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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Tuning Surface Acidity of Mixed Conducting Electrodes: Recovery of Si‐Induced Degradation of Oxygen Exchange Rate and Area Specific Resistance

Abstract Metal oxides are an important class of functional materials, and for many applications, ranging from solid oxide fuel/electrolysis cells, oxygen permeation membranes, and oxygen storage materials to gas sensors (semiconducting and electrolytic) and catalysts, the interaction between the surface and oxygen in the gas phase is central. Ubiquitous Si‐impurities are known to impede this interaction, commonly attributed to the formation of glassy blocking layers on the surface. Here, the surface oxygen exchange coefficient ( k chem ) is examined for Pr 0.1 Ce 0.9 O 2‐δ (PCO), a model mixed ionic electronic conductor, via electrical conductivity relaxation measurements, and the area‐specific resistance (ASR) by electrochemical impedance spectroscopy. It is demonstrated that even low silica levels, introduced by infiltration, depress k chem by a factor 4000, while the ASR increases 40‐fold and we attribute this to its acidity relative to that of PCO. The ability to fully regenerate the poisoned surface by the subsequent addition of basic Ca‐ or Li‐species is further shown. This ability to not only recover Si‐poisoned surfaces by tuning the relative surface acidity of an oxide surface, but subsequently outperform the pre‐poisoned response, promises to extend the operating life of materials and devices for which the catalytic oxygen/solid interface reaction is central.

30 DIRECT ENERGY CONVERSION↗
NASA NTRS2025

Integrating the Interconnections Between Groundwater and Land Surface Processes Through the Coupled NASA Land Information System and ParFlow Environment

Understanding the interactions between the atmosphere, the land, and the subsurface is fundamental to hydrology and is critical for a better assessment of the impacts of climate change and human management on hydrological systems. However, many land surface models simplify the subsurface hydrology and thereby these interactions. In this study, we couple the land surface model Noah-MP included in the NASA Land Information System (LIS) with the integrated hydrologic model ParFlow (ParFlow-LIS) using the Earth System Modeling Framework (ESMF) and the National United Operational Prediction Capability (NUOPC). This coupling improves the simulation of water and energy cycle processes by adding the three-dimensional variably saturated and heterogeneous flow in the subsurface using sophisticated and nonlinear physics-based equations as well as the advances in satellite remote sensing-based data assimilation of the land surface, thereby benefiting the integrated hydrologic modeling and data assimilation community. We use the High Plains aquifer, located in the central United States, as a testbed to evaluate the coupled ParFlow-LIS system. The new ParFlow-LIS system accounts for the effects of topographically driven flows on the land surface, producing more fine-scale patterns of land surface states and fluxes than standalone LIS. In addition, ParFlow-LIS enables the consideration of the effect of subsurface water storage on evapotranspiration. This is particularly important in areas and times with dry soils, such as during drought conditions or in the presence of a cone of depression due to pumping.

land surface modeling↗
NASA NTRS2012

N(50) Crater Retention Ages for an Expanded Inventory of Lunar Basins: Evidence for an Early Heavy Bombardment and a Late Heavy Bombardment?

LOLA topography and LOLA-derived crustal thickness data provide evidence for a population of impact basins on the Moon that is likely a factor 2 larger than the classical lists based on photogeology. Frey (2012) determined N(50) crater retention ages (CRAs) for 83 candidate basins > 300 km in diameter by counting LOLA-identified craters superimposed over the whole area of the basins. For some basins identified in topography or model crustal thickness it is not possible to unambiguously identify the crater rim as is traditionally done. Also, Quasi-Circular Depressions (QCDs) > 50 km in diameter are recognizable in the mare-filled centers of many basins. Even though these are not apparent in image data, they likely represent buried impact craters superimposed on the basin floor prior to mare infilling and so should be counted in determining the age of the basin. Including these as well as the entire area of the basins improves the statistics, though the error bars are still large when using only craters > 50 km in diameter. The distribution of N(50) CRAs had two distinct peaks which did not depend on whether the basins were named (based on photogeology) or recognized first in topography or crustal thickness data. It also did not depend on basin diameters (both larger and smaller basins made up both peaks) and both peaks persisted even when weaker candidates were excluded. Burgess (2012, unpublished data) redid the counts for 85 basins but improved on the earlier effort by adjusting the counting area where basins overlap. The two peak distribution of N(50) ages was confirmed, with a younger peak at N(50) ~ 40-50 and an older peak at N(50) ~ 80-90 (craters > 50 km diameter per million square km). We suggest this could represent two distinct populations of impactors on the Moon: one producing an Early Heavy Bombardment (EHB) that predates Nectaris and the second responsible for the more widely recognized Late Heavy Bombardment (LHB).

Frey, Herbert↗
NASA NTRS2003

Estimation of the Anthropogenic Influence in the Sahel by Terra and Aqua

Saharan dust impacts the Earth radiation balance. It was suggested that anywhere between 20-50% of the dust is anthropogenic, generated from human activity in the Sahel. Recent study By Prospero et al noticed that most of the sources should be north of Latitude of 15 deg. where population density is small. Here we use Aqua and Terra data to study the dust sources and their possible anthropogenic origin. Dust packages emitted from the Bodele depression and other sources in the southern part of the Sahara, are transported in the winter by a Northern East winds over the Sahel to the ocean. We are tracking these packages with MODIS from their sources to the ocean, showing that most of the dust reaching the Ocean from the Sahelian shore is generated in the Sahara, suggesting that the anthropogenic influence in the area is negligible. Saharan dust was suggested to be the main source of nutrients to the Amazon forest. Here we are also showing that these South Saharan sources around the Bodele depression are very active in the winter and rather passive in the summer, suggesting that the type of dust reaching Brazil, and its mineral content from these sources may be different from the dust that arrives to North America and Europe emitted in the summer from different sources.

Koren, I.↗
DOE OSTI2022

Forest structure and solar-induced fluorescence across intact and degraded forests in the Amazon

Tropical forest degradation (e.g., anthropogenic disturbances such as selective logging and fires) alters forest structure and function and influences the forest's carbon sink. In this study, we explored structure-function relationships across a variety of degradation levels in the southern Brazilian Amazon by 1) investigating how forest structural properties vary as a function of degradation history using airborne lidar data; 2) assessing the effects of degradation on solar-induced chlorophyll fluorescence (SIF) seasonality using TROPOMI data; and 3) quantifying the contribution of structural variables to SIF using multiple regression models with stepwise selection of lidar metrics. Forest degradation history was obtained through Landsat time-series classification. We found that fire, logging, and time since disturbance were major determinants of forest structure, and that forests affected by fires experienced larger variability in leaf area index (LAI), canopy height and vertical structure relative to logged and intact forests. Moreover, only recently burned forests showed significantly depressed SIF during the dry season compared to intact forests. Canopy height and the vertical distribution of foliage were the best predictors of SIF. Unexpectedly, we found that wet-season SIF was higher in active regenerating forests (~ 4 years after fires or logging) compared with intact forests, despite lower LAI. Furthermore, our findings help to elucidate the mechanisms of carbon accumulation in anthropogenically disturbed tropical forests and indicate that they can capture large amounts of carbon while recovering.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Computing water flow through complex landscapes – Part 3: Fill–Spill–Merge: flow routing in depression hierarchies

Abstract. Depressions – inwardly draining regions – are common to many landscapes. When there is sufficient moisture, depressions take the form of lakes and wetlands; otherwise, they may be dry. Hydrological flow models used in geomorphology, hydrology, planetary science, soil and water conservation, and other fields often eliminate depressions through filling or breaching; however, this can produce unrealistic results. Models that retain depressions, on the other hand, are often undesirably expensive to run. In previous work we began to address this by developing a depression hierarchy data structure to capture the full topographic complexity of depressions in a region. Here, we extend this work by presenting the Fill–Spill–Merge algorithm that utilizes our depression hierarchy data structure to rapidly process and distribute runoff. Runoff fills depressions, which then overflow and spill into their neighbors. If both a depression and its neighbor fill, they merge. We provide a detailed explanation of the algorithm and results from two sample study areas. In these case studies, the algorithm runs 90–2600 times faster (with a reduction in compute time of 2000–63 000 times) than the commonly used Jacobi iteration and produces a more accurate output. Complete, well-commented, open-source code with 97 % test coverage is available on GitHub and Zenodo.

58 GEOSCIENCES↗
NASA NTRS1976

Studies related to the development of the Viking 1975 labeled release experiment

The labeled release life detection experiment on the Viking 1975 Mars mission is based on the concept that microorganisms will metabolize radioactive organic substrates in a nutrient medium and release radioactive carbon dioxide. Several experiments, using laboratory equipment, were carried out to evaluate various aspects of the concept. Results indicate: (1) label is released by sterilization-treated soil, (2) substantial quantities of label are retained in solution under basic conditions, (3) the substrate used, as well as position of label in the molecule, affect release of label, (4) label release is depressed by radiolytic decomposition of substrates, and (5) About 100,000 organisms are required to produce a detectable response. These results, suggest additional areas for testing, add to the data base for interpretation of flight results, and have significance for broader application of this technique for assessing microbial activity.

Devincenzi, D. L.↗
NASA NTRS1985

Cryoconite holes on glaciers

Cryoconite holes are water-filled depressions on the surface of glaciers. They contain microbial communities and may contribute to glacial wastage and biological colonization of ice-free areas.

Wharton, R. A., Jr.↗
NASA NTRS1991

Channeling episodes of Kasei Valles, Mars, and the nature of ridged plains material

The geologic mapping compiled at 1:500,000 scale of the northern Kasei Valles area of Mars (MTMs 25062 and 25067) indicates (1) at least three periods of Kasei Valles channeling, (2) the development of Sacra Fossae (linear depressions on Tempe Terra and Lunae Planum) in relation to Kasei channeling episodes, and (3) the nature of ridged plains material dissected by Kasei Valles on northern Lunae Planum. (The three channeling periods consists of two flood events and a later, sapping related event). These findings suggest hydrologic conditions and processes that formed Kasei Valles and associated features and terrains. It is concluded that an early period of flooding, whose source is perhaps buried beneath lava flows of Tharsis Montes, may have eroded streamlined features in northern Lunae Planum. Also, later floods originating from Echus Chasma formed after the initial flooding and the mesas adjacent to the plateau. The Sacra Fossae formed after the initial flooding and during the second flooding by sapping, outbreak, scarp retreat, and collapse along joints and fractures in ridged plains materials.

Chapman, Mary G.↗
NASA NTRS1975

Hydrogeological investigations in the Pampa of Argentina

In large areas of the Argentinian Pampa the salinization of ground water creates water supply difficulties. Investigations of satellite imagery (Landsat-1 and Skylab) which were based on an extensive ground survey revealed that differences in the vegetation cover are closely related to depth and salinity of ground water. Narrow elongated depressions called bajos are often the only indication of fresh ground water. They can be easily detected on the imagery. Due to their high resolution, Skylab photos even allow a quantitative estimation of fresh ground water situated below the bajos. In general however Landsat-1 imagery sufficed for evaluation. In the area of the Rio Tercero a fossil drainage pattern was discovered and in Corrientes province, soil types could be discriminated and compared to the Soil Map of the World.

Kruck, W.↗
NASA NTRS1987

Wilson Cycle studies

The main activity relating to the study during this half year was a three week field trip to study Chinese sedimentary basins (June 10 to July 3, 1986) at no cost to the project. This study, while of a reconnaissance character, permitted progress in understanding how the processes of island arc-collision and micro-continental collision operated during the Paleozoic in far western China (especially the Junggar and Tarim basins and in the intervening Tien Shan Mountains). These effects of the continuing collision of India and Asia on the area were also studied. Most specifically, these result in the elevation of the Tien Shan to more than 4 km above sea level and the depression of Turfan to move 150m below sea level. Both thrusting and large-scale strike-slip motion are important in producing these elevation changes. Some effort during the half year was also devoted to the study of greenstone-belts in terms of the Wilson Cycle.

Burke, Kevin↗
NASA NTRS1991

Diagnostic evaluation of numerical model simulations using the tendency equation

A procedure is proposed to expand the diagnostic capabilities of the pressure tendency equation of a primitive equation NWP model by computing the pressure tendency in physical coordinates. The advantages of isolating the density advection as a diagnostic tool to understand pressure changes is shown. By simple thermodynamic arguments it is demonstrated that in areas of synoptic-scale cyclonic development, the vertically integrated density advection is more than sufficient to explain the depletion of mass over a growing depression. Consequently, the joint contribution of the net divergence and vertical motion opposes the pressure fall. This is illustrated for a case of rapid cyclogenesis in southern South America.

Jusem, Juan C.↗
NASA NTRS1993

Tectonics of Neyterkob corona on Venus

Neyterkob double corona (50 deg N 202 deg) presents an area of corona-related interfering tectonic patterns which are formed in different phases of evolution of the corona and modified by regional stresses. Analyzing the patterns can reveal something about the coronal formation. Tectonic features form distinct units on topographic depressions, slopes, and volcanic flows extending over one radius of the corona. A remarkable amount of compressional features were found near the rim and related to interaction between adjacent coronae. Radial extension was mainly observed on a peculiar NE-SW trending high crossing the corona. Concentric fractures were found to the east partly connected to the lithospheric flexure. Tectonic features indicate movements of volcanic activity and modification of the area by more regional stresses.

Kauhanen, K.↗
NASA NTRS1987

Distribution and timing of thick transient air-fall deposits in Electris: Implications for the nature of the upland plains

A large area in the Electris region of Mars is (or once was) covered by an unconformable and etched deposit. Although interpreted as lava filling volcano-tectonic depressions or fluvial deposits filling large degraded craters, more recent work has shown the deposit is more likely the result of air-fall deposition. Crater densities on both the surface of the deposit and on exhumed, underlying ridged plains indicate that the deposit was emplaced and eroded over a relatively short time. These crater statistics also demonstate that the relative age of the Electris deposit is similar to those obtained for other unconformable deposits, thereby suggesting they may be related.

Grant, J. A.↗
NASA NTRS1998

MOLA Topography of Impact Basins in the Northern Hemisphere of Mars

Coverage of the northern hemisphere of Mars by the Mars Orbiter Laser Altimeter (MOLA) during the aerobraking hiatus and the two Science Phasing Operation periods provides improved definition and characterization of large impact basins. Gridded MOLA data show the Utopia Basin has a pronounced bowl-like structure, as opposed to the interior rises suggested by the earlier USGS DEM. The elevation structure is concentric about the basin center as mapped by McGill. In particular, the proposed inner ring closely follows the -4 km contour over much of the southern, western and northwestern sides. Higher topography along portions of the dichotomy boundary aligns with the basin's outer ring. High topography in the polar region also occurs where the outer ring should lie, raising the possibility that perhaps some of the polar topography is due to basin structure as well as ice. Two MOLA passes near Phison Rupes provide evidence for a large "stealth" hole where Viking imagery show little evidence of any major structure. The 2 km deep, 600 km wide depression at 31OW, 3ON is as large as the Cassini impact basin 1000 km to the SW. While Cassini is easily recognized in image data, the "MOLA Hole" is not. If this depression is a deeply eroded and buried impact basin (as perhaps suggested by a decrease in the crater density and somewhat smoother terrain than in adjacent areas), it is not clear why it has managed to maintain its great depth. In Tempe at the dichotomy boundary a 300 km wide impact basin is revealed by pronounced bowl-like topography centered at 87W, 47N, even though only about 1/3 of the basin rim structure is obvious. The basin lies on a sloping boundary zone, with the more buried N rim up to 2 km below the rugged S rim. A similar N-S asymmetry in basin ring structure occurs for the much larger Isidis Basin, where the S rim rises 6 km but the subdued N rim rises barely 2 km above the floor. There is essentially no topographic expression of the main ring in the NE quadrant of Isidis where, if it exists, it lies below Hesperian-age plains.

Frey, Herbert↗
NASA NTRS1997

Evolution of Nonlinear Internal Waves in China Seas

Synthetic Aperture Radar (SAR) images from ERS-I have been used to study the characteristics of internal waves of Taiwan in the East China Sea, and east of Hainan Island in the South China Sea. Rank-ordered packets of internal solitons propagating shoreward from the edge of the continental shelf were observed in the SAR images. Based on the assumption of a semidiurnal tidal origin, the wave speed can be estimated and is consistent with the internal wave theory. By using the SAR images and hydrographic data, internal waves of elevation have been identified in shallow water due to a thicker mixed layer as compared with the bottom layer on the continental shelf. The generation mechanism includes the influences of the tide and the Kuroshio intrusion across the continental shelf for the formations of elevation internal waves. The effects of water depth on the evolution of solitons and wave packets are modeled by nonlinear Kortweg-deVries (KdV) type equation and linked to satellite image observations. The numerical calculations of internal wave evolution on the continental shelf have been performed and compared with the SAR observations. For a case of depression waves in deep water, the solitons first disintegrate into dispersive wave trains and then evolve to a packet of elevation waves in the shallow water area after they pass through a turning point of approximately equal layer depths has been observed in the SAR image and simulated by numerical model.

Liu, Antony K.↗
NASA NTRS1974

The application of airborne imaging radars (L and X-band) to earth resources problems

A multiplexed synthetic aperture Side-Looking Airborne Radar (SLAR) that simultaneously images the terrain with X-band (3.2 cm) and L-band (23.0 cm) radar wavelengths was developed. The Feasibility of using multiplexed SLAR to obtain useful information for earth resources purposes. The SLAR imagery, aerial photographs, and infrared imagery are examined to determine the qualitative tone and texture of many rural land-use features imaged. The results show that: (1) Neither X- nor L-band SLAR at moderate and low depression angles can directly or indirectly detect pools of water under standing vegetation. (2) Many of the urban and rural land-use categories present in the test areas can be identified and mapped on the multiplexed SLAR imagery. (3) Water resources management can be done using multiplexed SLAR. (4) Drainage patterns can be determined on both the X- and L-band imagery.

Drake, B.↗
NASA NTRS1976

Lineaments on Skylab photographs: Detection, mapping, and hydrologic significance in central Tennessee

The author has identified the following significant results. Lineaments were detected on Skylab photographs by stereo viewing, projection viewing, and composite viewing. Sixty-nine percent more lineaments were found by stereo viewing than by projection, but segments of projection lineaments are longer; total length of lineaments found by these two methods is nearly the same. Most Skylab lineaments consist of topographic depression: stream channel alinements, straight valley walls, elongated swales, and belts where sinkholes are abundant. Most of the remainder are vegetation alinements. Lineaments are most common in dissected areas having a thin soil cover. Results of test drilling show: (1) the median yield of test wells on Skylab lineaments is about six times the median yield of all existing wells; (2) three out of seven wells on Skylab lineaments yield more than 6.3 1/s (110 gal/min): (3) low yields are possible on lineaments as well as in other favorable locations; and (4) the largest well yields can be obtained at well locations of Skylab lineaments that also are favorably located with respect to topography and geologic structure, and are in the vicinity of wells with large yields.

Moore, G. K.↗