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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Microcalorimetric Measurements of Hydrogen Peroxide Stability

Recent interest in propellants with nontoxic reaction products has led to a resurgence of interest in hydrogen peroxide for various propellant applications. Because hydrogen peroxide is sensitive to contaminants and materials interactions, stability and shelf life are issues. A relatively new, ultrasensitive heat measurement technique, isothermal microcalorimetry, is being used at the White Sands Test Facility to monitor the decomposition of hydrogen peroxide at near ambient temperatures. Isothermal microcalorimetry measures the beat flow from a reaction vessel into a surrounding heat sink. In these applications, microcalorimetry is approximately 1,000 times more sensitive than accelerating rate calorimetry or differential scanning calorimetry for measuring thermal events. Experimental procedures have been developed for the microcalorimetric measurement of the ultra-small beat effects caused by incompatible interactions of hydrogen peroxide. The decomposition rates of hydrogen peroxide at the picomole/sec/gram level have been measured showing the effects of stabilizers and peroxide concentration. Typical measurements are carried out at 40 C over a 24-hour period, This paper describes a method for the conversion of the heat flow measurements to chemical reaction rates based on thermochemical considerations. The reaction rates are used in a study of the effects of stabilizer levels on the decomposition of propellant grade hydrogen peroxide.

Davis, Dennis D.↗

The total flow concept for geothermal energy conversion

A geothermal development project has been initiated at the Lawrence Livermore Laboratory (LLL) to emphasize development of methods for recovery and conversion of the energy in geothermal deposits of hot brines. Temperatures of these waters vary from 150 C to more than 300 C with dissolved solids content ranging from less than 0.1% to over 25% by weight. Of particular interest are the deposits of high-temperature/high-salinity brines, as well as less saline brines, known to occur in the Salton Trough of California. Development of this resource will depend on resolution of the technical problems of brine handling, scale and precipitation control, and corrosion/erosion resistant systems for efficient conversion of thermal to electrical energy. Research experience to date has shown these problems to be severe. Hence, the LLL program emphasizes development of an entirely different approach called the Total Flow concept.

Austin, A. L.↗

Effect of positive pulse charge waveforms on the energy efficiency of lead-acid traction cells

The effects of four different charge methods on the energy conversion efficiency of 300 ampere hour lead acid traction cells were investigated. Three of the methods were positive pulse charge waveforms; the fourth, a constant current method, was used as a baseline of comparison. The positive pulse charge waveforms were: 120 Hz full wave rectified sinusoidal; 120 Hz silicon controlled rectified; and 1 kHz square wave. The constant current charger was set at the time average pulse current of each pulse waveform, which was 150 amps. The energy efficiency does not include charger losses. The lead acid traction cells were charged to 70 percent of rated ampere hour capacity in each case. The results of charging the cells using the three different pulse charge waveforms indicate there was no significant difference in energy conversion efficiency when compared to constant current charging at the time average pulse current value.

Smithrick, J. J.↗

Satellite Constellation Orbit Design to Enable a Space-Based Radio Interferometer

Two different design methods for a networked constellation of N small satellites are presented. In the first method, the (linear) Clohessy-Wilthsire equations are used as an initial design tool, followed by conversion to a two-body model. Discrepancies between the linear and nonlinear solutions are minimized in the conversion process. The second method utilizes invariant manifold theory, by perturbing a reference trajectory in different directions along the center eigenvectors. Both methods require 5N parameters to fully define a constellation. In a relative, rotating frame of the reference path, the spacecraft appear as periodic ellipses of varying sizes. Deployment, reconfiguration using propulsive maneuvers, and station keeping costs for an example mission scenario are addressed.

Chien, Steve A.↗

Deriving New Mixing Ratios for Venus Atmospheric Gases Using Data From the Pioneer Venus Large Probe Neutral Mass Spectrometer

We present the first published method to convert data obtained by the Pioneer Venus Large Probe Neutral Mass Spectrometer (LNMS) into units of mixing ratio (ppm) and volume percent (v%) against CO 2 and N 2 , the dominant Venus atmospheric gases, including conversion to density (kg m −3 ). These unit conversions are key to unlocking the untapped potential of the data, which represents a significant challenge given the scant calibration data in the literature. Herein, we show that our data treatments and conversions yield mixing ratios and volume percent values for H 2 O, N 2 , and SO 2 that are within error to those reported for the gas chromatograph (LGC) on the Pioneer Venus Large Probe (PVLP). For the noble gases, we developed strategies to correct for instrument biases by treating the data as a relative scale and using PVLP and Venera-based measurements as calibration points. Together, these methods, conversions, calibrations, and comparisons afford novel unit conversions for the LNMS data and yield unified measures for Venus’ atmosphere from the LNMS and LGC on the PVLP. - Conversion into mixing ratio (ppm), volume percent (v%), and density (kg m −3 ). - Mixing ratios are expressed against CO 2 and N 2 . - LNMS and LGC measurements on the PVLP are consistent.

Venus↗

Device and Method for Digital-To-Analog Transformations and Reconstructions of Multi-Channel Electrocardiograms

The present invention includes a method and apparatus for digital to analog conversion and reconstruction of multichannel electrocardiograms. The method may include receiving digital information representative of a plurality of independent signals, producing a plurality of analog outputs from said digital information wherein a first analog output is designated as a common reference, and imposing a predetermined voltage on a second analog output with respect to said common reference, which provides for a substantial recreation of the original independent signals. The apparatus may comprise a processor operable for receiving digital information representative of independent lead signals from a first ECG machine and digital to analog circuitry for substantially reproducing the original lead signals for analysis on a second ECG machine for convenient and efficient second opinions of cardiac data.

Schlegel, Todd T.↗

Factors controlling fluxes of volatile sulfur compounds in Sphagnum peatlands

Exchange of DMS and OCS between the surface of Sphagnum peatlands and the atmosphere were measured with dynamic (S-free sweep air) and static enclosures. DMS emission rates determined by both methods were comparable. The dynamic method provided positive OCS flux rates (emission) for measurements performed at sites containing Sphagnum. Conversely, data from the static method indicated that OCS was consumed from the atmosphere. Short and long-term impacts of increased S deposition on fluxes of volatile S compounds (VSC's) from Sphagnum peatlands were investigated in a poor fen (Mire 239) at the Experimental Lakes Area, Ontario, Canada. Additional experiments were conducted in a poor fen (Sallie's Fen in Barrington, NH, USA). At Mire 239, emissions of VSC's were monitored, before and after acidification, at control and experimental sections within two major physiographic areas of the mire (oligotrophic and minerotrophic). DMS was the predominant VSC released from Mire 239 and varied largely with time and space. Sulfur addition did not affect DMS emissions in a period of hours to a few days. DMS emissions in the experimental oligotrophic area of the mire was approximately 3-fold greater than in the control oligotrophic area, and approximately 10-fold greater than in the minerotrophic zones. These differences could be due to a combination of differences in types of vegetation, nutritional status, and S input. At Sallie's Fen, DMS fluxes were not significantly affected by sulfate amendments, while DMS and MSH concentrations increased greatly with time in the top 10 cm of the peat column. The major environmental factors controlling fluxes of DMS in a Sphagnum-dominated peatland were investigated in Sallie's Fen, NH. DMS emissions from the surface of the peatland varied greatly over 24 hours and seasonally. Temperature seemed to be the major environmental factor controlling these variabilities. Concentrations of dissolved VSC's varied with time and space throughout the fen. Dissolved DMS, MSH, and OCS in the surface of the water table were supersaturated with respect to their concentrations in the atmosphere. Sphagnum mosses did not appear to be a direct source of VSC's, however they increase transport of DMS from the peat surface to the atmosphere.

Demello, William Zamboni↗

Application of static and dynamic enclosures in determining DMS and OCS fluxes in Sphagnum peatlands

A static enclosure method was applied to determine the exchange of dimethyl sulfide (DMS) and OCS between the surface of Sphagnum peatlands and the atmosphere. Measurements were performed concurrently with dynamic enclosure measurements with S-free air used as sweep gas. DMS emission rates determined by both methods were comparable between 5 and 500 nmol/m(sup -2)h(sup -1). The dynamic method provided positive OCS flux rates (emission) for measurements performed at sites containing Sphagnum. Conversely, data from the static method indicated that OCS was consumed from the atmosphere. Measurements using both techniques at a site devoid of vegetation showed that peat is a source of both DMS and OCS. Results suggested that OCS is produced in surface peat but it is taken up from the atmosphere by Sphagnum mosses. However, the net effect of both processes is that OCS uptake exceeds emission. The dynamic enclosure technique is adequate to measure rates of emissions of S gases which are produced in peatlands but not consumed, as long as attention is paid to the rate of sweep flow.

Demello, William Zamboni↗

Electrodynamic tethers for energy conversion

Conductive tethers have been proposed as a new method for converting orbital mechanical energy into electrical power for use on-board a satellite (generator mode) or conversely (motor mode) as a method of providing electric propulsion using electrical energy from the satellite. The operating characteristics of such systems are functionally dependent on orbit altitude and inclination. Effects of these relationships are examined to determine acceptable regions of application. To identify system design considerations, a specific set of system performance goals and requirements are selected. The case selected is for a 25 kW auxiliary power system for use on Space Station. Appropriate system design considerations are developed, and the resulting system is described.

Nobles, W.↗

Review of Computational Stirling Analysis Methods

Nuclear thermal to electric power conversion carries the promise of longer duration missions and higher scientific data transmission rates back to Earth for both Mars rovers and deep space missions. A free-piston Stirling convertor is a candidate technology that is considered an efficient and reliable power conversion device for such purposes. While already very efficient, it is believed that better Stirling engines can be developed if the losses inherent its current designs could be better understood. However, they are difficult to instrument and so efforts are underway to simulate a complete Stirling engine numerically. This has only recently been attempted and a review of the methods leading up to and including such computational analysis is presented. And finally it is proposed that the quality and depth of Stirling loss understanding may be improved by utilizing the higher fidelity and efficiency of recently developed numerical methods. One such method, the Ultra HI-Fl technique is presented in detail.

Dyson, Rodger W.↗

Investigation of the ionospheric Faraday rotation for use in orbit corrections

The possibility of mapping the Faraday factors on a worldwide basis was examined as a simple method of representing the conversion factors for any possible user. However, this does not seem feasible. The complex relationship between the true magnetic coordinates and the geographic latitude, longitude, and azimuth angles eliminates the possibility of setting up some simple tables that would yield worldwide results of sufficient accuracy. Tabular results for specific stations can easily be produced or could be represented in graphic form.

Llewellyn, S. K.↗

Redox Bulk Energy Storage System Study, Volume 1

Opportunities were found for electrochemical energy storage devices in the U.S. electric utility industry. Application requirements for these devices were defined, including techno-economic factors. A new device, the Redox storage battery was analyzed. The Redox battery features a decoupling of energy storage and power conversion functions. General computer methods were developed to simulate Redox system operations. These studies showed that the Redox system is potentially attractive if certain performance goals can be achieved. Pathways for reducing the cost of the Redox system were identified.

Ciprios, G.↗

A comparison of GaAs and Si hybrid solar power systems

Five different hybrid solar power systems using silicon solar cells to produce thermal and electric power are modeled and compared with a hybrid system using a GaAs cell. Among the indices determined are capital cost per unit electric power plus mechanical power, annual cost per unit electric energy, and annual cost per unit electric plus mechanical work. Current costs are taken to be $35,000/sq m for GaAs cells with an efficiency of 15% and $1000/sq m for Si cells with an efficiency of 10%. It is shown that hybrid systems can be competitive with existing methods of practical energy conversion. Limiting values for annual costs of Si and GaAs cells are calculated to be 10.3 cents/kWh and 6.8 cents/kWh, respectively. Results for both systems indicate that for a given flow rate there is an optimal operating condition for minimum cost photovoltaic output. For Si cell costs of $50/sq m optimal performance can be achieved at concentrations of about 10; for GaAs cells costing 1000/sq m, optimal performance can be obtained at concentrations of around 100. High concentration hybrid systems offer a distinct cost advantage over flat systems.

Heinbockel, J. H.↗

Critical research and advanced technology (CRT) support project

A critical technology base for utility and industrial gas turbines by planning the use of coal-derived fuels was studied. Development tasks were included in the following areas: (1) Combustion - investigate the combustion of coal-derived fuels and methods to minimize the conversion of fuel-bound nitrogen to NOx; (2) materials - understand and minimize hot corrosion; (3) system studies - integrate and focus the technological efforts. A literature survey of coal-derived fuels was completed and a NOx emissions model was developed. Flametube tests of a two-stage (rich-lean) combustor defined optimum equivalence ratios for minimizing NOx emissions. Sector combustor tests demonstrated variable air control to optimize equivalence ratios over a wide load range and steam cooling of the primary zone liner. The catalytic combustion of coal-derived fuels was demonstrated. The combustion of coal-derived gases is very promising. A hot-corrosion life prediction model was formulated and verified with laboratory testing of doped fuels. Fuel additives to control sulfur corrosion were studied. The intermittent application of barium proved effective. Advanced thermal barrier coatings were developed and tested. Coating failure modes were identified and new material formulations and fabrication parameters were specified. System studies in support of the thermal barrier coating development were accomplished.

Furman, E. R.↗

Tilt rotor aircraft aeroacoustics

This paper studies the state of knowledge and the needed improvement in noise methodology and measurements for tilt rotor aircraft. Similarities and differences between tilt rotor aeroacoustic conditions and helicopter and propeller experience are identified. A discussion of the possible principal noise mechanisms throughout the flight envelope shows a need for further experimental and analytical investigations to develop an adequate understanding of the important sources and influencing factors. Existing experimental data from flight tests suggest terminal area noise reduction by operating within certain portions of the conversion flight envelope. Prediction methods are found to provide approximate indications only for low frequency harmonic and broadband noise for several of the tilt rotor's operating conditions. The acoustic effects of the hover case 'fountain' flow are pronounced and need further research. Impulsive noise and high frequency harmonic noise remain problems, as on helicopters, pending major improvements in wake, unsteady aerodynamics, and acoustics methodology.

George, Albert R.↗

Quantitative Analysis of Venus Radar Backscatter Data in ArcGIS

Ongoing mapping of the Ganiki Planitia (V14) quadrangle of Venus and definition of material units has involved an integrated but qualitative analysis of Magellan radar backscatter images and topography using standard geomorphological mapping techniques. However, such analyses do not take full advantage of the quantitative information contained within the images. Analysis of the backscatter coefficient allows a much more rigorous statistical comparison between mapped units, permitting first order selfsimilarity tests of geographically separated materials assigned identical geomorphological labels. Such analyses cannot be performed directly on pixel (DN) values from Magellan backscatter images, because the pixels are scaled to the Muhleman law for radar echoes on Venus and are not corrected for latitudinal variations in incidence angle. Therefore, DN values must be converted based on pixel latitude back to their backscatter coefficient values before accurate statistical analysis can occur. Here we present a method for performing the conversions and analysis of Magellan backscatter data using commonly available ArcGIS software and illustrate the advantages of the process for geological mapping.

Long, S. M.↗