data while maintaining good overall consistency with experiment. These results provided the initial conditions for fully predictive flux driven simulations using the HFPS. From these simulations, quasi-linear gyrokinetic analysis was performed at ρ = 0.5 and ρ = 0.65. Collisionality was found to be a strong candidate for the turbulence suppression mechanism at ρ = 0.5, while a combination of collisionality and the T e /T i ratio was found to be the likely mechanism at ρ = 0.65. The results additionally suggested that increased Z eff (through main ion dilution) could play a role in the improved confinement, but this could not be confirmed due to a lack of experimental measurements. The modeling framework established here can now be used to evaluate and exploit a variety of future powder injection experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

On the very high energy confinement observed in super H-mode DIII-D experiments

Analysis of recent super H-mode experiments on DIII-D shows that high rotation, not high pedestal, plays the essential role in achieving very high confinement H 98y2 >1.5. Very high confinement is reached early on in the H-mode phase of these discharges, when the pedestal is still very low, but after the toroidal rotation has already built-up to very high levels in the core. As the discharge evolves, the rotation drops, and so does the energy confinement, despite a sustained very high-pressure pedestal. During this evolution, the confinement quality is linearly correlated with the core toroidal rotation, which varies according to different levels of injected neutral beam torque per particle. Core transport modeling shows that the contribution from rotation in the E×B shear is responsible for confinement quality significantly in excess of standard H-mode (H 98y2 ~1).

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Analysis of hydrogen fueling, recycling, and confinement at Wendelstein 7-X via a single-reservoir particle balance

Abstract A single-reservoir particle balance for the main plasma species hydrogen has been established for W7-X. This has enabled the quantitative characterization of the particle sources in the standard island divertor configuration for the first time. Findings from attached scenarios with two different island sizes with a boronized wall and turbo molecular pumping are presented. Fueling efficiencies, particle flows and source locations were measured and used to infer the total particle confinement time τ p . Perturbative gas injection experiments served to measure the effective particle confinement time τ p * . Combining both confinement times provides access to the global recycling coefficient R ¯ . Hydrogen particle inventories have been addressed and the knowledge of particle sources and sinks reveals the core fueling distribution and provides insight into the capability of the magnetic islands to control exhaust features. Measurements of hydrogen fueling efficiencies were sensitive to the precise fueling location and measured between 12% and 31% with the recycling fueling at the strike line modeled at only 6%, due to much higher densities. 15% of the total 5.2 × 10 22 a/s recycling flow ionizes far away from the recycling surfaces in the main chamber. It was shown that 60% of recycled particles ionize above the horizontal and 18% above the vertical divertor target, while the remainder of the recycling flow ionizes above the baffle (7%). Combining these source terms with their individual fueling efficiencies resolves the core fueling distribution. Due to the higher fueling efficiency in the main chamber, up to 51% of the total 5.1 × 10 21 s −1 core fueling particles are entering the confined plasma from the main chamber. τ p values in the range of 260 ms were extracted for these discharges. Together with τ p , the global recycling coefficient R ¯ was resolved for every τ p * measurement and a typical value close to unity was obtained. An increase of the island size, resulted in no change of τ p , but doubled τ p * , indicating the feasibility of the control coils as an actuator to control exhaust features without affecting core confinement properties.

recycling↗
DOE OSTI2022

Symmetry, Confinement, and the Higgs Phase

We show that the Higgs and confinement phases of a gauge Higgs theory, with the Higgs field in the fundamental representation of the gauge group, are distinguished both by a broken or unbroken realization of the global center subgroup of the gauge group, and by the type of confinement in each phase. This is color confinement in the Higgs phase, and a stronger property, which we call “separation-of-charge” confinement, in the confining phase.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2020

Directing the Rate‐Enhancement for Hydronium Ion Catalyzed Dehydration via Organization of Alkanols in Nanoscopic Confinements

Abstract Alkanol dehydration rates catalyzed by hydronium ions are enhanced by the dimensions of steric confinements of zeolite pores as well as by intraporous intermolecular interactions with other alkanols. The higher rates with zeolite MFI having pores smaller than those of zeolite BEA for dehydration of secondary alkanols, 3‐heptanol and 2‐methyl‐3‐hexanol, is caused by the lower activation enthalpy in the tighter confinements of MFI that offsets a less positive activation entropy. The higher activity in BEA than in MFI for dehydration of a tertiary alkanol, 2‐methyl‐2‐hexanol, is primarily attributed to the reduction of the activation enthalpy by stabilizing intraporous interactions of the C β ‐H transition state with surrounding alcohol molecules. Overall, we show that the positive impact of zeolite confinements results from the stabilization of transition state provided by the confinement and intermolecular interaction of alkanols with the transition state, which is impacted by both the size of confinements and the structure of alkanols in the E1 pathway of dehydration.

Shetty, Manish↗
DOE OSTI2025

Enhancing anomalous Hall effect with suppressed ferromagnetism in the SrTiO 3 -confined bilayer heterostructure of ultrathin SrRuO 3 and SrIrO 3

Ferromagnetism is an essential ingredient for anomalous Hall effect. SrRuO 3 is a representative ferromagnetic oxide that exhibits anomalous Hall effect even down to the monolayer confinement limit. Paramagnetic metal SrIrO 3 , on the other hand, becomes an antiferromagnetic insulator when confined to a monolayer. Here, in this study, we show that, by forming a confined bilayer structure of SrRuO 3 and SrIrO 3 monolayers with SrTiO 3 spacers, the anomalous Hall effect is significantly enhanced while the ferromagnetism as well as the perpendicular magnetic anisotropy are suppressed. These effects originate from interfacial Ru–Ir hybridization that modifies the electronic structure in the vicinity of the Fermi level. Our work demonstrates that confined bilayer heterostructure is an useful design for exploring the synergistic combination of interfacial coupling and quantum confinement of complex oxides.

anomalous hall effect↗
DOE OSTI2021

Microscopic assessment of ASR-affected concrete under confinement conditions

The Damage Rating Index (DRI), a semi-quantitative microscopic procedure, has been successfully used to describe alkali-silica reaction (ASR) damage development of concrete under “free expansion” conditions. Yet, the confinement impact on ASR-induced cracks' generation and propagation has not been fully investigated. This work aims to understand the influence of confinement on ASR development through the DRI. Eighteen concrete blocks incorporating a highly reactive coarse aggregate and distinct reinforcement configurations were manufactured, stored in conditions enabling ASR development, and monitored over time. Two expansion levels were selected for analysis (0.08% and 0.15%) and once reached, cores were extracted from three different directions (longitudinal, transverse and vertical) and the DRI conducted on those. Results demonstrate that ASR-induced expansion and deterioration change according to the direction and confinement configuration. Moreover, distinct crack features and orientations are generated in confined concrete, which attests that ASR displays different damage mechanisms under free and confinement conditions.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Temperature-Dependent Constrained Diffusion of Micro-Confined Alkylimidazolium Chloride Ionic Liquids

Alkylimidazolium chloride ionic liquids (ILs) have many uses in a variety of separation systems, including micro-confined separation systems. To understand the separation mechanism in these systems, the diffusion properties of analytes in ILs under relevant operating conditions, including micro-confinement dimension and temperature, should be known. For example, separation efficiencies for various IL-based microextraction techniques are dependent on the sample volume and temperature. Temperature-dependent (20–100 °C) fluorescence recovery after photobleaching (FRAP) was utilized to determine the diffusion properties of a zwitterionic, hydrophilic dye, ATTO 647, in alkylimidazolium chloride ILs in micro-confined geometries. These micro-confined geometries were generated by sandwiching the IL between glass substrates that were separated by ~1 to 100 μm. From the measured temperature-dependent FRAP data, we note alkyl chain length-, thickness-, and temperature-dependent diffusion coefficients, with values ranging from 0.021 to 46 μm 2 /s. Deviations from Brownian diffusion are observed at lower temperatures and increasingly less so at elevated temperatures; the differences are attributed to alterations in intermolecular interactions that reduce temperature-dependent nanoscale structural heterogeneities. Furthermore, the temperature- and thickness-dependent data provide a useful foundation for efficient design of micro-confined IL separation systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Mesoscale Confinement Effects and Emergent Quantum Interference in Titania Antidot Thin Films

The effect of confinement on electron and ion transport in oxide films is of interest both fundamentally and technologically for the design of next-generation electronic devices. In metal oxides with mobile ions and vacancies, it is the interplay of the different modes of charge transport and the corresponding current–voltage signatures that is of interest. We developed a patterned structure in titania films, with feature sizes of 11–20 nm, that allow us to explore confined transport. In this study, we describe how confinement changes the competing charge transport mechanisms, the patterned antidot array leads to displacement fields and confines the charge density that results in modified and emergent electron transport with an increase in conductivity. This emergent behavior can be described by considering electron interference effects. Characterization of the charge transport with electron holography and impedance spectroscopy, and through comparison with modeling, show that nanoscale confinement is a way to control quantum interference.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Mild-Temperature Supercritical Water Confined in Hydrophobic Metal–Organic Frameworks

Fluids under extreme confinement show characteristics significantly different from those of their bulk counterpart. This work focuses on water confined within the complex cavities of highly hydrophobic metal–organic frameworks (MOFs) at high pressures. A combination of high-pressure intrusion–extrusion experiments with molecular dynamic simulations and synchrotron data reveals that supercritical transition for MOF-confined water takes place at a much lower temperature than in bulk water, ~250 K below the reference values. This large shifting of the critical temperature (T c ) is attributed to the very large density of confined water vapor in the peculiar geometry and chemistry of the cavities of Cu 2 tebpz (tebpz = 3,3',5,5'-tetraethyl-4,4'-bipyrazolate) hydrophobic MOF. This is the first time the shift of Tc is investigated for water confined within highly hydrophobic nanoporous materials, which explains why such a large reduction of the critical temperature was never reported before, neither experimentally nor computationally.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Confinement of excited states in two-dimensional, in-plane, quantum heterostructures

Two-dimensional (2D) semiconductors are promising candidates for optoelectronic application and quantum information processes due to their inherent out-of-plane 2D confinement. In addition, they offer the possibility of achieving low-dimensional in-plane exciton confinement, similar to zero-dimensional quantum dots, with intriguing optical and electronic properties via strain or composition engineering. However, realizing such laterally confined 2D monolayers and systematically controlling size-dependent optical properties remain significant challenges. Here, we report the observation of lateral confinement of excitons in epitaxially grown in-plane MoSe 2 quantum dots (~15-60 nm wide) inside a continuous matrix of WSe 2 monolayer film via a sequential epitaxial growth process. Various optical spectroscopy techniques reveal the size-dependent exciton confinement in the MoSe 2 monolayer quantum dots with exciton blue shift (12-40 meV) at a low temperature as compared to continuous monolayer MoSe 2 . Finally, single-photon emission (g 2 (0) ~ 0.4) was also observed from the smallest dots at 1.6 K. Our study opens the door to compositionally engineered, tunable, in-plane quantum light sources in 2D semiconductors.

42 ENGINEERING↗
DOE OSTI2023

The crystal orientation of THF clathrates in nano-confinement by in situ polarized Raman spectroscopy

Gas hydrates form at high pressure and low temperatures in marine sediments and permafrost regions of the earth. Despite forming in nanoporous structures, gas hydrates have been extensively studied only in bulk. Understanding nucleation and growth of gas hydrates in nonporous confinement can help create ways for storage and utilization as a future energy source. Herein, we introduce a new method for studying crystal orientation/tilt during tetrahydrofuran (THF) hydrate crystallization under the influence of nano-confinement using polarized Raman spectroscopy. Uniform cylindrical nanometer size pores of anodic aluminum oxide (AAO) are used as a model nano-confinement, and hydrate experiments are performed in a glass microsystem for control of the flash hydrate nucleation kinetics and analysis via in situ polarized Raman spectroscopy. The average THF hydrate crystal tilt of 56 ± 1° and 30.5 ± 0.5° were observed for the 20 nm and 40 nm diameter pores, respectively. Crystal tilt observed in 20 and 40-nanometer-size pores was proportional to the pore diameter, resulting in lower tilt relative to the axis of the confinement at larger diameter pores. Finally, the results indicate that the hydrates nucleation and growth mechanism can depend on the nanoconfinement size. A 1.6 ± 0.01 °C to 1.8 ± 0.01 °C depression in melting point compared to the bulk is predicted using the Gibbs–Thomson equation as a direct effect of nucleation in confinement on the hydrate properties.

25 ENERGY STORAGE↗
DOE OSTI2023

Hydrodynamics of a multicomponent vesicle under strong confinement

Herein we numerically investigate the hydrodynamics and membrane dynamics of a multicomponent vesicle in two strongly confined geometries. This serves as a simplified model for red blood cells undergoing large deformations while traversing narrow constrictions. We propose a new parameterization for the bending modulus that remains positive for all lipid phase parameter values. For a multicomponent vesicle passing through a stenosis, we establish connections between various properties: lipid phase coarsening, size and flow profile of the lubrication layers, excess pressure, and the tank-treading velocity of the membrane. For a multicomponent vesicle passing through a contracting channel, we find that the lipid always phase separates so that the vesicle is stiffer in the front as it passes through the constriction. For both cases of confinement we find that lipid coarsening is arrested under strong confinement, and resumes at a high rate upon relief from extreme confinement. The results may be useful for efficient sorting lipid domains using microfluidic flows by controlled release of vesicles passing through strong confinement.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2020

Molecular polarizabilities as fingerprints of perturbations to water by ions and confinement

Perturbations to water, both by ions and confining media, have been the focus of numerous experimental and theoretical studies. Yet, several open questions remain, including the extent to which such perturbations modify the structural and dielectric properties of the liquid. Here, we present a first-principles molecular dynamics study of alkali cations in water (Li + , Na + , and K + ) as well as of water and LiCl and KCl solutions under confinement within carbon nanotubes (CNTs) of small diameter (1.1-1.5 nm). Our simulations support the view that the water structure is only modified locally in the presence of cations. We found that molecular polarizabilities are fingerprints of hydrogen bonding modifications, which occur at most up to the second solvation shell for all cations in bulk water. Under confinement, we found that the overall value of the molecular polarizability of water molecules near the surface is determined by the balance of two effects, which are quantitatively different in CNTs of different radii: the presence of broken hydrogen bonds at the surface leads to a decrease in the polarizabilities of water molecules, while the interaction with the CNT enhances polarizabilities. Interestingly, the reduction in dipole moments of interfacial water molecules under confinement is instead driven only by changes in the water structure and not by interfacial interactions. As expected, confinement effects on water molecular polarizabilities and dipole moments are more pronounced in the case of the 1.1 nm CNT.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Confinement effects on the solvation structure of solvated alkaline metal cations in a single-digit 1T-MoS 2 nanochannel: A first-principles study

Confinement plays an important role in determining ion transport in porous materials, which, in turn, may influence the performance of many energy storage and desalination devices. In this work, we combined density functional theory (DFT) with an implicit solvation model and ab initio molecular dynamics (AIMD) to investigate the effects of nanoconfinement on several solvated alkaline metal cations in a single-digit 1T-MoS 2 nanochannel. Our DFT calculations with a solvation model indicated that cations with stronger hydration energy introduce a higher number of co-intercalated water molecules into the channel, consistent with early experimental observation obtained for MXene (2D transition metal carbide) channels. The predicted optimal water numbers for the cations were then used for AIMD simulations that explicitly include the effects of the solvent. When compared with the cations in bulk solution, our simulations showed that the hydration structure and coordination number (CN) of the solvated cations confined in the MoS 2 channel can be significantly altered. Further, we found that larger cations with weaker hydration energy (K + , Rb + , and Cs + ) exhibited a distinctive CN decrease under confinement, while smaller cations (Li + and Na + ) retained a similar hydration shell as in the bulk solution. More specifically, the hydration shell of large cations (K + , Rb + , and Cs + ) in MoS 2 showed similar features of the coordination angle to the bulk, which suggests the partially broken hydration shell with no geometry change under confinement. Our simulations provided insights into the change of the hydration structure of alkaline metal cations under confinement, which may have important implications on their transport in the 1T-MoS 2 channel.

36 MATERIALS SCIENCE↗
DOE OSTI2024

The Orbitron: A crossed-field device for co-confinement of high energy ions and electrons

To explore the confinement of high-energy ions above the space charge limit, we have developed a hybrid magnetic and electrostatic confinement device called an Orbitron. The Orbitron is a crossed-field device combining aspects of magnetic mirrors, magnetrons, and orbital ion traps. Ions are confined in orbits around a high-voltage cathode with co-rotating electrons confined by a relatively weak magnetic field. Experimental and computational investigations focus on reaching ion densities above the space charge limit through the co-confinement of electrons. The experimental apparatus and suite of diagnostics are being developed to measure the critical parameters, such as plasma density, particle energy, and fusion rate for high-energy, non-thermal plasma conditions in the Orbitron. Initial results from experimental and computational efforts have revealed the need for cathode voltages on the order of 100–300 kV, leading to the development of a custom high voltage, ultra-high vacuum bushing rated for 300 kV.

Materials Science↗