Results for “correlated electron systems” — Page 5

NASA NTRS2018

A Laser-Induced Fluorescence Diagnostic for HERMeS and High-Power Electric Propulsion

NASA is continuing the development of a 12.5-kW Hall thruster system, which is baselined in a phased exploration concept to expand human presence to cis-lunar space and eventually to Mars. The development team is transitioning knowledge gained from the testing of the government-built Technology Development Unit (TDU) to the contractor-built Engineering Development Unit (EDU). A new laser-induced fluorescence diagnostic that is compatible with the testing of engineering hardware was developed to obtain data for thruster model validation in the lowest background pressure achievable. Prior to performing the test on the EDU, the team performed a functional checkout test of this new diagnostic using the TDU. In addition to providing a checkout of the diagnostic, this test provided data that can be correlated to electron mobility for comparison to the EDU at a later date. A number of technical challenges related to large test facilities and interfacing with engineering hardware were overcome while implementing the new laser diagnostic system. The initial data set was in good agreement with prior optical and non-optical diagnostics data collected on the TDU thrusters. This data set also revealed the spatial origin of high angle ions that have been of concern for spacecraft integration.

Huang, Wensheng↗

NASA NTRS2018

Ion Velocity in the Discharge Channel and Near-Field of the HERMeS Hall Thruster

NASA is continuing the development of a 12.5-kW Hall thruster system, which is baselined in a phased exploration concept to expand human presence to cis-lunar space and eventually to Mars. The development team is transitioning knowledge gained from the testing of the government-built Technology Development Unit (TDU) to the contractor-built Engineering Development Unit (EDU). A new laser-induced fluorescence diagnostic that is compatible with the testing of engineering hardware was developed to obtain data for thruster model validation in the lowest background pressure achievable. Prior to performing the test on the EDU, the team performed a functional checkout test of this new diagnostic using the TDU. In addition to providing a checkout of the diagnostic, this test provided data that can be correlated to electron mobility for comparison to the EDU at a later date. A number of technical challenges related to large test facilities and interfacing with engineering hardware were overcome while implementing the new laser diagnostic system. The initial data set was in good agreement with prior optical and non-optical diagnostics data collected on the TDU thrusters. This data set also revealed the spatial origin of high angle ions that have been of concern for spacecraft integration.

Huang, Wensheng↗

NASA NTRS2018

Ion Velocity in the Discharge Channel and Near-Field of the HERMeS Hall Thruster

NASA is continuing the development of a 12.5-kW Hall thruster system, which is baselined in a phased exploration concept to expand human presence to cis-lunar space and eventually to Mars. The development team is transitioning knowledge gained from the testing of the government-built Technology Development Unit (TDU) to the contractor-built Engineering Development Unit (EDU). A new laser-induced fluorescence diagnostic that is compatible with the testing of engineering hardware was developed to obtain data for thruster model validation in the lowest background pressure achievable. Prior to performing the test on the EDU, the team performed a functional checkout test of this new diagnostic using the TDU. In addition to providing a checkout of the diagnostic, this test provided data that can be correlated to electron mobility for comparison to the EDU at a later date. A number of technical challenges related to large test facilities and interfacing with engineering hardware were overcome while implementing the new laser diagnostic system. The initial data set was in good agreement with prior optical and non-optical diagnostics data collected on the TDU thrusters. This data set also revealed the spatial origin of high angle ions that have been of concern for spacecraft integration.

Huang, Wensheng↗

NASA NTRS1987

Mixed Cu-simple metal dimers and trimers - CuLi, CuLi2, CuNa, CuK, CuBe, CuBe2, Cu2Be, CuAl, and CuAl2

Theoretical studies of selected diatomic and triatomic molecules containing copper and the simple metals Li, Na, K, Be, and Al are presented, with emphasis on elucidating the nature of the bonding in mixed transition metal-simple metal systems. Large Gaussian basis sets are used in the diatomic calculations, and are used to calibrate the triatomic calculations, in which somewhat smaller Gaussian basis sets are employed. Electron correlation is incorporated using both the single-reference singles plus doubles configuration interaction and coupled pair functional methods. It is found that alkali atoms form very polar sigma bonds with copper, and that the ionicity increases with the inclusion of higher excitations because they improve the electron affinity of copper, which in turn allows a larger negative charge on copper. Aluminum is found to form stronger bonds than beryllium, since it does not have to undergo sp hybridization. Some of the trimers bond by forming three-center three-electron bonds. These multicenter bonds are quite strong even when compared to the two-electron bonds in the dimers or to other bonding mechanisms in the trimers.

Bauschlicher, Charles W., Jr.↗

NASA NTRS1987

The electronically steered thinned array radiometer

An L-band radiometer which allows global imaging of soil moisture from LEO is discussed. The system consists of an array of antennas with amplifiers, a device to cross-correlate the signals from the antennas, and a process to translate the resulting data into an image of brightness temperature over the field of view. The process is based on a Fourier transform relation that exists between the incident electric field strength as a function of incidence angle and electric fields across the aperture plane of the antenna. The system's image reconstruction technique and signal-to-noise performance are examined.

Ruf, C. S.↗

NASA NTRS1994

Theoretical Study of the Low-Lying States of TiHe(+),TiNe(+),TiAr(+),VAr(+),CrHe(+),CrAr(+),FeHe(+),FeAr(+),CoHe(+),and CoAr(+)

The potential energy curves for the manifold of molecular states dissociating to the lowest transition metal ion states derived from the 3d(sup n+1) and 3d(sup n)4s(sup 1) occupations have been determined for selected transition-metal ion- rare gas systems. These curves have been computed using large basis sets, and the state-averaged complete- active-space self-consistent-field/multireference configuration interaction level of electron correlation treatment. In general, the families of curves derived from the 3d(sup n+1) and 3d(sup n)4s(sup 1) metal occupations are disjoint; however, for Ti(+) there is a strong mixing of the 3d(sup 2)4s(sup 1) and 3d(sup 3) asymptotes, because of the small separation between the asymptotes. This mixing leads to a failure of single-reference-based techniques; this is discussed in the context of our previous single-reference-based treatments.

Partridge, Harry↗

NASA NTRS2018

Hybrid Theory of Scattering and Its Applications

A number of formulations have been used to investigate scattering of low-energy electrons and positrons from various targets. The hybrid theory of scattering, which takes into account the short-range correlations, and is variationally correct, is described in this article. This approach has been applied to calculate phase shifts for scattering of electrons and positrons, resonances in two-electron systems, photo detachment, and photoionization of two-electron systems. This approach has also been applied to calculate excitation of 2s state of atomic hydrogen by electron impact. In photo absorption the target can be left in 2p state instead of 1s state, resulting in the emission of Lyman-alpha radiation. Cross sections for this process are also calculated.

Bhatia, Anand K.↗

NASA NTRS2010

Analysis and Design of Phase Change Thermal Control for Light Emitting Diode (LED) Spacesuit Helmet Lights

LED Helmet Extravehicular Activity Helmet Interchangeable Portable (LEHIP) lights for the Extravehicular Mobility Unit (EMU) have been built and tested and are currently being used on the International Space Station. A design is presented of the passive thermal control system consisting of a chamber filled with aluminum foam and wax. A thermal math model of LEHIP was built and correlated by test to show that the thermal design maintains electronic components within hot and cold limits for a 7 hour spacewalk in the most extreme EVA average environments, and do not pose a hazard to the crew or to components of the EMU.

Bue, Grant C.↗

NASA NTRS1999

Interplanetary Microlaser Transponders

The feasibility of an asynchronous (i.e. independently firing) interplanetary laser transponder, capable of ranging between Earth and Mars and using the automated SLR2000 Satellite Laser Ranging (SLR) system as an Earth base station, has been suggested. Since that time, we have received a small amount of discretionary funding to further explore the transponder concept and to develop and test an engineering breadboard. Candidate operational scenarios for acquiring and tracking the opposite laser terminal over interplanetary distances have been developed, and breadboard engineering parameters were chosen to reflect the requirements of an Earth-Mars link Laboratory tests have been devised to simulate the Earth- Mars link between two independent SLR2000 transceivers and to demonstrate the transfer of range and time in single photon mode. The present paper reviews the concept of the asynchronous microlaser transponder, the transponder breadboard design, an operational scenario recently developed for an asteroid rendezvous, and the laboratory test setup. The optical head of the transponder breadboard fits within a cylinder roughly 15 cm in diameter and 32 cm in length and is mounted in a commercial two axis gimbal driven by two computer-controlled stepper motors which allows the receiver optical axis to be centered on a simulated Earth image. The optical head is built around a small optical bench which supports a 14.7 cm diameter refractive telescope, a prototype 2 kHz SLR2000 microlaser transmitter, a quadrant microchannel plate photomultiplier (MCP/PMT), a CCD array camera, spatial and spectral filters, assorted lenses and mirrors, and protective covers and sun shields. The microlaser is end-pumped by a fiber-coupled diode laser array. An annular mirror is employed as a passive transmit/receive (T/R) switch in an aperture-sharing arrangement wherein the transmitted beam passes through the central hole and illuminates only the central 2.5 cm of the common telescope (adequate to achieve a 10 arcsecond full laser beam divergence) while the receiver uses the remainder of the 14.7 cm aperture. Additional electronic instrumentation includes the diode pump array and associated heat sink and current drivers, rubidium frequency standard, timing distribution module, range gate generator, a recently developed all-digital correlation range receiver, and system computer. Acquisition of the opposite transponder terminal requires a search within a three-dimensional volume determined by the initial pointing uncertainty and a maximum 500 microsecond uncertainty in the laser time of fire at the opposite terminal for totally uncorrelated Earth and spacecraft clocks. The angular search is aided by a sensitive CCD array capable of imaging the Earth, Moon, and surrounding stars within the nominal + 0.5 degree cone of uncertainty associated with the initial pointing of a spacecraft body or microwave communications dish.

Degnan, John J.↗

NASA NTRS1984

Method and apparatus for calibrating the ionosphere and application to surveillance of geophysical events

The columnar electron content of the ionosphere between a spacecraft and a receiver is measured in realtime by cross correlating two coherently modulated signals transmitted at different frequencies (L1,L2) from the spacecraft to the receiver using a cross correlator. The time difference of arrival of the modulated signals is proportional to electron content of the ionosphere. A variable delay is adjusted relative to a fixed delay in the respective channels (L1,L2) to produce a maximum at the cross correlator output. The difference in delay required to produce this maximum is a measure of the columnar electron content of the ionosphere. A plurality of monitoring stations and spacecraft (Global Positioning System satellites) are employed to locate any terrestrial event that produces an ionospheric disturbance.

Macdoran, P. F.↗

NASA NTRS1992

Optical pattern recognition III; Proceedings of the Meeting, Orlando, FL, Apr. 21, 22, 1992

Consideration is given to transitioning of optical processing into systems (TOPS), optical correlator hardware, phase-only optical correlation filters, optical distortion-invariant correlation filters, and optical neural networks. Particular attention is given to a test target for optical correlators, a TOPS electronic warfare channelizer program, a portable video-rate optical correlator, a joint transform correlator employing electron trapping materials, a novelty filtered optical correlator using a photorefractive crystal, a comparison of correlation performance of smart ternary phase-amplitude filters with gray-scale and binary input scenes, real-time distortion-tolerant composite filters for automatic target identification, landscaping the correlation surface, fast designing of a circular harmonic filter using simulated annealing, feature-based correlation filters for distortion invariance, automatic target recognition using a feature-based optical neural network, and a holographic inner-product processor for pattern recognition.

Casasent, David P.↗

NASA NTRS2020

Observation of Strong Two-Electron-One-Photon Transitions in Few-Electron Ions

We resonantly excite the K series of O5+ and O6+ up to principal quantum number n = 11 with monochromatic x rays, producing K-shell holes, and observe their relaxation by soft-x-ray emission. Some photoabsorption resonances of O5+ reveal strong two-electron–one-photon (TEOP) transitions. We find that for the [(1s2s)15p3/2]3/2;1/2 states, TEOP relaxation is by far stronger than the radiative decay and competes with the usually much faster Auger decay path. This enhanced TEOP decay arises from a strong correlation with the near-degenerate upper states [(1s2p3/2 )14s]3/2;1/2 of a Li-like satellite blend of the He-like Kα transition. Even in three-electron systems, TEOP transitions can play a dominant role, and the present results should guide further research on the ubiquitous and abundant many-electron ions where electronic energy degeneracies are far more common and configuration mixing is stronger.

M Togawa↗

NASA NTRS2002

Gas-Phase Reaction Pathways and Rate Coefficients for the Dichlorosilane-Hydrogen and Trichlorosilane-Hydrogen Systems

As part of NASA Ames Research Center's Integrated Process Team on Device/Process Modeling and Nanotechnology our goal is to create/contribute to a gas-phase chemical database for use in modeling microelectronics devices. In particular, we use ab initio methods to determine chemical reaction pathways and to evaluate reaction rate coefficients. Our initial studies concern reactions involved in the dichlorosilane-hydrogen (SiCl2H2--H2) and trichlorosilane-hydrogen (SiCl2H-H2) systems. Reactant, saddle point (transition state), and product geometries and their vibrational harmonic frequencies are determined using the complete-active-space self-consistent-field (CASSCF) electronic structure method with the correlation consistent polarized valence double-zeta basis set (cc-pVDZ). Reaction pathways are constructed by following the imaginary frequency mode of the saddle point to both the reactant and product. Accurate energetics are determined using the singles and doubles coupled-cluster method that includes a perturbational estimate of the effects of connected triple excitations (CCSD(T)) extrapolated to the complete basis set limit. Using the data from the electronic structure calculations, reaction rate coefficients are obtained using conventional and variational transition state and RRKM theories.

Dateo, Christopher E.↗

NASA NTRS1984

Modifications to population rate equations resulting from correlations between collisional and radiative processes

There are many systems of physical interest for which a set of rate equations for level populations can provide insight. If the system has two (or more) different mechanisms for effecting transition between levels, total rates of transfer are usually taken as the sum of rates that the individual mechanisms would cause acting alone. Using the example of a hydrogen atom subjected to (ionic and electronic) collisions and external radiation, it is shown that when these individual mechanisms overlap, the total transfer rates must be modified to account for correlations between collisional and radiative processes. For a broad-band radiation field the modified rates have a simple physical interpretation. In the case of a narrow-band field the overlapping events may cause new coherences to appear and interpretation of the modified 'rates' is more complicated.

Ballagh, R. J.↗

NASA NTRS1990

Review of model sensor studies on Pd/SnO2(110) surfaces

Studies performed at the National Institute of Standards and Technology on the model gas sensor system, Pd/SnO2(110), are reviewed. Adsorption and interfacial effects play a primary role in the gas sensing process, as they do in catalysis. For this reason, researchers have used a variety of surface sensitive techniques in the research, including x ray and ultraviolet photoelectron spectroscopies (XPS and UPS), low energy electron diffraction (LEED), and ion scattering spectroscopy (ISS). By combining these complementary techniques with in situ gas response (conductance) measurements, researchers were able to correlate directly sensor activity with the composition and structure of the Pd/SnO2 interface. Although the intent of this work is to develop an understanding of gas sensing mechanisms, its relevance to Pt/SnO2 catalytic systems is obvious.

Fryberger, Teresa B.↗

NASA NTRS1988

WF/PC internal molecular contamination during system thermal-vacuum test

During the recent system thermal vacuum test of the Wide-Field/Planetary Camera (WF/PC), instrumentation was added to the WF/PC to characterize the internal molecular contamination and verify the instrument throughput down to 1470 angstroms. Analysis of data elements revealed two contaminants affecting the far-ultraviolet (FUV) performance of the WF/PC. The one contaminant (heavy volatile) is correlated with the electronic and housing temperature, and the contamination is significantly reduced when the electronics are operated below plus 8 degrees to plus 10 degrees C. The other contaminant (light volatile) is controlled by the heat pipe temperature, and the contamination is significantly reduced when the Thermal Electric Cooler (TEC) hot-junction temperature is below minus 40 degrees to minus 50 degrees C. The utility of contamination sensors located behind instruments during system tests was demonstrated.

Taylor, Daniel M.↗

NASA NTRS1994

Digital-Electronic/Optical Apparatus Would Recognize Targets

Proposed automatic target-recognition apparatus consists mostly of digital-electronic/optical cross-correlator that processes infrared images of targets. Infrared images of unknown targets correlated quickly with images of known targets. Apparatus incorporates some features of correlator described in "Prototype Optical Correlator for Robotic Vision System" (NPO-18451), and some of correlator described in "Compact Optical Correlator" (NPO-18473). Useful in robotic system; to recognize and track infrared-emitting, moving objects as variously shaped hot workpieces on conveyor belt.

Scholl, Marija S.↗

NASA NTRS1987

Digital solar edge tracker for the Halogen Occultation Experiment

The optical and electronic design of the Halogen Occultation Experiment (Haloe) elevation sun sensor is described. The Haloe instrument is a gas-correlation radiometer now being developed at NASA Langley for the Upper Atmosphere Research Satellite. The system uses a Galilean telescope to form a solar image on a linear silicon photodiode array. The array is a self-scanned monolithic CCD. The addresses of both solar edges imaged on the array are used by the control/pointing system to scan the Haloe science instantaneous field of view (IFOV) across the vertical solar diameter during instrument calibration and then to maintain the science IFOV 4 arcmin below the top edge during the science data occultation event. Vertical resolution of 16 arcsec and a radiometric dynamic range of 100 are achieved at the 700-nm operating wavelength. The design provides for loss of individual photodiode elements without loss of angular tracking capability.

Mauldin, L. E., III↗