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At least 91 records · Page 5

Solar abundances from gamma-ray spectroscopy - Comparisons with energetic particle, photospheric, and coronal abundances

Accelerated particle and ambient gas abundances have been derived using solar flare gamma-ray spectroscopy. The results with photospheric and coronal abundances, as well as with solar energetic particle abundances. This is the first time that the composition of accelerated particles interacting in an astrophysical source has been compared with the composition of particles escaping from the source. The analysis shows that the derived composition of the accelerated particles is different from the composition of particles observed in large proton flares; rather, it resembles the composition observed in He-3-rich flares. The analysis also suggests an ambient gas composition which differs from the composition of both the photosphere and the corona.

Murphy, R. J.↗

An interacting loop model of solar flare bursts

As a result of the strong heating produced at chromospheric levels during a solar flare burst, the local gas pressure can transiently attain very large values in certain regions. The effectiveness of the surrounding magnetic field at confining this high pressure plasma is therefore reduced and the flaring loop becomes free to expand laterally. In so doing it may drive magnetic field lines into neighboring, nonflaring, loops in the same active region, causing magnetic reconnection to take place and triggering another flare burst. The features of this interacting loop model are found to be in good agreement with the energetics and time structure of flare associated solar hard X-ray bursts.

Emslie, A. G.↗

An interacting loop model for solar flare bursts

A schematic model is presented which attempts to explain the quasi-periodic behavior (on a timescale of less than or approximately equal to 10 s) frequency observed in solar hard X-ray bursts. It is shown how, as a result of the strong heating produced during a solar flare burst, the local gas pressure can transiently attain very large values in regions corresponding to the upper preflare chromosphere. The effectiveness of the surrounding magnetic field at confining this high pressure plasma is therefore reduced and the flaring loop becomes free to expand laterally. In so doing it may drive magnetic field lines into neighboring, non-flaring, loops in the same active region, causing magnetic reconnection to take place and triggering another flare burst. The features of this interacting loop model are found to be in good agreement with the energetics and time structure of flare-associated solar hard X-ray bursts.

Emslie, A. G.↗

Delayed Development of Cool Plasmas in X-Ray Flares from the Young Sun-like Star κ1 Ceti

The Neutron star Interior Composition Explorer (NICER) X-ray observatory observed two powerful X-ray flares equivalent to superflares from the nearby young solar-like star κ 1 Ceti in 2019. NICER follows each flare from the onset through the early decay, collecting over 30 counts s −1 near the peak, enabling a detailed spectral variation study of the flare rise. The flare in September varies quickly in ∼800 s, while the flare in December has a few times longer timescale. In both flares, the hard-band (2–4 keV) light curves show typical stellar X-ray flare variations with a rapid rise and slow decay, while the soft X-ray light curves, especially of the September flare, have prolonged flat peaks. The time-resolved spectra require two temperature plasma components at kT ∼0.3–1 and ∼2–4 keV. Both components vary similarly, but the cool component lags by ∼200 s with a four to six times smaller emission measure (EM) compared to the hot component. A comparison with hydrodynamic flare loop simulations indicates that the cool component originates from X-ray plasma near the magnetic loop footpoints that mainly cools via thermal conduction. The time lag represents the travel time of the evaporated gas through the entire flare loop. The cool component has a several times smaller EM than its simulated counterpart, suggesting a suppression of conductive cooling, possibly by the expansion of the loop cross-sectional area or turbulent fluctuations. The cool component's time lag and EM ratio provide important constraints on the flare loop geometry.

main sequence stars↗

Isolated Single Metal Atoms Supported on Silica for One Step Non-Oxidative Methane Upgrading to Hydrogen and Value-Added Hydrocarbons

Natural gas in the United States offers substantial economic opportunities due to its abundance but its transportation is challenging because its primary component, methane (CH 4 ), does not liquefy at ambient temperature and typical pressures. As a result, a significant portion of natural gas is either used for heat, flared in remote locations, or remains unutilized, presenting a lost economic opportunity and an environmental harm. Converting natural gas to larger hydrocarbons in an economically competitive manner would enable transportation of products and further boost the economy and reduce environmental footprint. Our research goal is to enable efficient non-oxidative methane conversion (NMC) via catalyst innovation to convert CH 4 in one-step to olefins and aromatics and hydrogen (H 2 ) co-product. The catalysts are made of supported single metal atoms and operated at medium-high temperatures. The single metal atoms achieve methane activation by heterogeneous surface dehydrogenation to generate a hydrocarbon pool and importantly limit coke formation. The integration of novel single atom catalysts in a short contact time microreactor enable unprecedented NMC performance that could lead to economically-feasible, distributed natural gas upgrading by advanced manufacturing and process intensification. Our innovated catalyst and reactor technology promise to tap into previously uneconomic natural gas resources, such as stranded, vented, and flared methane.

03 NATURAL GAS↗

Gas Sloshing and Radio Galaxy Dynamics in the Core of the 3C 449 Group

We present results from a 140 ks Chandra/ACIS-S observation of the hot gas around the canonical FR I radio galaxy 3C 449. An earlier, shorter 30 ks Chandra observation of the group gas showed an unusual entropy distribution and a surface brightness edge in the gas that could be a strong shock around the inner radio lobes. In our deeper data we find no evidence for a temperature increase inside of the brightness edge, but a temperature decrease across part of the edge. This suggests that the edge is a "sloshing" cold front due to a merger within the last 1.3-1.6 Gyr. Both the northern and southern inner jets are bent slightly to the west in projection as they enter their respective lobes, suggesting that the sloshing core is moving to the east. The straight inner jet flares at approximately the position where it crosses the contact edge, suggesting that the jet is entraining and thermalizing some of the hot gas as it crosses the edge.We also detect filaments of X-ray emission around the southern inner radio jet and lobe which we attribute to low entropy entrained gas. The lobe flaring and gas entrainment were originally predicted in simulations of Loken et al. and are confirmed in our deep observation.

Lal, Dharam V.↗

The effects of flaring in H1 on the observed velocity field of spirals

This work is part of a larger project in which we want to determine the shapes of dark halos around spiral galaxies. Rotation curves 'probe' the halos in the radial direction. The derived halo mass distributions are badly constrained. The local halo densities fully determine the width of the gas distribution once the gaseous velocity dispersion is known. There where the dark halo dominates, the Full Width at Half Maximum (FWHM) of the gas layer is proportional to (rho(sub halo))(exp -0.5). Therefore, measuring the width of the gas layer probes the halo density directly. In a dark halo dominated potential, the FWHM of the gas layer increases linearly with radius. This increase of the thickness of the gas layer is known as 'flaring'. Flaring has been found inside the stellar disk. Beyond the edge of the stellar disk, the analysis is hampered by the onset of the warp. Since the galaxy we are studying, NGC 4244, has no significant warp we hope to extend Rupen's analysis into the halo dominated regime. The usual method to derive a rotation curve from an observed 2-dimensional velocity field is to assume that the hydrogen is distributed in infinitely thin rings. For a flaring disk, any line of sight samples many different parts of the galaxy, all having different densities and projected velocities. In order to fully exploit the information contained in the gas distribution, we have to understand the effects of flaring on the observables (the spectrum for each point of the galaxy). We have investigated the effects of a flaring disk on the observed velocity field. It is obvious that the largest (kinematical) effects are to be expected for low density dark halos at large inclinations. For low mass galaxies we expect that the flaring of the H1 layer will have a major effect on the observed kinematics. For galaxy with intermediate V(sub max,halo) seen at intermediate inclinations, one overestimates Vsin(i) typically by a few percent. For more massive galaxies, any effects arising from the flaring H1 layer are minuscule unless the inclination is not too far from 90 deg.

Olling, Rob↗

Microwave-Assisted Methane Dehydroaromatization: Impact of Process Parameters

Flaring of associated natural gas is a significant challenge for oil and gas producers that often results in high amounts of lost revenue for the industry. One way to improve economics of this process is to convert natural gas into value-added chemicals using chemical conversion. Methane, which is the principal component of natural gas, can typically be converted into valuable aromatics using non-oxidative conversion routes such as dehydroaromatization. For the current work, methane dehydroaromatization was investigated in a microwave-assisted reactor and the effect of various parameters such as reaction temperature (550-750 °C) and space velocity (3-8 L/gcat/hr) were studied. Both the parameters had a very strong effect on the overall performance of the reaction. The variation in temperature had significant impact on the overall methane conversion, whereas the variation in space velocity had significant impact on the selectivity and product distribution.

methane dehydroaromatization↗

Dynamic crystallization experiments as constraints on chondrule genesis

The effectiveness of dynamic recrystallization experiments to reconstruct chondrule textures is evaluated. Consideration is given to the results of several experimental simulations of the silicate spheres of pyroxene-olivine chondrules, Si-rich chondrules, chondrites, droplet chondrules, and microporphyritic chondrules. It is shown that many chondrules have textures consistent with heating to 1400-1600 C, and cooling rates from a few degrees to several thousands of degrees per hour. It is shown that this physical constraint effectively rules out mechanisms for chondrule genesis which do not require instantaneous or very slow cooling. Analysis of the available textural, chemical, and isotopic data suggest that chondrules were generated from primordial particles, and several mechanisms might have assisted in chondrule heating as they settled down toward the median plane of the nebula. The most important of these mechanisms appear to be friction with the nebular gas and heating by flares.

Hewins, R. H.↗

Prediction of magnetic orientation in driver gas associated -Bz events

The source regions of five strong -Bz events detected at 1 AU for which solar sources were identified by Tang et al. (1989) and Tsurutani et al. (1992) are investigated in order to determine whether the magnetic orientation of driver gas in the interplanetary medium observed at the earth can be predicted when its solar source is identified. Three -Bz events were traced to flare-associated coronal mass ejections (CMEs), one to an eruptive prominence associated CME, and one to three possible solar sources. The computed magnetic orientations at the candidate 'release height' (the height where the front of a CME ceases to accelerate) above the flare sites associated with CMEs show the existence of the expected southward field component. It is concluded that the magnetic orientation in flare-associated CME generated driver gas may be predictable.

Hoeksema, J. T.↗

On the flaring of cometary plasma tails

Assuming that hypersonic pressure balance with the solar wind governs the shape of plasma tails, it is found that the gas pressure of tail ions and the magnetic field strength at the flanks of the ionopause control the flaring state. The gas pressure exhibits the larger effect: for constant pressures above a certain critical value, the tail flares essentially without limit, while for smaller values the tail flares only near the head (becoming cylindrical at greater distances). The influence of the magnetic field is that the tail flares to larger distances the higher the field strength at the flanks of the ionopause. The observed variability in flaring (and the implied differences in gas pressure and magnetic field) are throught to be the result of changes in the position and shape of the sunward cometary ionopause. Insertion of reasonable comet and solar wind parameters into the pressure balance equations is found to give good agreement with the observations.

Ershkovich, A. I.↗

Upcycling Associated Natural Gas into Liquid Chemical Intermediates

This report assesses the opportunity to utilize associated natural gas (ANG) that is currently flared or vented by conversion to value-added chemicals. In cases where ANG production is not sufficient to justify on-site capture and added investments for transportation and storage, there may be commercial opportunities to perform conversion and value-added processing of ANG. This analysis focuses on CH 4 conversion to liquid intermediates, as opposed to gaseous product, due to the opportunity to transport large volumes of liquids, by truck or rail as opposed to pipeline. This report assesses market opportunities for four liquid intermediates: benzene, toluene, xylene, and formic acid.

03 NATURAL GAS↗

Gas-rich meteorites - Probes for particle environment and dynamical processes in the inner solar system

Although the asteroids are the most plausible candidates for the parent bodies of gas-rich meteorites, dynamical theories have been adduced which favor a cometary origin in certain cases, and some recent studies have indicated that, in the case of gas-rich carbonaceous chondrites, the solar flare irradiation of grains may have occurred prior to the formation of parent bodies. Attention is presently given to advances that have been made in the multidisciplinary studies, encompassing petrography, chemistry, and radiation effects, of the gas-rich meteorites. An evaluation is undertaken of the present understanding of gas-rich meteorite origin and evolution.

Goswami, J. N.↗

An integrated methane dehydroaromatization and chemical looping process

Most of the natural gas co-produced in oil wells is flared due to the high transportation costs of bringing it to market. Onsite upgrading of natural gas to liquid products could address this issue but there are few processes for effective direct conversion of natural gas to liquid products. Methane dehydroaromatization (DHA) over Mo/HZSM- 5 offers a potential route to a value-added liquid product, however, DHA conversion is severely limited by thermodynamics at most industrially relevant temperatures. Here we propose an integrated process coupling methane DHA, chemical looping for selective hydrogen oxidation, and subsequent water removal to achieve higher yields of aromatic products limited by the thermodynamics in one-pass systems. Here, we validate this process via the construction and operation of a one-of-a-kind multibed recirculating reactor, and achieve a combined aromatics yield of 42%. Detailed technoeconomic analysis of the process for mobile applications show that such a process could be economically viable under certain circumstances.

03 NATURAL GAS↗

Rare gases in etched 10084 ilmenite - A search for trapped solar-flare rare gases

Results are presented of rare-gas analyses of 10084 ilmenite samples which have been etched to depths of about 1 micrometer in an attempt to remove the surface layer of trapped solar-wind gases, thereby allowing detection of the more deeply implanted solar-flare ions in the remaining trapped gases. A tendency found for the Ne-20/Ne-22 ratios in the etched ilmenite to reflect the solar-wind ratio measured in the solar-wind composition experiment foils may represent a cancellation of mass-fractionation effects. The Ne-20/Ne-22 ratio in the saturated layer is lowered with respect to the solar wind by preferential diffusive loss, but is raised again in the gas diffusing inward by the same preferential mobilization of Ne-20 relative to Ne-22. Attention is also given to the significance of the findings in the case of argon, krypton, and xenon.

Leich, D. A.↗

Abundances from solar-flare gamma-ray line spectroscopy

Elemental abundances of the ambient gas at the site of gamma ray line production inthe solar atmosphere are deduced using gamma ray line observations from a solar flare. The resultant abundances are different from local galactic abundances which are thought to be similar to photospheric abundances.

Murphy, R. J.↗

The flare kernel in the impulsive phase

The impulsive phase of a flare is characterized by impulsive bursts of X-ray and microwave radiation, related to impulsive footpoint heating up to 50 or 60 MK, by upward gas velocities (150 to 400 km/sec) and by a gradual increase of the flare's thermal energy content. These phenomena, as well as non-thermal effects, are all related to the impulsive energy injection into the flare. The available observations are also quantitatively consistent with a model in which energy is injected into the flare by beams of energetic electrons, causing ablation of chromospheric gas, followed by convective rise of gas. Thus, a hole is burned into the chromosphere; at the end of impulsive phase of an average flare the lower part of that hole is situated about 1800 km above the photosphere. H alpha and other optical and UV line emission is radiated by a thin layer (approx. 20 km) at the bottom of the flare kernel. The upward rising and outward streaming gas cools down by conduction in about 45 s. The non-thermal effects in the initial phase are due to curtailing of the energy distribution function by escape of energetic electrons. The single flux tube model of a flare does not fit with these observations; instead we propose the spaghetti-bundle model. Microwave and gamma-ray observations suggest the occurrence of dense flare knots of approx. 800 km diameter, and of high temperature. Future observations should concentrate on locating the microwave/gamma-ray sources, and on determining the kernel's fine structure and the related multi-loop structure of the flaring area.

Dejager, C.↗