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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1978

Development of Low-cost, High Energy-per-unit-area Solar Cell Modules

The development of two hexagonal solar cell process sequences, a laserscribing process technique for scribing hexagonal and modified hexagonal solar cells, a large through-put diffusion process, and two surface macrostructure processes suitable for large scale production is reported. Experimental analysis was made on automated spin-on anti-reflective coating equipment and high pressure wafer cleaning equipment. Six hexagonal solar cell modules were fabricated. Also covered is a detailed theoretical analysis on the optimum silicon utilization by modified hexagonal solar cells.

Jones, G. T.↗

NASA NTRS1974

Transport of charged particles in the earth's magnetosphere

A review of recent data on and conceptions of processes in which high energy particles are transported across magnetic shells in the earth's magnetosphere is presented. The processes discussed include adiabatic processes (with conservation of all three adiabatic invariants of charged particle motion in the magnetic field), diffusion processes (with violation of only the third or third and second invariants), and the so-called fast nonadiabatic processes, which appear to result from the action of strong electric fields.

Shalimov, V. P.↗

NASA NTRS1974

Atom movements occurring at solid metal-semiconductor interfaces

Solid metal-semiconductor interfaces often undergo chemical reaction at rather low temperatures, in some cases not much above room temperature. After some general discussion of these reactions, more detailed consideration is given to simple noncompound-forming systems, and, in particular, to the Si-Al, Ge-Al, and Si-Au systems. Diffusive transport of Si or Ge in these solid metallizations is very rapid, though the converse process, diffusion of metal in solid Si or Ge, is usually so slow as to be negligible. The interface reaction itself is less well understood but is becoming controllable in intrinsically favorable cases like Ge-Al and in other cases by more sophisticated means.

Mccaldin, J. O.↗

NASA NTRS1990

Pitch angle diffusion of newborn ions due to intrinsic turbulence in the solar wind

The objective of the present study is to understand the interaction of the solar wind with newborn ions in far upstream regions of a comet where the level of intrinsic turbulence is moderately low. Based on the assumption that quasi-linear theory is adequate and applicable, the pitch angle diffusion process and the time evolution of the newborn ion distribution function are investigated. Numerical solutions to the quasi-linear diffusion equation, including the effect of resonance broadening and that of continuous creation of newborn ions due to the ionization process, are obtained under several assumptions and approximations. It is found that theoretical results are consistent with the Giotto observations recently reported by Neugebauer et al. (1989).

Ziebell, L. F.↗

NASA NTRS1975

The N I /5200 A/ dayglow

The production and loss mechanisms of metastable (2D) nitrogen atoms are studied on the basis of Atmosphere Explorer satellite's measurements of 5200-A emission by the visible airglow experiment, complemented by simultaneous measurements of the ion and neutral composition of the atmosphere and the photoelectron flux. The relative yield of (2D) metastable and (4S) ground-state nitrogen atoms in the creation and destruction processes is examined. The results are used to calculate NO densities, making allowance for photochemical and vertical diffusion processes.

Rusch, D. W.↗

NASA NTRS1980

Low cost processes for fabricating silicon solar cells

Solar cell fabrication processes, in particular junction formation and metallization, are evaluated in terms of cell efficiencies, process yields, module packing factors, and energy cost effectiveness. It is shown that for junction formation, the diffusion processes provide a relatively low-cost approach. The costs per unit cell area can be further reduced by increased wafer area and mechanized wafer handling. The costs for a large number of metallization processes, excluding the costs of the metal, are roughly comparable. However, their varying influence on cell performance leads to a significant spread in the allowable process costs.

Goldman, H.↗

NASA NTRS1994

Escarpment evolution on high-elevation rifted margins: Insights derived from a surface processes model that combines diffusion, advection and reaction

Experiments with a surface processes model of large-scale (1-1000 km) long-term (1-100 m.y.) erosional denudation are used to establish the controls on the evolution of a model escarpment that is related to the rifting of a continent. The mdoel describes changes in topographic form as a result of sumultaneous short- and long-range mass transport representing hillslope (diffusive) processes and fluvial transport (advection), repsectively. Fluvial entrainment is modeled as a first-order kinetic reaction which reflects the erodibility of the substrate, and therefore the fluvial system is not necessarily carrying at capacity. One dimensional and planform models demonstrate that the principal controls on the evolution of an initially steep model escarpment are (1) antecedent topography/drainage; (2) the timesale (or equivalently a length scale) in the fluvial entrainment reaction; (3) the flexural response of the lithosphere to denudation; and (4) the relative efficiencies of the short- and long-range transport processes. When rainfall and substrate lithology are uniform, a significant amount of discharge draining over the escarpment top causes it to degrade. Only when the top of the model escarpment coincides with a drainage divide can escarpment retreat occur for these conditions. An additional requirement for retreat of a model escarpment without decline is a long reaction time scale for fluvial entrainment. This corresponds to a substrate that is hard to detach by flucial erosion, and therefore to fluvial erosion that is not transport limited. Coninuous backtilting of an escarpment due ot flexural isostatic uplift in response to denudational unloading helps maintain the scarp top as a divide. It is essntial if the escarpment gradient is to be preserved during retreat in a uniform lithology. Low flexural rigidieties propote steep and slowly retreating escarpments. For given rainfall and substrate conditions, the morphology of a retraeating model escarpment is determined by the ratio of hte short-range diffusive and long range advective transport efficiencies. A low ration (which is interpreted to correspond to a more humid, temperate climate) produces a convex upper slope, and concave lower slope morphology and only major escarpments are predicted to preserve a high scarp gradient. Lithological contrasts in hte model produce more complex morphologies and predict the formation of scarps crowned by an erosionaly resistant caprock. However, resistant caprocks are not an essential requirement for model scarps to retreat. We conclude that the inferred controls and model behavior are both consistent with the present-day morphology of rifted continental margins and with modern conceptual models of landscape evolution.

Kooi, Henk↗

NASA NTRS1983

NMR (Nuclear Magnetic Resonance) and macromolecular migration in a melt or in concentrated solutions

The purpose of this paper is to analyze the migration process of long polymer molecules in a melt or in concentrated solutions as it may be observed from the dynamics of the transverse magnetization of nuclear spins linked to these chains. The low frequency viscoelastic relaxation of polymer systems is known to be mainly controlled by the mechanism of dissociation of topological constraints excited on chains and which are called entanglements. This mechanism exhibits a strong dependence upon the chain molecular weight. These topological constraints also govern the diffusion process of polymer chains. So, the accurate description of the diffusion motion of a chain may be a convenient way to characterize disentanglement processes necessarily involved in any model proposed to explain viscoelastic effects.

Addad, J. P. C.↗

NASA NTRS1989

Results of rocket measurements of D-region ionization over Thumba in MAP

Under MAP, two rockets were launched from Thumba (8.5 N, 76.8 E) around 1030 hrs Lt with identical payloads on 7 and 10 March 1986 for D region studies. Positive ion densities were measured by spherical probe and Gerdien condenser and electron densities were measured by Langmuir probe and propagation experiments. In both flights a valley in ionization height profile was noticed around 83 km. The density of ionization at this altitude was about 4 x 10(2) cu cm. A detailed positive ion-chemical scheme was used to reproduce the measured ionization height profiles. The density of NO needed to reproduce the valley in ionization at 83 km came around 5 x 10(5) cu cm. A photochemical treatment without diffusion process was found inadequate to explain this value of NO. Calculations showed that the value of vertical eddy diffusion needed to reproduce the value of NO was around 10(6)sq cm/s. Interestingly, the same value of eddy diffusion coefficient was obtained when derived in the manner described by Thrane and his coworkers using only the positive ion current data of spherical probes.

Chakrabarty, D. K.↗

NASA NTRS1992

The subsurface hydrologic response of Mars to the thermal evolution of its early crust

The Martian valley networks and outflow channels provide persuasive evidence that large bodies of groundwater were present on Mars throughout much of its early geologic history. However, little attention was focused on how these volatile reservoirs may have responded to the thermal evolution of the early Martian crust. In this regard, one process that has likely been of critical importance to the subsurface hydrologic evolution of Mars is thermal vapor diffusion. Various aspects of the thermal vapor diffusion process on Mars are discussed.

Clifford, S. M.↗

NASA NTRS2003

[Results of Simulation Studies]

Lattice Monte Carlo and off-lattice molecular dynamics simulations of h(sub 1)t(sub 4) and h(sub 4)t(sub l) (head/tail) amphiphile solutions have been performed as a function of surfactant concentration and temperature. The lattice and off-lattice systems exhibit quite different self-assembly behavior at equivalent thermodynamic conditions. We found that in the weakly aggregating regime (no preferred-size micelles), all models yield similar micelle size distributions at the same average aggregation number, albeit at different thermodynamic conditions (temperatures). In the strongly aggregating regime, this mapping between models (through temperature adjustment) fails, and the models exhibit qualitatively different micellization behavior. Incipient micellization in a model self-associating telechelic polymer solution results in a network with a transient elastic response that decays by a two-step relaxation: the first is due to a heterogeneous jump-diffusion process involving entrapment of end-groups within well-defined clusters and this is followed by rapid diffusion to neighboring clusters and a decay (terminal relaxation) due to cluster disintegration. The viscoelastic response of the solution manifests characteristics of a glass transition and entangled polymer network.

Source record↗

NASA NTRS2015

Kinetic Monte Carlo Simulation of Oxygen Diffusion in Ytterbium Disilicate

Ytterbium disilicate is of interest as a potential environmental barrier coating for aerospace applications, notably for use in next generation jet turbine engines. In such applications, the transport of oxygen and water vapor through these coatings to the ceramic substrate is undesirable if high temperature oxidation is to be avoided. In an effort to understand the diffusion process in these materials, we have performed kinetic Monte Carlo simulations of vacancy-mediated and interstitial oxygen diffusion in Ytterbium disilicate. Oxygen vacancy and interstitial site energies, vacancy and interstitial formation energies, and migration barrier energies were computed using Density Functional Theory. We have found that, in the case of vacancy-mediated diffusion, many potential diffusion paths involve large barrier energies, but some paths have barrier energies smaller than one electron volt. However, computed vacancy formation energies suggest that the intrinsic vacancy concentration is small. In the case of interstitial diffusion, migration barrier energies are typically around one electron volt, but the interstitial defect formation energies are positive, with the result that the disilicate is unlikely to exhibit experience significant oxygen permeability except at very high temperature.

Coatings↗

NASA NTRS1972

Sources, losses, and transport of magnetospherically trapped particles.

Trapping, pseudo-trapping, and non-trapping regions within an observed magnetospheric configuration are described. Time averaged proton and electron distributions and available data concerning the alpha particle distribution within the trapping and pseudo-trapping regions are presented. A review of the observational evidence leading to the identification of major sources, losses, and transport of magnetospherically trapped particles is given. Conclusions are summarized and additional suggestions offered on these factors for inner and outer zone protons and electrons. One general result of this review is that much is now known of source, loss, and transport processes, although specific experiments and calculations must still be done. It is shown that the inclusion of pitch angle diffusion processes within the magnetosphere significantly alters the concept of stable trapping and allows a consistent quiescent description of outer zone electrons to be formulated from energies of a few tens of kilovolts to several MeV.

Williams, D. J.↗

NASA NTRS1979

The Jovian magnetodisk

Magnetic field measurements made by the vector helium magnetometers on board Pioneers-10 and 11 reveal the existence of a current sheet (thickness of about 2 Jupiter radii) carrying an eastward current. Self-consistent studies of the current sheet show that the magnitude of the current is of the order of 0.01/Am and that the current is carried by a hot (T greater than 1 keV) plasma, the density of which varies between 1 cu cm at 30 Jupiter radii to 100 cu cm at 80 Jupiter radii. The current sheet is warped azimuthally and parallel to the magnetic dipole equator. The existence of an azimuthal field component indicates a poloidal plasma flow transporting some 10 to the 29th ions per second from Jupiter into the outer magnetosphere. It is shown that, if the outer magnetosphere is in a steady state, this plasma must be transported outward within the current sheet by a diffusion process which is faster than the one responsible for particle transport in the inner magnetosphere but slower than Bohm diffusion.

Goertz, C. K.↗

NASA NTRS1973

Diffusion of ring current particles by low-frequency long-wavelength electrostatic oscillations.

The diffusion of charged particles by randomly fluctuating low-frequency long-wavelength electrostatic oscillations in the magnetosphere is investigated as a possible mechanism for transporting ring current particles. The diffusion process is assumed to preserve the first adiabatic invariant. The magnetosphere is represented by a simple model with cylindrical geometry. In the model the ionospheres are assumed to be perfectly conducting and the ring current is assumed to have a Maxwellian distribution of velocities. The electrostatic oscillations are treated as natural modes of the magnetospheric cavity which are driven by variations in the electric potential on the magnetopause. It is concluded that diffusion of ring current protons by this process is not important in the magnetosphere.

Maggs, J. E.↗

NASA NTRS1983

The relationship between Saturn kilometric radiation and the solar wind

Voyager spacecraft radio, interplanetary plasma, and interplanetary magnetic field data are used to show that large amplitude fluctuations in the power generated by the Saturn kilometric radio emission are best correlated with solar wind ram pressure variation. In all, thirteen solar wind quantities previously found important in driving terrestrial magnetospheric substorms and other auroral processes were examined for evidence of correlations with the Saturn radio emission. The results are consistent with hydromagnetic wave or eddy diffusion processes driven by large scale solar wind pressure changes at Saturn's dayside magnetopause.

Desch, M. D.↗

NASA NTRS1983

The relationship between Saturn kilometric radiation and the solar wind

Desch, M. D.↗

NASA NTRS1979

Semiconductor technology program. Progress briefs

The current status of NBS work on measurement technology for semiconductor materials, process control, and devices is reported. Results of both in-house and contract research are covered. Highlighted activities include modeling of diffusion processes, analysis of model spreading resistance data, and studies of resonance ionization spectroscopy, resistivity-dopant density relationships in p-type silicon, deep level measurements, photoresist sensitometry, random fault measurements, power MOSFET thermal characteristics, power transistor switching characteristics, and gross leak testing. New and selected on-going projects are described. Compilations of recent publications and publications in press are included.

Bullis, W. M.↗