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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Integrated Energy System Investigation for the Eastman Chemical Company, Kingsport, Tennessee Facility

The industrial manufacturing industry is looking to implement new methods of energy production to ensure a consistent energy supply while reducing economic costs and environmental impacts. Much of the manufacturing industry relies on fossil fuels—primarily coal and natural gas—of which there are finite resources subject to price volatility due to an inelastic demand. These resources also come with significant negative environmental impacts related to emissions. While complete independence from fossil fuels is not immediately realistic, options are available to significantly reduce dependency on fossil fuel supplies, including integrated energy systems (IESs) which tightly couple nuclear energy source generators with energy consumers (i.e., industrial factories) to fulfill power and energy requirements. Once realized, optimized IESs may yield significant economic and environmental benefits over traditionally isolated generator and consumer facilities. This report presents a feasibility study for siting an IES to meet the steam and electricity needs of Eastman Chemical Company’s facility in Kingsport, Tennessee. This study explored reactor technology options, evaluation, and optimization, with a focus on meeting the facility’s operational and reliability requirements. This work is part of an ongoing effort by Eastman to be good environmental stewards and meet the demands of their customers by shifting to more environmentally sustainable solutions for their energy needs. Outcomes of this report are also of general interest and value to any design or development team seeking to deploy an IES, as many topics described herein are generally applicable to any nuclear power facility.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Heat pipes to reduce engine exhaust emissions

A fuel combustor is presented that consists of an elongated casing with an air inlet conduit portion at one end, and having an opposite exit end. An elongated heat pipe is mounted longitudinally in the casing and is offset from and extends alongside the combustion space. The heat pipe is in heat transmitting relationship with the air intake conduit for heating incoming air. A guide conduit structure is provided for conveying the heated air from the intake conduit into the combustion space. A fuel discharge nozzle is provided to inject fuel into the combustion space. A fuel conduit from a fuel supply source has a portion engaged in heat transfer relationship of the heat pipe for preheating the fuel. The downstream end of the heat pipe is in heat transfer relationship with the casing and is located adjacent to the downstream end of the combustion space. The offset position of the heat pipe relative to the combustion space minimizes the quenching effect of the heat pipe on the gaseous products of combustion, as well as reducing coking of the fuel on the heat pipe, thereby improving the efficiency of the combustor.

Schultz, D. F.↗

The Measurement of Fuel-Air Ratio by Analysis for the Oxidized Exhaust Gas

An investigation was made to determine a method of measuring fuel-air ratio that could be used for test purposes in flight and for checking conventional equipment in the laboratory. Two single-cylinder test engines equipped with typical commercial engine cylinders were used. The fuel-air ratio of the mixture delivered to the engines was determined by direct measurement of the quantity of air and of fuel supplied and also by analysis of the oxidized exhaust gas and of the normal exhaust gas. Five fuels were used: gasoline that complied with Army-Navy fuel Specification No. AN-VV-F-781 and four mixtures of this gasoline with toluene, benzene, and xylene. The method of determining the fuel-air ratio described in this report involves the measurement of the carbon-dioxide content of the oxidized exhaust gas and the use of graphs for the presented equation. This method is considered useful in aircraft, in the field, or in the laboratory for a range of fuel-air ratios from 0.047 to 0.124.

Gerrish, Harold C.↗

The Measurement of Fuel-air Ratio by Analysis of the Oxidized Exhaust Gas

An investigation was made to determine a method of measuring fuel-air ratio that could be used for test purposes in flight and for checking conventional equipment in the laboratory. Two single-cylinder test engines equipped with typical commercial engine cylinders were used. The fuel-air ratio of the mixture delivered to the engines was determined by direct measurement of the quantity of air and of fuel supplied and also by analysis of the oxidized exhaust gas and of the normal exhaust gas. Five fuels were used: gasoline that complied with Army-Navy Fuel Specification, No. AN-VV-F-781 and four mixtures of this gasoline with toluene, benzene, and xylene. The method of determining the fuel-air ratio described in this report involves the measurement of the carbon-dioxide content of the oxidized exhaust gas and the use of graphs or the presented equation. This method is considered useful in aircraft, in the field, or in the laboratory for a range of fuel-air ratios from 0.047 to 0.124

FUELS-TOLUENE↗

Fuel Cell Power Plant Initiative: Solid Oxide Fuel Cell/Logistics Fuel Processor 27 kWe Power System Demonstration for ARPA - Volume 1

This report describes the successful testing of a 27 kWe Solid Oxide Fuel Cell (SOFC) generator fueled by natural gas and/or a fuel gas produced by a brassboard logistics fuel preprocessor (LFP). The test period began on May 24, 1995 and ended on February 26, 1996 with the successful completion of all program requirements and objectives. During this time period, this power system produced 118.2 MWh of electric power. No degradation of the generator's performance was measured after 5582 accumulated hours of operation on these fuels: local natural gas - 3261 hours, jet fuel reformate gas - 766 hours, and diesel fuel reformate gas - 1555 hours. This SOFC generator was thermally cycled from full operating temperature to room temperature and back to operating temperature six times, because of failures of support system components and the occasional loss of test site power, without measurable cell degradation. Numerous outages of the LFP did not interrupt the generator's operation because the fuel control system quickly switched to local natural gas when an alarm indicated that the LFP reformate fuel supply had been interrupted. The report presents the measured electrical performance of the generator on all three fuel types and notes the small differences due to fuel type. Operational difficulties due to component failures are well documented even though they did not affect the overall excellent performance of this SOFC power generator. The final two appendices describe in detail the LFP design and the operating history of the tested brassboard LFP.

Veyo, S.E.↗

Air terminals and liquid hydrogen commercial air transports

An initial appraisal is made of results of two studies of the ground requirements of liquid hydrogen (LH2) air transports. Each hypothesized the use of a 400-passenger 5500 nautical mile range subsonic commercial LH2 transport. Two of the world's busiest commercial airports, Chicago O'Hare International and San Francisco International, were selected for study. The current and predicted wide-body traffic at these airports was assumed to simulate the LH2 transport traffic at these airports in the 1990-1995 time period. Both studies produced conceptual designs for facilities to generate the required quantities of fuel from pipeline gaseous hydrogen and to deliver liquid hydrogen to the airplanes. Although the LH2 and jet fuel facilities were kept apart, both study teams found it practical to converge the fuel supply lines so that with proper safety and operational procedures and specialized LH2 equipment both LH2 and jet fuel transports can use common ramp and gate facilities.

Korycinski, P. F.↗

RTF Analysis-Propulsion/Flowliner

The objective of the current task is to provide a computational framework for design and analysis of the entire fuel supply system of a liquid rocket engine, including high fidelity unsteady turbopump flow analysis. Time-accurate results obtained from shuttle fuel flowliner analysis using 66 Million grid points with 262 overlapped zones will be shown. We will present analysis results along with performance data of the simulation runs on Supercomputers such as Columbia.

Kiris, Centin↗

Propellant Mass Gauging in a Spherical Tank under Micro-Gravity Conditions Using Capacitance Plate Arrays and Machine Learning

Propellant mass gauging under micro-gravity conditions is a challenging task due to the unpredictable position and shape of the fuel body inside the tank. Micro-gravity conditions are common for orbiting satellites and rockets that operate on limited fuel supplies. Capacitance sensors have been investigated for this task in recent years; however, the effect of various positions and shapes of the fuel body is not analyzed in detail. In this paper, we investigate this with various fill types, such as annular, core-annular, and stratified fills at different positions. We compare the performance among several curve-fitting-based approaches and a machine-learning-based approach, the latter of which offers superior performance in estimating the fuel content.

47 OTHER INSTRUMENTATION↗

Fundamental phenomena on fuel decomposition and boundary layer combustion processes with applications to hybrid rocket motors

An experimental study on the fundamental processes involved in fuel decomposition and boundary layer combustion in hybrid rocket motors is being conducted at the High Pressure Combustion Laboratory of the Pennsylvania State University. This research should provide an engineering technology base for development of large scale hybrid rocket motors as well as a fundamental understanding of the complex processes involved in hybrid propulsion. A high pressure slab motor has been designed for conducting experimental investigations. Oxidizer (LOX or GOX) is injected through the head-end over a solid fuel (HTPB) surface. Experiments using fuels supplied by NASA designated industrial companies will also be conducted. The study focuses on the following areas: measurement and observation of solid fuel burning with LOX or GOX, correlation of solid fuel regression rate with operating conditions, measurement of flame temperature and radical species concentrations, determination of the solid fuel subsurface temperature profile, and utilization of experimental data for validation of a companion theoretical study also being conducted at PSU.

Kuo, Kenneth K.↗

Coupling of the Electricity and Transportation Sectors - Part II: Risk Assessment

This comprehensive report explores the intricate interplay through “sector coupling” between the Transportation Sector, Energy Sector, and the critical infrastructure challenges faced by the United States. Aligned with the ambitious federal goal of reducing greenhouse gas emissions, the report analyzes the present vulnerabilities in the fossil fuel supply chain, highlighting instances where the dependence on this industry has been susceptible to local and global disruptions. With a focus on risk assessment, this report establishes a framework to compare the fossil fuel-based transportation sector with the burgeoning electrified sector, considering the evolving technologies in electric vehicles (EVs) and the nascent charging infrastructure. This study delves into the historical reliability of fossil fuel-based transportation and identifies opportunities for strengthening sector coupling between transportation and the electric sector. Assessments of the gasoline-diesel supply chain provide insights into both opportunities and threats, offering a roadmap for creating a more reliable and resilient electrified transportation system. We modeled sectoral coupling scenarios for the current internal combustion engine (ICE)-based and future EV-dominant landscapes, leveraging qualitative sector attributes to identify relative strengths and weaknesses in Part 1 of the report. In this report (Part 2) we continue to understand the role of the electricity sector on transportation and develop a semi-quantitative methodology is employed to evaluate and compare the risks associated with the fossil fueled and electric transportation sector during emergency scenarios, drawing from real-world events like hurricanes and geopolitical disruptions. Different operational scenarios for the fossil fuel and electrified sectors have been developed to understand the risks associated with them. This report concludes with recommendations for the architectural designs of electric charging infrastructure, underlining the need for informed decisions in the transition towards a sustainable and resilient transportation future.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Isotope Production for UK PhD Student Visit [Slides]

Overview of INL isotope production work, including organizational structures, the current work and future plans of plutonium fuel supplies, cobalt-60 production, and BRR cask shipping.

07 ISOTOPE AND RADIATION SOURCES↗

An Experimental and Theoretical Study of Radiative Extinction of Diffusion Flames

The objective of this research was to experimentally and theoretically investigate the radiation-induced extinction of gaseous diffusion flames in microgravity. The microgravity conditions were required because radiation-induced extinction is generally not possible in 1-g but is highly likely in microgravity. In 1-g, the flame-generated particulates (e.g. soot) and gaseous combustion products that are responsible for flame radiation, are swept away from the high temperature reaction zone by the buoyancy-induced flow and a steady state is developed. In microgravity, however, the absence of buoyancy-induced flow which transports the fuel and the oxidizer to the combustion zone and removes the hot combustion products from it enhances the flame radiation due to: (1) transient build-up of the combustion products in the flame zone which increases the gas radiation, and (2) longer residence time makes conditions appropriate for substantial amounts of soot to form which is usually responsible for most of the radiative heat loss. Numerical calculations conducted during the course of this work show that even non-radiative flames continue to become "weaker" (diminished burning rate per unit flame area) due to reduced rates of convective and diffusive transport. Thus, it was anticipated that radiative heat loss may eventually extinguish the already "weak" microgravity diffusion flame. While this hypothesis appears convincing and our numerical calculations support it, experiments for a long enough microgravity time could not be conducted during the course of this research to provide an experimental proof. Space shuttle experiments on candle flames show that in an infinite ambient atmosphere, the hemispherical candle flame in microgravity will burn indefinitely. It was hoped that radiative extinction can be experimentally shown by the aerodynamically stabilized gaseous diffusion flames where the fuel supply rate was externally controlled. While substantial progress toward this goal was made during this project, identifying the experimental conditions for which radiative extinction occurs for various fuels requires further study. Details concerning this research which are discussed in published articles are included in the appendices.

Atreya, Arvind↗

Spherical Diffusion Flames: Structure and Dynamics

The spherical geometry is the most suitable one to study fundamental issues concerning the structure and the dynamics of diffusion flames. From a theoretical point of view, it is the only geometry that permits the existence of a truly one dimensional stationary diffusion flame. A stationary planar diffusion flame with the fuel supplied upstream, at x approaches -infinity say, and the oxidant downstream, at x approaches +infinity is not possible. For a steady diffusion flame to exist, one must have nonzero fluxes of fuel and oxidant towards the flame. However, in the unlimited region behind the planar flame the only bounded solutions to the reaction-free convective-diffusive operator are constants. Hence the oxidant concentration behind the flame remains constant and there is no mechanism to generate the necessary flux towards the flame. A one-dimensional problem can be formulated if the reactants are supplied at finite locations; but the boundary conditions in this case introduce unnecessary complications and do not appropriately model the physical reality. Indeed, a planar diffusion flame can be established in the stagnation-point flow of two opposed jets but the flame in this case is stretched and the flow is essentially two-dimensional. The only stationary one-dimensional diffusion flame in an unlimited environment is therefore the spherical flame.

Matalon, Moshe↗

Transient mixing behavior of a supercritical fluid injected into supercritical and subcritical environments

Transient, near-field mixing of a supercritical fluid injected into supercritical and subcritical environments is investigated experimentally. Fuel (propane) from a 100 μm diameter Bosch diesel injector is injected into a high-pressure test rig with a steady flow of heated, low-velocity nitrogen to control the ambient pressure and temperature. The fuel supply pressure is approximately 190 bar, allowing short injections lasting 3–4 ms to be performed in quick succession to acquire statistically significant datasets to represent the unsteady fuel–air mixing. Two test cases with the same ambient density and injector inlet pressure and temperature were chosen in an attempt to isolate effects of mixture phase behavior. Microscopic rainbow Schlieren deflectometry (RSD) is used for visualization and quantitative data acquisition. In the case of the supercritical ambient, the injector inlet and exit and ambient conditions are all supercritical. The RSD analysis reveals a mixing process similar to the single phase fluid mixing, though condensation is also observed locally, and can be explained by the adiabatic mixing theory presented in the paper. For the subcritical ambient case, the injector inlet is supercritical, but the injector exit and ambient conditions are both subcritical. The results show a rapid expansion in the near-field promoting mixing between propane and nitrogen. At downstream locations, significant condensation is also observed as predicted by the adiabatic mixing theory. As a result, the supercritical ambient case exhibited longer and narrower jet penetration compared to the subcritical ambient case.

02 PETROLEUM↗

Fuel injector including a lobed mixer and vanes for injecting alternate fuels in a gas turbine

A fuel injector for injecting alternate fuels having a different energy density in a gas turbine is provided. A first fuel supply channel (18) may be fluidly coupled to a radial passage (22) in a plurality of vanes (20) that branches into passages (24) (e.g., axial passages) to inject a first fuel without jet in cross-flow injection. This may be effective to reduce flashback in fuels having a relatively high flame speed. A mixer (30) with lobes (32) for injection of a second fuel may be arranged at the downstream end of a fuel delivery tube (12). A fuel-routing structure (38) may be configured to route the second fuel within a respective lobe so that fuel injection of the second fuel takes place radially outwardly relative to a central region of the mixer. This may be conducive to an improved (e.g., a relatively more uniform) mixing of air and fuel.

42 ENGINEERING↗

High speed commercial transport fuels considerations and research needs

NASA is currently evaluating the potential of incorporating High Speed Civil Transport (HSCT) aircraft in the commercial fleet in the beginning of the 21st century. NASA sponsored HSCT enabling studies currently underway with airframers and engine manufacturers, are addressing a broad range of technical, environmental, economic, and related issues. Supersonic cruise speeds for these aircraft were originally focused in the Mach 2 to 5 range. At these flight speeds, both jet fuels and liquid methane were considered potential fuel candidates. For the year 2000 to 2010, cruise Mach numbers of 2 to 3+ are projected for aircraft fuel with thermally stable liquid jet fuels. For 2015 and beyond, liquid methane fueled aircraft cruising at Mach numbers of 4+ may be viable candidates. Operation at supersonic speeds will be much more severe than those encountered at subsonic flight. One of the most critical problems is the potential deterioration of the fuel due to the high temperature environment. HSCT fuels will not only be required to provide the energy necessary for flight, but will also be subject to aerodynamic heating and, will be required to serve as the primary heat sink for cooling the engine and airframe. To define fuel problems for high speed flight, a fuels workshop was conducted at NASA Lewis Research Center. The purpose of the workshop was to gather experts on aviation fuels, airframe fuel systems, airport infrastructure, and combustion systems to discuss high speed fuel alternatives, fuel supply scenarios, increased thermal stability approaches and measurements, safety considerations, and to provide directional guidance for future R and D efforts. Subsequent follow-up studies defined airport infrastructure impacts of high speed fuel candidates. The results of these activities are summarized. In addition, an initial case study using modified in-house refinery simulation model Gordian code (1) is briefly discussed. This code can be used to simulate different types of refineries, emphasizing jet fuel production and relative cost factors.

Lee, C. M.↗

An Ab initio based OH initiated oxidation kinetics of glycerol carbonate: A promising biofuel component

The global energy demand is steadily increasing because of the population explosion and economic growth. Fossil fuels supply around 85 % of global primary energy demand. On one hand, fulfilling the increasing energy demands is a big challenge for the next few decades. On the other hand, the continued burning of fossil fuels leads to higher CO2 emissions, severely impacting global warming. Therefore, the policymakers vow to shift from conventional fuels to renewable resources for economic, environmental, and future energy security reasons. In this context, biofuels from lignocellulosic biomass and/or carbon-neutral fuels produced in the sustainable carbon cycle can close the carbon cycle and reach net zero-carbon emission. Recently, glycerol carbonate has been proposed as a promising fuel or fuel additive for future sustainability. Therefore, we investigated the hydrogen abstraction reactions of glycerol carbonate (GC) by OH radicals using high-level ab initio and variational transition state theory calculations. We mapped out the potential energy surface using the CCSD(T)/cc-pV(D, T)Z//MP2/cc-pVTZ level of theory. Here we used the ab initio parameters to obtain the site-specific rate coefficients by employing the variational transition state theory. We observed that every hydrogen atom in GC displays a unique reactivity with OH radicals. We derived branching ratio of each channel that are difficult to access experimentally. The overall rate coefficients exhibit a strong non-Arrhenius behaviour, which can be represented as: $k^{CVT/SCT}_{ov}$ (T) = 3.39 x 10 -20 x T 2.659 x e$\frac{-750.0 Jmol^{-1}}{RT}$ $\frac{cm^{3}}{molecule s}$ This is the first reported rate data for the glycerol carbonate and OH radicals reaction.

09 BIOMASS FUELS↗