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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Atomic-scale 3D imaging of individual dopant atoms in an oxide semiconductor

The physical properties of semiconductors are controlled by chemical doping. In oxide semiconductors, small variations in the density of dopant atoms can completely change the local electric and magnetic responses caused by their strongly correlated electrons. In lightly doped systems, however, such variations are difficult to determine as quantitative 3D imaging of individual dopant atoms is a major challenge. We apply atom probe tomography to resolve the atomic sites that donors occupy in the small band gap semiconductor Er(Mn,Ti)O 3 with a nominal Ti concentration of 0.04 at. %, map their 3D lattice positions, and quantify spatial variations. Our work enables atomic-level 3D studies of structure-property relations in lightly doped complex oxides, which is crucial to understand and control emergent dopant-driven quantum phenomena.

36 MATERIALS SCIENCE↗

Artificial Intelligence-Aided Wind Plant Optimization for Nationwide Evaluation of Land Use and Economic Benefits of Wake Steering

If clean energy pathways are to harness massive increases in wind power, innovations with broad geographic viability will be needed to support buildout in diverse locations. However, geodiversity in impact potential is seldom captured in technology assessment. Here we propose a scalable approach to plant-level optimization using artificial intelligence to evaluate land sparing and economic benefits of wake steering at more than 6,800 plausible onshore wind locations in the USA. This emerging controls strategy optimizes plant energy production by directing turbine wakes. On the basis of estimates from our artificial intelligence model trained on engineering wind flow simulations, co-optimizing plant layouts with wake steering can reduce land requirements by an average of 18% per plant (site-specific benefits range from 2% to 34%), subject to errors and uncertainties in the flow model, wind resource estimates, buildout scenario and geographic factors. According to model estimates, wake steering is predicted to increase power production during high-value (relatively low wind) periods, boosting the annual revenue of individual plants by up to US$3.7 million (equivalent to US$13,000 MW-1 yr-1) but producing negligible gains in some settings. Consideration of wake steering’s geographic potential reveals divergent nationwide prospects for improved economics and siting flexibility.

deployment↗

Theoretical insights into the surface physics and chemistry of redox-active oxides

Redox active oxides are ubiquitous in materials applications, including catalysis, photovoltaics, self-cleaning glasses, chemical sensors, and electronic components. Their utility derives from their unique ability to access multiple metal charge states within a finite energy window. However, this property also confounds our ability to study reducible oxides, because it leads to structural, compositional, and electronic complexities that elude simplistic models of materials structure and function. Oxygen vacancies play a critical role in shaping the functional properties of such oxides; most notably, they lead to mobile charge imbalances that impact surface processes at significant distances from the originating defect. Atomistic simulations are inherently equipped to illuminate these phenomena at a fundamental level; however, reducible oxides pose great challenges due to the high level of electron correlation needed to correctly describe them. Knowing how defects form, couple, propagate, agglomerate, or repel each other and influence the surface properties of reducible oxides is only now coming into the grasp of modern theory and simulation capabilities. This knowledge is also key to discovering and controlling emergent materials processes at nanometer scale and beyond. The manuscript was written with support of all three authors from U.S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. Work by RR and VG was performed at Pacific Northwest National Laboratory (PNNL), which is a multi-program laboratory operated by Battelle for DOE under Contract DE AC05 76RL01830. AS was supported under Award DE-SC0007347.

Rousseau, Roger J.↗

Phasor-Domain Modeling of Inverter Based Resources Considering Unbalanced Grid Faults

A significant increase in inverter-based distributed energy resources (DERs) is expected in distribution systems of the near future. The latest phasor modeling approach of DERs with emerging control technologies can capture relevant dynamics in large-scale three-phase distribution systems with unbalanced construction. However, there is a lack of appropriate phasor models to deal with unbalanced fault scenarios. As such, this paper describes per-phase phasor modeling approach appropriate for unbalanced grid disturbance studies in distribution systems with high penetration of DERs. The overall modeling performance of representative DERs is simulated in phasor domain GridLAB-D environment and validated against controller hardware-in-the loop (CHIL) testing or electromagnetic transient (EMT) based switching model simulation in PSCAD with test cases including different unbalanced grid faults. The high accuracy retained from the simulation verifies the effectiveness of the proposed phasor modeling approach considering interactions between positive and negative sequence signals.

Chen, Zhe↗

Actinides and Correlated Electron Materials

The Actinides and Correlated Electron Materials area of leadership spans Los Alamos National Laboratory competency in actinide materials research dating to the Manhattan Project as articulated in the Integrated Plutonium Science and Research Strategy and competency in strongly correlated electron systems dating back to at least the early 1980s. This area of leadership focuses on the goals of discovering, understanding, and controlling emergent electronic states and predictive performance of actinide materials. They are quintessentially linked by the fact that the physics of actinides—and plutonium in particular—are governed by strong electronic correlations. Not only is the electronic structure of actinides dictated by fine details of electron correlations, but chemical bonding and physical structure are as well. Hence, by addressing the first goal of this leadership area we can significantly accelerate progress on the second goal. To understand such matter requires probing the intertwined spin, charge, orbital, and lattice degrees of freedom with greater precision and developing models that accurately predict the consequences of these coupled degrees of freedom, on multiple length and time scales and including acute reactivity and effects of self-irradiation phenomena in these materials.

36 MATERIALS SCIENCE↗

Control System Upgrade for a Mass Property Measurement Facility

The Mass Property Measurement Facility (MPMF) at the Goddard Space Flight Center has undergone modifications to ensure the safety of Flight Payloads and the measurement facility. The MPMF has been technically updated to improve reliability and increase the accuracy of the measurements. Modifications include the replacement of outdated electronics with a computer based software control system, the addition of a secondary gas supply in case of a catastrophic failure to the gas supply and a motor controlled emergency stopping feature instead of a hard stop.

Chambers, William↗

Simulation Based Evaluation of Integrated Adaptive Control and Flight Planning Technologies

The objective of this work is to leverage NASA resources to enable effective evaluation of resilient aircraft technologies through simulation. This includes examining strengths and weaknesses of adaptive controllers, emergency flight planning algorithms, and flight envelope determination algorithms both individually and as an integrated package.

Campbell, Stefan Forrest↗

NASA Tech Briefs, September 2003

Topics include: Oxygen-Partial-Pressure Sensor for Aircraft Oxygen Mask; Three-Dimensional Venturi Sensor for Measuring Extreme Winds; Swarms of Micron-Sized Sensors; Monitoring Volcanoes by Use of Air-Dropped Sensor Packages; Capacitive Sensors for Measuring Masses of Cryogenic Fluids; UHF Microstrip Antenna Array for Synthetic- Aperture Radar; Multimode Broad-Band Patch Antennas; 164-GHz MMIC HEMT Frequency Doubler; GPS Position and Heading Circuitry for Ships; Software for Managing Parametric Studies; Software Aids Visualization of Computed Unsteady Flow; Software for Testing Electroactive Structural Components; Advanced Software for Analysis of High-Speed Rolling-Element Bearings; Web Program for Development of GUIs for Cluster Computers; XML-Based Generator of C++ Code for Integration With GUIs; Oxide Protective Coats for Ir/Re Rocket Combustion Chambers; Simplified Waterproofing of Aerogels; Improved Thermal-Insulation Systems for Low Temperatures; Device for Automated Cutting and Transfer of Plant Shoots; Extension of Liouville Formalism to Postinstability Dynamics; Advances in Thrust-Based Emergency Control of an Airplane; Ultrasonic/Sonic Mechanisms for Drilling and Coring; Exercise Device Would Exert Selectable Constant Resistance; Improved Apparatus for Measuring Distance Between Axles; Six Classes of Diffraction-Based Optoelectronic Instruments; Modernizing Fortran 77 Legacy Codes; Active State Model for Autonomous Systems; Shields for Enhanced Protection Against High-Speed Debris; Scaling of Two-Phase Flows to Partial-Earth Gravity; Neutral-Axis Springs for Thin-Wall Integral Boom Hinges.

Source record↗

NASA's Human Rating Requirements - A Historical Interpretive Perspective

Section 3.0 of NASA's Human Rating Requirements for Space Systems, NPR 8705.2, represents technical engineering requirements that the Agenc y requires of Human Space Systems. In many cases the requirements are not unlike requirements for any space system, crewed or uncrewed, th ey deal with successfully accomplishing the mission objectives. Howev er, they go one step further and have requirements that go beyond suc cessful completion of the mission and dictate functions or actions ne cessary to assure the survival of the crew. In that regard they are u nique from other space system requirements. Even with their uniquenes s the technical requirements of the NPR 8705.2 have been relatively u nchanged in overall intent over the revisions. They all have provided for system redundancy, crew habitable environment, crew situational awareness, crew operation, system control, emergency egress and abort systems. In a few cases the intent of the requirement was changed in tentionally, either to restrict certain types of systems or their fun ctions, or to encompass lessons learned from previous programs. For t he most part the requirements are non controversial and represent the current best practices for human space systems, however, a few requi rements are always debated and have evolved over revisions of the NPR due to studies conducted with various programs like the Orbital Spac e Plane and the Constellation Programs. Those requirements will be di scussed using results of trade studies conducted during past programs highlighting how these particular requirements have evolved through the revisions of the NPR. Comments will also be provided for requirem ents that although not debated, have provided challenges in interpret ation.

Langford, Gerald↗

COSPAS/SARSAT 406-MHz emergency beacon digital controller

The digital control portion of a low-cost 406-MHz COSPAS/SARSAT emergency beacon has been designed and breadboarded at the NASA Lewis Research Center. This report discusses the requirements and design tradeoffs of the digital controller and describes the hardware and software design, which is available only to United States citizens and companies.

Ivancic, William D.↗

A Risk Management Architecture for Emergency Integrated Aircraft Control

Enhanced engine operation--operation that is beyond normal limits--has the potential to improve the adaptability and safety of aircraft in emergency situations. Intelligent use of enhanced engine operation to improve the handling qualities of the aircraft requires sophisticated risk estimation techniques and a risk management system that spans the flight and propulsion controllers. In this paper, an architecture that weighs the risks of the emergency and of possible engine performance enhancements to reduce overall risk to the aircraft is described. Two examples of emergency situations are presented to demonstrate the interaction between the flight and propulsion controllers to facilitate the enhanced operation.

McGlynn, Gregory E.↗

An Emergency Helium Bubbling Control System for the Prevention of Geysering in the Lox Suction Lines of S-IC

An emergency helium bubbling system was devised for geyser suppression in the LOX suction lines of S-IC . Flight model pressure and temperature transducers were compared to more accurate transducers to determine the best sensor configuration. Transducers were electronically simulated to calibrate the circuit design. A development system was tested for feasibility on a full- scale LOX flow line test facility.

BUBBLE↗

Chlorophyllase from Arabidopsis thaliana Reveals an Emerging Model for Controlling Chlorophyll Hydrolysis

Chlorophyll (Chl) is one of Nature’s most complex pigments to biosynthesize and derivatize. This pigment is vital for survival and also paradoxically toxic if overproduced or released from a protective protein scaffold. Therefore, along with the mass production of Chl, organisms also invest in mechanisms to control its degradation and recycling. One important enzyme that is involved in these latter processes is chlorophyllase. This enzyme is employed by numerous photosynthetic organisms to hydrolyze the phytol tail of Chl. Although traditionally thought to catalyze the first step of Chl degradation, recent work suggests that chlorophyllase is instead employed during times of abiotic stress or conditions that produce reactive oxygen species. However, the molecular details regarding how chlorophyllases are regulated to function under such conditions remain enigmatic. Here, we investigate the Arabidopsis thaliana chlorophyllase isoform AtCLH2 using site-directed mutagenesis, mass spectrometry, dynamic light scattering, size-exclusion multiangle light scattering, and both steady-state enzyme kinetic and thermal stability measurements. Through these experiments, we show that AtCLH2 exists as a monomer in solution and contains two disulfide bonds. One disulfide bond putatively maps to the active site, whereas the other links two N-terminal Cys residues together. These disulfide bonds are cleaved by chemical or chemical and protein-based reductants, respectively, and are integral to maintaining the activity, stability, and substrate scope of the enzyme. This work suggests that Cys residue oxidation in chlorophyllases is an emerging regulatory strategy for controlling the hydrolysis of Chl pigments.

59 BASIC BIOLOGICAL SCIENCES↗

Emergent electric field control of phase transformation in oxide superlattices

Electric fields can transform materials with respect to their structure and properties, enabling various applications ranging from batteries to spintronics. Recently electrolytic gating, which can generate large electric fields and voltage-driven ion transfer, has been identified as a powerful means to achieve electric-field-controlled phase transformations. The class of transition metal oxides provide many potential candidates that present a strong response under electrolytic gating. However, very few show a reversible structural transformation at room-temperature. Here, we report the realization of a digitally synthesized transition metal oxide that shows a reversible, electric-field-controlled transformation between distinct crystalline phases at room-temperature. In superlattices comprised of alternating one-unit-cell of SrIrO 3 and La 0.2 Sr 0.8 MnO 3 , we find a reversible phase transformation with a 7% lattice change and dramatic modulation in chemical, electronic, magnetic and optical properties, mediated by the reversible transfer of oxygen and hydrogen ions. Strikingly, this phase transformation is absent in the constituent oxides, solid solutions and larger period superlattices. Our findings open up this class of materials for voltage-controlled functionality.

36 MATERIALS SCIENCE↗

Effects of Nose Shape and Spray Control Strips on Emergence and Planing Spray of Hydro-ski Models

The emergence and planing-spray characteristics of flat-bottom surfaces representative of hydro-skis with various bow shapes and deflectors were investigated for trims of 12° and 20° and a speed of 30 feet per second. The emergence-spray characteristics of the models with various bow shapes were investigated for depths of submersion of the bow from 0.50 inch to -0.50 inch. The planing-spray characteristics of the models with the various deflectors were determined for a draft corresponding to a length-beam ratio of 4 . The emergence- and planing-spray patterns are shown in the photographs taken from forward of and above the models and from the side of the models. The most favorable emergence spray was obtained with a bow of triangular plan form and sharp profile. The greatest improvement in planing spray was obtained with vertical chine strips and a transverse barrier strip located forward of the wetted planing area.

John R McGehee↗