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The Star Formation History of Orion and its Environs

During the period of performance, we have obtained the following observations and carried out the analysis of the Orion associations itemized below. Optical Photometry: The Quest camera that had been damaged by lightning on Sept. 2001 was reconfigured to use 10 chips and only 3 filters instead of the original 4 but retaining its spatial coverage of 2.3deg wide in declination. During the Winter and Fall 2002 observing campaigns, we obtained multifilter photometry using the Quest camera on the 1mt Schmidt of the Venezuelan National Observatory, to continue the survey of the Orion clouds. In the Winter 2002 season, we obtained photometry for 10 scans at DEC=+5, 7 scans at DEC=-5. Several additional scans at DEC=-3 were obtained during the Fall 2002 observing campaign. Slit spectroscopy of bright candidates: During 2002 spectra for some 235 candidate PMS stars were obtained with the FAST spectrograph at the SAO 1.5m telescope in Mt. Hopkins. These objects, all brighter than V=16, are located in two strips centered at DEC=+l and -5, and spanning from RA=5h-6h. The spectra are being analyzed. Multifiber spectroscopy: Spectroscopy for our fainter (V less than or equal to 16) candidates has not kept pace with our spectroscopy of brighter candidates, because of the delay in the commissioning of the Hectospec and Hectoechelle multi-object spectrographs at the new 6.5m MMT. We obtained some data with the Hydra spectrograph on the WIYN telescope: Feb 1-4, 2002. Time granted to the project: "A Large Scale Survey of the Low-Mass Young Population in the Orion OB1 Association" (P.I.: C. Briceno). Three half-nights (we used the first half of the night, the second half of the night was used with the Mini-Mosaic imager by another team). Only the first half night was clear. We observed 3 fields centered in a 2.3 deg wide strip centered at DEC=-1 and spanning RA=Sh to 6h. A total of 250 spectra were obtained for the same number of candidate PMS stars. Nov. 13-15, 2002. Time granted to the project "Cluster survey of protoplanetary disk evolution", (P.I.: A. Sicilia-Aguilar). Clear weather throughout. We obtained spectra for some 200 candidate PMS stars in 3 fields located in a 2.3 deg wide strip centered at DEC=+l and spanning from RA=5h20m to 5h35m. Data for both observing runs is partially reduced and is being analyzed. U photometry: During Nov.29-Dec.4, 2002 we were granted time with the 4-shooter CCD Mosaic Camera at the SAO 1.2m telescope, to obtain U-band photometry of a subset of the newly identified T Tauri stars in the strip centered at DEC=-1. This sample is composed of strong H(alpha) emitting PMS stars (Classical T Tauri stars) located mostly in the Orion OB lb association, around the Orion Belt area. Our data will be combined with our calibration of the U-band excess (Gullbring et al. 1998) to derive mass accretion rates. Because of bad weather we observed only 20 stars during 1.5 clear nights. Near IR photometry: During Dec. 14-19, 2002 we used the IR Camera on the SAO 1.2m telescope, to obtain L-band photometry of a set of 17 the newly identified Orion OB 1a and 1b stars, in order to look for IR excess emission coming from the hotter inner parts of circumstellar disks. Again, mediocre weather prevented a larger set to be observed. These stars were also observed with the OSCIR mid-IR camera on Gemini North during later 2001. Our goal is to construct SEDs from the visual out to the mid-IR (by combining our optical/IR data with 2MASS JHK magnitudes) in order to explore disk dissipation at the critical ages of 5-10 Myr spanned by these stars.

Calvet, Nuria↗

Preliminary science report on the directional solidification of hypereutectic cast iron during KC-135 low-G maneuvers

An ADSS-P directional solidification furnace was reconfigured for operation on the KC-135 low-g aircraft. The system offers many advantages over quench ingot methods for study of the effects of sedimentation and convection on alloy formation. The directional sodification furnace system was first flown during the September 1982 series of flights. The microstructure of the hypereutectic cast iron sample solidified on one of these flights suggests a low-g effect on graphite morphology. Further experiments are needed to ascertain that this effect is due to low-gravity and to deduce which of the possible mechanisms is responsible for it.

Curreri, P. A.↗

Control of the Folding Dynamics of Self-Reconfiguring Magnetic Microbots Using Liquid Crystallinity

Reconfigurable microdevices are being explored in a range of contexts where their life-like abilities to move and change shape are important. While much work has been done to control the motion of these microdevices by engineering their geometry and composition, little is known about their dynamics in complex fluid environments with non-Newtonian rheology. Here in this paper, it is shown how the actuation dynamics of reconfigurable microdevices made by assembly of patchy magnetic microcubes, which are referred to as “microbots,” can be modulated by their interactions with the anisotropic viscoelastic environment of a liquid crystal (LC). The free energy arising from the elastic strain of LC and formation of topological defects around the microbots influences their folding dynamics, which can be tuned by tailoring both the far-field orientation of the LC and the local ordering of the LC at the microbot surfaces. These findings represent a first step toward establishing a general set of design rules to control the dynamics of microbots using complex anisotropic fluids.

36 MATERIALS SCIENCE↗

Mechanisms enabling reconfigurability and long-term retention in vanadium oxide electrochemical memory

Phase coexistence in nanoscale electrochemical random-access memory (ECRAM) has recently been demonstrated to enable both information storage and extraordinary reconfigurability. These proof-of-principle demonstrations have left the mechanistic details of such a process unresolved. Particularly, the mechanisms that stabilize the multiple phases, and the underlying processes behind sustained memory retention, remain unclear, and are necessary to design such devices. Here we report microscale ECRAM devices composed of V⁢O𝑥, which enables us to directly probe the active region in an operando fashion using optical techniques. Using Raman mapping, we show the phase coexistence driven by the electrochemical injection of O vacancies to be spatially uniform (i.e., with no filaments). The stability was observed to be unusually long, with 1% loss over 14 years in ambient conditions. First-principles calculations of the oxygen vacancy formation energies in V⁢O 𝑥 further support the thermodynamic coexistence of multiple V⁢O 𝑥 phases and clarify the origin of the observed long-term retention in the ECRAM devices. Further, we demonstrate single devices that can be voltage programmed to exhibit synaptic, neuronal, and reconfigurable logic gate functionalities. Furthermore, we not only uncover the phase coexistence mechanism that may help device design, but also demonstrate the circuit-level applications of reconfigurability.

Electrical conductivity↗

Auroral ovals versus flare ribbons: Optical footprints of explosive magnetic field reconfiguration in Earth’s magnetosphere and the Sun’s corona

Despite drastically different plasma conditions in the two systems, eruptive energy release events in solar active regions and in Earth’s magnetosphere have a lot in common. Both solar active region eruptions and the substorm activity in the nightside magnetosphere are known to be associated with an abrupt large-scale reorganization of the supporting magnetic systems enabling the conversion and dissipation of the stored free magnetic energy. The rate of energy accumulation in either system tends to be by orders of magnitude slower than the energy release rate, leading to the formation of an impulsive loading-unloading cycle involving a relatively long pre-reconnection phase (substorm growth phase, pre-flare stressing of an active region magnetic field), a short and explosive reconnection phase (substorm breakup and expansion, eruptive flares and CMEs), and a prolonged post-reconnection phase (substorm recovery phase and the post-flare active region reconfiguration). In Earth’s magnetosphere, this loading-unloading cycle is diagnosed by monitoring characteristic changes in the particle precipitation pattern in the northern and southern auroral ovals marking the boundary between the open and close magnetic flux. The position, shape, structure, and dynamics of the auroral borealis were shown to communicate critically important information about an upcoming substorm, the location and timing of the initial reconnection onset, and the subsequent return of the magnetosphere to a lower-energy state. On the Sun, a similar role is played by the chromospheric flare ribbons which enable a detailed diagnostics of the overlying reconnecting magnetic field. In this talk, we’ll discuss similarities and differences in using auroral and flare ribbon observations for monitoring eruptive energy release in respectively Earth’s magnetosphere and solar corona. Special emphasis will be placed on the quantitative interpretation of the two types of optical signatures for empirical diagnostics of the underlying reconnection activity and for constraining its theoretical models. We’ll also compare forecasting capabilities of the two types of optical signatures in the context of space weather prediction objectives.

V. M. Uritskiy↗

Cleft contribution to ring current formation

The storm time transport of ionospheric plasma from the 'cleft fountain' to the plasma sheet and ring current is investigated by means of three-dimensional trajectory codes. Using observations to define the source location and flow rate, test particles are traced during a 'taillike' to 'dipolelike' reconfiguration of the geomagnetic field. Emphasis is placed on the behavior of heavy ions of low charge state, O(+). As a result of their long periods of gyration, these ions are highly sensitive to rapid field variations and possibly display transient nonadiabatic motions. It is demonstrated that O(+) which have originated in the high-latitude ionosphere but which find themselves in the vicinity of the equator at substorm onset can experience considerable energization (from several keV up to several hundred keV) and pitch angle increase leading to trapping, as an effect of the induced electric field.

Delcourt, D. C.↗

FEBIP for functional nanolithography of 2D nanomaterials

Lithographic patterning on emerging nanomaterials is one of essential ingredients for the development of new functional nanomaterial and device systems. Focused electron beam induced processing (FEBIP) in combination with an on-demand reconfigurable precursor injection system enables the highest resolution and controllability of nanolithography on two-dimensional (2D) nanomaterials. FEBIP allows for localized atomic-to-nanoscale engineering of nanomaterials and devices in a multi-mode format including geometrical patterning, functionalization/defect formation/doping, metal/metal oxide deposition, interface fusion and activation, active channel cleaning. This chapter discusses the scientific bases and showcases the state-of-the-art FEBIP technologies with a specific focus on functional lithography of 2D nanomaterials and provides future prospects of FEBIP technologies to address real industrial needs for the development of high-performance, next-generation functional devices.

2D materials, nanolithography, focused electron be↗

Secure, Mobile, Wireless Network Technology Designed, Developed, and Demonstrated

The inability to seamlessly disseminate data securely over a high-integrity, wireless broadband network has been identified as a primary technical barrier to providing an order-of-magnitude increase in aviation capacity and safety. Secure, autonomous communications to and from aircraft will enable advanced, automated, data-intensive air traffic management concepts, increase National Air Space (NAS) capacity, and potentially reduce the overall cost of air travel operations. For the first time ever, secure, mobile, network technology was designed, developed, and demonstrated with state-ofthe- art protocols and applications by a diverse, cooperative Government-industry team led by the NASA Glenn Research Center. This revolutionary technology solution will make fundamentally new airplane system capabilities possible by enabling secure, seamless network connections from platforms in motion (e.g., cars, ships, aircraft, and satellites) to existing terrestrial systems without the need for manual reconfiguration. Called Mobile Router, the new technology autonomously connects and configures networks as they traverse from one operating theater to another. The Mobile Router demonstration aboard the Neah Bay, a U.S. Coast Guard vessel stationed in Cleveland, Ohio, accomplished secure, seamless interoperability of mobile network systems across multiple domains without manual system reconfiguration. The Neah Bay was chosen because of its low cost and communications mission similarity to low-Earth-orbiting satellite platforms. This technology was successfully advanced from technology readiness level (TRL) 2 (concept and/or application formation) to TRL 6 (system model or prototype demonstration in a relevant environment). The secure, seamless interoperability offered by the Mobile Router and encryption device will enable several new, vehicle-specific and systemwide technologies to perform such things as remote, autonomous aircraft performance monitoring and early detection and mitigation of potential equipment malfunctions. As an additional benefit, team advancements were incorporated into open standards, ensuring technology transfer. Low-cost, commercial products incorporating the new technology are already available. Furthermore, these products are fully interoperable with legacy network technology equipment currently being used throughout the world.

Ivancic, William D.↗

Thermally reconfigurable monoclinic nematic colloidal fluids

Fundamental relationships are believed to exist between the symmetries of building blocks and the condensed matter phases that they form. For example, constituent molecular and colloidal rods and disks impart their uniaxial symmetry onto nematic liquid crystals, such as those used in displays. Low-symmetry organizations could form in mixtures of rods and disks, but entropy tends to phase-separate them at the molecular and colloidal scales, whereas strong elasticity-mediated interactions drive the formation of chains and crystals in nematic colloids. To have a structure with few or no symmetry operations apart from trivial ones has so far been demonstrated to be a property of solids alone, but not of their fully fluid condensed matter counterparts, even though such symmetries have been considered theoretically and observed in magnetic colloids. In this work, we show that dispersing highly anisotropic charged colloidal disks in a nematic host composed of molecular rods provides a platform for observing many low-symmetry phases. Depending on the temperature, concentration and surface charge of the disks, we find nematic, smectic and columnar organizations with symmetries ranging from uniaxial to orthorhombic and monoclinic. With increasing temperature, we observe unusual transitions from less- to more-ordered states and re-entrant phases. Most importantly, we demonstrate the presence of reconfigurable monoclinic colloidal nematic order, as well as the possibility of thermal and magnetic control of low-symmetry self-assembly. Our experimental findings are supported by theoretical modelling of the colloidal interactions between disks in the nematic host and may provide a route towards realizing many low-symmetry condensed matter phases in systems with building blocks of dissimilar shapes and sizes, as well as their technological applications.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Fractional Skyrmion Tubes in Chiral‐Interfaced 3D Magnetic Nanowires

Magnetic skyrmions are chiral spin textures with rich physics and great potential for unconventional computing. Typically, skyrmions form in bulk crystals with reduced symmetry or ultrathin film multilayers involving heavy metals. Here, the formation of fractional Bloch skyrmion tubes at room temperature is demonstrated by 3D printing ferromagnetic double‐helix nanowires with two regions of opposite chirality. Using X‐ray microscopy and micromagnetic simulations, it is shown that the coexistence of vortex and anti‐parallel spin states induces the formation of fractional skyrmion tubes at zero magnetic fields, minimizing the energy cost of breaking the coupling between geometric and magnetic chirality. Control over zero‐field states is also demonstrated, including pure vortex, or mixed skyrmion‐vortex states, highlighting the magnetic reconfigurability of these 3D nanowires. This work shows how interfacing chiral geometries at the nanoscale can enable advanced forms of topological spintronics.

X-ray microscopy↗

System status display evaluation

The System Status Display is an electronic display system which provides the crew with an enhanced capability for monitoring and managing the aircraft systems. A flight simulation in a fixed base cockpit simulator was used to evaluate alternative design concepts for this display system. The alternative concepts included pictorial versus alphanumeric text formats, multifunction versus dedicated controls, and integration of the procedures with the system status information versus paper checklists. Twelve pilots manually flew approach patterns with the different concepts. System malfunctions occurred which required the pilots to respond to the alert by reconfiguring the system. The pictorial display, the multifunction control interfaces collocated with the system display, and the procedures integrated with the status information all had shorter event processing times and lower subjective workloads.

Summers, Leland G.↗

A Self-Healing, Flowable, Yet Solid Electrolyte Suppresses Li-Metal Morphological Instabilities

In this article, lithium metal (Li 0 ) solid-state batteries encounter implementation challenges due to dendrite formation, side reactions, and movement of the electrode–electrolyte interface in cycling. Notably, voids and cracks formed during battery fabrication/operation are hot spots for failure. Here, a self-healing, flowable yet solid electrolyte composed of mobile ceramic crystals embedded in a reconfigurable polymer network is reported. This electrolyte can auto-repair voids and cracks through a two-step self-healing process that occurs at a fast rate of 5.6 µm h -1 . A dynamical phase diagram is generated, showing the material can switch between liquid and solid forms in response to external strain rates. The flowability of the electrolyte allows it to accommodate the electrode volume change during Li 0 stripping. Simultaneously, the electrolyte maintains a solid form with high tensile strength (0.28 MPa), facilitating the regulation of mossy Li 0 deposition. The chemistries and kinetics are studied by operando synchrotron X-ray and in situ transmission electron microscopy (TEM). Solid-state NMR reveals a dual-phase ion conduction pathway and rapid Li + diffusion through the stable polymer-ceramic interphase. This designed electrolyte exhibits extended cycling life in Li 0 –Li 0 cells, reaching 12 000 h at 0.2 mA cm -2 and 5000 h at 0.5 mA cm -2 . Furthermore, owing to its high critical current density of 9 mA cm -2 , the Li 0 –LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) full cell demonstrates stable cycling at 5 mA cm -2 for 1100 cycles, retaining 88% of its capacity, even under near-zero stack pressure conditions.

25 ENERGY STORAGE↗

Multiple Functional Bonds Integrated Interphases for Long Cycle Sodium-Ion Batteries

Sodium-ion batteries (SIBs) have garnered significant interest as one of the most promising energy suppliers for power grid energy storage. However, the poor electrode/electrolyte interfacial stability leads to continual electrolyte decomposition and transition metal dissolution, resulting in rapid performance degradation of SIBs. In this work, we propose a strategy integrating multiple functional bonds to regulate electrode/electrolyte interphase by triple-coupling of succinonitrile (SN), sodium hexafluorophosphate (NaPF 6 ) and fluorinated ethylene carbonate (FEC). Theoretical calculation and experiment results show that the solvation structure of Na + and ClO 4 – is effectively reconfigured by the solvated FEC, SN and PF 6 – in PC-based carbonate electrolyte. The newly developed electrolyte demonstrates increased Na + -FEC coordination, weakened interaction of Na + -PC and participation of SN and PF 6 – anions in solvation, resulting in the formation of a conformal interfacial layer comprising of sodium oxynitrides (NaN x O y ), sodium fluoride (NaF) and phosphorus oxide compounds (NaP x O y ). Consequently, a 3 Ah pouch full cell of hard carbon//NaNi 1/3 Fe 1/3 Mn 1/3 O 2 exhibits an excellent capacity retention of 90.4 % after 1000 cycles. Detailed postmortem analysis of interface chemistry is further illustrated by multiple characterization methods. Finally, this study provides a new avenue for developing electrolyte formulations with multiple functional bonds integrated interphases to significantly improve the long-term cycling stability of SIBs.

25 ENERGY STORAGE↗

Oxide nucleation via threshold-driven volume instability in Ni oxidation

Oxide nucleation dictates the onset of metal oxidation, yet the atomistic pathways bridging initial oxygen adsorption to bulk phase transformation remain elusive. Here, we utilize in-situ atomic-resolution imaging to directly capture the nucleation of nickel oxide, revealing a threshold-driven, cooperative transformation of Ni into NiO. Our observations identify a distinct incubation period during which oxygen progressively accumulates in subsurface layers. Once a critical concentration and penetration depth are reached, a collective lattice reconfiguration is triggered, abruptly converting multiple Ni layers into NiO. Atomistic simulations corroborate this mechanism, identifying a cooperative lattice instability induced by subsurface oxygen saturation. These results establish subsurface oxygen incorporation as the missing mechanistic link between surface adsorption and three-dimensional oxide formation, providing an atomistic framework to understand and control reactive phase transformations in materials synthesis, catalysis, and degradation.

36 MATERIALS SCIENCE↗

Dynamic Interfacial Design in Adaptive Hybrid Materials Enables Reversible and Tunable Mechano-Optic Smart Responses

Next-generation polymeric materials are shifting toward adaptive and interactive behaviors of living systems; however, designing materials that can reversibly modulate optical properties under mechanical deformation while maintaining mechanical robustness remains a key challenge. Here, we report a mechanically robust vitrimer-based adaptive hybrid material (AHM) that exhibits a stretch-induced reversible transparency-to-opacity transition, enabled by the integration of dynamic interactions at the polymer–silica nanoparticle interface and controlled nanoparticle self-assembly. The AHM combines boronic ester–functionalized polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene (S-Bpin) with diol-functionalized silica nanoparticles (diol-SiNPs) to form a hybrid network hosting both dynamic boronic ester and hydrogen-bonding interactions. These reversible linkages facilitate controlled nanoparticle self-assembly and enable strain-induced nanoparticle alignment/aggregation. Upon stretching, SiNP-rich domains align and aggregate within the polymer matrix, while local modulus mismatch between stiff aggregated SiNP/borylated-styrene-rich regions and the softer elastomeric midblock induces surface microwrinkle formation. These internal aggregates and surface wrinkles cooperatively enhance light scattering, producing the opaque state under strain. Furthermore, the tailored AHM exhibits high toughness, thermomechanical stability, reprocessability, and programmable shape-memory behavior. This work presents a dynamic interfacial design strategy for mechanically robust, optically reconfigurable, and reusable soft materials for adaptive optics, smart windows, sensing, soft robotics, and circular smart-material platforms.

adaptive hybrid materials↗

NEEDS - Information Adaptive System

The Information Adaptive System (IAS) is an element of the NASA End-to-End Data System (NEEDS) Phase II and is focused toward onboard image processing. The IAS is a data preprocessing system which is closely coupled to the sensor system. Some of the functions planned for the IAS include sensor response nonuniformity correction, geometric correction, data set selection, data formatting, packetization, and adaptive system control. The inclusion of these sensor data preprocessing functions onboard the spacecraft will significantly improve the extraction of information from the sensor data in a timely and cost effective manner, and provide the opportunity to design sensor systems which can be reconfigured in near real-time for optimum performance. The purpose of this paper is to present the preliminary design of the IAS and the plans for its development.

Kelly, W. L.↗

NASA End-to-End Data System /NEEDS/ information adaptive system - Performing image processing onboard the spacecraft

The Information Adaptive System (IAS) is an element of the NASA End-to-End Data System (NEEDS) Phase II and is focused toward onbaord image processing. Since the IAS is a data preprocessing system which is closely coupled to the sensor system, it serves as a first step in providing a 'Smart' imaging sensor. Some of the functions planned for the IAS include sensor response nonuniformity correction, geometric correction, data set selection, data formatting, packetization, and adaptive system control. The inclusion of these sensor data preprocessing functions onboard the spacecraft will significantly improve the extraction of information from the sensor data in a timely and cost effective manner and provide the opportunity to design sensor systems which can be reconfigured in near real time for optimum performance. The purpose of this paper is to present the preliminary design of the IAS and the plans for its development.

Kelly, W. L.↗