Search NASA⌕ Search

SEARCH · Search NASA

Results for “decaying mechanism”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Impact of substrates and quantum effects on exciton line shapes of 2D semiconductors at room temperature

Exciton resonances in monolayer transition-metal dichalcogenides (TMDs) provide exceptionally strong light–matter interaction at room temperature. Their spectral line shape is critical in the design of a myriad of optoelectronic devices, ranging from solar cells to quantum information processing. However, disorder resulting from static inhomogeneities and dynamical fluctuations can significantly impact the line shape. Many recent works experimentally evaluate the optical properties of TMD monolayers placed on a substrate and the line shape is typically linked directly to the material’s quality. Here, we highlight that the interference of the substrate and TMD reflections can strongly influence the line shape. We further show how basic, room-temperature reflection measurements allow investigation of the quantum mechanical exciton dynamics by systematically controlling the substrate reflection with index-matching oils. By removing the substrate contribution with properly chosen oil, we can extract the excitonic decay rates including the quantum mechanical dephasing rate. The results provide valuable guidance for the engineering of exciton line shapes in layered nanophotonic systems.

2D semiconductor↗
DOE OSTI2022

Rapid Allylic 1,6 H-Atom Transfer in an Unsaturated Criegee Intermediate

Here, a novel allylic 1,6 hydrogen-atom-transfer mechanism is established through infrared activation of the 2-butenal oxide Criegee intermediate, resulting in very rapid unimolecular decay to hydroxyl (OH) radical products. A new precursor, Z/E -1,3-diiodobut-1-ene, is synthesized and photolyzed in the presence of oxygen to generate anew four-carbon Criegee intermediate with extended conjugation across the vinyl and carbonyl oxide groups that facilitates rapid allylic 1,6 H-atom transfer. A low-energy reaction pathway involving isomerization of 2-butenal oxide from a lower-energy ( tZZ ) conformer to a higher-energy ( cZZ ) conformer followed by 1,6 hydrogen transfer via a seven-membered ring transition state is predicted theoretically and shown experimentally to yield OH products. The low-lying ( tZZ ) conformer of 2-butenaloxide is identified based on computed an harmonic frequencies and intensities of its conformers. Experimental IR action spectra recorded in the fundamental CH stretch region with OH product detection by UV laser-induced fluorescence reveal a distinctive IR transition of the low-lying ( tZZ ) conformer at 2996 cm -1 that results in rapid unimolecular decay to OH products. Statistical RRKM calculations involving a combination of conformational isomerization and unimolecular decay via 1,6 H-transfer yield an effective decay rate k eff ( E ) on the order of 10 8 s -1 at ca. 3000 cm -1 in good accord with the experiment. Unimolecular decay proceeds with significant enhancement due to quantum mechanical tunneling. A rapid thermal decay rate of ca. 10 6 s -1 is predicted by master-equation modeling of 2-butenal oxide at 298 K, 1 bar. This novel unimolecular decay pathway is expected to increase the nonphotolytic production of OH radicals upon alkene ozonolysis in the troposphere.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Precision spectroscopy of nuclear decays using quantum optomechanical sensors

This project developed and demonstrated a fundamentally new way to detect individual nuclear decays: rather than capturing the energy that decay products deposit in a detector, we measure the tiny mechanical recoil of the entire micron- or nanometer-sized particle in which the decaying nucleus is embedded. Because momentum is conserved, this approach is sensitive even to neutral, weakly interacting particles, including neutrinos, that escape conventional detectors. During the award, the Yale group reported the first-ever mechanical detection of single nuclear decays, a result featured widely in the scientific press, and pushed the sensitivity of smaller levitated nanoparticles into the quantum measurement regime, reaching an impulse resolution within a factor of five of the fundamental Standard Quantum Limit (SQL), good enough in principle to detect the momentum kicked to the particle by a single emitted neutrino. In parallel, the LBNL group developed the theory of quantum-enhanced (sub-SQL) readout tailored to this experiment, showing how squeezed light can push the sensitivity below the SQL. Together these results establish levitated optomechanical sensors as a new tool for precision nuclear decay spectroscopy, with further applications in neutrino physics, quantum metrology, and nuclear forensics and safeguards.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

Photoproduction of Lambda* Resonances using the CLAS Detector

This thesis presents the study of the reaction yp -> K^+Lambda* using the photo production data from the CLAS-g12 experiment performed in Hall B of Jefferson Laboratory. The decay of Lambda* resonances, Lambda(1520), Lambda(1670), and Lambda(1690), into two exclusive channels, Sigma+pi?and Sigma-pi+, is studied from the detected K+,pi+, and pi?particles. This work aims at understanding photoproduction mechanism to excited state baryons, and to facilitate phenomenological model predictions using precision experimental measurements. A good agreement is established for the Lambda(1520) differential cross sections with the previous CLAS measurements. The differential cross sections as a function of CM angle are extended to higher photon energies. Newly added are the differential cross sections as a function of invariant 4-momentum transfer, which is the natural variable to use for a theoretical model based on a Regge-exchange reaction mechanism. No new N* resonances decaying into the K+Lambda(1520) final state are found. The higher mass resonances, Lambda(1670)1/2- and Lambda(1690)3/2-, are studied for the first time using photoproduction. This work provides a model dependent preliminary cross sections for these excited states.

Shrestha, Utsav↗
DOE OSTI2020

The Effects of Field Line Curvature (FLC) Scattering on Ring Current Dynamics and Isotropic Boundary

Abstract In the ring current dynamics, various loss mechanisms contribute to the ring current decay, including losses to the upper atmosphere through particle precipitation. This study implements the field line curvature (FLC) scattering mechanism in a kinetic ring current model and investigates its role in precipitating ions into the ionosphere during the 17 March 2013 storm. Simulation results indicate that (1) the FLC scattering process exerts on energetic ions on the nightside where the magnetospheric configuration is more stretching. It is more effective on heavy ions (e.g., O + ). These ion losses thereafter lead to a faster recovery of the ring current. (2) The FLC‐associated ion precipitation mainly occurs in the outer region (L > 5 for protons and L > 4.5 for oxygen ions) on the nightside. The O + precipitation takes places in a wider region than protons although its intensity is much lower. Comparisons with POES observations suggest that more proton precipitation is needed in the inner region. This is probably caused by the less stretched configuration in the simulation that prevents more precipitation. It may also imply that other loss process is required in the model such as wave‐particle interactions. (3) The storm time precipitating proton flux of tens of keV due to the FLC scattering sometimes becomes comparable to that of electrons on the nightside, although electrons usually dominate the ionospheric energy deposition from the midnight eastward toward the dayside. (4) The FLC scattering process seems to be capable of explaining the formation of isotropic boundary in the ionosphere during the investigated event.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Numerical Analysis of Time Resolved Photoluminescence for Alumina/Cd(Se,Te) Double Heterostructures

Al2O3 has demonstrated excellent Cd(Se,Te) surface passivation. In this work, recombination mechanisms were investigated by comparing simulations of time resolved photoluminescence (TRPL) to PL decay data (320 ns effective lifetime) for Al2O3 /Cd(Se,Te)/Al2O3 double heterostructures. Models were employed to investigate the effects of bulk and surface recombination, electric fields, mobility, and doping by simulating intensity-dependent single- (1PE) and two-photon excitation (2PE) TRPL. 2PE simulations replicate decay behavior while 1PE simulations require attention to charge redistribution. Various coupled mechanisms cannot be distinguished from PL decay data alone. Complementary measurements are required to constrain the model parameters and isolate mechanisms.

CdTe↗
DOE OSTI2025

Search for a heavy pseudoscalar Higgs boson decaying to a 125 GeV Higgs boson and a Z boson in final states with two tau and two light leptons in proton-proton collisions at $\sqrt{s} = 13$ TeV

A search for a heavy pseudoscalar Higgs boson, A, decaying to a 125 GeV Higgs boson h and a Z boson is presented. The h boson is identified via its decay to a pair of tau leptons, while the Z boson is identified via its decay to a pair of electrons or muons. The search targets the production of the A boson via the gluon-gluon fusion process, gg → A, and in association with bottom quarks, $b\overline{b}A$. The analysis uses a data sample corresponding to an integrated luminosity of 138 fb −1 collected with the CMS detector at the CERN LHC in proton-proton collisions at a centre-of-mass energy of $\sqrt{s} = 13$ TeV. Constraints are set on the product of the cross sections of the A production mechanisms and the A → Zh decay branching fraction. The observed (expected) upper limit at 95% confidence level ranges from 0.049 (0.060) pb to 1.02 (0.79) pb for the gg → A process and from 0.053 (0.059) pb to 0.79 (0.61) pb for the $b\overline{b}A$ process in the probed range of the A boson mass, mA, from 225 GeV to 1 TeV. The results of the search are used to constrain parameters within the $M^{125}_{h,EFT}$ benchmark scenario of the minimal supersymmetric extension of the standard model. Values of tan β below 2.2 are excluded in this scenario at 95% confidence level for all mA values in the range from 225 to 350 GeV.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Supercurrent decay in ballistic magnetic Josephson junctions

We investigate transport properties of ballistic magnetic Josephson junctions and establish that suppression of supercurrent is an intrinsic property of the junctions, even in absence of disorder. By studying the role of ferromagnet thickness, magnetization, and crystal orientation we show how the supercurrent decays exponentially with thickness and identify two mechanisms responsible for the effect: (i) large exchange splitting may gap out minority or majority carriers leading to the suppression of Andreev reflection in the junction, (ii) loss of synchronization between different modes due to the significant dispersion of the quasiparticle velocity with the transverse momentum. Our results for Nb/Ni/Nb junctions are in good agreement with recent experimental studies. Our approach combines density functional theory and the Bogoliubov-de Gennes model and opens a path for material composition optimization in magnetic Josephson junctions and superconducting magnetic spin valves.

36 MATERIALS SCIENCE↗
DOE OSTI2024

K isomers in atomic nuclei

The properties of K isomers are reviewed. Energies and decay hindrance factors are considered in detail for selected isomers in the A ≈ 160–190 region, focusing on pairing effects and the key K-mixing mechanisms that influence γ-ray decay rates. The β-decay of K isomers is studied, indicating that, far from the valley of β stability, high-K β-decaying isomers will populate high-K states in the daughter nuclei. The challenges of revealing predicted, but as-yet undiscovered, long-lived isomers in the neutron-rich N ≈ 16 prolate–oblate shape transition region are highlighted, and the occurrence of oblate high-K isomers is discussed. The 2015 multi-quasiparticle K-isomer table of Kondev, Dracoulis, and Kibédi is updated.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2026

Effect of Sample Mass, Confinement, and Preheating Time on the Thermal Response of LLM‐105: Experiments and Kinetic Analysis

Various small-scale experiments were performed to provide data for developing a model to predict the thermal response of LLM-105 over a wide range of conditions. The thermal decomposition of LLM-105 was studied as a function of sample mass, confinement of volatile products, and preheating time in both isothermal and ramped heating experiments. The thermal decomposition of LLM-105 is a two-step process, as shown by the two exothermic peaks in the heat flow profiles, which were fitted to two nth-order autocatalytic reaction models with a similar activation energy of ∼289 kJ/mol. The magnitude and shape of these peaks varied with sample mass and confinement. Increasing sample mass enhanced the second exotherm with respect to the first one, while increasing the level of confinement promoted a transition from a sublimation-dominated regime towards thermal decomposition. The effect of LLM-105 particle size on the rate of weight loss was evident for open-pan experiments, where bigger particles sublimed at lower temperatures than smaller particles. Thermal response and solid residue composition of LLM-105 samples were analyzed following preheating for different durations. Longer preheating times caused a shift of the second exotherm to lower temperatures and a decrease in the reaction enthalpy, confirming that LLM-105 decay is a consecutive reaction mechanism, probably autocatalytic. In conclusion, the kinetic model derived from ramped experiments was validated against the measured LLM-105 fraction remaining and the enthalpy remaining of the solid residue as a function of preheating times and showed good agreement.

Chemistry - Chemical explosives↗
DOE OSTI2021

Parametrizations of the spin density matrix

Highlights: • Proposed two methods for parametrizing the SDM of spinning, unstable particles. • All non-negativity conditions fulfilled; adaptability to various constraints. • First method: based on a theorem; applicable in a simple and flexible way. • Second method: particularly suitable for especial conditions. • Applications: two of them interesting in the search for new physics. We propose for the spin density matrix two parametrizations which automatically fulfill the non-negativity conditions, without setting any bound on the parameters. The first one relies on a theorem, that we prove, and it is rather simple and easily adaptable to some specific reactions, where, for example, parity is conserved or angular momentum conservation entails selection rules. Moreover, in the case when the rank is less than the order of the density matrix, we show how to improve the fits to the data, either by implementing previous suggestions, or by elaborating an alternative method, for which we prove a second theorem. Our second parametrization is a variant of previous treatments, it appears suitable for some particular processes. Moreover, we discuss about the possibility of inferring the elements of the density matrix from the differential decay width. Last, we illustrate various examples of current interest, both in strong and weak decays; some of them may be helpful in the investigation of physics beyond the standard model.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2026

Buried Interfaces in Organic Photocathodes for H 2 Evolution: Fermi-Level Pinning and Recombination

Herein, we demonstrate how Fermi-level pinning at buried contacts impacts solar fuel generation in all-polymer photocathodes by systematically comparing the effects of work function, hydroxyl coverage, and hydrogen evolution using chemically modified indium tin oxide (ITO) supports. Photovoltages and net photocathode performance are improved when the ITO is passivated using phosphonic acids, independent of work function, suggesting that the passivation reduces Fermi-level pinning at the buried interface arising from blended heterojunction interactions with surface metal hydroxyls. Transient photovoltage decay reveals differences in recombination mechanisms, supported by light intensity-dependent measurements. Briefly, nonpassivated, hydrophilic contacts exhibit trap-assisted recombination, while passivated, hydrophobic contacts follow bimolecular recombination. We then investigate changes in electroactivity of hole-transfer processes as a function of scan rate and repetitive cycling using a diffusion-controlled molecular redox probe, analogous to a hole-only device achieved via the electrolyte. The nonpassivated buried contacts exhibit higher overpotentials for oxidation, indicative of hole injection/extraction barriers. We observe irreversible electron transfer via the hole-transport level of the blended heterojunction and a strong cycle dependence, consistent with changes in the hole trap state density. Passivation results in more reversible redox behaviors, consistent with more Ohmic-like contacts. Collectively, these results provide context toward the realization of durable organic photoelectrodes with optimized photovoltages and net solar-to-hydrogen conversion efficiencies via fundamental understanding of the rates of carrier generation, recombination, and transport in high-dielectric aqueous environments and opportunities to characterize buried interfaces under device-relevant electric fields.

buried interfaces↗
DOE OSTI2024

Transverse emittance reduction in muon beams by ionization cooling

Accelerated muon beams have been considered for the next-generation studies of high-energy lepton–antilepton collisions and neutrino oscillations. However, high-brightness muon beams have not yet been produced. The main challenge for muon acceleration and storage stems from the large phase-space volume occupied by the beam, derived from the production mechanism of muons through the decay of pions. The phase-space volume of the muon beam can be decreased through ionization cooling. Here we show that ionization cooling leads to a reduction in the transverse emittance of muon beams that traverse lithium hydride or liquid hydrogen absorbers in the Muon Ionization Cooling Experiment. Our results represent a substantial advance towards the realization of muon-based facilities that could operate at the energy and intensity frontiers.

43 PARTICLE ACCELERATORS↗
DOE OSTI2021

Application of saturation absorption spectroscopy to study the hyperfine structure of 235U and accurate 235U/238U isotope ratio determinations at 861.031 nm

The uranium transition 5f 3 6d7s 2 ( 5 L 6 ) → 5f 3 7s 2 7p ( 5 K 5 ) at 861.031 nm was studied using saturation absorption spectroscopy. The hyperfine structure of the 235 U isotope was determined by measuring the Doppler-suppressed absorption spectrum, and the hyperfine structure constants were obtained by employing transition-specific line strength theory and spectral fitting. The magnetic-dipole and electric-quadrupole constants were determined to be A = -3.2887 ± 0.1957 mK and B = 31.8712 ± 8.0789 mK for the upper state 5f 3 7s 2 7p ( 5 K 5 ). A theoretical calculation for the hyperfine structure constants of the 235 U isotope was also carried out by the relativistic configuration-interaction (RCI) method, and the obtained values were found to be in agreement with the measured values. In addition, the line profile of 238 U was experimentally investigated for different excitation intensities and modeled using the RCI method for estimating the transition probability and oscillator strength, with various residual broadening mechanisms considered beyond the radiative decay. Finally, we show that these results allow us to make improvements on the precision of spectral measurements using our previously developed technique for isotope ratio determinations in atomic beams.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

SN 2020bqj: A Type Ibn supernova with a long-lasting peak plateau

We report type Ibn supernovae (SNe Ibn) are a rare class of stripped envelope supernovae interacting with a helium-rich circumstellar medium (CSM). The majority of the SNe Ibn reported in the literature display a surprising homogeneity in their fast-evolving lightcurves and are typically found in actively starforming spiral galaxies. We present the discovery and the study of SN 2020bqj (ZTF20aalrqbu), a SN Ibn with a long-duration peak plateau lasting 40 days and hosted by a faint low-mass galaxy. We aim to explain its peculiar properties using an extensive photometric and spectroscopic data set. We compare the photometric and spectral evolution of SN 2020bqj with regular SNe Ibn from the literature, as well as with other outliers in the SN Ibn subclass. We fit the bolometric and multi-band lightcurves with powering mechanism models such as radioactive decay and CSM interaction. We also model the host galaxy of SN 2020bqj. The risetime, peak magnitude and spectral features of SN 2020bqj are consistent with those of most SNe Ibn, but the SN is a clear outlier in the subclass based on its bright, long-lasting peak plateau and the low mass of its faint host galaxy. We show through modeling that the lightcurve of SN 2020bqj can be powered predominantly by shock heating from the interaction of the SN ejecta and a dense CSM, combined with radioactive decay. The peculiar Type Ibn SN 2011hw is a close analog to SN 2020bqj in terms of lightcurve and spectral evolution, suggesting a similar progenitor and CSM scenario. In this scenario a very massive progenitor star in the transitional phase between a luminous blue variable and a compact Wolf-Rayet star undergoes core-collapse, embedded in a dense helium-rich CSM with an elevated opacity compared to normal SNe Ibn, due to the presence of residual hydrogen. This scenario is consistent with the observed properties of SN 2020bqj and the modeling results. SN 2020bqj is a compelling example of a transitional SN Ibn/IIn based on not only its spectral features, but also its lightcurve, host galaxy properties and the inferred progenitor properties. The strong similarity with SN 2011hw suggests this subclass may be the result of a progenitor in a stellar evolution phase that is distinct from those of progenitors of regular SNe Ibn.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Observational constraints on warm natural inflation

Warm natural inflation is studied for the case of the original cosine potential. The radiation bath during inflation induces a dissipation (friction) rate in the equation of motion for the inflation field, which can potentially reduce the field excursion needed for an observationally viable period of inflation. Here we examine if the dissipation thus provides a mechanism to avoid the large decay constant f ≳ M pl of cold cosine natural inflation. Whereas temperature independent dissipation has previously been shown to alleviate the need for a trans-Planckian decay constant f, we illustrate here the difficulties of accommodating a significantly sub-Planckian decay constant (f < 10 -1 M pl ) for the case of a temperature dependent dissipation rate in the form Γ ∝ T c , with c = {1,3}. Such dissipation rates represent physically well-motivated constructions in the literature. For each model, we map its location in the r-n s plane and compare with cosmic microwave background (CMB) data. For c = 1 (c = 3), we find that agreement with CMB data requires that dissipation be in the weak (moderate) regime and that the minimum allowed value of the decay constant in the potential is f min = 0.3 (0.8) M pl , respectively.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Universally high transcript error rates in bacteria

Errors can occur at any level during the replication and transcription of genetic information. Genetic mutations derived mainly from replication errors have been extensively studied. However, fundamental details of transcript errors, such as their rate, molecular spectrum, and functional effects, remain largely unknown. To globally identify transcript errors, we applied an adapted rolling-circle sequencing approach to Escherichia coli, Bacillus subtilis, Agrobacterium tumefaciens, and Mesoplasma florum, revealing transcript-error rates 3 to 4 orders of magnitude higher than the corresponding genetic mutation rates. The majority of detected errors would result in amino-acid changes, if translated. With errors identified from 9929 loci, the molecular spectrum and distribution of errors were uncovered in great detail. A G→A substitution bias was observed in M. florum, which apparently has an error-prone RNA polymerase. Surprisingly, an increased frequency of nonsense errors towards the 3' end of mRNAs was observed, suggesting a Nonsense-Mediated Decay-like quality-control mechanism in prokaryotes.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Physics of the Inverted Harmonic Oscillator: From the lowest Landau level to event horizons

In this work, we present the inverted harmonic oscillator (IHO) Hamiltonian as a paradigm to understand the quantum mechanics of scattering and time-decay in a diverse set of physical systems. As one of the generators of area preserving transformations, the IHO Hamiltonian can be studied as a dilatation generator, squeeze generator, a Lorentz boost generator, or a scattering potential. In establishing these different forms, we demonstrate the physics of the IHO that underlies phenomena as disparate as the Hawking–Unruh effect and scattering in the lowest Landau level (LLL) in quantum Hall systems. We derive the emergence of the IHO Hamiltonian in the LLL in a gauge invariant way and show its exact parallels with the Rindler Hamiltonian that describes quantum mechanics near event horizons. This approach of studying distinct physical systems with symmetries described by isomorphic Lie algebras through the emergent IHO Hamiltonian enables us to reinterpret geometric response in the lowest Landau level in terms of relativistic effects such as Wigner rotation. Further, the analytic scattering matrix of the IHO points to the existence of quasinormal modes (QNMs) in the spectrum, which have quantized time-decay rates. We present a way to access these QNMs through wave packet scattering, thus proposing a novel effect in quantum Hall point contact geometries that parallels those found in black holes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗