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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Monolayer Semiconductor Auger Detector

Auger recombination in semiconductors is a many-body phenomenon in which the recombination of electrons and holes is accompanied by excitation of other charge carriers. The excess energy of the excited carriers is normally rapidly converted to heat, making Auger processes difficult to probe directly. In this paper, we employ a technique in which the Auger-excited carriers are detected by their ability to tunnel out of the semiconductor through a thin barrier, generating a current. We use vertical van der Waals heterostructures with monolayer WSe 2 as the semiconductor, with hexagonal boron nitride as the tunnel barrier, and a graphite collector electrode. The Auger processes combined with resonant absorption produce characteristic negative photoconductance. We detect holes Auger-excited by both neutral and charged excitons and find that the Auger scattering is surprisingly strong under weak excitation. Our work expands the range of techniques available for probing relaxation processes in 2D materials.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Unexpected inverse correlations and cooperativity in ion-pair phase transfer

Liquid/liquid extraction is one of the most widely used separation and purification methods, where a forefront of research is the study of transport mechanisms for solute partitioning and the relationships that these have to solution structure at the phase boundary. To date, organized surface features that include protrusions, water-fingers, and molecular hinges have been reported. Many of these equilibrium studies have focused upon small-molecule transport – yet the extent to which the complexity of the solute, and the competition between different solutes, influence transport mechanisms have not been explored. Here we report molecular dynamics simulations that demonstrate that a metal salt (LiNO 3 ) can be transported via a protrusion mechanism that is remarkably similar to that reported for H 2 O by tri-butyl phosphate (TBP), a process that involves dimeric assemblies. Yet the LiNO 3 out-competes H 2 O for a bridging position between the extracting TBP dimer, which in-turn changes the preferred transport pathway of H 2 O. Examining the electrolyte concentration dependence on ion-pair transport unexpectedly reveals an inverse correlation with the extracting surfactant concentration. As [LiNO 3 ] increases, surface adsorbed TBP becomes a limiting reactant in correlation with an increased negative surface charge induced by excess interfacial NO 3 – , however the rate of transport is enhanced. Within the highly dynamic interfacial environment, we hypothesize that this unique cooperative effect may be due to perturbed surface organization that either decreases the energy of formation of transporting protrusion motifs or makes it easier for these self-assembled species to disengage from the surface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

An R&D program for milliampere spin-polarized electron beams

The electron injector driving the positron conversion target for Ce+BAF requires a spin-polarized beam with at least 1 mA of average current. While the parameters are not unusual from a beam dynamics point of view, the high average current is challenging due to the finite charge lifetime of the GaAs-based high-polarization photocathodes, even when operated in state-of-the-art load-lock photo-guns. We discuss the dominant limitations and present a systematic experimental program at the Gun Test Stand aiming to overcome them. With a multi-pronged approach involving a redesign of the photo-gun electrodes and an optimized drive laser profile, we hope to demonstrate a charge lifetime in excess of 1 kC from a high-polarization photocathode, mitigating one of the main risks in the injector design.

Bruker, Max [Thomas Jefferson National Accelerator↗
NASA NTRS1976

A local diffusion process associated with the sweeping of energetic particles by Io

A local, turbulent diffusion process which may rapidly refill the partial cavity of energetic particles created by Io's passage through a flux tube is discussed. A model is developed of Io's sweeping action on energetic particles in which a wake is formed behind the flux tube threading Io. It is shown to be possible that this wake contains an excess of positive charge, thereby creating an electric field. The particle drift produced by this field, coupled with the density gradient of energetic protons, can generate an instability. It is this instability that is responsible for the turbulent diffusion process. The sweeping of energetic particles is also discussed in relation to particle energy and pitch angle distribution.

Huba, J. D.↗
NASA NTRS1977

Parametric Performance of a Spiral-Artery, Liquid-Trap-Diode Heat Pipe

A series of parametric investigations are described which determine the effect of various fluid charges on the performance of a 0.635-cm-diam spiral-artery, liquid-trap diode in both the forward and reverse modes. Specific parameters such as forward- and reverse-mode conductances, shutdown times and energies, and recovery to forward-model operation, are evaluated for ethane as a working fluid in the temperature range 170 K to 220 K. Results indicate that the heat pipe will not reliably start up in the forward mode. However, startup can be initiated when preceded by a diode reversal. Also included are data which show the susceptibility of the diode to fluid charge and tilt. The optimum fluid charge was found to be 2.67 g and transport capability at this charge was in excess of 1200 W-cm at 200 K. The diode in the reverse mode exhibited a rapid shutdown (within 9 min) with a shutdown energy of 1150 J (0.32 Wh).

Williams, R. J.↗
NASA NTRS1978

Investigation of a cryogenic thermal diode

This paper describes a series of parametric investigations to determine the effect of various fluid charges on the performance of a 0.635-cm-diameter spiral-artery, liquid-trap diode in both the forward and reverse modes. Specific parameters such as forward- and reverse-mode conductances, shutdown times and energies, and recovery to forward-mode operation, are evaluated for ethane as a working fluid in the temperature range 170 K to 220 K. Results indicate that the heat pipe will not reliably start up in the forward mode. However, startup can be initiated when preceded by a diode reversal. Also concluded are data which show the susceptibility of the diode to fluid charge and tilt. The optimum fluid charge was found to be 2.67 g, and transport capability at this charge was in excess of 1200 W-cm at 200 K. The diode in the reverse mode exhibited a rapid shutdown (within 9 min) with a shutdown energy of 1150 J (0.32 Wh).

Williams, R. J.↗
NASA NTRS1984

Limiting mechanisms in large-grain polycrystalline silicon Spatial homogeneity

An experiment to investigate the spatial homogeneity of large-grain polycrystalline silicon shows a number of performance-loss mechanisms. Arrays of up to 400 small (about 0.2 sq cm in area) photodiodes were fabricated on a selection of 10 cm x 10 cm polycrystalline silicon wafers. Measurements of the illuminated current-voltage (J-V) characteristics were used to generate maps of Voc, Jsc, and FF as a function of position; and dark J-V and LBIC analysis were used to determine the cause of low performance in areas with significantly degraded J-V characteristics. In addition to the presence of inclusions, which act as resistive shunts, the performance of many of the cells is limited by quasineutral recombination current, which may vary by up to an order of magnitude across a wafer. The increase is the result of either electrically-active grain boundaries or numerous subgrain boundaries within the grain bulk. In other isolated instances, the open-circuit voltage is reduced by excess space-charge recombination current that is not correlated with either grain or subgrain boundary activity.

Culik, J.↗
NASA NTRS1991

Radio telescopes as the detectors of super-high-energy neutrinos

The registration of super high energy neutrinos is a very difficult and also very important problem that requires construction of detectors with large effective target masses. Askaryan pointed out the possibility of registering cascades in dense media by the Cherenkov radio emission of an excess of negative charges in the cascades which arose in interaction between high energy particles and the atoms of medium. The telescopes for cosmic high energy neutrino detection by radioemission of cascades induced underground, but whose development continues in the atmosphere were proposed by others. The effective target masses of such detectors could be approx. 10(exp 9) tons and more. The properties of Cherenkov radio emission of cascades and the properties of ice in the Antarctic Region make it possible to propose Radio Antarctic Muon and Neutrino Detection (RAMAND): antennas should be placed on the ice surface of approx. 10 sq km to search for radio signals for neutrino (muon) cascades of energy. It is evident from data given that the largest radio telescopes gives the opportunity for registration of the cascades induced by neutrinos with the energies E is greater than or = 10(exp 20) eV.

Dagkesamansky, R. D.↗
NASA NTRS2005

ACTS Battery and Solar Array Assembly On-Orbit Measured Performance

The Advanced Communications Technology Satellite (ACTS) is a NASA experimental communications satellite system designed to demonstrate on-orbit Ka-band communications and switching technologies that will be used by NASA and the commercial sector in the 21st century. The ACTS was launched on September 12, 1993, and has performed over 10 years of successful experimental operations. The purpose of this report is to describe the ACTS power subsystem and the ACTS solar array and battery assemblies located within the power subsystem and then to document on-orbit measured performance from launch to mission end on April 28, 2004. Solar array and battery performance data is presented, and respective conclusions are drawn. The total solar array power available to the spacecraft was measured each year at the same time, and battery voltage performance was measured twice per year at the same times during peak solar eclipse. At the highest spacecraft power demand, the ACTS uses approximately 1113 W of electrical power during the low-burstrate experiment to operate all six satellite subsystems. After 10 years of on-orbit operation, solar array available output power normal to the Sun measured 1508 W, which represents 395 W of excess margin. The ACTS batteries have successfully supported the ACTS experiment program for over 10 years and operated in excess of 900 charge and discharge cycles through 21 eclipse seasons.

Hilderman, Don R.↗
NASA NTRS1990

Response of a DRAM to single-ion tracks of different heavy-ion species and stopping powers

Multiple-bit errors caused by single-ion tracks in a 256-kb DRAM fabricated by a bulk process were observed for different ion species and stopping power values. The results demonstrate the utility of this device for the evaluation of ion-beam uniformity and ion-beam-induced charge collection in IC devices. The data indicate that single-ion-induced charge transport results in multiple-bit error clusters due to lateral diffusion of excess minority carriers (electrons). Charge collection occurred from a depth of up to 35 microns from the surface of the device. An apparent charge loss was observed for very heavy ions with a high stopping power (Au at 350 MeV).

Zoutendyk, J. A.↗
DOE OSTI2020

Water-Assisted Proton Transport in Confined Nanochannels

Hydrated excess protons under hydrophobic confinement are a critical component of charge transport behavior and reactivity in nanoporous materials and biomolecular systems. In this study, excess proton confinement effects are computationally investigated for sub-2 nm hydrophobic nanopores by varying the diameters (d = 0.81, 0.95, 1.09, 1.22, 1.36, 1.63, and 1.90 nm), lengths (l ~3 and ~5 nm), curvature, and chirality of cylindrical carbon nanotube (CNT) nanopores. CNTs with a combination of different diameter segments are also explored. The spatial distribution of water molecules under confinement is diameter-dependent; however, proton solvation and transport are consistently found to occur in the water layer adjacent to the pore wall, showing an “amphiphilic” character of the hydrated excess proton hydronium-like structure. The proton transport free energy barrier also decreases significantly as the nanopore diameter increases and proton transport becomes almost barrierless in the d > 1 nm nanopores. Among the nanopores studied, the Zundel cation (H 5 O 2 + ) is populated only in the d = 0.95 nm CNT (7,7) nanopore. The presence of the hydrated excess proton and K + inside the CNT (7,7) nanopore induces a water density increase by 40 and 20%, respectively. The K + transport through CNT nanopores is also consistently higher in the free energy barrier than proton transport. Interestingly, the evolution of excess protonic charge defect distribution reveals a “frozen” single water wire configuration in the d = 0.81 nm CNT (6,6) nanopore (or segment), through which hydrated excess protons can only shuttle via the Grotthuss mechanism. Vehicular diffusion becomes relevant to proton transport in the “flat” free energy regions and in the wider nanopores, where protons do not primarily shuttle in the axial direction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Proton Dissociation and Delocalization under Stepwise Hydration of Zeolite HZSM-5

The protonation behavior of zeolite Brønsted acid sites (BAS) in the presence of water is important for the performance of these widely used catalysts. Despite extensive study, the number of water molecules necessary for deprotonation is not well understood, in large part because experiments have been unable to access this information. In this work, we report experimental evidence for full deprotonation of the BAS in the presence of two or more water molecules, with a deprotonation energy of 1.6 kcal/mol. Linear IR absorption and 2D IR spectra were measured over a wide range of controlled hydration levels from 0.5 to 8.0 equivalents of H 2 O/Al at a constant temperature. Distinct spectral signatures of the protonated BAS and excess proton are identified, and their hydration dependence is analyzed quantitatively. Using the experiment as a benchmark, ab initio molecular dynamics simulations are reported that reproduce the experimental trends in the protonation state and IR spectra. The proton charge position and delocalization are quantified in clusters of 1–8 H 2 O molecules using the recently developed rCEC method. This analysis provides insight into the proton structure in confined water clusters, showing that the excess charge remains relatively localized between two oxygen atoms across the hydration range.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2004

Charge-Dissipative Electrical Cables

Electrical cables that dissipate spurious static electric charges, in addition to performing their main functions of conducting signals, have been developed. These cables are intended for use in trapped-ion or ionizing-radiation environments, in which electric charges tend to accumulate within, and on the surfaces of, dielectric layers of cables. If the charging rate exceeds the dissipation rate, charges can accumulate in excessive amounts, giving rise to high-current discharges that can damage electronic circuitry and/or systems connected to it. The basic idea of design and operation of charge-dissipative electrical cables is to drain spurious charges to ground by use of lossy (slightly electrically conductive) dielectric layers, possibly in conjunction with drain wires and/or drain shields (see figure). In typical cases, the drain wires and/or drain shields could be electrically grounded via the connector assemblies at the ends of the cables, in any of the conventional techniques for grounding signal conductors and signal shields. In some cases, signal shields could double as drain shields.

Kolasinski, John R.↗
DOE OSTI2025

Impact of the LiPF6 Concentration on the Interfacial Charge Transfer and Fast-charging Capabilities of Lithium-Ion Batteries

Fast-charging lithium-ion batteries (LIB) demand optimized electrolyte formulations to balance ionic conductivity, viscosity, and interfacial charge transfer kinetics. This study examines how LiPF 6 concentration shapes solvation structure, desolvation energy, charge transfer activation energy, and solid electrolyte interphase (SEI) properties, which are critical for fast-charging performance. Using Raman spectroscopy, electrochemical cycling, X-ray photoelectron spectroscopy, and atomistic modeling, we analyze how varying LiPF 6 concentrations impact interfacial and bulk transport properties. Our findings show that increasing LiPF 6 concentration alters lithium solvation structures, reduces desolvation energy, and accelerates charge transfer at the electrode interface. Higher concentrations lower the activation energy for charge transfer and suppress excessive SEI growth, improving interfacial kinetics. However, concentrations above a certain threshold increase viscosity and reduce ionic conductivity, limiting transport efficiency. These results offer insights into electrolyte solvation and interfacial charge transfer mechanisms, providing guidelines for designing next-generation fast-charging LIB electrolytes with enhanced efficiency, stability, and longevity.

Son, Seoung-Bum [Argonne National Laboratory (ANL)↗
DOE OSTI2025

Oxidation and recharge of reactive structural Fe( II ) in titanomagnetite (Fe 3− x Ti x O 4 ) nanoparticles

Mixed-valent iron oxide minerals, such as magnetite (Fe(II)(Fe(III)) 2 O 4 ), are an important source of solid-state ferrous iron (Fe(II)) that can impact the speciation and transport of electron accepting contaminants in the Earth’s subsurface, such as radioactive pertechnetate ( 99 Tc(VII)O 4 − ). However, when oxidizing conditions are encountered, structural Fe(II) at the mineral surface is consumed yielding a maghemite (γ-Fe(III) 2 O 3 )-like layer that limits further electron transfer. This oxidized surface layer can be recharged back to the original Fe(II)/(III) ratio by re-exposure to reducing conditions, i.e., aqueous solutions containing Fe 2+ . However, for substituted magnetite (Fe 3−x M x O 4 , M = transition metal cation), the extent of this redox recyclability is unclear. Here, we examine oxidation and recharge for titanomagnetite (Fe 3−x Ti x O 4 ) nanoparticles, where the Fe(II)/Fe(III) ratio varies by the amount of Fe(II) required to charge balance the titanium (Ti(IV)) substituted into the structure. The nanoparticles were synthesized by aqueous precipitation from a solution containing ferrous, ferric and titanium chloride at room temperature. Transmission electron microscopy combined with electron energy loss spectroscopy revealed that rapid precipitation formed core–shell-like nanoparticles consisting of a hyperstoichiometric magnetite core, with Ti(IV) and charge balancing Fe(II) enriched at the surface. This surface enrichment made Fe(II) more available for electron transfer reactions with redox active solution species. Examination of oxidation by H 2 O 2 followed by recharge with aqueous Fe 2+ indicates recyclability of reducing equivalents in the nanoparticles, yielding a core recrystallized to stoichiometric magnetite and a shell bearing excess Fe(II) to charge balance the substituted Ti(IV). The recharged particles are shown to have restored redox reactivity with 99 Tc(VII)O 4 − resulting in reduction to 99 Tc(IV)O 2 and oxidation of the structural Fe(II) to Fe(III).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Search for the lepton-flavor violating decay B s 0 → ϕ μ ± τ ∓

A search for the lepton-flavor violating decays B s 0 → ϕ μ ± τ ∓ is presented, using a sample of proton-proton collisions at center-of-mass energies of 7, 8, and 13 TeV, collected with the LHCb detector and corresponding to a total integrated luminosity of 9 fb − 1 . The τ leptons are selected using decays with three charged pions. No significant excess is observed, and an upper limit on the branching fraction is determined to be B ( B s 0 → ϕ μ ± τ ∓ ) < 1.0 × 10 − 5 at 90% confidence level. © 2024 CERN, for the LHCb Collaboration 2024 CERN

Aaij, R. (ORCID:0000000305331952)↗
DOE OSTI2023

Cycling of block copolymer composites with lithium-conducting ceramic nanoparticles

Solid polymer and perovskite-type ceramic electrolytes have both shown promise in advancing solid-state lithium metal batteries. Despite their favorable interfacial stability against lithium metal, polymer electrolytes face issues due to their low ionic conductivity and poor mechanical strength. Highly conductive and mechanically robust ceramics, on the other hand, cannot physically remain in contact with redox-active particles that expand and contract during charge-discharge cycles unless excessive pressures are used. To overcome the disadvantages of each material, polymer-ceramic composites can be formed; however, depletion interactions will always lead to aggregation of the ceramic particles if a homopolymer above its melting temperature is used. In this study, we incorporate Li 0.33 La 0.56 TiO 3 (LLTO) nanoparticles into a block copolymer, polystyrene- b -poly (ethylene oxide) (SEO), to develop a polymer-composite electrolyte (SEO-LLTO). TEMs of the same nanoparticles in polyethylene oxide (PEO) show highly aggregated particles whereas a significant fraction of the nanoparticles are dispersed within the PEO-rich lamellae of the SEO-LLTO electrolyte. We use synchrotron hard x-ray microtomography to study the cell failure and interfacial stability of SEO-LLTO in cycled lithium-lithium symmetric cells. Three-dimensional tomograms reveal the formation of large globular lithium structures in the vicinity of the LLTO aggregates. Encasing the SEO-LLTO between layers of SEO to form a “sandwich” electrolyte, we prevent direct contact of LLTO with lithium metal, which allows for the passage of seven-fold higher current densities without signatures of lithium deposition around LLTO. We posit that eliminating particle clustering and direct contact of LLTO and lithium metal through dry processing techniques is crucial to enabling composite electrolytes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1982

Low-background performance of a monolithic InSb CCD array

A 20 element monolithic InSb charge coupled device (CCD) detector array was measured under low background conditions to assess its potential for orbital astronomical applications. At a temperature of 64 K, previous results for charge transfer efficiency (CTE) were reproduced, and a sensitivity of about 2 x 10 to the minus 15th power joules was measured. At 27 and 6 K, extended integration times were achieved, but CTE was substantially degraded. The noise was approximately 6000 charges, which was in excess of the level where statistical fluctuations from the illumination could be detected. A telescope demonstration was performed showing that the array sensitivity and difficulty of operation were not substantially different from laboratory levels. Ways in which the device could be improved for astronomical applications were discussed.

Bregman, J. D.↗