Climatic consequences of very high CO2 levels in Earth's early atmosphere
Earth has approximately 60 bars of carbon dioxide tied up in carbonate rocks, or roughly 2/3 the amount of CO2 of the atmosphere of Venus. Two different lines of evidence, one based on thermodynamics and the other on geochemical cycles, indicate that a substantial fraction of thes CO2 may have resided in the atmosphere during the first few hundred million years of the Earth's history. A natural question which arises is whether this much CO2 would have resulted in a runaway greenhouse effect. One dimensional radiative/convective model calculations presented showed that the surface temperature of a hypothetical primitive atmosphere containing 20 bars of CO2 was less than 100 C; thus no runaway greenhouse effect would have occurred. The climatic stability of the early atmosphere is a consequence of three factors: reduced solar luminosity at that time, an increase in planetary albedo caused by Rayleigh scattering by CO2, and the stabilizing effects of a moist convection. The latter two factors are sufficient to prevent a CO2 induced runaway greenhouse effect on the present Earth as well, for CO2 levels up to 100 bars. Further studies are being undertaken to determine whether a runaway greenhouse effect could have occurred during the latter stages of the accretion process and, if so, whether it would have collapsed one the influx of material slowed down.