Tropospheric Ozone Profile Information Derived From "Cloud Slicing"
This study introduces a new approach to obtain ozone vertical profile information given coincident satellite measurements of both cloud-top pressure and above-cloud column ozone. This method is denoted "cloud slicing". In this study information of cloud-top pressure is derived from Geostationary Orbital Earth Satellite (GOES) infrared data, while above-cloud column ozone is obtained from the Earth Probe total ozone mapping spectrometer (TOMS) instrument. Several case examples are presented showing the feasibility of this technique as well as providing new geophysical results. Because the TOMS instrument measures backscattered UV radiation, it does detect ozone lying below dense water vapor clouds. This opaque property of TOMS can be used directly in conjunction with co-located cloud-top pressure data to derive ozone profile information in the troposphere. The cloud slicing method is an extension of the "Convective Cloud Differential" (CCD) method. In the CCD method, tropospheric column ozone (i.e., the total vertical column of ozone lying in the troposphere) is computed by taking total column ozone with low reflectivity (R less than 0.2) and subtracting from this a nearby measurement of above-cloud column ozone amount under conditions of high reflectivity (R greater than 0.9). (High reflectivity away from snow/ice conditions coincides with strong convection and tropopause-level clouds). The key element in determining tropospheric ozone profile information from the cloud slicing method is to have simultaneous and co-located measurements of both above-cloud column ozone and cloud-top pressure.