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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Averaged invariants in storage rings with synchrotron motion

In an ideal accelerator, the single-particle dynamics can be decoupled into transverse motion—the betatron oscillations— and longitudinal motion—the synchrotron oscillations. Chromatic and dispersive effects introduce a coupling between these dynamics, the so-called synchro-betatron coupling. We present an analysis of the fully coupled dynamics over a single synchrotron oscillation that leads to an averaged invariant with synchro-betatron coupling in a generic lattice. Here, we apply this analysis to two problems: first, a toy lattice where the computations are analytically tractable, then a design for a rapid cycling synchrotron built using the integrable optics described by Danilov and Nagaitsev, showing that although there is fairly complex behavior over the course of a synchrotron oscillation, the Danilov-Nagaitsev invariants are nevertheless periodic with the synchrotron motion.

43 PARTICLE ACCELERATORS↗

Detecting and disentangling nonlinear structure from solar flux time series

Interest in solar activity has grown in the past two decades for many reasons. Most importantly for flight dynamics, solar activity changes the atmospheric density, which has important implications for spacecraft trajectory and lifetime prediction. Building upon the previously developed Rayleigh-Benard nonlinear dynamic solar model, which exhibits many dynamic behaviors observed in the Sun, this work introduces new chaotic solar forecasting techniques. Our attempt to use recently developed nonlinear chaotic techniques to model and forecast solar activity has uncovered highly entangled dynamics. Numerical techniques for decoupling additive and multiplicative white noise from deterministic dynamics and examines falloff of the power spectra at high frequencies as a possible means of distinguishing deterministic chaos from noise than spectrally white or colored are presented. The power spectral techniques presented are less cumbersome than current methods for identifying deterministic chaos, which require more computationally intensive calculations, such as those involving Lyapunov exponents and attractor dimension.

Ashrafi, S.↗

Application of a temporal multiscale method for efficient simulation of degradation in PEM Water Electrolysis under dynamic operating conditions

Hydrogen is emerging as a vital energy carrier, driven by the need to reduce carbon emissions. Proton Electrolyte Membrane Water Electrolysis (PEMWE) enables hydrogen production under fluctuating renewable power conditions but requires improved understanding and stability of the anode catalyst layer under dynamic operating conditions, especially with low noble metal loadings. Long-term degradation experiments are both time-consuming and costly; therefore, a systematic, model-aided approach is essential. In the present work, a temporal multiscale method is applied to reduce the computational effort of simulating long-term degradation processes in PEMWE, with an exemplary focus on catalyst dissolution. A mechanistic model incorporating the oxygen evolution reaction, catalyst dissolution, and hydrogen permeation from the cathode to the anode was hypothesized and implemented. In this way, the local periodicity of transport and reaction processes in dynamic PEMWE operation, which influence the gradual degradation of the catalyst layer, is captured. The temporal multiscale method significantly reduces the computational effort of simulation, decreasing processing time from hours to mere minutes. This efficiency gain is attributed to the limited evolution of Slow-Scale variables during each period of time P of the Fast-Scale variables. Consequently, simulation is required only until local periodicity is achieved within each Slow-Scale time step. Hence, the fully resolved dynamic problem is decoupled into these two scales, employing a heterogeneous multiscale technique. The developed approach effectively accelerates parameter estimation and predictive simulations, supporting systematic modeling of PEMWE degradation under dynamic conditions.

08 HYDROGEN↗

Exact Linearization For Control Of Robots

Equivalence of several theoretical approaches discussed. Report comments on application of geometric control theory (GCT), resolved-acceleration control (RAC), operational-space control (OSC), and nonlinear-decoupling theory (NDT) to remote manipulator consisting of multiple rigid links. Principal concern, search for nonlinear feedback law making end effector behave, for purposes of control, as though its dynamics linear and decoupled.

Kreutz, Kenneth K.↗

General approach and scope

This paper describes a joint activity involving NASA and Army researchers at the NASA Langley Research Center to develop optimization procedures aimed at improving the rotor blade design process by integrating appropriate disciplines and accounting for all of the important interactions among the disciplines. The disciplines involved include rotor aerodynamics, rotor dynamics, rotor structures, airframe dynamics, and acoustics. The work is focused on combining these five key disciplines in an optimization procedure capable of designing a rotor system to satisfy multidisciplinary design requirements. Fundamental to the plan is a three-phased approach. In phase 1, the disciplines of blade dynamics, blade aerodynamics, and blade structure will be closely coupled, while acoustics and airframe dynamics will be decoupled and be accounted for as effective constraints on the design for the first three disciplines. In phase 2, acoustics is to be integrated with the first three disciplines. Finally, in phase 3, airframe dynamics will be fully integrated with the other four disciplines. This paper deals with details of the phase 1 approach and includes details of the optimization formulation, design variables, constraints, and objective function, as well as details of discipline interactions, analysis methods, and methods for validating the procedure.

Adelman, Howard M.↗

Manipulator control by exact linearization

Comments on the application to rigid link manipulators of geometric control theory, resolved acceleration control, operational space control, and nonlinear decoupling theory are given, and the essential unity of these techniques for externally linearizing and decoupling end effector dynamics is discussed. Exploiting the fact that the mass matrix of a rigid link manipulator is positive definite, a consequence of rigid link manipulators belonging to the class of natural physical systems, it is shown that a necessary and sufficient condition for a locally externally linearizing and output decoupling feedback law to exist is that the end effector Jacobian matrix be nonsingular. Furthermore, this linearizing feedback is easy to produce.

Kruetz, K.↗

Unraveling the pathway towards superionic transport in polymer electrolytes

Ionic transport in polymers is critical for Li-ion batteries, fuel cells, flow batteries and many other energy storage and conversion technologies. A significant enhancement of ion conductivity in polymers may be achieved through an increase in the polarity of side chains and their self-organization into specific morphologies, which can potentially act as percolated ionic structures. However, higher polarity increases attractive interactions within a polymer matrix and slows down its segmental dynamics, which conversely hinders ionic transport. To overcome this tradeoff, we designed the functionalization of a Li salt-doped polymer matrix by tailored amounts of zwitterionic (ZI) groups. Our results suggest the emergence of a self-assembled percolation conductivity regime above a specific ZI concentration, in which ion hopping decouples from segmental dynamics by up to ten orders of magnitude. Consequently, in the highly concentrated ZI regime, our polymeric materials exhibit in their glassy state energy barriers for ion hopping similar to, or even smaller than, those reported for superionic ceramics. Our study also reveals that ion dynamics in the poly(zwitterion) with all monomers carrying ZI groups is significantly faster than that of a monomeric ZI compound, although the latter has much faster structural relaxation. Furthermore, this result highlights the crucial role played by the local morphology on the ion transport of polymer electrolytes and opens a new pathway for the design of superionic polymers, significantly expanding the current limited portfolio of solid-state electrolytes for energy applications.

Ion conductivity↗

Distinct dynamical and structural properties of marine stratocumulus and shallow cumulus clouds in the Eastern North Atlantic

Low-level clouds in a marine environment are examined using multiple ground-based instruments. Here, we used Doppler radar and Doppler lidar measurements (1) to examine cloud properties including cloud base and top height and thickness and (2) to investigate vertical velocity (w) statistics throughout the subcloud and in-cloud layers. Marine stratocumulus (Sc) and shallow cumulus (Cu) clouds have distinct properties in their horizontal and vertical extent. We also find that the two cloud types have different thermodynamic (coupled and decoupled conditions) and dynamical characteristics for the first four moments of the w distributions (mean, variance, skewness, and kurtosis). We identify a strong dependence of subcloud mean w on near-surface horizontal wind direction, implying that topographic effects exert a substantial impact on boundary layer dynamics and cloud properties at Graciosa Island. Our findings strongly suggest that care must be taken when interpreting island-based observations as representative of a generic marine dynamical environment. This information also can be useful for guiding and constraining the future global model development using observational dataset.

54 ENVIRONMENTAL SCIENCES↗

From Weibel seeds to dynamo beyond pair-plasmas

Bridging the spatiotemporal scales of magnetic seed field generation and subsequent dynamo amplification in the weakly collisional intracluster medium presents an extreme numerical challenge. We perform collisionless turbulence simulations with initially unmagnetised electrons that capture both magnetic seed generation via the electron Weibel instability and the ensuing dynamo amplification. Going beyond existing pair-plasma studies, we use an ion-to-electron mass ratio of 100 for which we find electron and ion dynamics are sufficiently decoupled. These simulations are enabled by the 10-moment collisionless fluid solver of Gkeyll, which evolves the full pressure tensor for all species. The electron heat-flux closure regulates pressure isotropisation and effectively sets the magnetic Reynolds number. We investigate how the strength of the closure influences the transition between a regime reminiscent of previous kinetic pair-plasma simulations and a regime exhibiting dynamo behaviour qualitatively similar to magnetohydrodynamics.

astrophysical plasmas↗

Celestial gluon amplitudes from the outside in

We show that, given a two-dimensional realization of the celestial OPE in self-dual Yang-Mills, we can find a scalar source around which scattering amplitudes replicate correlation functions computed from the 2D ‘gluon’ operators in a limit where a dynamic massless scalar decouples. We derive conditions on the two-dimensional three-point correlation function so that such a source exists and give two particular examples of this construction, one in which gluons are constructed from vertex operators in the semiclassical limit of Liouville theory and another in which the soft gluons arise from generalized free fields. Finally, we identify a bulk dual to the level of the boundary Kac-Moody algebra and discuss moving beyond the decoupling limit.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Non-Isochronal Behavior of Charge Transport at Liquid–Liquid and Liquid–Glass Transition in Aprotic Ionic Liquids

A reversible, first-order transition separating two liquid phases of a single-component material is a fascinating yet poorly understood phenomenon. Here, we investigate the liquid–liquid transition (LLT) ability of two tetraalkylphosphonium ionic liquids (ILs), [P 666,14 ]Cl and [P 666,14 ][1,2,4-triazolide], using differential scanning calorimetry and dielectric spectroscopy. The latter technique also allowed us to study the LLT at elevated pressure. We found that cooling below 205 K transforms [P 666,14 ]Cl and [P 666,14 ][Trz] from one liquid state (liquid 1) to another (the self-assembled liquid 2), while the latter facilitates the charge transport decoupled from structural dynamics. In contrast to temperature, pressure was found to play an essential role in the self-organization of a liquid 2 phase, resulting in different time scales of charge transport for rapidly and slowly compressed samples. Furthermore, τ σ (P LL ) was found to be much shorter than τ σ (T LL , P=atm), which constitutes the first example of non-isochronal behavior of charge transport at LLT. In turn, dielectric studies through the liquid–glass transition revealed the non-monotonic behavior of τ σ at elevated pressure for [P 666,14 ]Cl, while for [P 666,14 ][Trz] τ σ (P g ) was almost constant. These results highlight the diversity of liquid–liquid transition features within the class of phosphonium ionic liquids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Interfacial Cation Arrangement Controls Electrocatalytic Kinetics in CO 2 Reduction

The identity of electrolyte cations is known to strongly influence electrocatalytic activity, but the relationship between their interfacial arrangement and observed performance remains poorly understood. Organic cations, with their molecular tunability, provide a powerful platform for systematically probing these effects. Here, we leverage phosphonium-based geminal dications to control interfacial cation arrangement and identify the variables that most strongly influence catalytic rates. As a case study, we examine CO 2 reduction to CO over polycrystalline silver electrodes in dry aprotic acetonitrile. Through a combination of rotating disk electrode measurements, electrochemical impedance spectroscopy, and molecular dynamics simulations, we decouple the effects of cation–electrode distance and interfacial cation density on catalytic rates. We find that smaller, more densely packed cations induce stronger interfacial electric fields, which lower the activation barrier for CO 2 adsorption and increase reaction rates. Using geminal phosphonium dications [C n (P mmm ) 2 ][ClO 4 ] 2 , we demonstrate that both the vertical and lateral positioning of organic cations within the electrical double layer independently affect reactivity. These results demonstrate that electrolyte cation identity primarily influences catalytic kinetics by determining how efficiently charge can be arranged at electrochemical interfaces. Altogether, our findings support an electrostatic view of cation effects in catalysis and provide design principles for next-generation electrolytes.

Cations↗

Precision pointing and tracking system /PPTS/

As part of its advanced development work, JPL is developing a Precision Pointing and Tracking System (PPTS) for science platform control on unmanned planetary spacecraft. The PPTS will extend science capabilities on future missions by providing highly accurate (10 arcsec) and stable (0.2 arcsec) pointing of the platform. Key features of the design include closed-loop tracking of target bodies using an optical sensor and decoupling of spacecraft dynamics via high-bandwidth, inertially stabilized control. This paper discusses the analyses and design. Computer simulations were used to establish the feasibility of the design approach and to verify that the performance requirements can be met. A breadboard demonstration of the entire system is expected in late 1980.

Brown, T. K.↗

Radio emission from nova shells

This paper presents data from multifrequency radio observations of the novae HR Del 1967 and FH Ser 1970 made from June 1970 to December 1978 and of V1500 Cyg 1975 made from September 1975 to December 1978. The data for FH Ser and V1500 Cyg constitute a complete history of the important phases of their radio 'light' curves, while all but the rising portion of the optically thick phase of an expanding nova shell is present for HR Del. A simple solution of the spherically symmetric equations of mass and momentum conservation for an isothermal gas, for which pressure gradients are effectively decoupled from the dynamics, is shown to fit the radio data for all three novae quite well. The main features of this model are strong density and velocity gradients that lead to long periods when the 'observable' shell evolves from an optically thick 'disk' to a completely optically thin shell.

Hjellming, R. M.↗

Research on the control of large space structures

The research effort on the control of large space structures at the University of Houston has concentrated on the mathematical theory of finite-element models; identification of the mass, damping, and stiffness matrix; assignment of damping to structures; and decoupling of structure dynamics. The objective of the work has been and will continue to be the development of efficient numerical algorithms for analysis, control, and identification of large space structures. The major consideration in the development of the algorithms has been the large number of equations that must be handled by the algorithm as well as sensitivity of the algorithms to numerical errors.

Denman, E. D.↗

Flexible spacecraft maneuver - Inverse attitude control and modal stabilization

A control law is presented for three-axis rotational maneuvers of a spacecraft (orbiter)-beam-tip body (antenna or a reflector) configuration based on nonlinear inversion and modal velocity feedback. Using invertibility and functional reproducibility results, a decoupling attitude control law is presented such that, in the closed-loop system, the attitude angles of the spacecraft are independently controlled using the control moments acting on the space vehicle. This controller asymptotically decouples the flexible dynamics from the rigid one and also allows the decomposition of the elastic dynamics into two subsystems representing the transverse deflections of the beam in two orthogonal planes. These low-order subsystems are used for derivation of a modal velocity feedback stabilizer using the force and moment actuators at the end body. Simulation results are presented to show that, in the closed-loop system, attitude control and elastic mode stabilization are accomplished in spite of the parameter uncertainty and disturbance torque input in the system.

Singh, Sahjendra N.↗

Three axis rotational maneuver and vibration stabilization of elastic spacecraft

A control law for three-axis rotational maneuvers of a spacecraft beam-tip body configuration based on non-linear inversion and modal velocity feedback is presented. A decoupling attitude control law is presented such that in the closed-loop system the attitude angles of the spacecraft are independently controlled, using the control moments acting on the space vehicle. This controller asymptotically decouples the flexible dynamics from the rigid one and also allows the decomposition of the elastic dynamics into two subsystems representing the transverse deflections of the beam in two orthogonal planes. These low-order subsystems are used for the derivation of a modal velocity feedback stabilizer using the force and moment actuators at the end body. Simulation results are presented to show the capability of the controller.

Singh, Sahjendra N.↗

Dynamics and control of coordinated multiple manipulators

A technique is presented for controlling multiple manipulators which are holding a single object and therefore form a closed kinematic chain. The object, which may or may not be in contact with a rigid environment, is assumed to be held rigidly by robot end-effectors. The derivation is based on setting up constraint equations which reduce the 6 x n degrees of freedom of a manipulators each having six joints. Additional constraint equations are considered when one or more of the degrees of freedom of the object is reduced due to external constraints. Utilizing the operational space dynamics equations, a decoupling controller is designed to control both the position and the interaction forces of the object with the environment. Finally, simulation results for the control of a pair of two-link manipulators are presented.

Hayati, S. A.↗