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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
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NASA NTRS2021

Climate-driven Chemistry and Aerosol Feedbacks in CMIP6 Earth System Models

Feedbacks play a fundamental role in determining the magnitude of the response of the climate system to external forcing, such as from anthropogenic emissions. The latest generation of Earth system models includes aerosol and chemistry components that interact with each other and with the biosphere. These interactions introduce a complex web of feedbacks that is important to understand and quantify. This paper addresses multiple pathways for aerosol and chemical feedbacks in Earth system models. These focus on changes in natural emissions (dust, sea salt, dimethyl sulfide, biogenic volatile organic compounds (BVOCs) and lightning) and changes in reaction rates for methane and ozone chemistry. The feedback terms are then given by the sensitivity of a pathway to climate change multiplied by the radiative effect of the change. We find that the overall climate feedback through chemistry and aerosols is negative in the sixth Coupled Model Intercomparison Project (CMIP6) Earth system models due to increased negative forcing from aerosols in a climate with warmer surface temperatures following a quadrupling of CO2 concentrations. This is principally due to increased emissions of sea salt and BVOCs which are sensitive to climate change and cause strong negative radiative forcings. Increased chemical loss of ozone and methane also contributes to a negative feedback. However, overall methane lifetime is expected to increase in a warmer climate due to increased BVOCs. Increased emissions of methane from wetlands would also offset some of the negative feedbacks. The CMIP6 experimental design did not allow the methane lifetime or methane emission changes to affect climate, so we found a robust negative contribution from interactive aerosols and chemistry to climate sensitivity in CMIP6 Earth system models.

Aerosol feedbacks↗
NASA NTRS1992

Optical fiber spectroscopy: A study of the luminescent properties of the europium ion for thermal sensors

Recently, there has been interest in developing a distributed temperature sensor integrated into an optical fiber. Such a system would allow embedding of the optical fiber within or on a structural material to provide for continuous monitoring of the material's temperature. Work has already begun on the development of a temperature sensor using the temperature dependent emission spectra from the lanthanide rare earths doped into crystalline hosts. The lifetime, the linewidth and the integrated intensity of this emission are each sensitive to changes in the temperature and can provide a basis for thermometry. One concept for incorporating this phenomena into an optical fiber based sensor involves bonding the optically active material to the cladding of an optical fiber and allowing the luminescent light to couple into the the fiber by the evanescent wave. Experimental work developing this concept has already been reported. Measurements of the linewidth of Eu3+:Y2O3, diffused into a fiber, made by Albin clearly show a strong and regular dependence on temperature over the range of 300 to 1000 K. We report here on a study of the temperature dependence of the lineshape of the emission at 611 nm using the data in references. We focus attention on understanding the general behavior of the Eu3+:Y2O3 system. Building upon understanding of this system we will be able to establish the physical criterial for a good optical fiber based temperature sensor and then to examine available data on other lanthanide rare earths and transition metal ions to determine the best luminescent system for temperature sensing in an optical fiber.

Buoncristiani, A. Martin↗
NASA NTRS2000

The Preparation Conditions of Chromium Doped ZnSe and Their Effect on The Infrared Luminescence Properties

We report the investigation by photoluminescence lifetime measurements of the near-IR emissions from a series of chromium-doped ZnSe samples, correlated to their preparation conditions. The samples were polycrystalline or single crystals prepared by post growth diffusion doping or single crystals doped during growth by the Physical Vapor Transport method. Room temperature lifetime values between 6 and 8 microseconds were measured for samples with Cr (2+) concentrations from low 10 (exp 17) to high 10 (exp 18) per cubic centimeter range. Lifetime data taken down to 78 K was found to be rather temperature independent, reconfirming previous reports indicating a quantum yield of the corresponding emission of close to 100% at room temperature. A strong decrease in the room temperature lifetime was found for chromium concentrations higher than 10 (exp 19) per cubic centimeter.

Burger, A.↗
NASA NTRS2000

The Preparation Conditions of Chromium Doped ZnSe and Their Effect on the Infrared Luminescence Properties

We report the investigation by photoluminescence lifetime measurements of the near-IR emissions from a series of chromium-doped ZnSe samples, correlated to their preparation conditions. The samples were polycrystalline or single crystals prepared by post growth diffusion doping or single crystals doped during growth by the physical vapor transport method. Room temperature lifetime values between 6 and 8 micro seconds were measured for samples with Cr2+ from low 10(exp 17) to high 10(exp 18) / cubic cm range. Lifetime data taken down to 78 K was found to be rather temperature independent, reconfirming previous reports indicating a quantum yield of the corresponding emission of close to 100% at room temperature. A strong decrease in the room temperature lifetime was found for chromium concentrations higher than 10(exp 19) / cubic CM.

Burger, A.↗
NASA NTRS2012

Taking the Pulse of PyroCumulus Clouds

Forest fires can burn large areas, but can also inject smoke into the upper troposphere/lower stratosphere (UT/LS), where stakes are even higher for climate, because emissions tend to have a longer lifetime, and can produce significant regional and even global climate effects, as is the case with some volcanoes. Large forest fires are now believed to be more common in summer, especially in the boreal regions, where pyrocumulus (pyroCu), and occasionally pyrocumuionimbus (pyroCb) clouds are formed, which can transport emissions into the UT/LS. A major difficulty in developing realistic fire plume models is the lack of observational data within fire plumes that resolves structure at a few 100 m scales, which can be used to validate these models. Here, we report detailed airborne radiation measurements within strong pyroCu taken over boreal forest fires in Saskatchewan, Canada during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) summer field campaign in 2008. We find that the angular distribution of radiance within the pyroCu is closely related to the diffusion domain in water clouds and can be described by very similar simple cosine functions. We demonstrate with Monte Carlo simulations that radiation transport in pyroCu is inherently a 3D phenomenon and must account for particle absorption. However, the simple cosine function promises to offer an easy solution for climate models. The presence of a prominent smoke core, defined by strong extinction in the UV, VIS and NIR, suggests that the core might be an important pathway for emission transport to the upper troposphere and lower stratosphere. We speculate that this plume injection core is generated and sustained by complex processes not yet well understood, but not necessarily related directly to the intense fires that originally initiated the plume rise.

Gatebe, C. K.↗
NASA NTRS2001

Life Model of Hollow Cathodes Using a Barium Calcium Aluminate Impregnated Tungsten Emitter

Hollow cathodes with barium calcium aluminate impregnated tungsten emitters for thermionic emission are widely used in electric propulsion. These high current, low power cathodes are employed in ion thrusters, Hall thrusters, and on the International Space Station in plasma contactors. The requirements on hollow cathode life are growing more stringent with the increasing use of electric propulsion technology. The life limiting mechanism that determines the entitlement lifetime of a barium impregnated thermionic emission cathode is the evolution and transport of barium away from the emitter surface. A model is being developed to study the process of barium transport and loss from the emitter insert in hollow cathodes. The model accounts for the production of barium through analysis of the relevant impregnate chemistry. Transport of barium through the approximately static gas is also being treated. Finally, the effect of temperature gradients within the cathode are considered.

Kovaleski, S. D.↗
NASA NTRS1989

Measurements of oscillator strengths for EUV emissions of ionized oxygen, nitrogen and sulfur

Oscillator-strength determinations for EUV branching emissions of atomic oxygen, nitrogen and sulfur are reported. The transitions studied were excited using a beam-foil source and both branching ratios and radiative lifetimes were determined. Calculated transition-probability data for multiply-ionized neon and oxygen emissions were used to obtain an in situ relative sensitivity curve for the EUV detection system used. New oscillator strengths for NII, OII, SII, and SIII EUV branching emissions that terminate on metastable states of the respective ions are reported, together with new lifetime data for ionized sulfur emissions.

Ryan, L. J.↗
NASA NTRSDate not supplied

Tracking 2020 Decreases in Carbon Dioxide Due to the COVID19 Pandemic in NASA’s GEOS Modeling system: Implications for Space-Based Carbon Monitoring

The COVID19 pandemic led to abrupt, worldwide changes in human activity and related emissions of air pollutants and greenhouse gases that are unprecedented in modern times. NASA satellites have demonstrated their ability to observe some of these impacts, particularly in relation to short-lived gases like nitrogen dioxide (NO2), which is emitted primarily from transportation. Bottom-up analyses of carbon dioxide (CO2) emissions suggest that the growth of atmospheric CO2 has also slowed, but differences are much more subtle than for NO2 because of the lifetime of atmospheric CO2 and sectoral differences in emission reductions. Estimates of CO2 from NASA’s Orbiting Carbon Observatory 2 (OCO-2) provide a unique view of COVID19 impacts, but observed changes in the column-average CO2 can be difficult to interpret because of gaps in spatial coverage. Assimilating these data into the Goddard Earth Observing System (GEOS), an integrated Earth system model with an advanced Constituent Data Assimilation System (CoDAS), helped to reveal changes in CO2 that are consistent with separate, bottom-up analyses of emissions reductions. Both indicate that from February-April of 2020, the growth in CO2 over Europe, North America, and Asia was roughly 0.3 ppm less than during the previous four years. Anomalies derived from gap-filled GEOS OCO-2 CoDAS products contribute to a joint effort by the world’s space agencies to track COVID19 impacts on the Earth. However, attribution of these changes is complicated by interannual variability in atmospheric circulation and the influence of climate on ocean and land carbon sinks. We discuss these results from the perspective of space-based carbon monitoring, which has received considerable support over the past decade from NASA. Our results demonstrate the accomplishments of current sensors and data assimilation systems, but also highlight challenges in providing high quality, low latency information to the public. In particular, understanding and attributing CO2 changes during 2020 requires year-specific information about land and ocean fluxes, which is often delayed for months or even years. We discuss current limitations and potential solutions to address these lags, which would support more reliable and timely space-based carbon monitoring.

COVID-19↗
NASA NTRS1970

An improved Orbitron ionization gage measures ultrahigh vacuum

Ionization gage with improved signal-to-noise ratio has a helical coil electrode which separates the solid cathode ion collector from the volume where ionization of gas molecules takes place. Helical coil increases lifetime of electrons and reduces secondary emission from the collector.

Gosselin, C. M.↗
NASA NTRS1979

Vaporization of comet nuclei - Light curves and life times

The effects of vaporization from the nucleus of a comet are examined and it is shown that a latitude dependence of vaporization can explain the asymmetries in cometary light curves. An attempt is made to explain the observed variation in molecular production rates with heliocentric distance when employing CO2 and clathrate hydrate ice as cometary nuclei substances. The energy balance equation and the vapor pressure equations of water and CO2 are used in calculating the vaporization from a surface. Calculations were carried out from both dry-ice and water-ice nuclei, using a variety of different effective visual albedos, but primarily for a thermal infrared of 0 (emission). Attention is given to cometary lifetimes and light curves and it was determined that the asymmetry in light curves occurs (occasionally) as a 'seasonal' effect due to a variation in the angle between the comet's rotation axis and the sun-comet line.

Cowan, J. J.↗
NASA NTRS1987

Shock heated dust in L1551: L(IR) greater than 20 solar luminosities

The infrared bolometric luminosity of the extended emission from the L1551 flow exceeds 20 solar luminosities. Ultraviolet radiation from the shock associated with the flow appears to heat the dust requiring shock temperatures from 10,000 to 90,000 K in L1551, velocities of approximately 50 km/s near the end of the flow, and a minimum mechanical luminosity of approximately 40 solar luminosities. The total energy requirement of the infrared emission over a 10,000 year lifetime is 10 to the 46th to 47th ergs, two orders of magnitude higher than previous estimates for L1551. Infrared radiation offers a method of probing interstellar shocks, by sampling the untraviolet halo surrounding the shock. At least one current model for bipolar flows is capable of meeting the energetic requirements.

Clark, F. O.↗
NASA NTRS1992

Two micron laser development for atmospheric remote sensing at NASA Langley Research Center

The topics addressed are: (1) eye safety revision of infrared MPE; (2) Tm:Ho dynamics characterization, which includes spectroscopy, laser experiments, and modeling; and (3) Q.M. model calculation, which includes energy levels, electric and magnetic dipole transition probabilities, lifetimes, branching ratios, absorption spectra, and emission spectra; (3) Q.M. model calculation; and (4) heat propagation in a laser rod.

Brockman, Philip↗
NASA NTRSDate not supplied

Cropland and Land-Clearing Emission Factors From Firex-AQ

The Fire Influence on Regional to Global Environments and Air Quality (FIREX-AQ) campaign is a NOAA/NASA interagency intensive study of North American fires that took place from July to September 2019. Agricultural fires were sampled on 7 flights from August 21st to September 3rd, 2019. We present emission factors for gas-phase and aerosol-phase species for the different fuel types identified during the campaign. We discuss the dependence of these emission factors on both fuel type and burning characteristics such as modified combustion efficiency (MCE). We analyze 73 fires encompassing four different agricultural fuels (corn, rice, soybean, wheat) and four different types of land-clearing fuels (grass, slash, pile, shrub). Approximately half of all sampled fires were burning corn agricultural residue. We report emission factors for 118 VOCs, where two thirds of emissions are made up of species with lifetimes against oxidation by OH of less than 12 hours (near-field impacts) and the remainder have longer-lifetimes (far-field impacts). We also include an additional 9 aerosol species, 12 halogenated species, 5 sulfur-containing species, and 22 nitrogen-containing species, including NH3 and NOx. There is a statistically significant difference in MCE between agricultural and land-clearing fires that accounts for some of the differences in emission factors across these fuels. VOCs generally have a strong negative correlation with MCE but with different slopes across fuel types. There is a significant positive relationship between MCE and three gas-phase (NO, NO2, SO2) and two aerosol-phase (pCl, pNH4) species. Many emission factors show additional dependence factors beyond MCE that could be related to fuel composition, fire temperature, soil moisture, or other possible differences in burning conditions. Therefore, important differences in emission factors may result when averaging together different types of agricultural and land-clearing fuels in compilations for use in modeling efforts.

biomass burning↗
NASA NTRS2016

Evaluation of Observed and Modelled Aerosol Lifetimes Using Radioactive Tracers of Opportunity and an Ensemble of 19 Global Models

Aerosols have important impacts on air quality and climate, but the processes affecting their removal from the atmosphere are not fully understood and are poorly constrained by observations. This makes modelled aerosol lifetimes uncertain. In this study, we make use of an observational constraint on aerosol lifetimes provided by radionuclide measurements and investigate the causes of differences within a set of global models. During the Fukushima Dai-Ichi nuclear power plant accident of March 2011, the radioactive isotopes cesium-137 (Cs-137) and xenon-133 (Xe-133) were released in large quantities. Cesium attached to particles in the ambient air, approximately according to their available aerosol surface area. Cs-137 size distribution measurements taken close to the power plant suggested that accumulation mode (AM) sulfate aerosols were the main carriers of cesium. Hence, Cs-137 can be used as a proxy tracer for the AM sulfate aerosol's fate in the atmosphere. In contrast, the noble gas Xe-133 behaves almost like a passive transport tracer. Global surface measurements of the two radioactive isotopes taken over several months after the release allow the derivation of a lifetime of the carrier aerosol. We compare this to the lifetimes simulated by 19 different atmospheric transport models initialized with identical emissions of Cs-137that were assigned to an aerosol tracer with each model's default properties of AM sulfate, and Xe-133 emissions that were assigned to a passive tracer. We investigate to what extent the modelled sulfate tracer can reproduce the measurements, especially with respect to the observed loss of aerosol mass with time. Modelled Cs-137and Xe-133 concentrations sampled at the same location and times as station measurements allow a direct comparison between measured and modelled aerosol lifetime. The e-folding lifetime e, calculated from station measurement data taken between 2 and 9 weeks after the start of the emissions, is 14.3 days (95% confidence interval 13.1-15.7 days). The equivalent modelled e lifetimes have a large spread, varying between 4.8 and 26.7 days with a model median of 9.42.3 days, indicating too fast a removal in most models. Because sufficient measurement data were only available from about 2 weeks after the release, the estimated lifetimes apply to aerosols that have undergone long-range transport, i.e. not for freshly emitted aerosol. However, modelled instantaneous lifetimes show that the initial removal in the first 2 weeks was quicker (lifetimes between 1 and 5 days) due to the emissions occurring at low altitudes and co-location of the fresh plume with strong precipitation. Deviations between measured and modelled aerosol lifetimes are largest for the northernmost stations and at later time periods, suggesting that models do not transport enough of the aerosol towards the Arctic. The models underestimate passive tracer (Xe-133) concentrations in the Arctic as well but to a smaller extent than for the aerosol (Cs-137) tracer. This indicates that in addition to too fast an aerosol removal in the models, errors in simulated atmospheric transport towards the Arctic in most models also contribute to the underestimation of the Arctic aerosol concentrations.

Radioactive isotopes↗
NASA NTRS2013

Global and Regional Temperature-change Potentials for Near-term Climate Forcers

We examine the climate effects of the emissions of near-term climate forcers (NTCFs) from 4 continental regions (East Asia, Europe, North America and South Asia) using results from the Task Force on Hemispheric Transport of Air Pollution Source-Receptor global chemical transport model simulations. We address 3 aerosol species (sulphate, particulate organic matter and black carbon) and 4 ozone precursors (methane, reactive nitrogen oxides (NOx), volatile organic compounds and carbon monoxide). We calculate the global climate metrics: global warming potentials (GWPs) and global temperature change potentials (GTPs). For the aerosols these metrics are simply time-dependent scalings of the equilibrium radiative forcings. The GTPs decrease more rapidly with time than the GWPs. The aerosol forcings and hence climate metrics have only a modest dependence on emission region. The metrics for ozone precursors include the effects on the methane lifetime. The impacts via methane are particularly important for the 20 yr GTPs. Emissions of NOx and VOCs from South Asia have GWPs and GTPs of higher magnitude than from the other Northern Hemisphere regions. The analysis is further extended by examining the temperature-change impacts in 4 latitude bands, and calculating absolute regional temperature-change potentials (ARTPs). The latitudinal pattern of the temperature response does not directly follow the pattern of the diagnosed radiative forcing. We find that temperatures in the Arctic latitudes appear to be particularly sensitive to BC emissions from South Asia. The northern mid-latitude temperature response to northern mid-latitude emissions is approximately twice as large as the global average response for aerosol emission, and about 20-30% larger than the global average for methane, VOC and CO emissions.

North America↗
NASA NTRS1991

Room temperature Dy:YLF laser operation at 4.34 micron

A Dy:YLF laser operating on the 6H11/2 to 6H13/2 transition at 4.34 micron and using a laser pumping scheme is reported. This pumping scheme is necessitated by the short upper-laser-level lifetime and the small effective stimulated-emission cross section. A suitable laser for this application is the Er:YLF laser operating at 1.73 micron. A simple model that approximates Dy:YLF laser performance well is presented. Results on laser performance, including a determination of the slope efficiency and threshold as a function of the output mirror reflectivity and a correlation of the pulse length with the laser output energy, are reported. Overall laser efficiency is found to be limited primarily by the ratio of the pump wavelength to laser output wavelength and the terminated four-level laser operation. Spectroscopic results, including the measurement of the absorption spectra and the lifetimes of both the upper- and lower-laser manifolds, are given.

Barnes, Norman P.↗