Low solar absorptance and emittance surfaces utilizing vacuum deposited techniques Final report, 1 Jun. 1967 - 25 Mar. 1968
Optical properties and stability of vacuum deposited silver and dielectric film coatings
Greenberg, S. A.↗
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Improved thermophotovoltaic power system
Improvements in thermophotovoltaic (TPV) system design to ease the geometry and performance requirements are discussed. A TPV system usually consists of a receiver cavity lined with reflective materials and Si solar cells. A suspended central absorber/radiator converter absorbs solar energy and heats to an equilibrium temperature of 2000-23,000 K. Radiant heat at that temperature is well matched to Si solar cell low energy excitation. An elliptical geometry cavity is described which bypasses normal cell mounting problems by having the cells fixed to a plate positioned between the loci of the cavity. Incoming concentrated solar flux is absorbed by the absorber/radiator, which emits the radiation for reflection from the cavity walls to eventually pass through the solar cell wall. Dielectric stack coatings can be used on the walls. A theoretical model was developed for the performance and verified with a laboratory apparatus. Efficiencies of nearly 30% were found practical with existing materials and technologies.
Horne, W. E.↗
Dielectric Fabry-Perot mirror coatings for infrared astronomy
A number of Fabry-Perot (FP) coating designs have been developed specifically for IR astronomy. These have been optimized for uniform reflectance over five contiguous spectral ranges of particular astronomical interest between 1 and 5 microns. Wavelength coverage in individual designs is given by (maximum wavelength/minimum wavelength) greater than 1.4, over which reflective finesse is maintained near 35. Consideration has been made for the peculiar requirements of FP coatings. Visual alignment and testing of the FP has been made convenient by bringing the reflective finesse of the coating at 632.8 nm to the same value as the main IR reflection band. For example, a calcium fluoride FP can be aligned and tested at 632.8-nm He-Ne laser line, with the assurance of a corresponding finesse and spectral resolving power over its IR (3.6-5.1-micron) range. In addition, the FP can be used for IR spectroscopy while being simultaneously monitored and/or actively controlled at the laser wavelength. The potential for the coating itself to degrade the effective surface flatness of the FP through either mechanical stress or thickness nonuniformities is minimized by reducing to a minimum the number and thickness of coating layers. Several of these coatings have been fabricated and are actively in use at a number of observatories.
Trauger, J.↗
Electrodynamic interactions
The electrodynamic interaction of long metallic tethers with the ionosphere is introduced. Due to the tether's motion across the Earth's field, a polarization electric field is generated along the tether. In a system like the Tethered Satellite System (TSS) where the tether is coated with dielectric and the electrical contact is between its two terminations and the ionosphere, the upper end termination will collect electrons and, in a passive system, the lower end termination will collect ions. Space charge regions will develop around the two terminations of the system, which can be at considerable potential with respect to the unperturbed ionospheric plasma and the current in the tether will be most significantly determined by local processes in such space charge regions. A qualitative view of the global perturbation induced by TSS in the ionosphere is outlined. One of the applications of electrodynamic tethers is that of using them as low frequency wave generators to communicate to the Earth. This application is briefly discussed. An equivalent circuit of the tether system is described. The basic equation of the circuit is given.
Dobrowolny, M.↗
Trifluorophenylethylidene Condensation Polyimides
Report describes synthesis and properties of trifluorophenylethylidene (3F) condensation polyimides. Properties of these new polymers make suitable thermal-control coatings, interlayer dielectrics in advanced wafer chips, and electronic-multilevel-interconnection layers.
Alston, William B.↗
Tunable UV Filters
This report describes an investigation intended to determine the practical short wavelength limit for Fabry-Perot etalons operating in the far ultraviolet. This portion of the investigation includes a design study of multilayer dielectric reflector coatings that would be required by such an etalon. Results of the study indicate that etalons may be made to operate at wavelengths as short as 121 nm.
Bruner, Marilyn E.↗
SUMI - The Solar Ultraviolet Magnetograph Investigation
Solar physics has been successful in characterizing the full vector magnetic field in the photosphere, where the ratio of gas pressure to magnetic pressure (Beta) is >1. However, at higher levels in the atmosphere, where Beta <<1 and flares and CMEs are believed to be triggered, observations are difficult, severely limiting the understanding of these processes. In response to this situation, we are developing SUMI (the Solar Ultraviolet Magnetograph Investigation) a unique instrument designed to measure the circular and linear polarization of upper chromospheric Mg II lines (280 nm) and circular polarization of transition region C IV lines (155 nm). To date the telescope mirrors have been built, tested and coated with dielectric stacks designed to reflect only the wavelengths of interest. We have also developed a unique UV polarimeter and completed the design of a high-resolution spectrograph that uses dual toroidal varied- line-space (TVLS) gratings. Incorporating measurements of those components developed so far, the revised estimate of the system throughput exceeds our original estimate by more than an order of magnitude. A sounding rocket flight is anticipated in 2006. Our objectives and progress are detailed in this presentation.
Porter, J. G.↗
Increasing Durability of Flame-Sprayed Strain Gauges
Thermally sprayed dielectric ceramic coatings are the primary means of attaching strain and temperature gauges to hot-section rotating parts of turbine engines. As hot-section temperatures increase, lifetimes of installed gauges decrease, and seldom exceed one hour above 2,000 F (approx.1,100 C). Advanced engine components are expected to operate at temperatures approaching 2,200 F (approx.1,200 C), and the required high-temperature lifetime is 10 hours minimum. Typically, to enable a ceramic coating to adhere to the smooth surface of an engine component, a thermally sprayed NiCrAlY or NiCoCrAlY bond coat is applied to the smooth surface, thereby providing a textured surface to which the ceramic coat can adhere. The main failure mechanism of this system is decohesion and/or delamination at the interface between the ceramic top coat and the bond coat, caused by oxidation of the bond coat and stresses from the mismatch between the coefficients of thermal expansion of the ceramic top coat and the metallic bond coat. The approach taken to increase the high-temperature lifetime of a gauge attached to an engine component by the method described above involves (1) selective oxidation of the bond coat by means of a heat treatment in reduced oxygen partial pressure followed by (2) the application of a noble-metal diffusion barrier. In experiments to test this approach, heat treatments of NiCoCrAlY bond coats were carried out in a tube furnace in which, in each case, the temperature was alternately (1) increased at a rate of 3 C per minute and (2) held steady for one hour until the desired temperature was reached. The tube furnace was continuously purged with dry nitrogen gas. A final heat-treatment temperature range of 1,600 to 1,800 F (871 to 982 C) proved most beneficial.
Gregory, Otto J.↗
Fabrication of Compact Superconducting Lowpass Filters for Ultrasensitive Detectors
It is extremely important for current and future far-infrared and sub-millimeter ultrasensitive detectors, which include transition edge sensors (TES) and microwave kinetic inductance detectors, to be adequately filtered from stray electromagnetic radiation in order to achieve their optimal performance. One means of filtering stray radiation is to block leakage associated with electrical connections in the detector environment. Here we discuss a fabrication methodology for realizing non-dissipative planar filters imbedded in the wall of the detector enclosure to limit wave propagation modes up to far-infrared frequencies. Our methodology consists of fabricating a boxed stripline transmission line, in which a superconducting (Nb, Mo, or Al) transmission line is encased in a silicon dioxide dielectric insulator coated with a metallic shell. We report on achieved attenuation and return loss and find that it replicates the simulated data to a high degree.
Brown, Ari↗
Fluorinated Poly(Phenylene Ether Ketones)
Fluorinated poly(phenylene ether ketones) are colorless, transparent, low-dielectric-constant, highly thermally stable polymers. Particularly suitable for use as film and coating materials in electronic and thermal-control applications such as; passivant insulating coats and interlevel dielectrics in microelectronic circuits, or as protective transparent coats on solar cells or mirrors. Solubility and transparency of 12F-PEK along with its lower dielectric constant and other properties make it more useful as dielectric film and coating material in many applications.
St. Clair, Anne K.↗
Development for application of parylene coatings
A practical method of applying a parylene (paraxylene) coating to hybrid microcircuit devices was developed for the prevention of circuit malfunctions existing prior to package sealing or formed upon exposure to the service environment. It was found that paralene and an associated primer (if used) had generally little or no adverse effect on the active and passive elements of typical hybrid microcircuits. Exceptions were related to high frequency circuitry, low resistivity thick film resistors, and highly sensitive PIN diodes. Advantages of the use of the coating included increased dielectric strength and increased interconnection bond strength. Coating service life in nitrogen or nitrogen with low levels of oxygen as a contaminant is shown to be in excess of 1000 hours at 150 C and can be projected to be in excess of 5000 hours at 125 C.
Oberin, F. W.↗
Flush-mounted dielectric-loaded axial slot on circular cylinder
An investigation is conducted of electric field patterns of a TE axial slot antenna which radiates through a dielectric window in a circular cylinder. The cylinder is partially coated with a dielectric layer. The investigation is to provide information regarding the effects of a high-temperature dielectric layer on the performance of antennas mounted on a space shuttle. Numerical results are presented for the far-field patterns. It is pointed out that the calculations show excellent agreement with experimental measurements.
Richmond, J. H.↗
Electrolytic preparation of high dielectric films quarterly report, may 4 - aug. 3, 1965
Electrolytic preparation of high dielectric thin film coatings on refractory metal substrates
THIN FILM↗
Optical Properties of Thin Film Molecular Mixtures
Thin films composed of molecular mixtures of metal and dielectric are being considered for use as solar selective coatings for a variety of space power applications. By controlling the degree of molecular mixing, the solar selective coatings can be tailored to have the combined properties of high solar absorptance, alpha, and low infrared emittance, epsilon. On orbit, these combined properties would simultaneously maximize the amount of solar energy captured by the coating and minimize the amount of thermal energy radiated. Mini-satellites equipped with solar collectors coated with these cermet coatings may utilize the captured heat energy to power a heat engine to generate electricity, or to power a thermal bus that directs heat to remote regions of the spacecraft. Early work in this area identified the theoretical boundary conditions needed to operate a Carnot cycle in space, including the need for a solar concentrator, a solar selective coating at the heat inlet of the engine, and a radiator. A solar concentrator that can concentrate sunlight by a factor of 100 is ideal. At lower values, the temperature of the solar absorbing surface becomes too low for efficient heat engine operation, and at higher values, cavity type heat receivers become attractive. In designing the solar selective coating, the wavelength region yielding high solar absorptance must be separated from the wavelength region yielding low infrared emittance by establishing a sharp transition in optical properties. In particular, a sharp transition in reflectance is desired in the infrared to achieve the desired optical performance. For a heat engine operating at 450C, a sharp transition at 1.8 micrometers is desired. The radiator completes the heat flow through the Carnot cycle. Additional work has been done supporting the use of molecular mixtures for terrestrial applications. Sputter deposition provides a means to apply coatings to the tubes that carry a working fluid at the focus of trough-style collectors. Sputtering offers considerable flexibility in coating conditions, including a wide variety of metal and dielectric targets. Coating designs range from simple two or three layer coatings to complex coatings that are purposely graded to be metal-rich at their base and oxide-rich at their surface in order to yield the desired solar selective properties. In these cermet coatings, molecular islands of metal are thought to be embedded in a three dimensional matrix of dielectric. Recent work has identified the use of custom made ion beam sputter deposition targets to produce coatings containing molecular mixtures of metal and dielectric. The targets are cylindrical and the surface consists of a gradually changing composition of metal and dielectric. Rotating the cylinder under the beam during ion beam sputter deposition yields a coating that is a molecular mixture of metal and dielectric, with the composition changing through the thickness of the coating. The optical properties of these coatings are not only dependent on their thickness and chemical composition, but are also dependent on the extent of the through thickness gradient established during deposition. This paper presents a summary of the optical properties of several thin film molecular mixtures designed as solar selective coatings. Optical performance is first identified as a function of wavelength, from the ultraviolet to the visible and infrared. Coating composition, thickness, and gradient from metal to dielectric also play an important role. Additional work for future activities is also identified.
Jaworske, Donald A.↗
Optical performance of exposed solar cell covers
The characterization results of samples flown on the Long Duration Exposure Facility (LDEF) are discussed. These samples included both coated and uncoated fused silica and ceria glass substrates used in the manufacture of solar cell covers. The coatings comprised a single-layer magnesium fluoride antireflection coating and an all-dielectric high-reflector multilayer coating centered at 350 nm. Samples were mounted on both the leading and trailing surfaces of the LDEF for exposure to the environment of space. The optical properties of the coatings will be compared to control samples which were stored on the ground during the LDEF Mission. Results of Auger Electron Spectroscopy and Rutherford Backscatter Spectroscopy measurements made on several of the coatings are presented to explain the effects of space on the chemical composition of the coatings.
Hichwa, Bryant P.↗
Optical performance of exposed solar cell covers
This paper discusses the characterization results of samples flown on the Long Duration Exposure Facility (LDEF). These samples included both coated and uncoated fused silica and ceria glass substrates used in the manufacture of solar cell covers. The coatings comprised a single-layer magnesium fluoride antireflection coating and an all-dielectric high-reflector multilayer coating centered at 350 nm. Samples were mounted on both the leading and trailing surfaces of the LDEF for exposure to the environment of space. The optical properties of the coatings will be compared to control samples which were stored on the ground during the LDEF Mission. Results of Auger Electron Spectroscopy and Rutherford Backscatter Spectroscopy measurements made on several of the coatings will be presented to explain the effects of space on the chemical composition of the coatings.
Thomas H Allen↗
Flush-mounted dielectric-loaded axial slot on circular cylinder
The theory, computer program, and numerical results of an investigation of an axial slot antenna on a circular cylinder are discussed. The cylinder is partially coated with a dielectric layer and the antenna radiates through a flush mounted window. The study was conducted to determine the effects of a high temperature dielectric layer on the performance of antennas mounted on a space shuttle. Mathematical models are developed to show the relationships of the parameters. Curves are developed to compare the theoretical and actual far field radiation patterns.
Richmond, J. H.↗
High-frequency techniques for RCS prediction of plate geometries and a physical optics/equivalent currents model for the RCS of trihedral corner reflectors
Part 1 of this report continues the investigation, initiated in previous reports, of scattering from rectangular plates coated with lossy dielectrics. The hard polarization coefficients given in the last report are incorporated into a model, which includes second- and third-order diffractions, for the coated plate. Computed results from this model are examined and compared to measured data. A breakdown of the contribution of each of the higher-order terms to the total radar cross section (RCS) is given. The effectiveness of the uniform theory of diffraction (UTD) model in accounting for the coating effect is investigated by examining a Physical Optics (PO) model which incorporates the equivalent surface impedance approximation used in the UTD model. The PO, UTD, and experimental results are compared. Part 2 of this report presents a RCS model, based on PO and the Method of Equivalent Currents (MEC), for a trihedral corner reflector. PO is used to account for the reflected fields, while MEC is used for the diffracted fields. Single, double, and triple reflections and first-order diffractions are included in the model. A detailed derivation of the E(sub theta)-polarization, monostatic RCS is included. Computed results are compared with finite-difference time-domain (FDTD) results for validation. The PO/MEC model of this report compares very well with the FDTD model, and it is a much faster model in terms of computational speed.
Balanis, Constantine A.↗