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DOE OSTI2020

Long-range transported North American wildfire aerosols observed in marine boundary layer of eastern North Atlantic

Wildfire is a major source of biomass burning aerosols, which greatly impact Earth climate. Tree species in North America (NA) boreal forests can support high-intensity crown fires, resulting in elevated injection height and longer lifetime (on the order of months) of the wildfire aerosols. Given the long lifetime, the properties of aged NA wildfire aerosols are required to understand and quantify their effects on radiation and climate. Here we present comprehensive characterization of climatically relevant properties, including optical properties and cloud condensation nuclei (CCN) activities of aged NA wildfire aerosols, emitted from the record-breaking Canadian wildfires in August 2017. Despite the extreme injection height of ~12 km, some of the wildfire plumes descended into the marine boundary layer in the eastern North Atlantic over a period of ~2 weeks, owing to the dry intrusions behind mid-latitude cyclones. The aged wildfire aerosols have high single scattering albedos at 529 nm (ω 529 ; 0.92–0.95) while low absorption Ångström exponents (Å abs ) at 464 nm/648 nm (0.7–0.9). In comparison, Å abs of fresh/slightly aged ones are typically 1.4–3.5. This low Å abs 529 and low Å abs ~110 nm diameter) with thick non-absorbing coatings. The accelerated descent of the wildfire plume also led to strong increase of CCN concentration at the supersaturation levels representative of marine low clouds. The hygroscopicity parameter, κ CCN , of the aged wildfire aerosols varies from 0.2 to 0.4, substantially lower than that of background marine boundary layer aerosols. However, the high fraction of particles with large diameter (i.e., within accumulation size ranges, ~100–250 nm) compensates for the low values of κ, and as a result, the aged NA wildfire aerosols contribute more efficiently to CCN population. These results provide direct evidence that the long-range transported NA wildfires can strongly influence CCN concentration in remote marine boundary layer, therefore the radiative properties of marine low clouds. Given the expected increases of NA wildfire intensity and frequency and regular occurrence of dry intrusion following mid-latitude cyclones, the influence of NA wildfire aerosols on CCN and clouds in remote marine environment need to be further examined.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Closure of Earth’s Global Seasonal Cycle of Energy Storage

Abstract The global seasonal cycle of energy in Earth’s climate system is quantified using observations and reanalyses. After removing long-term trends, net energy entering and exiting the climate system at the top of the atmosphere (TOA) should agree with the sum of energy entering and exiting the ocean, atmosphere, land, and ice over the course of an average year. Achieving such a balanced budget with observations has been challenging. Disagreements have been attributed previously to sparse observations in the high-latitude oceans. However, limiting the local vertical integration of new global ocean heat content estimates to the depth to which seasonal heat energy is stored, rather than integrating to 2000 m everywhere as done previously, allows closure of the global seasonal energy budget within statistical uncertainties. The seasonal cycle of energy storage is largest in the ocean, peaking in April because ocean area is largest in the Southern Hemisphere and the ocean’s thermal inertia causes a lag with respect to the austral summer solstice. Seasonal cycles in energy storage in the atmosphere and land are smaller, but peak in July and September, respectively, because there is more land in the Northern Hemisphere, and the land has more thermal inertia than the atmosphere. Global seasonal energy storage by ice is small, so the atmosphere and land partially offset ocean energy storage in the global integral, with their sum matching time-integrated net global TOA energy fluxes over the seasonal cycle within uncertainties, and both peaking in April.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Isolating the effect of biomass burning aerosol emissions on 20th century hydroclimate in South America and Southeast Asia

Abstract Biomass burning is a significant source of aerosol emissions in some regions and has a considerable impact on regional climate. Earth system model simulations indicate that increased biomass burning aerosol emissions contributed to statistically significant decreases in tropical precipitation over the 20th century. In this study, we use the Community Earth System Model version 1 Large Ensemble (CESM1-LENS) experiment to evaluate the mechanisms by which biomass burning aerosol contributed to decreased tropical precipitation, with a focus on South America and Southeast Asia. We analyze the all-but-one forcing simulations in which biomass burning aerosol emissions are held constant while other forcings (e.g., greenhouse gas concentrations) vary throughout the 20th century. This allows us to isolate the influence of biomass burning aerosol on processes that contribute to decreasing precipitation, including cloud microphysics, the radiative effects of absorbing aerosol particles, and alterations in regional circulation. We also show that the 20th century reduction in precipitation identified in the CESM1-LENS historical and biomass burning experiments is consistent across Coupled Model Intercomparison Project Phase 5 models with interactive aerosol schemes and the CESM2 single-forcing experiment. Our results demonstrate that higher concentrations of biomass burning aerosol increases the quantity of cloud condensation nuclei and cloud droplets, limiting cloud droplet size and precipitation formation. Additionally, absorbing aerosols (e.g., black carbon) contribute to a warmer cloud layer, which promotes cloud evaporation, increases atmospheric stability, and alters regional circulation patterns. Corresponding convectively coupled circulation responses, particularly over the tropical Andes, contribute to further reducing the flow of moisture and moisture convergence over tropical land. These results elucidate the processes that affect the water cycle in regions prone to biomass burning and inform our understanding of how future changes in aerosol emissions may impact tropical precipitation over the 21st century.

Environmental Sciences & Ecology↗

DOE OSTI2025

AERO-MAP: a data compilation and modeling approach to understand spatial variability in fine- and coarse-mode aerosol composition

Abstract. Aerosol particles are an important part of the Earth climate system, and their concentrations are spatially and temporally heterogeneous, as well as being variable in size and composition. Particles can interact with incoming solar radiation and outgoing longwave radiation, change cloud properties, affect photochemistry, impact surface air quality, change the albedo of snow and ice, and modulate carbon dioxide uptake by the land and ocean. High particulate matter concentrations at the surface represent an important public health hazard. There are substantial data sets describing aerosol particles in the literature or in public health databases, but they have not been compiled for easy use by the climate and air quality modeling community. Here, we present a new compilation of PM2.5 and PM10 surface observations, including measurements of aerosol composition, focusing on the spatial variability across different observational stations. Climate modelers are constantly looking for multiple independent lines of evidence to verify their models, and in situ surface concentration measurements, taken at the level of human settlement, present a valuable source of information about aerosols and their human impacts complementarily to the column averages or integrals often retrieved from satellites. We demonstrate a method for comparing the data sets to outputs from global climate models that are the basis for projections of future climate and large-scale aerosol transport patterns that influence local air quality. Annual trends and seasonal cycles are discussed briefly and are included in the compilation. Overall, most of the planet or even the land fraction does not have sufficient observations of surface concentrations – and, especially, particle composition – to characterize and understand the current distribution of particles. Climate models without ammonium nitrate aerosols omit ∼ 10 % of the globally averaged surface concentration of aerosol particles in both PM2.5 and PM10 size fractions, with up to 50 % of the surface concentrations not being included in some regions. In these regions, climate model aerosol forcing projections are likely to be incorrect as they do not include important trends in short-lived climate forcers.

Mahowald, Natalie M. (ORCID:000000022873997X)↗

NASA NTRS1975

Executive summary

Possible effects of fluorocarbon-initiated stratospheric ozone depletion on the stratosphere, earth climate, biological organisms, and public health are briefly reviewed. The fluorocarbon industry and governmental regulation of these compounds are discussed. Research projects concerning the subject are also mentioned.

Source record↗

NASA NTRS1988

Observed variability of the solar luminosity

Data on solar luminosity variations are compiled in graphs and analyzed, with a focus on the SMM satellite bolometric measurements and other observations made since 1983. Consideration is given to total irradiance measurements in integrated light; emission-line variability in the visible, UV, and IR; mechanisms contributing to the solar variability (sunspots, faculae, rotation, oscillations, granulation, and active networks); the role of the solar magnetic cycle; and other observable parameters indicating variability. Also discussed are the effects of solar variations on the earth climate and the implications of the observations for theoretical models of convective-envelope processes (thermal diffusion near the surface and magnetic pressure in the interior).

Hudson, H. S.↗

NASA NTRS1990

The GEO platform

NASA plans for a Geostationary Earth Observatory (GEO) platform meant to operate in conjunction with the polar orbiting Earth Observing System (EOS) are discussed. The scientific goals of the GEO platform are summarized, and the facility's instruments are examined, including the microwave precipitation radiometer, atmospheric profiler, earth processes spectrometer, advanced lightning mapper, high resolution earth processes imager, operational instrument suite, solar constant and spectrum monitors, earth climate sensor, and trace gas imager. The GEO system to provide data and information to users is addressed.

Koczor, R. J.↗

NASA NTRS1990

The NASA Geostationary Earth Observatory - A status report

The design concept of the NASA Geostationary Earth Observatory (GEO), which is the geostationary component of the NASA Mission to Planet Earth program, is discussed together with the science goals, the mission objectives, the platform concept, the data and information system, and the instrument complement of the GEO. The instruments proposed for GEO will include a geostationary microwave precipitation radiometer, a geostationary atmospheric profiler, a geostationary earth processes spectrometer, an advanced lightning mapper, a high-resolution earth processes imager, an operational instrument suite, a solar constant monitor and a spectrum monitor, a geostationary earth climate sensor, and a trace gas imager. Current technology and engineering studies indicate that GEO will be ready for launch by the year 2000.

Koczor, Ronald J.↗

NASA NTRS2001

Assimilation of Cloud- and Land-Affected TOVS/ATOVS Level 1B Radiances in DAO's Next Generation Finite-Volume Data Assimilation System

The Physical-space/Finite-volume Data Assimilation System (fvDAS) is the next generation global atmospheric data assimilation system in development at the Data Assimilation Office (DAO) at NASA's Goddard Space Flight Center. It is based on a new finite-volume general circulation model jointly developed by NASA and NCAR, and on the Physical-Space Statistical Analysis System (PSAS) developed at the DAO. In this talk we will focus on the assimilation of data from the (Advanced) TIROS Operational Vertical Sounder (ATOVS), with emphasis on the impact of cloud- and land-affected level 1B radiances. Recently, it has been shown that the use of observations from satellite-borne microwave and infrared radiometers in data assimilation systems consistently increases forecast skill. Considerable effort has been expended over the past two decades, particularly with the (Advanced) TIROS Operational Vertical Sounder (ATOVS), to achieve this result. The positive impact on forecast skill has resulted from improvements in quality control algorithms, systematic error correction schemes, and more sophisticated data assimilation algorithms. Despite these advances, there are still many issues regarding the use of satellite data in data assimilation systems that remain unresolved. In particular, most operational centers still do not assimilate cloud- and land-affected TOVS data. In this study, we evaluate the impact of assimilating cloud-and land-affected TOVS/ATOVS level 1B data in DAO's next generation fvDAS, using a 1D variational scheme. We will discuss the impact of these data on both tropospheric and stratospheric forecasts, as well as on the general aspects of the earth climate system.

Joiner, J.↗

NASA NTRS2000

Estimation of Aerosol Direct Radiative Effects from Satellite and In Situ Measurements

Ames researchers have combined measurements from satellite, aircraft, and the surface to estimate the effect of airborne particles (aerosols) on the solar radiation over the North Atlantic region. These aerosols (which come from both natural and pollution sources) can reflect solar radiation, causing a cooling effect that opposes the warming caused by carbon dioxide. Recently, increased attention has been paid to aerosol effects to better understand the Earth climate system.

Bergstrom, Robert W.↗

NASA NTRS2012

The Use of Satellite-Measured Aerosol Optical Depth to Constrain Biomass Burning Emissions Source Strength in a Global Model GOCART

Small particles in the atmosphere, called "atmospheric aerosol" have a direct effect on Earth climate through scattering and absorbing sunlight, and also an indirect effect by changing the properties of clouds, as they interact with solar radiation as well. Aerosol typically stays in the atmosphere for several days, and can be transported long distances, affecting air quality, visibility, and human health not only near the source, but also far downwind. Smoke from vegetation fires is one of the main sources of atmospheric aerosol; other sources include anthropogenic pollution, dust, and sea salt. Chemistry transport models (CTMs) are among the major tools for studying the atmospheric and climate effects of aerosol. Due to the considerable variation of aerosol concentrations and properties on many temporal and spatial scales, and the complexity of the processes involved, the uncertainties in aerosol effects on climate are large, as is featured in the latest report of Intergovernmental Panel on Climate Change (IPCC) in 2007. Reducing this uncertainty in the models is very important both for predicting future climate scenarios and for regional air quality forecasting and mitigation. During vegetation fires, also called biomass burning (BB) events, complex mixture of gases and particles is emitted. The amount of BB emissions is usually estimated taking into account the intensity and size of the fire and the properties of burning vegetation. These estimates are input into CTMs to simulate BB aerosol. Unfortunately, due to large variability of fire and vegetation properties, the quantity of BB emissions is very difficult to estimate and BB emission inventories provide numbers that can differ by up to the order of magnitude in some regions. Larger uncertainties in data input make uncertainties in model output larger as well. A powerful way to narrow the range of possible model estimates is to compare model output to observations. We use satellite observations of aerosol properties, specifically aerosol optical depth, which is directly proportional to the amount of aerosol in the atmosphere, and compare it to the model output. Assuming the model represents aerosol transport and particle properties correctly, the amount of BB emissions determines the simulated aerosol optical depth. In this study, we explore the regional performance of 13 commonly used emission estimates. These are each input to global Goddard Chemistry Aerosol Radiation and Transport (GOCART) model. We then evaluate how well each emission estimate reproduces the smoke aerosol optical depth measured by the MODIS instrument. We compared GOCART-simulate aerosol optical depth with that measured from the satellite for 124 fire cases around the world during 2006 and 2007. We summarize the regional performance of each emission inventory and discuss reasons for their differences by considering the assumptions made during their development. We also show that because stronger wind disperses smoke plumes more readily, in cases with stronger wind, a larger increase in emission amount is needed to increase aerosol optical depth. In quiet, low-wind-speed environments, BB emissions produce a more significant increase in aerosol optical depth, other things being equal. Using the region-specific, quantitative relationships derived in our paper, together with the wind speed obtained from another source for a given fire case, we can constrain the amount of emission required in the model to reproduce the observations. The results of this paper are useful to the developers of BB emission inventories, as they show the strengths and weaknesses of individual emission inventories in different regions of the globe, and also for modelers who use these inventories and wish to improve their model results.

Petrenko, Mariya↗

NASA NTRS2013

An All-Solid-State, Room-Temperature, Heterodyne Receiver for Atmospheric Spectroscopy at 1.2 THz

Heterodyne receivers at submillimeter wavelengths have played a major role in astrophysics as well as Earth and planetary remote sensing. All-solid-state heterodyne receivers using both MMIC (monolithic microwave integrated circuit) Schottky-diode-based LO (local oscillator) sources and mixers are uniquely suited for long-term planetary missions or Earth climate monitoring missions as they can operate for decades without the need for any active cryogenic cooling. However, the main concern in using Schottky-diode-based mixers at frequencies beyond 1 THz has been the lack of enough LO power to drive the devices because 1 to 3 mW are required to properly pump Schottky diode mixers. Recent progress in HEMT- (high-electron-mobility- transistor) based power amplifier technology, with output power levels in excess of 1 W recently demonstrated at W-band, as well as advances in MMIC Schottky diode circuit technology, have led to measured output powers up to 1.4 mW at 0.9 THz. Here the first room-temperature tunable, all-planar, Schottky-diode-based receiver is reported that is operating at 1.2 THz over a wide (≈20%) bandwidth. The receiver front-end (see figure) consists of a Schottky-diode-based 540 to 640 GHz multiplied LO chain (featuring a cascade of W-band power amplifiers providing around 120 to 180 mW at W-band), a 200-GHz MMIC frequency doubler, and a 600-GHz MMIC frequency tripler, plus a biasable 1.2-THz MMIC sub-harmonic Schottky-diode mixer. The LO chain has been designed, fabricated, and tested at JPL and provides around 1 to 1.5 mW at 540 o 640 GHz. The sub-harmonic mixer consists of two Schottky diodes on a thin GaAs membrane in an anti-parallel configuration. An integrated metal insulator metal (MIM) capacitor has been included on-chip to allow dc bias for the Schottky diodes. A bias voltage of around 0.5 V/diode is necessary to reduce the LO power required down to the 1 to 1.5 mW available from the LO chain. The epilayer thickness and doping profiles have been specifically optimized to maximize the mixer performance beyond 1 THz. The measured DSB noise temperatures and conversion losses of the receiver are 2,000 to 3,500 K and 12 to 14 dB, respectively, at 120 K, and 4,000 to 6,000 K and 13 to 15 dB, respectively, at 300 K. These results establish the state-of-the-art for all-solid-state, all-planar heterodyne receivers at 1.2 THz operating at either room temperature or using passive cooling only. Since no cryogenic cooling is needed, the receiver is eminently suited to atmospheric heterodyne spectroscopy of the outer planets and their moons.

Siles, Jose V.↗

NASA NTRS2014

Sea Ice Concentration and Extent

Among the most seasonal and most dynamic parameters on the surface of the Earth is sea ice which at any one time covers about 3-6% of the planet. In the Northern Hemisphere, sea ice grows in extent from about 6 x 10(exp 6) sq km to 16 x 10(exp 6) sq km, while in the Southern Hemisphere, it grows from about 3 x 10(exp 6) sq km to about 19 x 10(exp 6) sq km (Comiso, 2010; Gloersen et al., 1992). Sea ice is up to about 2-3 m thick in the Northern Hemisphere and about 1 m thick in the Southern Hemisphere (Wadhams, 2002), and compared to the average ocean depth of about 3 km, it is a relatively thin, fragile sheet that can break due to waves and winds or melt due to upwelling of warm water. Being constantly advected by winds, waves, and currents, sea ice is very dynamic and usually follows the directions of the many gyres in the polar regions. Despite its vast expanse, the sea ice cover was previously left largely unstudied and it was only in recent years that we have understood its true impact and significance as related to the Earths climate, the oceans, and marine life.

sea ice extent↗

NASA NTRS2016

A Multi-Frequency Wide-Swath Spaceborne Cloud and Precipitation Imaging Radar

Microwave and millimeter-wave radars have proven their effectiveness in cloud and precipitation observations. The NASA Earth Science Decadal Survey (DS) Aerosol, Cloud and Ecosystems (ACE) mission calls for a dual-frequency cloud radar (W band 94 GHz and Ka-band 35 GHz) for global measurements of cloud microphysical properties. Recently, there have been discussions of utilizing a tri-frequency (KuKaW-band) radar for a combined ACE and Global Precipitation Measurement (GPM) follow-on mission that has evolved into the Cloud and Precipitation Process Mission (CaPPM) concept. In this presentation we will give an overview of the technology development efforts at the NASA Goddard Space Flight Center (GSFC) and at Northrop Grumman Electronic Systems (NGES) through projects funded by the NASA Earth Science Technology Office (ESTO) Instrument Incubator Program (IIP). Our primary objective of this research is to advance the key enabling technologies for a tri-frequency (KuKaW-band) shared-aperture spaceborne imaging radar to provide unprecedented, simultaneous multi-frequency measurements that will enhance understanding of the effects of clouds and precipitation and their interaction on Earth climate change. Research effort has been focused on concept design and trade studies of the tri-frequency radar; investigating architectures that provide tri-band shared-aperture capability; advancing the development of the Ka band active electronically scanned array (AESA) transmitreceive (TR) module, and development of the advanced radar backend electronics.

imaging↗

NASA NTRS2018

Aerosol-Radiation-Cloud Interactions in the South-East Atlantic: Model-Relevant Observations and the Beneficiary Modeling Efforts in the Realm of the EVS-2 Project ORACLES

Globally, aerosols remain a major contributor to uncertainties in assessments of anthropogenically-induced changes to the Earth climate system, despite concerted efforts using satellite and suborbital observations and increasingly sophisticated models. The quantification of direct and indirect aerosol radiative effects, as well as cloud adjustments thereto, even at regional scales, continues to elude our capabilities. Some of our limitations are due to insufficient sampling and accuracy of the relevant observables, under an appropriate range of conditions to provide useful constraints for modeling efforts at various climate scales. In this talk, I will describe (1) the efforts of our group at NASA Ames to develop new airborne instrumentation to address some of the data insufficiencies mentioned above; (2) the efforts by the EVS-2 ORACLES project to address aerosol-cloud-climate interactions in the SE Atlantic and (3) time permitting, recent results from a synergistic use of A-Train aerosol data to test climate model simulations of present-day direct radiative effects in some of the AEROCOM phase II global climate models.

Redemann, Jens↗

NASA NTRSDate not supplied

Investigating seasonal ENSO forecast amplitude calibration for GEOS-S2S-2

The GEOS-S2S-2 is a global coupled model and assimilation system, encompassing many aspects of the Earth climate system. This project looked at seasonal (nine-month) ensemble forecasts, over the period from 1982 through the present. We explored and validated a forecast amplitude correction technique used by the North American Multi-Model Ensemble (NMME), of which GEOS is a member, for Niño3.4 sea-surface temperature (SST) anomaly predictions. The method relies on deriving a set of correction factors based on the standard deviations of hindcast and observed SST anomalies. This algorithm was implemented at the Global Modeling and Assimilation Office (GMAO) and applied to the GEOS-S2S-2 Niño 3.4 hindcasts. In general, the correction reduced the forecast amplitude. This improved the quality of the forecasts when measured by the root mean square error (RMSE) of the ensemble mean forecast. RMSE decreased for most initialization months and forecast leads. The correction had a larger impact on seasons with strong El Niño-Southern Oscillation (ENSO) events than neutral seasons. The effects of the correction on the ensemble characteristics were also examined, and a variation of the algorithm was proposed that preserves the ensemble spread. The outcome of this project is a tool that can be used to calibrate GEOS-S2S-2 ENSO forecasts and potentially improve the precision of multi-model El Niño outlooks.

ENSO↗

NASA NTRS2023

The Calipso Version 4.5 Stratospheric Aerosol Subtyping Algorithm

The accurate classification of aerosol types injected into the stratosphere is important to properly characterize their chemical and radiative impacts within the Earth climate system. The updated stratospheric aerosol subtyping algorithm used in the version 4.5 (V4.5) release of the Cloud Aerosol Lidar with Orthogonal Polarization (CALIOP) level 2 data products now delivers more comprehensive and accurate classifications than its predecessor. The original algorithm identified four aerosol subtypes for layers detected above the tropopause: volcanic ash, smoke, sulfate/other, and polar stratospheric aerosol (PSA). In the revised algorithm, sulfates are separately identified as a distinct, homogeneous subtype, and the diffuse, weakly scattering layers previously assigned to the sulfate/other class are recategorized as a fifth “unclassified” subtype. By making two structural changes to the algorithm and revising two thresholds, the V4.5 algorithm improves the ability to discriminate between volcanic ash and smoke from pyrocumulonimbus injections, improves the fidelity of the sulfate subtype, and more accurately reflects the uncertainties inherent in the classification process. The 532 nm lidar ratio for volcanic ash was also revised to a value more consistent with the current state of knowledge. This paper briefly reviews the previous version of the algorithm (V4.1 and V4.2) then fully details the rationale and impact of the V4.5 changes on subtype classification frequency for specific events where the dominant aerosol type is known based on the literature. Classification accuracy is best for volcanic ash due to its characteristically high depolarization ratio. Smoke layers in the stratosphere are also classified with reasonable accuracy, though during the daytime a substantial fraction are misclassified as ash. It is also possible for mixtures of ash and sulfate to be misclassified as smoke. The V4.5 sulfate subtype accuracy is less than that for ash or smoke, with sulfates being misclassified as smoke about one-third of the time. However, because exceptionally tenuous layers are now assigned to the unclassified subtype and the revised algorithm levies more stringent criteria for identifying an aerosol as sulfate, it is more likely that layers labeled as this subtype are in fact sulfate compared to those assigned the sulfate/other classification in the previous data release.

Jason L Tackett↗

NASA NTRSDate not supplied

Study of Martian Polar Caps with GISS ROCKE-3D GCM

Martian polar caps consist of both H 2 O and CO 2 ice. While H 2 O ice is mainly passive on modern Mars, it may have not been the case in recent Martian history, when its obliquity was higher, or when it was changing rapidly. The distribution of ice species in the snowpack affects its physical and thermodynamic properties. In the upper layers, it determines its albedo and thermal emissivity. Thus understanding the mutual effect between these ices and their interaction with the atmosphere is crucial for understanding the evolution of Martian polar regions. In this study, we employ a newly-developed Exotic Ices snow model coupled to the NASA Goddard Institute for Space Studies (GISS) ROCKE-3D planetary General Circulation Model (GCM) [1] to study the behavior of Martian polar caps. ROCKE-3D is a planetary GCM developed at NASA GISS as an extension of its Earth climate model, modelE [2]. It has been extensively used to simulate climate of various planets, including Mars (e.g. [3,4]). The Exotic Ices snow model was specially developed for planetary applications which involve more than one condensable in the atmosphere, in which case snow can contain multiple species of ice (CO2 and H 2 O in the Mars case). For each species of ice, the model uses their proper physical properties and phase diagram, but otherwise it treats all species of ice on an equal footing. The combined effects on albedo, thermal inertia and mutual insulation are treated accordingly. The snowpack interacts with the atmospheric dust cycle, and can accumulate a prognostic amount of dust, though the effect of dust on snow properties is not currently treated explicitly, and is prescribed. In this study, we first validate our model against the modern Martial climate, for which we use mission results from Mars Climate Sounder (atmospheric temperature and dust optical depth), SPICAM on Mars Express (atmospheric water), and Viking 2 (surface pressure). We investigate the effect of snow radiative properties on CO 2 and water cycles and the ability of our model to accurately reproduce those with minimal model tuning. We then perform simulations for several obliquities from a recent Martian past, and investigate the behavior of the Martian polar caps in such conditions.

Mars↗